In this thesis, the focus is on the study of new catalytic
properties of unsupported nanoporous metals in heterogeneous
organic reactions under liquid-phase conditions. The author was the
first to fabricate nanoporous copper with tunable nanoporosity and
apply it for organic reactions. The catalyst can be reused up to
ten times without loss of catalytic activity. In addition, the
author developed the highly selective semihydrogenation of alkynes
using nanoporous gold as a catalyst for the first time, affording
Z-alkenes in 100% selectivity, which cannot be realized by
traditional catalysts. All of the results described here will help
readers to develop new catalytic performance of nanoporous metals
for organic reactions.
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