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Books > Science & Mathematics > Physics > Thermodynamics & statistical physics
This book presents the statistical theory of complex wave scattering and quantum transport in physical systems which have chaotic classical dynamics, as in the case of microwave cavities and quantum dots, or which possess quenched randomness, as in the case of disordered conductors - with an emphasis on mesoscopic fluctuations. The statistical regularity of the phenomena is revealed in a natural way by adopting a novel maximum-entropy approach. Shannon's information entropy is maximised, subject to the symmetries and constraints which are physically relevant, within the powerful and non-perturbative theory of random matrices; this is a most distinctive feature of the book. Aiming for a self-contained presentation, the quantum theory of scattering, set in the context of quasi-one-dimensional, multichannel systems, and related directly to scattering problems in mesoscopic physics, is introduced in chapters two and three. The linear-response theory of quantum electronic transport, adapted to the context of mesoscopic systems, is discussed in chapter four. These chapters, together with chapter five on the maximum-entropy approach and chapter eight on weak localization, have been written in a most pedagogical style, suitable for use on graduate courses. In chapters six and seven, the problem of electronic transport through classically chaotic cavities and quasi-one-dimensional disordered systems is discussed. Many exercises are included, most of which are worked through in detail, aiding graduate students, teachers, and research scholars interested in the subject of quantum transport through disordered and chaotic systems.
This volume contains papers based on presentations at the "Nagoya Winter Workshop 2015: Reality and Measurement in Algebraic Quantum Theory (NWW 2015)", held in Nagoya, Japan, in March 2015. The foundations of quantum theory have been a source of mysteries, puzzles, and confusions, and have encouraged innovations in mathematical languages to describe, analyze, and delineate this wonderland. Both ontological and epistemological questions about quantum reality and measurement have been placed in the center of the mysteries explored originally by Bohr, Heisenberg, Einstein, and Schroedinger. This volume describes how those traditional problems are nowadays explored from the most advanced perspectives. It includes new research results in quantum information theory, quantum measurement theory, information thermodynamics, operator algebraic and category theoretical foundations of quantum theory, and the interplay between experimental and theoretical investigations on the uncertainty principle. This book is suitable for a broad audience of mathematicians, theoretical and experimental physicists, and philosophers of science.
This classic text provides an excellent introduction to a new and rapidly developing field of research. Now well established as a textbook in this rapidly developing field of research, the new edition is much enlarged and covers a host of new results.
Starting from a broad overview of heat transport based on the Boltzmann Transport Equation, this book presents a comprehensive analysis of heat transport in bulk and nanomaterials based on a kinetic-collective model (KCM). This has become key to understanding the field of thermal transport in semiconductors, and represents an important stride. The book describes how heat transport becomes hydrodynamic at the nanoscale, propagating very much like a viscous fluid and manifesting vorticity and friction-like behavior. It introduces a generalization of Fourier's law including a hydrodynamic term based on collective behavior in the phonon ensemble. This approach makes it possible to describe in a unifying way recent experiments that had to resort to unphysical assumptions in order to uphold the validity of Fourier's law, demonstrating that hydrodynamic heat transport is a pervasive type of behavior in semiconductors at reduced scales.
This volume collects ten surveys on the modeling, simulation, and applications of active particles using methods ranging from mathematical kinetic theory to nonequilibrium statistical mechanics. The contributing authors are leading experts working in this challenging field, and each of their chapters provides a review of the most recent results in their areas and looks ahead to future research directions. The approaches to studying active matter are presented here from many different perspectives, such as individual-based models, evolutionary games, Brownian motion, and continuum theories, as well as various combinations of these. Applications covered include biological network formation and network theory; opinion formation and social systems; control theory of sparse systems; theory and applications of mean field games; population learning; dynamics of flocking systems; vehicular traffic flow; and stochastic particles and mean field approximation. Mathematicians and other members of the scientific community interested in active matter and its many applications will find this volume to be a timely, authoritative, and valuable resource.
Natural phenomena consist of simultaneously occurring transport processes and chemical reactions. These processes may interact with each other and may lead to self-organized structures, fluctuations, instabilities, and evolutionary systems. "Nonequilibrium Thermodynamics, 3rd edition" emphasizes the unifying role of thermodynamics in analyzing the natural phenomena. This third edition updates and expands on the first and second editions by focusing on the general balance equations for coupled processes of physical, chemical, and biological systems. The new edition contains a new chapter on stochastic approaches to include the statistical thermodynamics, mesoscopic nonequilibrium thermodynamics, fluctuation theory, information theory, and modeling the coupled biochemical systems in thermodynamic analysis. This new addition also comes with more examples and practice problems.
Features twenty-five chapter contributions from an international array of distinguished academics based in Asia, Eastern and Western Europe, Russia, and the USA. This multi-author contributed volume provides an up-to-date and authoritative overview of cutting-edge themes involving the thermal analysis, applied solid-state physics, micro- and nano-crystallinity of selected solids and their macro- and microscopic thermal properties. Distinctive chapters featured in the book include, among others, calorimetry time scales from days to microseconds, glass transition phenomena, kinetics of non-isothermal processes, thermal inertia and temperature gradients, thermodynamics of nanomaterials, self-organization, significance of temperature and entropy. Advanced undergraduates, postgraduates and researchers working in the field of thermal analysis, thermophysical measurements and calorimetry will find this contributed volume invaluable. This is the third volume of the triptych volumes on thermal behaviour of materials; the previous two receiving thousand of downloads guaranteeing their worldwide impact.
Maximum Dissipation: Non-Equilibrium Thermodynamics and its Geometric Structure explores the thermodynamics of non-equilibrium processes in materials. The book develops a general technique created in order to construct nonlinear evolution equations describing non-equilibrium processes, while also developing a geometric context for non-equilibrium thermodynamics. Solid materials are the main focus in this volume, but the construction is shown to also apply to fluids. This volume also: * Explains the theory behind thermodynamically-consistent construction of non-linear evolution equations for non-equilibrium processes * Provides a geometric setting for non-equilibrium thermodynamics through several standard models, which are defined as maximum dissipation processes * Emphasizes applications to the time-dependent modeling of soft biological tissue Maximum Dissipation: Non-Equilibrium Thermodynamics and its Geometric Structure will be valuable for researchers, engineers and graduate students in non-equilibrium thermodynamics and the mathematical modeling of material behavior.
This book provides deep insight into the physical quantity known as chemical activity. The author probes deep into classical thermodynamics in Part I, and then into statistical thermodynamics in Part II, to provide the necessary background. The treatment has been streamlined by placing some background material in appendices. Chemical Activity is of interest not only to those in chemical thermodynamics, but also to chemical engineers working with mass transfer and its applications - for example, separation methods.
This thesis reveals how the feedback trap technique, developed to trap small objects for biophysical measurement, could be adapted for the quantitative study of the thermodynamic properties of small systems. The experiments in this thesis are related to Maxwell's demon, a hypothetical intelligent, "neat fingered" being that uses information to extract work from heat, apparently creating a perpetual-motion machine. The second law of thermodynamics should make that impossible, but how? That question has stymied physicists and provoked debate for a century and a half. The experiments in this thesis confirm a hypothesis proposed by Rolf Landauer over fifty years ago: that Maxwell's demon would need to erase information, and that erasing information-resetting the measuring device to a standard starting state-requires dissipating as much energy as is gained. For his thesis work, the author used a "feedback trap" to study the motion of colloidal particles in "v irtual potentials" that may be manipulated arbitrarily. The feedback trap confines a freely diffusing particle in liquid by periodically measuring its position and applying an electric field to move it back to the origin.
Low Grade Heat Driven Multi-effect Distillation and Desalination describes the development of advanced multi-effect evaporation technologies that are driven by low grade sensible heat, including process waste heat in refineries, heat rejection from diesel generators or microturbines, and solar and geothermal energy. The technologies discussed can be applied to desalination in remote areas, purifying produced water in oil-and-gas industries, and to re-concentrate process liquor in refineries. This book is ideal for researchers, engineering scientists, graduate students, and industrial practitioners working in the desalination, petrochemical, and mineral refining sectors, helping them further understand the technologies and opportunities that relate to their respective industries. For researchers and graduate students, the core enabling ideas in the book will provide insights and open up new horizons in thermal engineering.
The author introduces the supersymmetric localization technique, a new approach for computing path integrals in quantum field theory on curved space (time) defined with interacting Lagrangian. The author focuses on a particular quantity called the superconformal index (SCI), which is defined by considering the theories on the product space of two spheres and circles, in order to clarify the validity of so-called three-dimensional mirror symmetry, one of the famous duality proposals. In addition to a review of known results, the author presents a new definition of SCI by considering theories on the product space of real-projective space and circles. In this book, he explains the concept of SCI from the point of view of quantum mechanics and gives localization computations by reducing field theoretical computations to many-body quantum mechanics. He applies his new results of SCI with real-projective space to test three-dimensional mirror symmetry, one of the dualities of quantum field theory. Real-projective space is known to be an unorientable surface like the Mobius strip, and there are many exotic effects resulting from Z2 holonomy of the surface. Thanks to these exotic structures, his results provide completely new evidence of three-dimensional mirror symmetry. The equivalence expected from three-dimensional mirror symmetry is transformed into a conjectural non-trivial mathematical identity through the new SCI, and he performs the proof of the identity using a q-binomial formula.
This book investigates the common nature of granular and active systems, which is rooted in their intrinsic out-of-equilibrium behavior, with the aim of finding minimal models able to reproduce and predict the complex collective behavior observed in experiments and simulations. Granular and active matter are among the most studied systems in out-of-equilibrium statistical physics. The book guides readers through the derivation of a fluctuating hydrodynamic description of granular and active matter by means of controlled and transparent mathematical assumptions made on a lattice model. It also shows how a macroscopic description can be provided from microscopic requirements, leading to the prediction of collective states such as cooling, swarming, clustering and the transitions among them. The analytical and numerical results shed new light on the physical connection between the local, microscopic properties of few particles and the macroscopic collective motion of the whole system.
This book is about dark matter's particle nature and the implications of a new symmetry that appears when a hypothetical dark matter particle is heavy compared to known elementary particles. Dark matter exists and composes about 85% of the matter in the universe, but it cannot be explained in terms of the known elementary particles. Discovering dark matter's particle nature is one of the most pressing open problems in particle physics. This thesis derives the implications of a new symmetry that appears when the hypothetical dark matter particle is heavy compared to the known elementary particles, a situation which is well motivated by the null results of searches at the LHC and elsewhere. The new symmetry predicts a universal interaction between dark matter and ordinary matter, which in turn may be used to determine the event rate and detectable energy in dark matter direct detection experiments. The computation of heavy wino and higgsino dark matter presented in this work has become a benchmark for the field of direct detection. This thesis has also spawned a new field of investigation in dark matter indirect detection, determining heavy WIMP annihilation rates using effective field theory methods. It describes a new formalism for implementing Lorentz invariance constraints in nonrelativistic theories, with a surprising result at 1/M^4 order that contradicts the prevailing ansatz in the past 20 years of heavy quark literature. The author has also derived new perturbative QCD results to provide the definitive analysis of key Standard Model observables such as heavy quark scalar matrix elements of the nucleon. This is an influential thesis, with impacts in dark matter phenomenology, field theory formalism and precision hadronic physics.
This volume looks afresh at the life and works of Lord Kelvin including his standing and relationships with Charles Darwin, T. S Huxley and the X-club, thereby throwing new light on the nineteenth-century conflict between the British energy and biology specialists. It focuses on two principal issues. Firstly, there is the contribution made by Kelvin to the formulation of the Laws of Thermodynamics, both personal and in the content of the scientific communications exchanged with other workers, such as Joule and Clausius. Secondly, there is Kelvin's impact on the wider field of science such as thermoelectricity and geology (determination of the age of the earth). Of late a number of studies and initiatives, including the Centenary celebrations of Kelvin's death and exhibits such as that of the 'Revolutionary Scientist' in the Hunterian Museum, Glasgow, have been undertaken aiding the redefinition of Kelvin's greatness and achievements. The book also raises awareness to 'improve our approach to the teaching of elementary thermodynamics by attempting to empathise with Kelvin's perspective'.It is completed by a full biography, overviews of various monuments to his memory, and short 'Stories in Pictures' on the Atlantic cable, Maxwell's Demon, the universities associated with the development of thermodynamics and the Royal Society of Edinburgh. Scientists and engineers with an interest in thermodynamics and anyone interested in the work of Lord Kelvin will find benefit in Kelvin, Thermodynamics and the Natural World.
Perturbative Algebraic Quantum Field Theory (pAQFT), the subject of this book, is a complete and mathematically rigorous treatment of perturbative quantum field theory (pQFT) that doesn't require the use of divergent quantities and works on a large class of Lorenzian manifolds. We discuss in detail the examples of scalar fields, gauge theories and the effective quantum gravity. pQFT models describe a wide range of physical phenomena and have remarkable agreement with experimental results. Despite this success, the theory suffers from many conceptual problems. pAQFT is a good candidate to solve many, if not all, of these conceptual problems. Chapters 1-3 provide some background in mathematics and physics. Chapter 4 concerns classical theory of the scalar field, which is subsequently quantized in chapters 5 and 6. Chapter 7 covers gauge theory and chapter 8 discusses effective quantum gravity. The book aims to be accessible to researchers and graduate students, who are interested in the mathematical foundations of pQFT.
This book presents Markov and quantum processes as two sides of a coin called generated stochastic processes. It deals with quantum processes as reversible stochastic processes generated by one-step unitary operators, while Markov processes are irreversible stochastic processes generated by one-step stochastic operators. The characteristic feature of quantum processes are oscillations, interference, lots of stationary states in bounded systems and possible asymptotic stationary scattering states in open systems, while the characteristic feature of Markov processes are relaxations to a single stationary state. Quantum processes apply to systems where all variables, that control reversibility, are taken as relevant variables, while Markov processes emerge when some of those variables cannot be followed and are thus irrelevant for the dynamic description. Their absence renders the dynamic irreversible. A further aim is to demonstrate that almost any subdiscipline of theoretical physics can conceptually be put into the context of generated stochastic processes. Classical mechanics and classical field theory are deterministic processes which emerge when fluctuations in relevant variables are negligible. Quantum mechanics and quantum field theory consider genuine quantum processes. Equilibrium and non-equilibrium statistics apply to the regime where relaxing Markov processes emerge from quantum processes by omission of a large number of uncontrollable variables. Systems with many variables often self-organize in such a way that only a few slow variables can serve as relevant variables. Symmetries and topological classes are essential in identifying such relevant variables. The third aim of this book is to provide conceptually general methods of solutions which can serve as starting points to find relevant variables as to apply best-practice approximation methods. Such methods are available through generating functionals. The potential reader is a graduate student who has heard already a course in quantum theory and equilibrium statistical physics including the mathematics of spectral analysis (eigenvalues, eigenvectors, Fourier and Laplace transformation). The reader should be open for a unifying look on several topics.
This book describes and systemizes analytical and numerical solutions for a broad range of instantaneous and continuous, stationary and moving, concentrated and distributed, 1D, 2D and 3D heat sources in semi-infinite bodies, thick plane layers, thin plates and cylinders under various boundary conditions. The analytical solutions were mainly obtained by the superimposing principle for various parts of the proposed 1D, 2D and 3D heat sources and based on the assumption that only heat conduction plays a major role in the thermal analysis of welds. Other complex effects of heat transfer in weld phenomena are incorporated in the solutions by means of various geometrical and energetic parameters of the heat source. The book is divided into 13 chapters. Chapter 1 briefly reviews various welding processes and the energy characteristics of welding heat sources, while Chapter 2 covers the main thermophysical properties of the most commonly used alloys. Chapter 3 describes the physical fundamentals of heat conduction during welding, and Chapter 4 introduces several useful methods for solving the problem of heat conduction in welding. Chapters 5 and 6 focus on the derivation of analytical solutions for many types of heat sources in semi-infinite bodies, thick plane layers, thin plates and cylinders under various boundary conditions. The heat sources can be instantaneous or continuous, stationary or moving, concentrated or distributed (1D, 2D or 3D). In Chapter 7 the temperature field under programmed heat input (pulsed power sources and weaving sources) is analyzed. In turn, Chapters 8 and 9 cover the thermal cycle, melting and solidification of the base metal. Heating and melting of filler metal are considered in Chapter 10. Chapter 11 addresses the formulation and solution of inverse heat conduction problems using zero-, first- and second-order algorithms, while Chapter 12 focuses on applying the solutions developed here to the optimization of welding conditions. In addition, case studies confirm the usefulness and feasibility of the respective solutions. Lastly, Chapter 13 demonstrates the prediction of local microstructure and mechanical properties of welded joint metals, while taking into account their thermal cycle. The book is intended for all researches, welding engineers, mechanical design engineers, research engineers and postgraduate students who deal with problems such as microstructure modeling of welds, analysis of the mechanical properties of welded metals, weldability, residual stresses and distortions, optimization of welding and allied processes (prewelding heating, cladding, thermal cutting, additive technologies, etc.). It also offers a useful reference guide for software engineers who are interested in writing application software for simulating welding processes, microstructure modeling, residual stress analysis of welds, and for robotic-welding control systems.
The aim of this book is to give a physical treatment of the kinetic theory of gases and magnetoplasmas, covering the standard material in as simple a way as possible, using mean-free-path arguments when possible and identifying problem areas where received theory has either failed or has fallen short of expectations. Examples are provided by strong shock waves, ultrasonic waves (high Knudsen numbers), and transport across strong magnetic fields. Examples of problem areas provided by strong shock waves, ultrasonic waves (high Knudsen numbers), and transport across strong magnetic fields. One of the paradoxes arising in kinetic theory concerns the fluid pressure. Collisions are necessary for a fluid force to result, yet standard kinetic theory does not entail this, being satisfied to bypass Newton's equations by defining pressure as a momentum flux. This omission usually has no adverse consequences, but with increasing Knudsen number, it leads to errors. This text pays particular attention to pressure, explaining the importance of allowing for its collisional nature from the outset in developing kinetic theory.
This book provides detailed calculated values for the thermal radiative and thermodynamic functions of black-body radiation in finite spectral ranges. The results are presented in tabular form. The areas of thermal power generation, infrared medical diagnostics, solar power and nuclear generation, and astrophysics are included. A range of the thermal radiative and thermodynamic functions are calculated by the authors in the finite frequency/wavenumber/wavelength intervals at different temperatures. This book also contains the tables of the chromaticity coordinates and RGB parameters calculated for different color spaces (Rec.709 (HDTV), sRGB, Adobe RGB). A number of the optimization problems is formulated and solved for various thermal black-body radiative and thermodynamic functions in a finite range of frequencies.
The monograph compares two approaches that describe the statistical stability phenomenon - one proposed by the probability theory that ignores violations of statistical stability and another proposed by the theory of hyper-random phenomena that takes these violations into account. There are five parts. The first describes the phenomenon of statistical stability. The second outlines the mathematical foundations of probability theory. The third develops methods for detecting violations of statistical stability and presents the results of experimental research on actual processes of different physical nature that demonstrate the violations of statistical stability over broad observation intervals. The fourth part outlines the mathematical foundations of the theory of hyper-random phenomena. The fifth part discusses the problem of how to provide an adequate description of the world. The monograph should be interest to a wide readership: from university students on a first course majoring in physics, engineering, and mathematics to engineers, post-graduate students, and scientists carrying out research on the statistical laws of natural physical phenomena, developing and using statistical methods for high-precision measurement, prediction, and signal processing over broad observation intervals. To read the book, it is sufficient to be familiar with a standard first university course on mathematics.
This work sheds new light on fundamental aspects of phase separation in polymer-blend thin films. A key feature underlying the theoretical models is the unification of one-dimensional thermodynamic phase equilibria with film evolution phenomena in two- and three dimensions. Initially, an established 'phase portrait' method, useful for visualising and calculating phase equilibria of polymer-blend films, is generalised to systems without convenient simplifying symmetries. Thermodynamic equilibria alone are then used to explain a film roughening mechanism in which laterally coexisting phases can have different depths in order to minimise free energy. The phase portraits are then utilised to demonstrate that simulations of lateral phase separation via a transient wetting layer, which conform very well with experiments, can be satisfactorily explained by 1D phase equilibria and a 'surface bifurcation' mechanism. Lastly, a novel 3D model of coupled phase separation and dewetting is developed, which demonstrates that surface roughening shadows phase separation in thin films.
This monograph investigates violations of statistical stability of physical events, variables, and processes and develops a new physical-mathematical theory taking into consideration such violations - the theory of hyper-random phenomena. There are five parts. The first describes the phenomenon of statistical stability and its features, and develops methods for detecting violations of statistical stability, in particular when data is limited. The second part presents several examples of real processes of different physical nature and demonstrates the violation of statistical stability over broad observation intervals. The third part outlines the mathematical foundations of the theory of hyper-random phenomena, while the fourth develops the foundations of the mathematical analysis of divergent and many-valued functions. The fifth part contains theoretical and experimental studies of statistical laws where there is violation of statistical stability. The monograph should be of particular interest to engineers and scientists in general who study the phenomenon of statistical stability and use statistical methods for high-precision measurements, prediction, and signal processing over long observation intervals.
This book provides state-of-the-art computational approaches for accelerating materials discovery, synthesis, and processing using thermodynamics and kinetics. The authors deliver an overview of current practical computational tools for materials design in the field. They describe ways to integrate thermodynamics and kinetics and how the two can supplement each other. |
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