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Experimental and Kinetic Modeling Study of Cyclohexane and Its Mono-alkylated Derivatives Combustion (Hardcover, 1st ed. 2018)
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Experimental and Kinetic Modeling Study of Cyclohexane and Its Mono-alkylated Derivatives Combustion (Hardcover, 1st ed. 2018)
Series: Springer Theses
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This thesis investigates the combustion chemistry of cyclohexane,
methylcyclohexane, and ethylcyclohexane on the basis of
state-of-the-art synchrotron radiation photoionization mass
spectrometry experiments, quantum chemistry calculations, and
extensive kinetic modeling. It explores the initial decomposition
mechanism and distribution of the intermediates, proposes a novel
formation mechanism of aromatics, and develops a detailed kinetic
model to predict the three cycloalkanes' combustion properties
under a wide range of conditions. Accordingly, the thesis provides
an essential basis for studying much more complex cycloalkanes in
transport fuels and has applications in engine and fuel design, as
well as emission control.
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