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Chemical Kinetics and Inorganic Reaction Mechanisms (Hardcover, 2nd ed. 2003)
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Chemical Kinetics and Inorganic Reaction Mechanisms (Hardcover, 2nd ed. 2003)
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The serious study of the reaction mechanisms of transition metal
com plexes began some five decades ago. Work was initiated in the
United States and Great Britain; the pioneers ofthat era were,
inalphabetical order, F. Basolo, R. E. Connick, 1. O. Edwards, C.
S. Garner, G. P.Haight, W. C. E. Higgision, E.1. King, R. G.
Pearson, H. Taube, M.1. Tobe, and R. G. Wilkins.A larger community
of research scientists then entered the field, many of them stu
dents ofthose just mentioned. Interest spread elsewhere as well,
principally to Asia, Canada, and Europe. Before long, the results
ofindividual studies were being consolidated into models, many of
which traced their origins to the better-established field of
mechanistic organic chemistry. For a time this sufficed, but major
revisions and new assignments of mechanism became necessary for
both ligand sub stitution and oxidation-reduction reactions.
Mechanistic inorganic chemistry thus took on a shape of its own.
This process has brought us to the present time. Interests have
expanded both to include new and more complex species (e.g.,
metalloproteins) and a wealth of new experimental techniques that
have developed mechanisms in ever-finer detail. This is the story
the author tells, and in so doing he weaves in the identities of
the investigators with the story he has to tell. This makes an
enjoyable as well as informative reading."
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