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Laser Electrochemistry of Intermediates (Hardcover)
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Laser Electrochemistry of Intermediates (Hardcover)
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Laser photoelectron emission not only allows investigation of
interfaces between electrodes and solution, but also provides a
method for fast generation of intermediate species in the vicinity
of the interface and so permits study of their electrode reactions.
Laser Electrochemistry of Intermediates presents the first-ever
comprehensive review of this important phenomenon and its
electrochemical applications.
The book explores how the innovative method of laser electron
emission from metal electrodes resolves two fundamental problems
inherent in current methods of intermediate species (IS) generation
and detection: difficulty generating IS quickly in the vicinity of
the electrode surface and low IS surface concentration. In
addition, for the first time, quasi-free and solvated electrons,
hydrogen atoms, simple organic and inorganic radicals, and ions
with anomalous valence are systematically studied.
Laser Electrochemistry of Intermediates incorporates a unique,
two-pronged analytical approach. First, the authors consider the
kinetics and thermodynamics of the processes based on the
participation of IS in its one-electron stages, thus allowing the
assignment of real physical meaning to the electrochemical
measurables. Second, they consider electrode reactions side by side
with homogeneous reactions of electron transfer, facilitating
understanding of the universal theory of electron transfer
reactions in polar media as well as the peculiarities of these
reactions occurring in the interface between electrode and
solution.
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