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Kinetics and Equilibrium in Mineral Reactions (Paperback, 1983 ed.)
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Kinetics and Equilibrium in Mineral Reactions (Paperback, 1983 ed.)
Series: Advances in Physical Geochemistry, 3
Expected to ship within 10 - 15 working days
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The third volume in this series consists of eight chapters. The
first three deal with kinetic aspects of compositional variations
both within individual phases and across crystal boundaries.
Basically, the authors use the kinetic theory and the sparsely
available rate data to explain the formation of various types of
zoning and the exsolution processes in silicates. Loomis rightly
argues that "the kinetic inhibitions to reequilibration that
preserve primary igneous crystals and high- grade metamorphic
assemblages also affect the crystallization and prograde meta-
morphism of these rocks." These "kinetic inhibitions" appear in the
form of zoned crystals, reaction rims and disequilibrium
assemblages. Their proper recognition and quantitative
characterization leads to an understanding of the physico-chem-
ical history of the rock. On a similar theme, I examine possible
relationships between the exsolution processes in Ca-Fe-Mg
pyroxenes and the cation order-disorder on nonequiva- lent
crystallographic sites. A multi-technique study of exsolutions in
crystals employing electron microscopy and X-ray structural
refinements should contrib- ute greatly in understanding the
thermal history of the rock. Many geothermometric studies result in
discordant temperatures when the estimates are done using serveral
coexisting pairs of minerals in a single specimen. Lasaga uses the
kinetic rates of diffusion of various chemical species and explains
the discordance through his "geospeedometric" approach.
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