This book represents the proceedings of the first major international meeting dedi cated to discuss environmental aspects of produced water. The 1992 International Pro duced Water Symposium was held at the Catamaran Hotel, San Diego, California, USA, on February 4-7, 1992. The objectives of the conference were to provide a forum where scientists, regulators, industry, academia, and the enviromental community could gather to hear and discuss the latest information related to the environmental considerations of produced water discharges. It was also an objective to provide a forum for the peer review and international publication of the symposium papers so that they would have wide availability to all parties interested in produced water environmental issues. Produced water is the largest volume waste stream from oil and gas production activities. Onshore, well over 90% is reinjected to subsurface formations. Offshore, and in the coastal zone, most produced water is discharged to the ocean. Over the past several years there has been increasing concern from regulators and the environmental commu nity. There has been a quest for more information on the composition, treatment systems and chemicals, discharge characteristics, disposal options, and fate and effects of the produced water. As so often happens, much of this information exists in the forms of reports and internal research papers. This symposium and publication was intended to make this information available, both for open discussion at the conference, and for peer review before publication."

With the end of the Cold War, new opportunities for interaction have opened up between the United States and the countries of the Former Soviet Union. Many of these important initiatives involve the US Department of Energy (DOE) and the Ministry of the Russian Federation for Atomic Energy (MINA TOM). Currently, collaboration is under way which involves reactor safety, the disposition of fissile materials from the weapons program, radioactive waste disposal, and the safety of nuclear warheads. Another fruitful area of interchange resulted from the radiochemical storage tank accident at the site of the Siberian Chemical Compound at Tomsk-7 in 1993. DOE and MINATOM agreed to meet and exchange information about the accident for the purposes of improving safety. A meeting on the Tomsk tank accident was held in Hanford, Washington in 1993, followed by a second meeting in st. Petersburg, Russia in 1994 in which the agenda expanded to include radiochemical processing safety. A third exchange took place in 1995 in Los Alamos, New Mexico, and additional papers were presented on nonreactor nuclear safety. Following a planning session in 1996 in Seattle, Washington, it was decided to hold a fourth technical exchange on the broader subject of nuclear materials safety management. Through a grant from the North Atlantic Treaty Organization (NATO) Disarmament Programme, the meeting took place on March 17- 21, 1997, in Amarillo, Texas as a NATO Advanced Research Workshop (ARW) through grant no. DISRM 961315.

Co-utilization or blending of residuals offers a unique opportunity to develop products with particular characteristics that are able to target specific customer needs. The very notion of deliberately blending by-products suggests that the recycling and beneficial reuse industries are taking a quantitative step forward towards developing products rather than simply reusing residuals. At the same time that this step provides unique opportunities, it also presents unique challenges. The science associated with the beneficial use of one product may not apply when that product is mixed with another residual. Blending of materials may alter the chemistry of the components of the mixture. This may offer additional benefits, as in the case of disease suppression in composts, or present unexpected problems, as the use of lime-stabilized biosolids has done in Maryland. This book consists of the proceedings of the Beltsville Symposium. The organizers of the Symposium attempted to structure a meeting that would outline both the potential benefits of co-utilization as well as concerns. The editors have divided the proceedings into sections that describe the practical basis for co-utilization of residuals as well as the potential benefits. Specific considerations are described. Finally, case studies include descriptions of successful operations and data that detail results of research involving co-utilization materials. Blending of materials for specific objectives needs to be the focus of any successful co-utilization effort. The scientific implications of the mix need to be determined before a product can be used properly.

The surplus of plutonium in the world is both an important security issue, and a fact with implications for nuclear energy and environmental policy internationally. The two perspectives are inextricably intertwined in considering options for dealing with the plutonium surplus. It was for this reason that two research programmes at the Royal Institute of International Affairs - respectively on Energy and Environment, and on International Security - jointly approached NATO with a view to organising a work shop on the issue. It was most welcome then to learn that the NATO Science Programe was already supporting plans for a workshop on the issue, initiated by Richard Garwin, and we were pleased to accept the resulting invitation to host that workshop. DrGarwin prepared the initial agenda and established contacts and initial approaches to many of the participants; we were able to develop the agenda further and extend participation in some complementary ways. The result was a most lively and broad-ranging internation al and inter-disciplinary discussion. As the hosts, the RIIA was also given lead responsibility for producing the pro ceedings of the workshop as a publication for NATO. Many of the papers to the work shop are more technical than usually involved in a workshop at the Royal Institute. Yet this is an area in which the policy options are unusually dependent upon a good under standing of the technical issues. which themselves are often a matter of dispute."

Significant amounts of liquid and solid radioactive waste have been generated in Russia during the production of nuclear weapons, and there is an urgent need to find suitable ways to manage these wastes in a way that protects both the current population and future generations. This book contains contributions from pure and applied scientists and other representatives from Europe, North America, and Russia, who are, or have been, actively involved in the field of radioactive waste management and disposal. First-hand experience of specific problems associated with defence-related wastes in the USA and the Russian Federation is presented, and current plans are described for the disposal of solid wastes arising from civilian nuclear power production programmes in other countries, including Belgium, Bulgaria, Canada, Germany and the UK. The book provides a good insight into ongoing research at local and national level within Russia, devoted to the safe disposal of defence-related radioactive waste. It also demonstrates how existing expertise and technology from civilian nuclear waste management programmes can be applied to solving the problems created by nuclear defence programmes. Contributions address methods of immobilisation, site selection methodology, site characterisation techniques and data interpretation, the key elements of safety/performance assessments of planned deep (geological) repositories for radioactive waste, and radionuclide transport modelling. Concerns associated with certain specific nuclear waste disposal concepts and repository sites are also presented.

Leon N. Moses In June 1991, the Transportation Center at Northwestern University sponsored Hazmat Transport '91: A National Conference on the Transportation of Hazardous Materials and Wastes. The faculty associated with the center were aware that there had been many professional, industrial and government conferences and meetings on the subject. However, they believed that the unique capacity of the Transportation Center to bring together leaders from industry and government, as well as leading scholars from economics, law, engineering, psychology and sociology who have done research on the problems associated with the transportation of hazardous materials and wastes (hazmats), could produce a set of integrated insights and understandings that would go well beyond those of previous conferences. The papers that make up this volume were all delivered at Hazmat Transport '91. From a legislative point of view, they tend to deal with issues associated with the Hazardous Materials Transportation Act of 1975 (HMTA), the original act passed to regulate the transportation of hazardous materials, and the Hazardous Materials Transportation Uniform Safety Act of 1990 (HMTVSA). There were talks and papers presented at the conference that focused on other recent legislation and transportation issues with which HMTUSA does not deal. The conference proceedings volume also had discussions and papers on significant managerial and regulatory issues that could not be included in this volume because of constraints on its size. Therefore, this essay is made up of three parts.

Based on a symposium sponsored by the Environmental Division of the American Chemical Society, Perchlorate in the Environment is the first comprehensive book to address perchlorate as a potable water contaminant. The two main topics are: analytical chemistry (focusing on ion chromatography and electrospray ionization mass spectrometry), and treatment or remediation. Also included are topics such as ion exchange, phytoremediation, bacterial reduction of perchlorate, bioreactors, and in situ bioremediation. To provide complete coverage, background chapters on fundamental chemistry, toxicology, and reulatory issues are also included. The authors are environmental consultants, government researchers, industry experts, and university professors from a wide array of disciplines.

Prior to 1979, consideration of the problem of the carcinogenicity of the aromatic amine class of chemicals took place primarily in poster sessions and symposia of annual meetings of the American Association for Cancer Research and analogous international associations. In November 1979 the first meeting concerned with the aromatic amines was held in Rockville, Haryland under primary sponsorship of the National Cancer Institute. The proceedings from this meeting were published as Monograph 58 of the Journal of the National Cancel' Institute in 1981. The second meeting in this series, the Second International Conference on N-Substituted Aryl Compounds, was held in March/April of 1982 in Hot Springs, Arkansas. The National Cancer Institute and The National Center for Toxicological Research were the primary sponsors of this meeting. The proceedings were published as Volume 49 of the journal En-vil'onmental Health Perspectives in 1983. The third meeting in this series was held in April of 1987 at the Dearborn Hyatt in Dearborn, Michigan. The principal sponsor of this meeting was the Heyer L. Pre ntis Comprehensive Cancer Center of Metropolitan Detroit. The proceedings, Carcinogenic and Mutagenic Responses to Aromatic Amines and Nitroal'enes, were published in 1987 by Elsevier Press. The fourth meeting was held in Cleveland, Ohio, on July 15-19, 1989.

A survey of the feasibility of aircraft- and satellite-based methods for revealing environmental-geological problems. Throughout, a balanced ratio between explanations on the methodological/technical side and presentations of case studies is maintained. The comparison of case studies from North America and Germany shows how the respective territorial conditions lead to distinct methodological approaches. Equally, the considerable dissimilarities in population density and in distances between waste disposal areas, settlements, and areas of protected groundwater necessitate a "diversified methods" approach.

The purpose of these proceedings was to address the technological, economic, insti- tutional and social questions raised by the rapidly evolving u se of biotechnology for the protection. restoration, and sustainability of our environment. The symposium, "Biotech- nology in the Sustainable Environment" emphasized the future-oriented nature of biotech- nology, that is, the potential use of biotechnology in upstream decisions about materials management, in addition to the status and directions of urrent c applications. This sympo- sium incorporated statc-of-the-science. as well as risk and policy issues into the lopics of biotechnology and remediation, waste treatment, environmental evaluation and monitor- ing, and versatility and future directions in biotechnology and sustainability. Achieving a sustainable environment cannot be accomplished by one discipline or one sector of soci- ety. Likewise, long-term environmental sustainability cannot be accomplished by one gov- ernment. Sustainability must be a global effort as is evident from the multinational participation in these proceedings. The importance of biotechnology, sustainability, and the environment is highlighted by the combined support that this discipline receives from industry and the government. In this regard, we acknowledge the foresight of the sponsors and supporters of this sympo- sium: Eastman Chemical Company, E. !. DuPont De Nemours and Company, Inc.

The management and disposal of radioactive wastes are key international issues requiring a sound, fundamental scientific basis to insure public and environmental protection. Large quantities of existing nuclear waste must be treated to encapsulate the radioactivity in a form suitable for disposal. The treatment of this waste, due to its extreme diversity, presents tremendous engineering and scientific challenges. Geologic isolation of transuranic waste is the approach currently proposed by all nuclear countries for its final disposal. To be successful in this endeavor, it is necessary to understand the behavior of plutonium and the other actinides in relevant environmental media. Conceptual models for stored high level waste and waste repository systems present many sCientific difficulties due to their complexity and non-ideality. For example, much of the high level nuclear waste in the US is stored as alkaline concentrated electrolyte materials, where the chemistry of the actinides under such conditions is not well understood. This lack of understanding limits the successful separation and treatment of these wastes. Also, countries such as the US and Germany plan to dispose of actinide bearing wastes in geologic salt deposits. In this case, understanding the speciation and transport properties of actinides in brines is critical for confidence in repository performance and risk assessment activities. Many deep groundwaters underlying existing contaminated sites are also high in ionic strength. Until recently, the scientific basis for describing actinide chemistry in such systems was extremely limited."

Since their first industrial use polymers have gained a tremendous success. The two volumes of "Polymers - Opportunities and Risks" elaborate on both their potentials and on the impact on the environment arising from their production and applications. Volume 11 "Polymers - Opportunities and Risks I: General and Environmental Aspects" is dedicated to the basics of the engineering of polymers - always with a view to possible environmental implications. Topics include: materials, processing, designing, surfaces, the utilization phase, recycling, and depositing. Volume 12 "Polymers - Opportunities and Risks II: Sustainability, Product Design and Processing" highlights raw materials and renewable polymers, sustainability, additives for manufacture and processing, melt modification, biodegradation, adhesive technologies, and solar applications. All contributions were written by leading experts with substantial practical experience in their fields. They are an invaluable source of information not only for scientists, but also for environmental managers and decision makers.

A review of such natural disasters as floods and landslides, highlighting the possibility of safe and correct land planning and management by means of a global approach to territory. Since the events deriving from slope and fluvial dynamics are commonly triggered by the same factor, occur at the same time and are closely related, this book analyses floods and slope stability phenomena as different aspects of the same dynamic system: the drainage basin.

Purpose ofthe Workshop In the spirit of enhancing developments in science and technology by facilitating international scientific cooperation, the Science Committee of NATO is sponsoring AR W's in several selected priority areas. The objective of this workshop was to discuss what microbial mediated problems have been experienced in the area of nuclear waste management and spent fuel storage. Long term storage of high-level wastes in repositories is just starting in some countries. However, low and medium level wastes have been stored for several decades. In the area of spent fuel interim, storage has been extended at many locations far beyond the intended time. It was a priority of the workshop to examine and discuss what deleterious effects have been observed under these storage conditions or under conditions used in simulated trial tests for predicting material performance under the storage conditions. For example, one chronic problem that was discussed was possibility that microbial influenced corrosion (MIC) could be taking place in the wet storage of spent fuel thereby initiating or accelerating the process of corrosion. Another discussion in the area of waste forms, focused on the presence ofbiofilms which may be breaking down the structure of the waste form and thereby jeopardizing its integrity. The meeting focused on discussing the observations and data collected relating to problems encountered in the storage of these types of wastes, and sharing this information with others that have not monitored their facilities for similar problems.

The ffiM Japan International Symposium Energy and Environment - Global Warming was held in the Keidanren Guesthouse at the foot of Mt. Fuji, from October 21 to 24, 1990. The symposium was conducted in the context of ffiM Japan's longstanding commitment to good corporate citizenship. On this beautiful planet with its inter-dependent waters, lands and atmo sphere, we consider that the problems relating to the global environment are the most serious that the human race will face in the near future. The symposium provided an opportunity for forty scientists and researchers, from a wide variety of international backgrounds, to address matters relating to the global environment in an international forum. Eighteen papers were presented followed by panel and group discussions, on which the concluding remarks and recommendations are based. We chose three types of papers to target different aspects of the condition of the global environment: the natural science component; the socio-economic component; and the energy component which links these two. On the first day the symposium began with a plenary speech by Dr. J. Kondo followed by three keynote speeches, each with a particular focus. The following day, six speakers offered papers relating to the previous day's keynote speeches."

This manuscript was made possible by the exceptional support provided by INSA (Institut National des Sciences Appliquees) Toulouse, the University of New Mexico and the University of Cincinnati College of Engineering. The authors, as listed in this book, took the time to prepare excellent manuscripts focusing on scientific and technical areas relevant to emerging environmental issues. These manuscripts were rigorously reviewed and refereed by scientists and engineers before inclusion in this book. An introductory chapter was prepared to summarize and integrate technical issues covered and the last chapter was written to present policy perspectives. The editors are most grateful to the contributors, sponsor organizations, and many colleagues who were kind enough to assist us in making this manuscript possible. Background information about the editors, principal authors and other contributor: s to this manuscript follows. Editors Professor Dr. Ravi K. Jain Associate Dean for Research and International Engineering College of Engineering University of Cincinnati Mail Location 0018 Cincinnati OH 45221-0018 U.S.A

This book focuses on sustainable solid waste management in an urban context and gives an example of how a modern city can work with waste management for increased sustainability in close cooperation with the academy. The book describes challenges which the city is facing and presents a case on how these can be tackled based on several research and development projects performed in the City of Malmoe over the last decade. In these projects, the city has worked as a test bed for new solutions, developed with and evaluated by the university. The projects and evaluations of the same have been developed with a multi-dimensional approach; including technical aspects, resource efficiency, economic parameters, information strategies towards households and user friendliness. Methods used for evaluation are presented in a comprehensive way together with a discussion on how results from performed evaluations have affected the solid waste management policy making in the city. The book describes a bridging over a commonly noticed gap between research on the one hand and policy making and technical management on the other. Several examples are given on how academy and real life and full-scale developments in the city can have a fruit-full collaboration, where feed-back from evaluation of made changes are used for continuous improvements - at the same time as the actual needs from the city forces the academy to develop new methods for evaluations and develop new solutions to previously un-known or un-addressed problems.

This book originated in a series of cross-disciplinary conversations in the years 1984-1990 between the editor, who is a physician-researcher involved in clinical and laboratory research, and a dioxin toxicologist. During the years in which the conversations took place, an extraordinary amount of new scientific literature was published related to dioxins, defined for purposes of this text as the chlorinated dibenzo-p-dioxins, dibenzofurans, polychlorinated biphe nyls (PCB's) and other compounds that are structurally and toxicologically similar to 2,3,7,8-tetrachlorodibenzo-p-dioxin (2,3,7 ,8-TCDD), the most extensively studied and most toxic of this group of chemicals. Dioxins also began to interest not only chemists and toxicologists, but also specialists from diverse disciplines such as wildlife and environmental science, immunology, neuroscience,public health, epidemiology, med icine, government, law, sociology, and journalism. Specialists from such varied disciplines, while familiar with their own literature, frequently did not have time to follow the dioxin literature outside their specialty area. In addition, each specialty had unique knowledge, methods, and perspectives. Cross disciplinary conversation was necessary, but all too frequently, specialists from the various disciplines did not speak the same language, resulting in misunderstanding.

The discipline of surface and colloid chemistIy has experienced a considerable resurgence since the early sixties. This perhaps reflects a growing realisation of the wide applicability of modern colloid and surface theory to many important industrial, medical and environmental problems. This increased activity has resulted in a very complex and at times even confusing area of science being consolidated within a firm theoretical framework. The clearer insights gained into the underlying principles have no doubt acted in an autocatalytic manner to stimulate further interest in an expanding range of applications. A good example in the area of environmental chemistry has been the realization of the important role played by colloidal material and surface interactions in natural biogeochemical processes that has been the subject of increasing attention over the last few decades. This is well illustrated by the numerous studies carried out to elucidate the speciation, toxicity, transport and fate of pollutants in aquatic systems. In the vast majority cases these have clearly implicated some involvement of an aSSOciation between the of pollutant (e. g. trace metal, toxic organic compound or nutrient) and a colloidal component (e. g. particle, humic substance, foam). In order to understand these interactions fully and their effect on pollutant mobility it is important to develop a full appreciation of the surface chemistry of these complex systems. Australian SCientists have long been prominent in the area of colloid and surface chemistry particularly dUring the latter half of this century.

Biochemistry of Halogenated Organic Compounds has been written as a general reference source for researchers in several related areas, including organic chemists, medicinal chemists, pharmacologists, toxicologists, and medical researchers. The development of halogenated compounds as medicinal agents and pharmacological tools and the fascinating biochemi cal processes that have been discovered and studied using these analogues have generated extremely active areas of research and an enormous volume of literature. Thus, halogenated organic compounds pervade every aspect of biochemistry, a fact made apparent by the numerous reviews and monographs available on individual topics-halogenated nucleosides, halogenated carbohydrates, and so forth. Given the quantity of material already written on these topics, some of which material is quite current, it might be asked whether a one-volume review of these subjects is useful, or possible. Having now completed this work, I feel the answer to both questions is an emphatic yes. There are fascinating stories to be related in each area, and, where appropriate, I have attempted to develop these topics . from a historical perspective. For example, the discovery of the anticancer activity of fluorouracil, the unraveling of the several mechanisms of its action, and the development of a host of later generations of anticancer and antiviral agents based on the parent fluoro-, iodo-, bromo-, and trifluoromethylpyrimidines were, and are, contributions of major magnitude to medical science."

When, in 1966, the Gennan Research Society directed the attention of oceanographers in the Federal Republic of Ger many to problems of marine pollution, I was not enthusiastic. Emphasis on this problem area meant that other important research plans had to be postponed. But the lectures at the Third International Oceanographic Congress, September 1970, in Tokyo, and at the FAO Conference on Marine Pollution and its Effects on Living Resources and Fishing, December 1970, in Rome, convinced me that research on problems of marine pollution is a social obligation, and that the oceanographer has to take a stand. I issued public warnings about the continuing use of pesticides and had to defend myself against protests by the fishing industry and many colleagues who were, in Novem ber 1970, unaware of the extent of the threat. Thus, I was required by my profession to acquire an overview of the prob lems of ocean pollution. In 1971 I only needed to familiarize myself with some one hundred bibliographical items. In the interim, the flood of data has risen dramatically, and in the year 1975, no fewer than 868 publications under the heading of "Marine Pollution" were reported (Table 1). It is, therefore, more and more diffi cult to distinguish new results of scientific research from the many repetitions and variations, and I fear that from year to year my efforts to illustrate the actual status of the problem at a given moment will be subject to more gaps."

Reviews of Environmental Contamination and Toxicology provides detailed review articles concerned with aspects of chemical contaminants, including pesticides, in the total environment with toxicological considerations and consequences.

Reviews of Environmental Contamination and Toxicology attempts to provide concise, critical reviews of timely advances, philosophy and significant areas of accomplished or needed endeavor in the total field of xenobiotics, in any segment of the environment, as well as toxicological implications.

The subject of rainfall-runoff modeling involves a wide spectrum of topics. Fundamental to each topic is the problem of accurately computing runoff at a point given rainfall data at another point. The fact that there is currently no one universally accepted approach to computing runoff, given rainfall data, indicates that a purely deter ministic solution to the problem has not yet been found. The technology employed in the modern rainfall-runoff models has evolved substantially over the last two decades, with computer models becoming increasingly more complex in their detail of describing the hydrologic and hydraulic processes which occur in the catchment. But despite the advances in including this additional detail, the level of error in runoff estimates (given rainfall) does not seem to be significantly changed with increasing model complexity; in fact it is not uncommon for the model's level of accuracy to deteriorate with increasing complexity. In a latter section of this chapter, a literature review of the state-of-the-art in rainfall-runoff modeling is compiled which includes many of the concerns noted by rainfall-runoff modelers. The review indicates that there is still no deterministic solution to the rainfall-runoff modeling problem, and that the error in runoff estimates produced from rainfall-runoff models is of such magnitude that they should not be simply ignored."

Monitoring the environment is absolutely essential if we are to identify hazards to human health, to assess environmental cleanup efforts, and to prevent further degradation of the ecosystem. Biomonitors and biomarkers combined with chemical monitoring offer the only approach to making these assessments. Based on an International Association of Great Lakes Research conference, this book is intended for researchers who want to incorporate new and different technologies in their development of specifically-crafted monitors; students who are learning the field of biomonitoring; and regulatory agencies that want to consider newer technologies to replace inadequate and less powerful test regimes.