The discipline of surface and colloid chemistIy has experienced a considerable resurgence since the early sixties. This perhaps reflects a growing realisation of the wide applicability of modern colloid and surface theory to many important industrial, medical and environmental problems. This increased activity has resulted in a very complex and at times even confusing area of science being consolidated within a firm theoretical framework. The clearer insights gained into the underlying principles have no doubt acted in an autocatalytic manner to stimulate further interest in an expanding range of applications. A good example in the area of environmental chemistry has been the realization of the important role played by colloidal material and surface interactions in natural biogeochemical processes that has been the subject of increasing attention over the last few decades. This is well illustrated by the numerous studies carried out to elucidate the speciation, toxicity, transport and fate of pollutants in aquatic systems. In the vast majority cases these have clearly implicated some involvement of an aSSOciation between the of pollutant (e. g. trace metal, toxic organic compound or nutrient) and a colloidal component (e. g. particle, humic substance, foam). In order to understand these interactions fully and their effect on pollutant mobility it is important to develop a full appreciation of the surface chemistry of these complex systems. Australian SCientists have long been prominent in the area of colloid and surface chemistry particularly dUring the latter half of this century.

Biological markers (biomarkers) are useful tools for understanding the nature and extent of human exposure and risk from environmental toxicants. Biomarkers are classified into three basic categories: exposure, effect, or susceptibility. A marker of exposure is the product of the interaction between a target cell or molecule and a foreign substance (NAS, 1989). These markers can be used to determine the biologically effective dose necessary to elicit a particular physiological change in an organism. A marker of effect is a biochemical or physiological change in an organism that can predict the onset of adverse health effects resulting from a given exposure. Lastly, markers of susceptibility act as indicators of an inherent or acquired tendency of an organism to experience an adverse health effect (NAS, 1989). These markers are already used to detect a variety of diseases and show great promise for developing a better understanding of the mechanicisms of disease. Additionally, biomarkers can be used to establish a more rational basis for quantitative risk extrapolation between species, as weIl as to obtain more precise estimates of the time of critical exposure. These markers can also prove helpful in identifying potentially damaging exposures before the onset of adverse health effects. Biomarkers serve as a valuable exposure assessment tool because they take into account exposure from all routes and integrate exposure from all sources. They have the potential to yield better risk estimates than current monitoring and modeling protocols. In lune 1992, Dr. Travis and Dr.

This book represents the efforts of over a hundred individuals who planned and executed the NSTS field experiments, analyzed the billions of data points, and distilled their findings and insights into the summaries found here. Because these experiments were of a scope that will seldom, if ever, be duplicated, and because the program brought together many of the foremost field experimentalists in this country, we all felt from the beginning that it was important to preserve the outcome. This was done in two ways. First, the raw data were made available to any interested investigator within 18 months of the completion of each experiment. Secondly, both the methodology of the experiments and the findings from them were codified in the form of a monograph. This book is that result. I have had the occasion recently (Sediments '87 Proceedings, Vol. 1, pp. 642-651) to assess the NSTS performance. I found that we made giant strides in our understanding of the surf zone hydrodynamics --far more than our fondest expectations at the beginning. We were able to do less than we had hoped about the response of the sediment, largely because of a limited ability to measure it at a point. As I reported in the Sediments '87 assessment, we established a new state of the art in measurement techniques and we demonstrated the effectiveness of large, multi-investigator, instrument-intensive experiments for studying nearshore processes.

This volume, unlike the three preceding it, represents the collected papers from an experiment with an "electronic symposium." Co-participators in this symposium included The George Washington University, The Smithsonian Institution, Clark Atlanta University, the Agriculture Research Service of the United States Department of Agriculture, The University of Georgia, Morris Brown College, Spellman College, Morehouse College, North Carolina State University at Raleigh, The United States Food and Drug Administration, and the Forest Service of the United States Department of Agriculture among others. This unusual "electronic symposium" concept was developed by members of the Program, Planning and Organizing Committee as an alternative to the more costly convention-type symposium. As before, leading scientists in specific topic areas were invited to participate. Topic Session chairpersons were encouraged to arrange their own method of communication by telephone, electronic mail, or conference call, and report their findings back to the symposium center at The George Washington University. Additional papers were accepted from individuals and laboratories who are actively involved in relevant areas of research and study. Participation was also arranged for internationally established scientists. International authors are represented herein from Nigeria, Italy, Spain, Brazil and Argentina. Our goal was to present a research composite volume that reflected current developments, informed reviews, new and recently developing areas of the present state of knowledge as it relates to these proceeding topics. All of the reports included in this volume have undergone scientific, technical and editorial peer review.

Environmental Chemistry is a relatively young science. Interestin this subject, however, is growing very rapidly and, although no agreement has been reached as yet about the exact content and Iimits of this interdisciplinary discipline, there appears to be increasing interest in seeing environmental topics which are based on chemistry embodied in this subject. One of the first objectives ofEnvironmental Chemistry must be the study ofthe environment and of natural chemical processes which occur in the environment. A major purpose of this series on Environmental Chemistry, therefore, is to present a reasonably uniform view of various aspects of the chemistry of the environ ment and chemical reactions occurring in the environment. The industrial activities of man have given a new dimension to Environ mental Chemistry. Wehave now synthesized and described over five million chemical compounds and chemical industry produces about hundred and fifty million tons of synthetic chemieals annually. We ship billions of tons of oil per year and through mining operations and other geophysical modifications, large quantities of inorganic and organic materials are released from their natural deposits. Cities and metropolitan areas ofup to 15 million inhabitants produce large quantities ofwaste in relatively small and confined areas. Much of the chemical products and waste products of modern society are released into the environment either during production, storage, transport, use or ultimate disposal. These released materials participate in natural cycles and reactions and frequently Iead to interference and disturbance of natural systems."

Biochemistry of Halogenated Organic Compounds has been written as a general reference source for researchers in several related areas, including organic chemists, medicinal chemists, pharmacologists, toxicologists, and medical researchers. The development of halogenated compounds as medicinal agents and pharmacological tools and the fascinating biochemi cal processes that have been discovered and studied using these analogues have generated extremely active areas of research and an enormous volume of literature. Thus, halogenated organic compounds pervade every aspect of biochemistry, a fact made apparent by the numerous reviews and monographs available on individual topics-halogenated nucleosides, halogenated carbohydrates, and so forth. Given the quantity of material already written on these topics, some of which material is quite current, it might be asked whether a one-volume review of these subjects is useful, or possible. Having now completed this work, I feel the answer to both questions is an emphatic yes. There are fascinating stories to be related in each area, and, where appropriate, I have attempted to develop these topics . from a historical perspective. For example, the discovery of the anticancer activity of fluorouracil, the unraveling of the several mechanisms of its action, and the development of a host of later generations of anticancer and antiviral agents based on the parent fluoro-, iodo-, bromo-, and trifluoromethylpyrimidines were, and are, contributions of major magnitude to medical science."

Reviews of Environmental Contamination and Toxicology attempts to provide concise, critical reviews of timely advances, philosophy and significant areas of accomplished or needed endeavor in the total field of xenobiotics, in any segment of the environment, as well as toxicological implications.

During the past five years increased awareness of environmental contamination by nitroaromatic compounds has led to a dramatic increase in research on their biodegradation. The resulting discoveries have markedly extended our understanding of degradation mecha nisms and pathways in bacteria and fungi. Futhermore, this new basic knowledge promises the development of field applications of biodegradation systems for nitroaromatic com pounds. In May of 1994, an International Symposium on the Biodegradation of Nitro aromatic Compounds was held in Las Vegas, Nevada. This symposium brought together the scientists at the frontiers of research into the biodegradation of nitro aromatic compounds. The invited speakers were asked to review their area of expertise and write a critical, comprehensive synthesis of their work and related work by others. This book is the result of their efforts. The emphasis of the reviews is on basic research in biodegradation and biotransfor mation. Therefore, the reactions of nitroaromatic compounds in plants, animals, bacteria, fungi, soil, and even nonbiological systems are considered. The goal of the work is to provide the reader with an appreciation of the tremendous range of possibilities for metabolism of aromatic nitro compounds and the experimental approaches used to understand them. This volume should be of interest to biochemists, microbiologists, engineers, toxicologists, and anyone interested in the behavior of synthetic chemicals in the environment or in living systems. Furthermore, a variety of commercial applications can be envisioned for some of the reactions described here.

This is a collection of papers presented at the 1985 annual meeting of the Society for Risk Analysis. As always seems to occur at these meetings, the discussion was lively, the sessions were filled, and people complained about not being able to hear all the papers they wanted to because of concurrent sessions. If ever someone is in charge of a meeting, I wish them the good luck to have it be one for the Society for Risk Analysis. While I was responsible for the meeting, it could not have taken place without the efforts of the general chairman, Alan Moshissi. The program committee was chaired by Janice Longstreth, and included Lee Abramson and Vincent Covello. Together we assembled disparate papers into reasonably coherent sessions, prodded authors into getting us manuscrLpts on time, and dealt with all the last minute changes that are required for a major meeting. The Washington chapter of the Society for Risk Analysis hosted the meeting. Dr. Longstreth was president of the chapter during this fateful year and deserves a great deal of thanks for her organizational skills and efforts. Rick Cothern, Jerry Chandler, Kathleen Knox, Sue Perlin, and Paul Price played major roles in organ1z1ng the meeting and making it run smoothly. Special thanks go to Richard J. Burk, Jr. , Executive Secretary of the Society, and his staff for handling the logistics.

This book is a collection of all the lectures by the professors attending the 3rd "Interna tional School on Marine Chemistry" held in Ustica (Palermo, Italy, September 2000), under the auspices of the United Nations and the Italian Chemical Society. The School was organized by the University of Palermo in co-operation with the Natural Marine Reserve of Ustica Island. The Organising Committee of the School wishes to thank the University of Messina, the University of Roma "La Sapienza: ' the Italian University Consortium of Environ mental Chemistry, and the Marine Reserve of Ustica Island for their financial support to the School. This book has been printed with the financial support of the Environmental Re search Centre CIRITA of the University of Palermo. thank all the professors whose outstanding scientific contributions have The editors made it possible to publish this book. Professor Antonio Gianguzza Professor Ezio Pelizzetti Professor Silvio Sammartano Contents Part I Biogeochemical Processes at the Air-Water and Water-Sediment Interface .............................................. ."

Waste incineration is the art of completely combusting waste, while maintaining or reducing emission levels below current emission standards. Where possible, objectives include the recovering of energy as well as the combustion residues. Successful waste incineration makes it possible to achieve a deep reduction in waste volume, obtain a compact and sterile residue, and eliminate a wide array of pollutants. This book places waste incineration within the wider context of waste management, and demonstrates that, in contrast to landfills and composting, waste incineration can eliminate objectionable and hazardous properties such as flammability and toxicity, result in a significant reduction in volume, and destroy gaseous and liquid waste streams leaving little or no residues beyond those linked to flue gas neutralization and treatment. Moreover, waste incineration sterilizes and destroys putrescible matter, and produces usable heat. Incineration Technologies first appeared as a peer-reviewed contribution to the Encyclopedia of Sustainability Science and Technology. It provides detailed treatment of the challenges of this technically complex process, which requires huge investment and operating costs, as well as good technical skills in maintenance and plant operation. Particular attention is paid to technologies for ensuring the complete burn-out of flue gas and residues and for controlling the resulting pollutants.

This book represents the proceedings of the first major international meeting dedi cated to discuss environmental aspects of produced water. The 1992 International Pro duced Water Symposium was held at the Catamaran Hotel, San Diego, California, USA, on February 4-7, 1992. The objectives of the conference were to provide a forum where scientists, regulators, industry, academia, and the enviromental community could gather to hear and discuss the latest information related to the environmental considerations of produced water discharges. It was also an objective to provide a forum for the peer review and international publication of the symposium papers so that they would have wide availability to all parties interested in produced water environmental issues. Produced water is the largest volume waste stream from oil and gas production activities. Onshore, well over 90% is reinjected to subsurface formations. Offshore, and in the coastal zone, most produced water is discharged to the ocean. Over the past several years there has been increasing concern from regulators and the environmental commu nity. There has been a quest for more information on the composition, treatment systems and chemicals, discharge characteristics, disposal options, and fate and effects of the produced water. As so often happens, much of this information exists in the forms of reports and internal research papers. This symposium and publication was intended to make this information available, both for open discussion at the conference, and for peer review before publication."

In 1949, when the North Atlantic Treaty was ratified, one of its articles explicitly noted '1hat member countries should contribute towards the further development of peaceful and friendly international relations." Specific problems related to the human environment were addressed by the Committee of Challenges of Modern Society (CCMS) of NATO, established in 1969. This provided a framework within which a series of International Technical Meetings (ITMs) on Air Pollution Modelling has been held. This volume documents the proceedings of the 18th meeting in this series. Science, like the arts and sports, provides an ideal vehicle for "developing peaceful and friendly international relations". National boundaries have never been barriers to the movement of air pollution, and fortunately this has also proved true of scientists studying the transport of air pollution. It is thus satisfying to record that since the mid-seventies it has been commonplace to find Eastern European scientists among attendees at the ITMs which have (in a very modest way) participated in a precursor to the process which has led to historical changes in Europe and which will undoubtedly lead to a tremendous increase in personal and intellectual exchange on a worldwide basis.

An Introduction to Environmental Biotechnology provides an introduction to the subject of environmental biotechnology. Environmental biotechnology refers to the use of micro-organisms and other living systems to solve current environmental problems such as the detoxification of pollutants and clean-up of oil tanker spills. Additionally, it refers to the biotechnology of the agricultural environment, as well as the use of biopesticides and the application of microorganisms to the mining, metal recovery and paper industries. This is the only comprehensive introductory account of this subject matter. Beginning with an introduction to microbial growth, An Introduction to Environmental Biotechnology aims to provide the non-specialist with a complete overview of environmental biotechnology. It is presented in an easy to read style with illustrations and includes frequent references to the use of higher plants as well as micro-organisms in environmental biotechnology. An Introduction to Environmental Biotechnology is geared toward a non-specialist audience, including engineers and environmental chemists, and environmental scientists who have limited knowledge of microbiology and biotechnology.

Motivation The other day I was waiting at the station for my train. Next to me a young lady was nonchalantly leaning against the wall. Suddenly, she took a cigarette pack out of her handbag, pulled out the last cigarette, put it between her lips, crushed the empty pack, threw it on the ground and hedonistically lit the cigarette. I thought to myself, "What a behavior? ." The nearest trashcan was just five meters away. So I bent down, took the crushed pack and gave it back to her, saying that she had lost it. She looked at me in a rather deranged way, but she said nothing and of waste to the trashcan. brought the piece Often people are not aware of the waste they produce. They get rid of it and that's it. As soon as the charming lady dropped the cigarette pack, the problem was solved for her. The pack was on the ground and it suddenly no longer belonged to her. It is taken for granted that somebody else will do the cleaning up. There is a saying that nature does not produce waste. For long as humans obtained the goods they needed from the ground where they lived, the waste that was produced could be handled by nature. This has drastically changed due to urbanization and waste produced by human activities has become a severe burden.

In this timely volume, scientists examine examine the physical, structural, and analytical chemistry of fuel combustion. Their contributions also address the issue of combustion efficiency and how air quality can be protected or improved. Supported by numerous illustrations, this volume be appreciated by researchers and students working in various areas of chemistry.

A survey of recent developments in the field of plutonium disposal by the application of advanced nuclear systems, both critical and subcritical. Current national R&D plans are summarized. The actinide-fuelled critical reactors are associated with control problems, since they tend to have a small delayed neutron fraction coupled with a small Doppler effect and a positive void coefficient. Current thinking is turning to accelerator-driven subcritical systems for the transmutation of actinides. The book's conclusion is that the various systems proposed are technically feasible, even though not yet technically mature. The book presents a unique summary and evaluation of all relevant possibilities for burning surplus plutonium, presented by experts from a variety of different disciplines and interests, including the defence establishment. The obvious issue - the non-proliferation of nuclear weapons - is vital, but the matter represents a complex technological challenge that also requires an assessment in economic terms.

In 1969 the North Atlantic Treaty Organization (NATO) established the Committee on Chal- lenges of Modern Society (CCMS). The subject of air pollution was from t,lw start one of the priority problems under study within the framework of various pilot. studi('s undertaken by this committee. The organization of a periodic conference dealing with air pollution modelling and its application has become one of the main activities within the pilot ~tudy relatillg to air pollution. The first five international conferences were organized by the United Statcs as the pilot country; the second five by the Federal Republic of Germany: thc third five by sselgium; the next four by The Netherlands; ami the two most recent by Delllllark. This volume contains the papers presented at the 21st NATOjCCMS International Technical Meeting (ITM) on Air Pollution Modelling and Its Application, held in ssaltimorc. Maryland, during November 6-10, 1995. This ITM was jointly organized by the Riso National Laboratory of Denmark (Pilot Country); by the EPA National Exposurp Research Labora- tory, United States (Host Country); and by thc American MNeorologiea.! Soci('t.: *. Cnited States (Host Organization). The ITM was attended by 137 participants representing 29 countri('~ from North and South America, Europe, Asia and Australia. The members of t.hc NATO/CCMS Scientific Committee for the 21st ITM were R.M. van Aalst (The Nethcrlallds), D. Allfossi (Haly), C. Borrego (Portugal), N. Chaumerliac (Francc), H. van Dop (Thc :\Tethcrla.nds). S.-E. Gryning.

Chemical pretreatment of nuclear wastes refers to the sequence of separations processes used to partition such wastes into a small volume of high-level waste for deep geologic disposal and a larger volume of low-level waste for disposal in a near-surface facility. Pretreatment of nuclear wastes now stored at several U. S. Department of Energy sites ranges from simple solid-liquid separations to more complex chemical steps, such as dissolution of sludges and removal of selected radionuclides, e. g. , 90Sr, 99Tc, 137CS, and TRU (transuranium) elements. The driving force for development of chemical pretreatment processes for nuclear wastes is the economic advantage of waste minimization as reflected in lower costs for near-surface disposal compared to the high cost of disposing of wastes in a deep geologic repository. This latter theme is expertly and authoritatively discussed in the introductory paper by J. and L. Bell. Seven papers in this volume describe several separations processes developed or being developed to pretreat the large volume of nuclear wastes stored at the US DOE Hanford and Savannah River sites. These papers include descriptions of the type and amount of important nuclear wastes stored at the Hanford and Savannah River sites as well as presently envisioned strategies for their treatment and final disposal. A paper by Strachan et al. discusses chemical and radiolytic mechanisms for the formation and release of potentially explosive hydrogen gas in Tank 241-SY-101 at the Hanford site.

The authors explain the rewarding results from the interdisciplinary collaboration between an environmental study group working on coastal ecosystems and effects of oil spills and applied mathematicians modelling wave motion on sandy beaches. By using the unified Navier-Stokes equations with a Bingham fluid model for spilled oil, multi-phase flow analysis were made. Decomposition of spilled oil by bacteria was simulated as a chemical reaction, and the theoretical and numerical analysis suggested a countermeasure to help reduce stress on coastal ecosystems. The new understanding of how ecosystems both depend upon, and help to determine, the nature of the shoreline demonstrates promising ways to better assist and exploit the regenerative powers inherent in nature.

The purpose of these proceedings was to address the technological, economic, insti- tutional and social questions raised by the rapidly evolving u se of biotechnology for the protection. restoration, and sustainability of our environment. The symposium, "Biotech- nology in the Sustainable Environment" emphasized the future-oriented nature of biotech- nology, that is, the potential use of biotechnology in upstream decisions about materials management, in addition to the status and directions of urrent c applications. This sympo- sium incorporated statc-of-the-science. as well as risk and policy issues into the lopics of biotechnology and remediation, waste treatment, environmental evaluation and monitor- ing, and versatility and future directions in biotechnology and sustainability. Achieving a sustainable environment cannot be accomplished by one discipline or one sector of soci- ety. Likewise, long-term environmental sustainability cannot be accomplished by one gov- ernment. Sustainability must be a global effort as is evident from the multinational participation in these proceedings. The importance of biotechnology, sustainability, and the environment is highlighted by the combined support that this discipline receives from industry and the government. In this regard, we acknowledge the foresight of the sponsors and supporters of this sympo- sium: Eastman Chemical Company, E. !. DuPont De Nemours and Company, Inc.

Co-utilization or blending of residuals offers a unique opportunity to develop products with particular characteristics that are able to target specific customer needs. The very notion of deliberately blending by-products suggests that the recycling and beneficial reuse industries are taking a quantitative step forward towards developing products rather than simply reusing residuals. At the same time that this step provides unique opportunities, it also presents unique challenges. The science associated with the beneficial use of one product may not apply when that product is mixed with another residual. Blending of materials may alter the chemistry of the components of the mixture. This may offer additional benefits, as in the case of disease suppression in composts, or present unexpected problems, as the use of lime-stabilized biosolids has done in Maryland. This book consists of the proceedings of the Beltsville Symposium. The organizers of the Symposium attempted to structure a meeting that would outline both the potential benefits of co-utilization as well as concerns. The editors have divided the proceedings into sections that describe the practical basis for co-utilization of residuals as well as the potential benefits. Specific considerations are described. Finally, case studies include descriptions of successful operations and data that detail results of research involving co-utilization materials. Blending of materials for specific objectives needs to be the focus of any successful co-utilization effort. The scientific implications of the mix need to be determined before a product can be used properly.

With the end of the Cold War, new opportunities for interaction have opened up between the United States and the countries of the Former Soviet Union. Many of these important initiatives involve the US Department of Energy (DOE) and the Ministry of the Russian Federation for Atomic Energy (MINA TOM). Currently, collaboration is under way which involves reactor safety, the disposition of fissile materials from the weapons program, radioactive waste disposal, and the safety of nuclear warheads. Another fruitful area of interchange resulted from the radiochemical storage tank accident at the site of the Siberian Chemical Compound at Tomsk-7 in 1993. DOE and MINATOM agreed to meet and exchange information about the accident for the purposes of improving safety. A meeting on the Tomsk tank accident was held in Hanford, Washington in 1993, followed by a second meeting in st. Petersburg, Russia in 1994 in which the agenda expanded to include radiochemical processing safety. A third exchange took place in 1995 in Los Alamos, New Mexico, and additional papers were presented on nonreactor nuclear safety. Following a planning session in 1996 in Seattle, Washington, it was decided to hold a fourth technical exchange on the broader subject of nuclear materials safety management. Through a grant from the North Atlantic Treaty Organization (NATO) Disarmament Programme, the meeting took place on March 17- 21, 1997, in Amarillo, Texas as a NATO Advanced Research Workshop (ARW) through grant no. DISRM 961315.

The surplus of plutonium in the world is both an important security issue, and a fact with implications for nuclear energy and environmental policy internationally. The two perspectives are inextricably intertwined in considering options for dealing with the plutonium surplus. It was for this reason that two research programmes at the Royal Institute of International Affairs - respectively on Energy and Environment, and on International Security - jointly approached NATO with a view to organising a work shop on the issue. It was most welcome then to learn that the NATO Science Programe was already supporting plans for a workshop on the issue, initiated by Richard Garwin, and we were pleased to accept the resulting invitation to host that workshop. DrGarwin prepared the initial agenda and established contacts and initial approaches to many of the participants; we were able to develop the agenda further and extend participation in some complementary ways. The result was a most lively and broad-ranging internation al and inter-disciplinary discussion. As the hosts, the RIIA was also given lead responsibility for producing the pro ceedings of the workshop as a publication for NATO. Many of the papers to the work shop are more technical than usually involved in a workshop at the Royal Institute. Yet this is an area in which the policy options are unusually dependent upon a good under standing of the technical issues. which themselves are often a matter of dispute."

Significant amounts of liquid and solid radioactive waste have been generated in Russia during the production of nuclear weapons, and there is an urgent need to find suitable ways to manage these wastes in a way that protects both the current population and future generations. This book contains contributions from pure and applied scientists and other representatives from Europe, North America, and Russia, who are, or have been, actively involved in the field of radioactive waste management and disposal. First-hand experience of specific problems associated with defence-related wastes in the USA and the Russian Federation is presented, and current plans are described for the disposal of solid wastes arising from civilian nuclear power production programmes in other countries, including Belgium, Bulgaria, Canada, Germany and the UK. The book provides a good insight into ongoing research at local and national level within Russia, devoted to the safe disposal of defence-related radioactive waste. It also demonstrates how existing expertise and technology from civilian nuclear waste management programmes can be applied to solving the problems created by nuclear defence programmes. Contributions address methods of immobilisation, site selection methodology, site characterisation techniques and data interpretation, the key elements of safety/performance assessments of planned deep (geological) repositories for radioactive waste, and radionuclide transport modelling. Concerns associated with certain specific nuclear waste disposal concepts and repository sites are also presented.