Handbook of Modern Coating Technologies: Advanced Characterization Methods reviews advanced characterization methods of modern coating technologies. The topics in this volume consist of scanning vibrating electrode technique, spectroscopic ellipsometry, advances in X-ray diffraction, neutron reflectivity, micro- and nanoprobes, fluorescence technique, stress measurement methods in thin films, micropotentiometry, and localized corrosion studies.

Powder technology is a rapidly expanding technology and nowhere more than in particle characterization. There has been an explosion of new particle measuring techniques in the past ten year particularly in the field of on-line measurement. One of the main aims of this book is to bring the reader up-to-date with current practices. One important area of interest is the improvements in on-line light scattering instruments and the introduction of ultrasonic on-line devices. Another is the introduction of on-line microscopy, which permits shape analysis in conjunction with particle sizing.
Schools of powder technology are common in Europe and Japan but the importance of this subject has only recently been recognised in America with the emergence of the Particle Research Centre (PERC) at the University of Florida in Gainsville.
- Details all the latest developments in powder technology
- Written by established authority on powder technology
- A comprehensive text covering all aspects of powder technology and handling of particulate solids including characterization, handling and applications

This book covers the rich phenomenology exhibited by fine powders when they are fluidized by a gas flow. Fine powder cohesiveness leads to poor flowability, clumping, difficulty in fluidizing, irregular avalanching behavior, etc. Despite all the inconveniences, fine powder processes pervade the chemical, pharmaceutical, agricultural and mining industries among others. The author in this book analyzes the mechanism by which interparticle adhesive forces are reduced by means of surface additives. Different techniques have been developed in the last years to assist fluidization by helping the gas flow to mobilize and break cohesive aggregates, which help to homogenize fluidization. As reviewed in this book, the use of these techniques may have a relevant impact on novel processes based on fluidized beds of fine powder and with relevant applications on leading edge technologies such as Atomic Layer Deposition on nanoparticles and CO2 capture by gas-fluidized beds of adsorbent powders. The study of fluidized beds has a marked interdisciplinary character. This book is thus intended for academic and industrial researchers in applied physics, mechanical, chemical, and environmental engineering, who are interested in the special characteristics of fine powders.

Crystal structure analysis from powder diffraction data has attracted considerable and ever growing interest in the last decades. X-ray powder diffraction is best known for phase analysis (Hanawalt files) dating back to the 30s. In the late 60s the inherent potential of powder diffraction for crystallographic problems was realized and scientists developed methods for using powder diffraction data at first only for the refinement of crystal structures. With the development of ever growing computer power profile fitting and pattern decomposition allowed to extract individual intensities from overlapping diffraction peaks opening the way to many other applications, especially to ab initio structure determination.

Powder diffraction today is used in X-ray and neutron diffraction, where it is a powerful method in neutron diffraction for the determination of magnetic structures. In the last decade the interest has dramatically improved. There is hardly any field of crystallography where the Rietveld, or full pattern method has not been tried with quantitative phase analysis the most important recent application.

This monograph covers phenomena of deformation and machining of granular media: macroscopic particles of different size, shape, and surface properties which typically exhibit behavior similar to fluids, as well as the behavior of solids under deformation. The book analyses the behavior of granular media in soils, rocks and stones, metals and various synthetic materials, presenting a theoretical description, applications and understanding of basic phenomena in granular matter.

flour, potato starch, cracking catalyst, sand, and gravel, one will probably agree that the first four materials definitely are powders and the last one certainly is not. Whether one would call sand a powder probably depends on the partiele size and on personal Vlews. When the astronaut Neil Armstrong returned to the Earth from his trip on the surface of the Moon, he stated: 'The surface is fine and powdery. I can kick it up loosely with my toe. It does adhere in fine layers like powdered charcoal to the sole and inside of my boots. I only go in a small fraction of an inch, but I can see the footprints of my boots and the treads in the fine sandy partieles. ' These words elearly show that the behaviour of powders de pends on the circumstances. In wh at respects are those on the Moon different from those on the Earth? (1) The gravitational force on the surface of the Moon is only one-sixth of that on the Earth. (2) There is no gas on the Moon. The latter aspect means that any water brought there would evaporate and disappear immediately, hence powders on the Moon will always be perfect1y dry so that cohesion between the separate partieles due to liquid bridges will be zero.

An understanding ofthe properties and the handling characteristics of liquids and gases has long been regarded as an essential requirement for most practising engineers. It is therefore not surprising that, over the years, there has been a regular appearance of books dealing with the fundamentals of fluid mechanics, fluid flow, hydraulics and related topics. What is surprising is that there has been no parallel development of the related discipline of Bulk Solids Handling, despite its increasing importance in modern industry across the world. It is only very recently that a structured approach to the teaching, and learning, of the subject has begun to evolve. A reason for the slow emergence of Bulk Solids Handling as an accepted topic of study in academic courses on mechanical, agricultural, chemical, mining and civil engineering is perhaps that the practice is so often taken for granted. Certainly the variety of materials being handled in bulk is almost endless, ranging in size from fine dust to rocks, in value from refuse to gold, and in temperature from deep-frozen peas to near-molten metal.

Over half of the products of the chemical and process industries are sold in a particulate form. The range of such products is vast: from agrochemicals to pigments, from detergents to foods, from plastics to pharmaceuticals. However, surveys of the performance of processes designed to produce particulate products have consistently shown inadequate design and poor reliability. Particle technology' is a new subject facing new challenges. Chemical and process engineering is becoming less concerned with the design of plants to produce generic simple chemicals (which are often single phase fluids) and is now more concerned with speciality effect' chemicals which may often be in particulate form. Chemical and process engineers are also being recruited in increasing numbers into areas outside their tranditional fields, such as the food industry, pharmaceuticals and the manufacture of a wide variety of consumer products. This book has been written to meet their needs. It provides comprehensive coverage of the technology of particulate solids, in a form which is both accessible and concise enough to be useful to engineering and science students in the final year of an undergraduate degree, and at Master's level. Although it was written with students of chemical engineering in mind, it will also be of use and interest to students of other disciplines. It comprises an account of the fundamentals of teh subject, illustrated by worked examples, and followed by a wide range of selected applications.

Significant experimental work is devoted to the preparation of one and zero dimensional semiconductor structures in view of future electronic and optical devices which involve quantum effects. The aim is good control in the realisation of nanometer structures both in vertical and lateral direction. Conventional processing techniques based on lithography face inherent problems such as limited resolution and surface defects caused by reactive ion etching. During the last few years several research groups started working on direct syntheses of semiconductor nanostructures by combining epitaxial growth techniques such as molecular beam epitaxy and chemical vapour deposition with pre patterning of the substrate wafers. Another idea is based on island formation in strained layer heteroepitaxy. Zero and one dimensional structures with dimensions down to a few atomic distances have been realised this way. An important point is that the size of the quantum structures is controlled within the epitaxial deposition in a self-adjusting process. The main subjects of the book are: Theoretical aspects of epitaxial growth, selfassembling nanostructures and cluster formation, epitaxial growth in tilted and non-(001) surfaces, cleaved edge overgrowth, nanostructure growth on patterned silicon substrates, nanostructures prepared by selective area epitaxy or growth on patterned substrates, in-situ etching and device applications based on epitaxial regrowth on patterned substrates. The experimental work mainly concentrated on GaAs/A1GaAs, GaAs/InGaAs, InGaP/InP and Si/SiGe based semiconductor heterostructures. Growth related problems received special attention. The different concepts for preparation of low dimensional structures are presented to allow direct comparison and to identify new concepts for future research work.

teacher Professor Ernst-Joachim Ivers to whom I still owe many insights 20 years after the end of his working life. This English edition is not an unedited translation of the German edition of 1990. The text has been substantially revised in some chapters, taking into account the literature published in the mean time. I wish to thank Dr.-Ing. H. Finken, Freiberg, who has prepared the translation from German into English with deep scientific understanding and in close contact with the author. I also wish to express my gratitude to Chapman & Hall for their support to this project without which the English edition could not have been published. Dr.-Ing. habil. C. Bernhardt Freiberg 1 Position, tasks and structure of particle size analysis Today the concept of particle size analysis is that of a special field of particle measurement technology, which in turn is part of particulate technology. This classification has developed over the last 20 years; it is the result of a scientific integration process taking place in many industrialized countries of the world. In recent years, the meaning and mutual connection of the related concepts as well as the tasks of the scientific disciplines designated by them have been the subject of intensive discussion which, however, has not led to a generally accepted terminology.

This volume chronicles the proceedings of the Third Symposium on Particles on Surfaces : Detection, Adhesion and Removal held as a part of the 21st Annual Meeting of the Fine Particle Society in San Diego , California, August 21 - 25 , 1990 . The first two symposia i n t h i s series were held in 1986 and 1988 , respectively, and have been properly l documented ,2. Li ke its antecedent s the Third symposium was very well received, and the continuing success of these symposia reinforced our earlier belief that regular symposia on the topic of particles on surfaces were very much needed. Concomitantly, the fourth symposium in this series is planned in Las Vegas , July 13-17 , 199 2 . l As pointed out in the Preface to the earlier two volumes ,2, the topic of particles on surfaces is of tremendous interest and concern in a wide spectrum of technological areas . The objectives of the Third symposium were es s ent i a l ly the same as those of the earlier two and our intent her e was to provide an update on the research and development activities in the world of particles on surfaces . Apropos , there has been a deliberate attempt every time to s eek out new people to present their research results and we have been very succes s f ul in this mission.

Emerging Fields in Sol-gel Science and Technology contains selected papers from the symposium on "Sol-Gel and Vitreous Materials and Applications" held during the International Materials Research Congress in Cancun, Mexico in August 2002. One hundred and twenty researchers representing 10 countries attended this symposium.

Some of the subjects covered in this symposium include 1.) synthesis of new materials endowed with outstanding and non-conventional optical, magnetic, electrical, thermal, catalytic, and mechanical properties; 2.) study of the sorption properties of model porous materials in order to test the validity of previous and recent theories; 3.) theoretical studies related to density functional theory, fractal and scaling law approaches, 4.) synthesis of biomaterials for use in medicine and pollution control; 5.) application of sol-gel colloids in the fine-chemistry industry in products such as fragrances and pharmaceuticals; 6.) development of special vitreous materials; 7.) implementation of inorganic thin films, and 8.) synthesis of materials for energy saving. "

Optical particle s1z1ng is undoubtedly a fascinating field of research of the utmost practical importance. In the Universe fluids are nearly everywhere, and when they occur they almost invariably contain particles. Inside our bodies we can take the example of blood transporting a vi tal procession of red and white cells. Around us, we can find various particles in the air we breathe, bubbles in the champagne or the soda we drink, or natural and artificial (polluting ) particles in the lakes we swim in. Industrial processes and systems are also concerned with particles, from pulverized coal flames to fluidized beds, in a range of applications involving rocket exhausts, pneuma tic transport and more generally the infinite realm of mul tiphase situations. Such an obviously vast field would require a whole volume like this one merely to attempt to describe it superficially. To be sure, we would need a scientific Prevert to catalogue such an endless inventory. Finally, even outside our terrestrial spaceship particles can be detected in alien atmospheres or between stars. Theorists will enjoy analyzing the richness of light/particle interact. ion, a subject which is very far from being exhausted. Experimental researchers will love designing and studying various probing instruments with a laser source at the input and a computer at the output, two requisites of today' s technological revolution.

Many industrial, power generation and chemical processes produce unwanted fine particulate material as a consequence of their operation. Electrostatic precipitation is a highly efficient method of removing entrained particulate contaminants from exhaust gases and is extensively used in these industries to limit particulate emissions. New legislation aimed at improving the environment by further limiting these discharges has resulted in the technique undergoing considerable development over the past decade, to the point where it has become the method of choice, over a wide range of applications, for limiting particulate discharges. In this new book, the editor has brought together an international team of contributors, mainly industrialists and consultants, to produce an authorative and practical guide to electrostatic precipitation. This book is of interest to all those in process industries or power generation and to academics concerned with gas cleaning and environmental issues.

This introductory text develops the fundamental physics of the behavior of granular materials. It covers the basic properties of flow, friction, and fluidization of uniform granular materials; discusses mixing and segregation of heterogeneous materials (the famous "brazil-nut problem"); and concludes with an introduction to numerical models. The presentation begins with simple experiments and uses their results to build concepts and theorems about materials whose behavior is often quite counter-intuitive; presenting in a unified way the background needed to understand current work in the field. Developed for students at the University of Paris, the text will be suitable for advanced undergraduates and beginning graduates; while also being of interest to researchers and engineers just entering the field.

This book provides not only a comprehensive introduction to the subject, but also describes in details the many techniques which can be used. These cover the detection, sampling and analysis of particles and identify those most relevant to particular applications.

This is the fifth edition of the highly successful work first published in 1968, comprising two definitive volumes on particle characterisation. The first volume is devoted to sampling and particle size measurement, while surface area and pore size determination are reviewed in volume 2. Particle size and characterisation are central to understanding powder properties and behaviour. This book describes numerous potential measuring devices, how they operate and their advantages and disadvantages. It comprise a fully comprehensive treatise on the wide range of available equipment with an extensive literature survey, and a list of manufacturers and suppliers. The author's blend of academic and industrial experience results in a readable technical book with information on how to analyse, present, and extract useful information from data. This is an essential reference book for both industrial and academic research workers in a variety of areas including: pharmaceuticals, food science, pollution analysis and control, electronic materials, agricultural products, polymers, pigments and chemicals.

Fine Particles Science and Technology deals with the preparation, characterization and technological applications of monodisperse particles in the micro to nano size range. A broad view of this frontier field is given, covering understanding the mechanisms by which uniform fine particles are formed and the search for new processes; the mechanism of the precipitation technique, requiring knowledge of the relationship between the complex solution chemistry and the products formed; the sequence of events leading to the formation of monodisperse colloids. The following topics are presented: microparticles, nanoparticles, applications in the preparation of materials, synthesis and properties, environmental applications, and many others.

The interest in control of particulate processes has been triggered by the need to achieve tight distributed control of size distributions that greatly influence particulate product properties and quality. Drawing from recent advances in dynamics of infinite-dimensional systems and nonlinear control theory, control of particulate processes using population balances has evolved into a very active research area within the field of process control. This book - the first of its kind - presents general methods for the synthesis of nonlinear, robust and constrained feedback controllers for broad classes of particulate process models and illustrates their applications to industrially-important crystallization, aerosol and thermal spray processes. The controllers use a finite number of measurement sensors and control actuators to achieve stabilization of the closed-loop system, output tracking, attenuation of the effect of model uncertainty and handling of actuator saturation.
Beginning with an introduction to control of particulate processes, the book discusses nonlinear order reduction and nonlinear, robust and constrained control of particulate spatially-homogeneous processes, and nonlinear control of spatially-homogeneous particulate processes. The synthesis of the controllers is performed by using geometric and Lyapunov-based control techniques. The book includes comparisons of the methods followed for controller synthesis with other approaches and discussions of practical implementation issues that can help researchers and engineers understand the development and application of the methods in greater depth. The methods are applied to continuous and batch crystallization processes, atitania aerosol reactor and a thermal spray process to regulate product size distribution. The resulting benefits in closed-loop performance, robustness and actuator saturation handling compared to other techniques for control of particulate processes are demonstrated through computer simulations.
The book assumes a basic knowledge about population balances and nonlinear control.
Researchers and graduate students in process control, particle technology and control systems theory, applied mathematicians and process control engineers will find this book a useful resource.

The operation of a powder mixer requires a knowledge not only of the mixing mechanisms but of the physical properties of the powders being mixed. Powder Mixing is unique in that it explores the relevant physics of the powder systems including characterization procedures and rheology, and contains an extensive review of different methods that have been employed to study the structure of mixtures. The techniques for achieving structured mixtures such as microencapsulation, and recent developments in deterministic chaos theory and fractal geometry as applied to the study of powder mixing systems, are reviewed. In particular, new techniques for studying the mixing powders based on avalanching theory and critically self-organized systems are studied. These are followed by a review of the wide range of different mixers commercially available and an extensive bibliography. Powder Mixing is an essential reference for all those interested in the basic science of powder mixing and the availability of industrial systems to achieve a mixture of different kinds. The main emphasis of the text is on working principles and operative systems, and is suitable for industrial workers, chemical engineers and students alike.

Chemistry of Powder Production focuses on the solid-state chemistry of powder materials and relates this to the structure, properties and preparation, and characterization techniques for these important industrial products. Additionally, the properties of the particles are discussed in relation to their surface structure and characteristics. This book describes the fundamentals of statistical methods for measuring the characteristics of particles. New advanced materials being developed in powder technology manufacturing techniques are also emphasised, including powdered materials for advanced ceramics as well as magnetic and pigment materials.

It is difficult to imagine modem technology without small particles, 1-1000 nm in size, because virtually every industry depends in some way on the use of such materials. Catalysts, printing inks, paper, dyes and pigments, many medicinal products, adsorbents, thickening agents, some adhesives, clays, and hundreds of other diverse products are based on or involve small particles in a very fundamental way. In some cases finely divided materials occur naturally or are merely a convenient form for using a material. In most cases small particles play a special role in technology because in effect they constitute a different state of matter because of the basic fact that the surface of a material is different from the interior by virtue of the unsaturated bonding interactions of the outermost layers of atoms at the surface of a solid. Whereas in a macroscale particle these differences are often insignificant, as the 9 surface area per unit mass becomes larger by a factor of as much as 10, physical and chemical effects such as adsorption become so pronounced as to make the finely divided form of the bulk material into essentially a different material usually one that has no macroscale counterpart."

Powder technology is extremely important to a wide range of disciplines and industries including food, pharmaceutical manufacturing, minerals and metals processing, among others. Modeled after a short course designed specifically for graduate engineers working in industry, it presents the fundamental engineering properties of materials--essential knowledge for the design and operation of industrial equipment and processes. Contributors--all experts in their fields--provide comprehensive coverage, with a somewhat academic emphasis on the problems involved in handling massive solids, gases and liquids as industry calls for greater expertise in this field.

This is the fifth edition of the highly successful work first published in 1968, comprising two definitive volumes on particle characterisation. The first volume is devoted to sampling and particle size measurement, while surface area and pore size determination are reviewed in volume 2. Particle size and characterisation are central to understanding powder properties and behaviour. This book describes numerous potential measuring devices, how they operate and their advantages and disadvantages. It comprise a fully comprehensive treatise on the wide range of available equipment with an extensive literature survey, and a list of manufacturers and suppliers. The author's blend of academic and industrial experience results in a readable technical book with information on how to analyse, present, and extract useful information from data. This is an essential reference book for both industrial and academic research workers in a variety of areas including: pharmaceuticals, food science, pollution analysis and control, electronic materials, agricultural products, polymers, pigments and chemicals.