The NATO Advanced Study Institute on "Functional Gradient Materials and Surface Layers Prepared by Fine Particles Technology" was held in Kiev (Ukraine) on June 18- 28, 2000 where more than 90 participants, ranging from Ph.D. students to experienced senior scientists, met and exchanged ideas. This meeting was aimed at stimulating the research work across traditional disciplinary lines by bringing together scientists from diverse research areas related to functional gradient materials and surface layers. It also intended to give opportunities for initiating collaborative works between scientists from NATO and Partner countries and to trigger fruitful and exciting discussions between experienced and young researchers. In this respect, this NATO-ASI has been quite successful. The term of functional gradient materials which originates from Japan in the 1980's describes a class of engineering materials with spatially inhomogeneous microstructures and properties (MRS Bulletin, 1995,20, N Degreesl). These materials can be successfully utilized in various applications like electronic devices, optical films, anti wear and anti-corrosion coatings, thermal barrier coatings, biomaterials, to name only a few. Although these functional gradient materials are not fundamentally new, the use of nanoparticles in their fabrication and in surface layers as well has greatly improved their performances to meet challenging requirements for industrial applications.

The NATO Advanced Study Institute on "Functional Gradient Materials and Surface Layers Prepared by Fine Particles Technology" was held in Kiev (Ukraine) on June 18- 28, 2000 where more than 90 participants, ranging from Ph.D. students to experienced senior scientists, met and exchanged ideas. This meeting was aimed at stimulating the research work across traditional disciplinary lines by bringing together scientists from diverse research areas related to functional gradient materials and surface layers. It also intended to give opportunities for initiating collaborative works between scientists from NATO and Partner countries and to trigger fruitful and exciting discussions between experienced and young researchers. In this respect, this NATO-ASI has been quite successful. The term of functional gradient materials which originates from Japan in the 1980's describes a class of engineering materials with spatially inhomogeneous microstructures and properties (MRS Bulletin, 1995,20, N Degreesl). These materials can be successfully utilized in various applications like electronic devices, optical films, anti wear and anti-corrosion coatings, thermal barrier coatings, biomaterials, to name only a few. Although these functional gradient materials are not fundamentally new, the use of nanoparticles in their fabrication and in surface layers as well has greatly improved their performances to meet challenging requirements for industrial applications.

Particle characterization is an important component in product research and development, manufacture, and quality control of particulate materials and an important tool in the frontier of sciences, such as in biotechnology and nanotechnology. This book systematically describes one major branch of modern particle characterization technology - the light scattering methods. This is the first monograph in particle science and technology covering the principles, instrumentation, data interpretation, applications, and latest experimental development in laser diffraction, optical particle counting, photon correlation spectroscopy, and electrophoretic light scattering. In addition, a summary of all major particle sizing and other characterization methods, basic statistics and sample preparation techniques used in particle characterization, as well as almost 500 latest references are provided. The book is a must for industrial users of light scattering techniques characterizing a variety of particulate systems and for undergraduate or graduate students who want to learn how to use light scattering to study particular materials, in chemical engineering, material sciences, physical chemistry and other related fields.

This introductory text develops the fundamental physics of the behavior of granular materials. It covers the basic properties of flow, friction, and fluidization of uniform granular materials; discusses mixing and segregation of heterogeneous materials (the famous "brazil-nut problem"); and concludes with an introduction to numerical models. The presentation begins with simple experiments and uses their results to build concepts and theorems about materials whose behavior is often quite counter-intuitive; presenting in a unified way the background needed to understand current work in the field. Developed for students at the University of Paris, the text will be suitable for advanced undergraduates and beginning graduates; while also being of interest to researchers and engineers just entering the field.

It is difficult to imagine modem technology without small particles, 1-1000 nm in size, because virtually every industry depends in some way on the use of such materials. Catalysts, printing inks, paper, dyes and pigments, many medicinal products, adsorbents, thickening agents, some adhesives, clays, and hundreds of other diverse products are based on or involve small particles in a very fundamental way. In some cases finely divided materials occur naturally or are merely a convenient form for using a material. In most cases small particles play a special role in technology because in effect they constitute a different state of matter because of the basic fact that the surface of a material is different from the interior by virtue of the unsaturated bonding interactions of the outermost layers of atoms at the surface of a solid. Whereas in a macroscale particle these differences are often insignificant, as the 9 surface area per unit mass becomes larger by a factor of as much as 10, physical and chemical effects such as adsorption become so pronounced as to make the finely divided form of the bulk material into essentially a different material usually one that has no macroscale counterpart."

This book presents a complete and comprehensive analysis of the behaviour of granular materials including the description of experimental results, the different ways to define the global behaviour from local phenomena at the particle scale, the various modellings which can be used for a D.E.M. analysis to solve practical problems and finally the analysis of strain localisation. The concepts developed in this book are applicable to many kinds of granular materials considered in civil, mechanical or chemical engineering.

A prestigious form of research grant in Germany is the Sonderforschungsbereich, which provides continuous funding over a period of up to 15 years, but only as long as the work is yielding worthwhile results. We acknowledge financial support of our work at Erlangen by the Deutsche Forschungsgemeinschaft (DFG), Sonder- forschungsbereich 222. Thanks to this support, the experimental results from six Dr. -Ing. dissertations have provided the basis for our book: 8 * Schweinzer, J. (1987) Heat transfer in bubbling fluidized beds at Ar;a. 10 * Seiter, M. (1990) Particle motion and solids concentration in circulating fluidized beds * Mattmann, W. (1991) Heat transfer in pressurized circulating fluidized beds * Burschka, A. (1993) Pulsed light method * Dietz, S. (1994) Heat transfer in bubbling fluidized beds * Gruber, U. (1995) Heat transfer in lean phase systems This book is the result of the enthusiastic and trustful cooperation of its authors. Nevertheless, we are separate individuals. Chapters 1 to 12 and 19 are by O. Molerus; Chapters 13 to 18 are by K. -E. Wirth. This book came into existence after many rewrites, patiently endured by Mrs Winter, who typed all versions of the manuscript, and by Mrs Scheffler-Kohler, who drew all the figures. Bob Farmer and David Penfold helped us bridge the language gap to produce a readable book. Weare grateful to Professor Brian Scarlett of Delft University, who on behalf of Chapman & Hall allowed us to write this book.

The operation of a powder mixer requires a knowledge not only of the mixing mechanisms but of the physical properties of the powders being mixed. Powder Mixing is unique in that it explores the relevant physics of the powder systems including characterization procedures and rheology, and contains an extensive review of different methods that have been employed to study the structure of mixtures. The techniques for achieving structured mixtures such as microencapsulation, and recent developments in deterministic chaos theory and fractal geometry as applied to the study of powder mixing systems, are reviewed. In particular, new techniques for studying the mixing powders based on avalanching theory and critically self-organized systems are studied. These are followed by a review of the wide range of different mixers commercially available and an extensive bibliography. Powder Mixing is an essential reference for all those interested in the basic science of powder mixing and the availability of industrial systems to achieve a mixture of different kinds. The main emphasis of the text is on working principles and operative systems, and is suitable for industrial workers, chemical engineers and students alike.

Over half of the products of the chemical and process industries are sold in a particulate form. The range of such products is vast: from agrochemicals to pigments, from detergents to foods, from plastics to pharmaceuticals. However, surveys of the performance of processes designed to produce particulate products have consistently shown inadequate design and poor reliability. Particle technology' is a new subject facing new challenges. Chemical and process engineering is becoming less concerned with the design of plants to produce generic simple chemicals (which are often single phase fluids) and is now more concerned with speciality effect' chemicals which may often be in particulate form. Chemical and process engineers are also being recruited in increasing numbers into areas outside their tranditional fields, such as the food industry, pharmaceuticals and the manufacture of a wide variety of consumer products. This book has been written to meet their needs. It provides comprehensive coverage of the technology of particulate solids, in a form which is both accessible and concise enough to be useful to engineering and science students in the final year of an undergraduate degree, and at Master's level. Although it was written with students of chemical engineering in mind, it will also be of use and interest to students of other disciplines. It comprises an account of the fundamentals of teh subject, illustrated by worked examples, and followed by a wide range of selected applications.

Bringing together the leading European expertise in behaviour and design of silos, this important new book is an essential reference source for all concerned with current problems and developments in silo technology. Silos are used in an enormous range of industries and the handling characteristics of many industrial materials require different approaches for successful, economical installations. For the first time, the many approaches taken by specialists in different fields are brought together in a unified way so that common problems can be addressed.
This book is the result of a four-year European project - Concerted Action - Silos - funded under the Brite Euram programme which has involved over 100 expert engineers and researchers from all over Europe, in seven working groups.

eBook available with sample pages: 0203223519

Since the publication of the first edition of Canada, and Australia have increased teach Handbook of Powder Science and Technology, ing, research, and training activities in areas the field of powder science and technology has related to particle science and technology. gained broader recognition and its various ar In addition, it is worth mentioning the many eas of interest have become more defined and books and monographs that have been pub focused. Research and application activities lished on specific areas of particle, powder, related to particle technology have increased and particle fluid by professional publishers, globally in academia, industry, and research technical societies and university presses. Also, institutions. During the last decade, many to date, there are many career development groups, with various scientific, technical, and courses given by specialists and universities on engineering backgrounds have been founded various facets of powder science and technol to study, apply, and promote interest in areas ogy."

Many industrial, power generation and chemical processes produce unwanted fine particulate material as a consequence of their operation. Electrostatic precipitation is a highly efficient method of removing entrained particulate contaminants from exhaust gases and is extensively used in these industries to limit particulate emissions. New legislation aimed at improving the environment by further limiting these discharges has resulted in the technique undergoing considerable development over the past decade, to the point where it has become the method of choice, over a wide range of applications, for limiting particulate discharges. In this new book, the editor has brought together an international team of contributors, mainly industrialists and consultants, to produce an authorative and practical guide to electrostatic precipitation. This book is of interest to all those in process industries or power generation and to academics concerned with gas cleaning and environmental issues.

This is the fifth edition of the highly successful work first published in 1968, comprising two definitive volumes on particle characterisation. The first volume is devoted to sampling and particle size measurement, while surface area and pore size determination are reviewed in volume 2. Particle size and characterisation are central to understanding powder properties and behaviour. This book describes numerous potential measuring devices, how they operate and their advantages and disadvantages. It comprise a fully comprehensive treatise on the wide range of available equipment with an extensive literature survey, and a list of manufacturers and suppliers. The author's blend of academic and industrial experience results in a readable technical book with information on how to analyse, present, and extract useful information from data. This is an essential reference book for both industrial and academic research workers in a variety of areas including: pharmaceuticals, food science, pollution analysis and control, electronic materials, agricultural products, polymers, pigments and chemicals.

This is the fifth edition of the highly successful work first published in 1968, comprising two definitive volumes on particle characterisation. The first volume is devoted to sampling and particle size measurement, while surface area and pore size determination are reviewed in volume 2. Particle size and characterisation are central to understanding powder properties and behaviour. This book describes numerous potential measuring devices, how they operate and their advantages and disadvantages. It comprise a fully comprehensive treatise on the wide range of available equipment with an extensive literature survey, and a list of manufacturers and suppliers. The author's blend of academic and industrial experience results in a readable technical book with information on how to analyse, present, and extract useful information from data. This is an essential reference book for both industrial and academic research workers in a variety of areas including: pharmaceuticals, food science, pollution analysis and control, electronic materials, agricultural products, polymers, pigments and chemicals.

Chemistry of Powder Production focuses on the solid-state chemistry of powder materials and relates this to the structure, properties and preparation, and characterization techniques for these important industrial products. Additionally, the properties of the particles are discussed in relation to their surface structure and characteristics. This book describes the fundamentals of statistical methods for measuring the characteristics of particles. New advanced materials being developed in powder technology manufacturing techniques are also emphasised, including powdered materials for advanced ceramics as well as magnetic and pigment materials.

Fine Particles Science and Technology deals with the preparation, characterization and technological applications of monodisperse particles in the micro to nano size range. A broad view of this frontier field is given, covering understanding the mechanisms by which uniform fine particles are formed and the search for new processes; the mechanism of the precipitation technique, requiring knowledge of the relationship between the complex solution chemistry and the products formed; the sequence of events leading to the formation of monodisperse colloids. The following topics are presented: microparticles, nanoparticles, applications in the preparation of materials, synthesis and properties, environmental applications, and many others.

Significant experimental work is devoted to the preparation of one and zero dimensional semiconductor structures in view of future electronic and optical devices which involve quantum effects. The aim is good control in the realisation of nanometer structures both in vertical and lateral direction. Conventional processing techniques based on lithography face inherent problems such as limited resolution and surface defects caused by reactive ion etching. During the last few years several research groups started working on direct syntheses of semiconductor nanostructures by combining epitaxial growth techniques such as molecular beam epitaxy and chemical vapour deposition with pre patterning of the substrate wafers. Another idea is based on island formation in strained layer heteroepitaxy. Zero and one dimensional structures with dimensions down to a few atomic distances have been realised this way. An important point is that the size of the quantum structures is controlled within the epitaxial deposition in a self-adjusting process. The main subjects of the book are: Theoretical aspects of epitaxial growth, selfassembling nanostructures and cluster formation, epitaxial growth in tilted and non-(001) surfaces, cleaved edge overgrowth, nanostructure growth on patterned silicon substrates, nanostructures prepared by selective area epitaxy or growth on patterned substrates, in-situ etching and device applications based on epitaxial regrowth on patterned substrates. The experimental work mainly concentrated on GaAs/A1GaAs, GaAs/InGaAs, InGaP/InP and Si/SiGe based semiconductor heterostructures. Growth related problems received special attention. The different concepts for preparation of low dimensional structures are presented to allow direct comparison and to identify new concepts for future research work.

teacher Professor Ernst-Joachim Ivers to whom I still owe many insights 20 years after the end of his working life. This English edition is not an unedited translation of the German edition of 1990. The text has been substantially revised in some chapters, taking into account the literature published in the mean time. I wish to thank Dr.-Ing. H. Finken, Freiberg, who has prepared the translation from German into English with deep scientific understanding and in close contact with the author. I also wish to express my gratitude to Chapman & Hall for their support to this project without which the English edition could not have been published. Dr.-Ing. habil. C. Bernhardt Freiberg 1 Position, tasks and structure of particle size analysis Today the concept of particle size analysis is that of a special field of particle measurement technology, which in turn is part of particulate technology. This classification has developed over the last 20 years; it is the result of a scientific integration process taking place in many industrialized countries of the world. In recent years, the meaning and mutual connection of the related concepts as well as the tasks of the scientific disciplines designated by them have been the subject of intensive discussion which, however, has not led to a generally accepted terminology.

This book provides not only a comprehensive introduction to the subject, but also describes in details the many techniques which can be used. These cover the detection, sampling and analysis of particles and identify those most relevant to particular applications.

This work describes the different operational regimes and the dominant mechanisms of flows in disperse systems.

The fundamentals of wet classification are described and a scientific basis for solving classification is presented. For the practical engineer, there is an overview of the technical solutions available.

This volume chronicles the proceedings of the Third Symposium on Particles on Surfaces : Detection, Adhesion and Removal held as a part of the 21st Annual Meeting of the Fine Particle Society in San Diego , California, August 21 - 25 , 1990 . The first two symposia i n t h i s series were held in 1986 and 1988 , respectively, and have been properly l documented ,2. Li ke its antecedent s the Third symposium was very well received, and the continuing success of these symposia reinforced our earlier belief that regular symposia on the topic of particles on surfaces were very much needed. Concomitantly, the fourth symposium in this series is planned in Las Vegas , July 13-17 , 199 2 . l As pointed out in the Preface to the earlier two volumes ,2, the topic of particles on surfaces is of tremendous interest and concern in a wide spectrum of technological areas . The objectives of the Third symposium were es s ent i a l ly the same as those of the earlier two and our intent her e was to provide an update on the research and development activities in the world of particles on surfaces . Apropos , there has been a deliberate attempt every time to s eek out new people to present their research results and we have been very succes s f ul in this mission.

flour, potato starch, cracking catalyst, sand, and gravel, one will probably agree that the first four materials definitely are powders and the last one certainly is not. Whether one would call sand a powder probably depends on the partiele size and on personal Vlews. When the astronaut Neil Armstrong returned to the Earth from his trip on the surface of the Moon, he stated: 'The surface is fine and powdery. I can kick it up loosely with my toe. It does adhere in fine layers like powdered charcoal to the sole and inside of my boots. I only go in a small fraction of an inch, but I can see the footprints of my boots and the treads in the fine sandy partieles. ' These words elearly show that the behaviour of powders de pends on the circumstances. In wh at respects are those on the Moon different from those on the Earth? (1) The gravitational force on the surface of the Moon is only one-sixth of that on the Earth. (2) There is no gas on the Moon. The latter aspect means that any water brought there would evaporate and disappear immediately, hence powders on the Moon will always be perfect1y dry so that cohesion between the separate partieles due to liquid bridges will be zero.

Powder metallurgy, commonly designated by its initial letters asPM or PM, may be defined as the production of useful artefacts from metal powder without passing through the molten state. This introductory text examines the processes by which these powders are produced, and explores their behaviour in the subsequent consolidation stages. An outline of the sequence of operations following the manufacture of the powder in various forms is then described in the text. There are also selected case studies, details of porous PM components and wrought PM products, and other specialities.

An understanding ofthe properties and the handling characteristics of liquids and gases has long been regarded as an essential requirement for most practising engineers. It is therefore not surprising that, over the years, there has been a regular appearance of books dealing with the fundamentals of fluid mechanics, fluid flow, hydraulics and related topics. What is surprising is that there has been no parallel development of the related discipline of Bulk Solids Handling, despite its increasing importance in modern industry across the world. It is only very recently that a structured approach to the teaching, and learning, of the subject has begun to evolve. A reason for the slow emergence of Bulk Solids Handling as an accepted topic of study in academic courses on mechanical, agricultural, chemical, mining and civil engineering is perhaps that the practice is so often taken for granted. Certainly the variety of materials being handled in bulk is almost endless, ranging in size from fine dust to rocks, in value from refuse to gold, and in temperature from deep-frozen peas to near-molten metal.