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Reactions in Compartmentalized Liquids - Proceedings of a Symposium held at the Zentrum fur interdisziplinare Forschung, Bielefeld/ FRG, September 11.-14, 1988 (Paperback, Softcover reprint of the original 1st ed. 1989)
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Reactions in Compartmentalized Liquids - Proceedings of a Symposium held at the Zentrum fur interdisziplinare Forschung, Bielefeld/ FRG, September 11.-14, 1988 (Paperback, Softcover reprint of the original 1st ed. 1989)
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At the annual meetings ofthe "Fast Reactions in Solution Discussion
Group" of the Royal Society of Chemistry, an increasing number of
contributions is concerned with reactions in complex liquids, where
the solvents cannot be regarded as homogeneous media but where
their microstructure has to be taken into account. In order to
summarize the different aspects of those solvents, the 1988 meeting
of the group has been held as a symposium devoted to
"Compartmentalized Liquids". The contributions concerned different
fields of science from mathematics, physics, and chemistry to food
research and pharmacy. Thus it was appropriate to organize the
meeting afthe Zentrum fUr interdiszipliniire Forschung at
Bielefeld. Envisaging compartmentalized liquids on a scale
descending size, we may order the systems described in this volume
from colloidal solutions, gels, hydro col loids, membranes,
vesicles, microemulsions, micellar solutions, macrocyclic complexes
to "cages" involved in bimolecular encounter. In recent years many
experimental and theoretical studies have been performed on those
systems, and they are also of growing interest for technical
applications. Two important reasons for the investigation of
compartmentalized liquids as reaction media are: i) they are suited
for performing reactions between water-soluble and oil-soluble
reactants, ii) they provide large internal interfaces, where
reactions may be catalyzed. Due to the large interfaces, the
diffusion of molecules is restricted, and for the theoretical
treatment of reaction rates in these systems the concept offractal
geometry seems to be appropriate. Therefore contribu tions
concerning fractals are included in this volume.
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