In the high energy gas flows, associating high velocities and high temperatures, physical and chemical processes such as molecular vibrational excitation, dissociation, ionisation or various reactions take palce and deeply influence the structure of the flows. The characteristic times of these processes have the same order of magnitude as aerodynamic characteristic times so that these reactive media are generally in thermodynamic and chemical non-equilibrium. This book presents a general introductory study of these media. In the first part their fundamental statistical aspects are described, starting from their discrete structure and taking into account the interactions between elementary particles: the transport phenomena, relaxation and kinetics as well as their coupling are thus analysed and illustrated by many examples. The second part deals with the macroscopic re-entry bodies. Finally the experimental aspects of these flows, their simulations in shock tube and shock tunnel are described as well as their application, particularly in the aero- spatial domain.
This book is intended for researchers and students that have acquired basic knowledge in thermodynamics, statistical physics and fluid mechanics. It must also interest the engineers engaged in research and industry related to the applications of the reactive flows, in particular in the aerospace field and, more generally, all the researchers trying to simulate and calculate complex reactive flows.

It was not until 1971 that the authority for defining scientific units, the General Conference of Weights and Measures got around to defining the unit that is the basis of chemistry (the mole, or the quantity of something). Yet for all this tardiness in putting the chemical sciences on a sound quantitative basis, chemistry is an old and venerable subject and one naturally asks the question, why? Well, the truth is that up until the mid-1920s, many physicists did not believe in the reality of molecules. Indeed, it was not until after the physics community had accepted Ernest Rutherford's 1913 solar-system-like model of the atom, and the quantum mechanical model of the coupling of electron spins in atoms that physicists started to take seriously the necessity of explaining the chemical changes that chemists had been observing, investigating and recording since the days of the alchemists.

The book provides an integrated energy/exergy analysis method to identify the energy utilization issues and systematically propose the cost-effective energy-saving and CO2 mitigation/capture solution. There is a strong market needs on energy-saving and greenhouse gas (GHG) reduction. CO2 mitigation/capture will achieve economic benefit of fuel, power, and carbon tax saving as well as environmental GHG reduction. The book is a professional book for energy-saving and GHG gas mitigation technology in oil & gas, oil refining, and chemical industry. It is an integrated technical book that combines energy utilization theory and practical method, including: thermodynamic analysis for unit operation and process units; energy and exergy calculation for various process streams and utilities; three-link energy/exergy analysis model; energy/exergy balance of equipment, process units, and entire plant; approach and technology of energy saving; optimization of pipeline and equipment; pinch energy-saving technology and its application; CO2 capture and utilization with 8 case studies incorporated for all different scenarios; key energy-saving technologies such gas turbine, FCCU regeneration CO combustion and energy recovery, flue gas turbine system optimization, low-grade heat recovery and utilization. The book is intended for engineers and professional personnel who are working in process engineering, EPC companies, chemical and petrochemical plants, refineries, oil & gas production facilities, power generation plant. It can also be a professional reference or textbook for undergraduate or graduate-level university students and teaching personnel of chemical, energy, and process engineering faculties of universities.

Thermodynamics is fundamental to university and college curricula in chemistry, physics, engineering and many life sciences around the world. It is also notoriously difficult for students to understand, learn and apply. What makes this book different, and special, is the clarity of the text. The writing style is fluid, natural and lucid, and everything is explained in a logical and transparent manner. Thermodynamics is a deep, and important, branch of science, and this book does not make it "easy". But it does make it intelligible. This book introduces a new, 'Fourth Law' of Thermodynamics' based on the notion of Gibbs free energy, which underpins almost every application of thermodynamics and which the authors claim is worthy of recognition as a 'law'. The last four chapters bring thermodynamics into the twenty-first century, dealing with bioenergetics (how living systems capture and use free energy), macromolecule assembly (how proteins fold), and macromolecular aggregation (how, for example, virus capsids assemble). This is of great current relevance to students of biochemistry, biochemical engineering and pharmacy, and is covered in very few other texts on thermodynamics. The book also contains many novel and effective examples, such as the explanation of why friction is irreversible, the proof of the depression of the freezing point, and the explanation of the biochemical standard state.

High speed catamaran and multihull high speed marine vessel have become very popular in the last two decades. The catamaran has become the vessel of choice for the majority of high speed ferry operators worldwide. There have been significant advances in structural materials, and structural design has been combined with higher power density and fuel efficient engines to deliver ferries of increasing size. The multihull has proven itself to be a suitable configuration for active power projection across oceans as well as for coastal patrol and protection, operating at high speedd for insertion or retrieval with a low energy capability. At present there is no easily accessible material covering the combination of hydrodynamics, aerodynamics, and design issues including structures, powering and propulsion for these vehicles. Coverage in High Speed Catamarans and Multihulls includes an introduction to the history, evolution, and development of catamarans, followed by a theoretical calculation of wave resistance in shallow and deep water, as well as the drag components of the multihull. A discussion of vessel concept design describing design characteristics, empirical regression for determination of principal dimensions in preliminary design, general arrangement, and methods is also included. The book concludes with a discussion of experimental future vehicles currently in development including the small waterplane twin hull vessels, wave piercing catamarans, planing catamarans, tunnel planing catamarans and other multihull vessels.

Solid Fuels and Heavy Hydrocarbon Liquids: Thermal Characterisation and Analysis, Second Edition integrates the developments that have taken place since publication of the first edition in 2006. This updated material includes new insights that help unify the thermochemical reactions of biomass and coal, as well as new developments in analytical techniques, including new applications in size exclusion chromatography, several mass spectrometric techniques, and new applications of nuclear magnetic spectroscopy to the characterization of heavy hydrocarbon liquids The topics covered are essential for the energy and fuels research community, including academics, students, and research engineers working in the power, oil and gas, and renewable energy industries.

This textbook introduces the molecular side of physical chemistry. It offers students and practitioners a new approach to the subject by presenting numerous applications and solved problems that illustrate the concepts introduced for varied and complex technical situations. The book offers a balance between theory, tools, and practical applications. The text aims to be a practical manual for solving engineering problems in industries where processes depend on the chemical composition and physical properties of matter. The book is organized into three main topics: (I) the molecular structure of matter, (II) molecular models in thermodynamics, and (III) transport phenomena and mechanisms. Part I presents methods of analysis of the molecular behavior in a given system, while the following parts use these methods to study the equilibrium states of a material system and to analyze the processes that can take place when the system is in a state of non-equilibrium, in particular the transport phenomena. Molecular Physical Chemistry for Engineering Applications is designed for upper-level undergraduate and graduate courses in physical chemistry for engineers, applied physical chemistry, transport phenomena, colloidal chemistry, and transport/transfer processes. The book will also be a valuable reference guide for engineers, technicians, and scientists working in industry. Offers modeling techniques and tools for solving exercises and practical cases; Provides solutions and conclusions so students can follow results more closely; Step-by-step problem solving enables students to understand how to approach complex issues.

This book covers some fundamental aspects and frontiers in non-equilibrium physics and soft matter research. Apart from the basic knowledge on nonlinear statistic physics, dynamics, computer simulations, and main approaches and emerging systems in soft matter research, particular attention is devoted to new conceptual flexible functional materials and the enriching areas, such as silk meso-molecular materials, molecular gels, liquid crystals, flexible electronics and new types of catalysis, etc. One of the main characteristics of this book is to start with the structure formation dynamics and the correlation between the structures and macroscopic performance. This lays down the foundation for the mesoscopic materials design and functionalization. The book is intended for upper undergraduate students, graduate students, and researchers who are interested in soft matter researches. As one of main references, the basic principles and technologies of computer simulations and experimental methods adopted in soft matter research are also explained. Illustrations and tables are included in this book to improve the readability, and examples and exercises are added to help understanding.

The nonequilibrium behavior of nanoscopic and biological systems, which are typically strongly fluctuating, is a major focus of current research. Lately, much progress has been made in understanding such systems from a thermodynamic perspective. However, new theoretical challenges emerge when the fluctuating system is additionally subject to time delay, e.g. due to the presence of feedback loops. This thesis advances this young and vibrant research field in several directions. The first main contribution concerns the probabilistic description of time-delayed systems; e.g. by introducing a versatile approximation scheme for nonlinear delay systems. Second, it reveals that delay can induce intriguing thermodynamic properties such as anomalous (reversed) heat flow. More generally, the thesis shows how to treat the thermodynamics of non-Markovian systems by introducing auxiliary variables. It turns out that delayed feedback is inextricably linked to nonreciprocal coupling, information flow, and to net energy input on the fluctuating level.

This textbook presents the classical treatment of the problems of heat transfer in an exhaustive manner with due emphasis on understanding of the physics of the problems. This emphasis will be especially visible in the chapters on convective heat transfer. Emphasis is also laid on the solution of steady and unsteady two-dimensional heat conduction problems. Another special feature of the book is a chapter on introduction to design of heat exchangers and their illustrative design problems. A simple and understandable treatment of gaseous radiation has been presented. A special chapter on flat plate solar air heater has been incorporated that covers mathematical modeling of the air heater. The chapter on mass transfer has been written looking specifically at the needs of the students of mechanical engineering. The book includes a large number and variety of solved problems with supporting line diagrams. A number of application-based examples have been incorporated where applicable. The end-of-chapter exercise problems are supplemented with stepwise answers. Though the book has been primarily designed to serve as a complete textbook for undergraduate and graduate students of mechanical engineering, it will also be useful for students of chemical, aerospace, automobile, production, and industrial engineering streams. The book fully covers the topics of heat transfer coursework and can also be used as an excellent reference for students preparing for competitive graduate examinations.

This book presents different thermodynamic approaches in the area of constitutive theory: thermodynamics of irreversible processes, rational thermodynamics, and extended thermodynamics. These different approaches are analyzed with respect to their presuppositions, as well as to their results, and each method is applied to several important examples. In many cases these examples are archetypes for numerous technologically important materials; i.e. complex materials having an internal structure. Some of the examples dealt with in this book are liquid crystals, colloid suspensions, ans fiber suspensions. The book well serves students and researchers who have basic knowledge in continuum mechanics and thermodynamics. It provides a systematic overview of the vast field of thermodynamic constitutive theory, beginning from a historical perspective and concluding with outstanding questions in recent research.

This book presents a collection of essays that explore the life and works of Tatjana Afanassjewa (1876-1964), a Russian-Dutch physicist-mathematician. Readers will discover a scientist whose work on the foundations of thermodynamics significantly influenced the field itself as well as the philosophy of physics. This book highlights the philosophical consequences of her work in physics and mathematics and discusses historical aspects of her writings on the foundations of physics. In addition, it features English translations and critical reviews of key selections from her texts. First and foremost, the book highlights the numerous contributions that Afanassjewa made to the field. In particular, the authors examine her work on the foundations of thermodynamics and statistical physics, starting in the 1920s and extending to 1956, well after the untimely death of her husband in 1933. They also explore her almost entirely forgotten work on the didactics of mathematics. In addition, they discuss her influential collaboration with her husband, the Austrian physicist Paul Ehrenfest (1880-1933). The portrait that emerges is that of a highly original physicist and mathematician, whose legacy continues to influence scientists and philosophers today and whose lesser-known works deserve more attention than they have received. Readers will find a rich body of work that continues to this day to yield insights into the foundations of physics and mathematics.

In a comprehensive treatment of Statistical Mechanics from thermodynamics through the renormalization group, this book serves as the core text for a full-year graduate course in statistical mechanics at either the Masters or Ph.D. level. Each chapter contains numerous exercises, and several chapters treat special topics which can be used as the basis for student projects. The concept of scaling is introduced early and used extensively throughout the text. At the heart of the book is an extensive treatment of mean field theory, from the simplest decoupling approach, through the density matrix formalism, to self-consistent classical and quantum field theory as well as exact solutions on the Cayley tree. Proceeding beyond mean field theory, the book discusses exact mappings involving Potts models, percolation, self-avoiding walks and quenched randomness, connecting various athermal and thermal models. Computational methods such as series expansions and Monte Carlo simulations are discussed, along with exact solutions to the 1D quantum and 2D classical Ising models. The renormalization group formalism is developed, starting from real-space RG and proceeding through a detailed treatment of Wilson's epsilon expansion. Finally the subject of Kosterlitz-Thouless systems is introduced from a historical perspective and then treated by methods due to Anderson, Kosterlitz, Thouless and Young. Altogether, this comprehensive, up-to-date, and engaging text offers an ideal package for advanced undergraduate or graduate courses or for use in self study.