This book is part of a set of books which offers advanced students successive characterization tool phases, the study of all types of phase (liquid, gas and solid, pure or multi-component), process engineering, chemical and electrochemical equilibria, and the properties of surfaces and phases of small sizes. Macroscopic and microscopic models are in turn covered with a constant correlation between the two scales. Particular attention has been given to the rigor of mathematical developments. This second volume in the set is devoted to the study of liquid phases.

This introduction to random walks on infinite graphs gives particular emphasis to graphs with polynomial volume growth. It offers an overview of analytic methods, starting with the connection between random walks and electrical resistance, and then proceeding to study the use of isoperimetric and Poincare inequalities. The book presents rough isometries and looks at the properties of a graph that are stable under these transformations. Applications include the 'type problem': determining whether a graph is transient or recurrent. The final chapters show how geometric properties of the graph can be used to establish heat kernel bounds, that is, bounds on the transition probabilities of the random walk, and it is proved that Gaussian bounds hold for graphs that are roughly isometric to Euclidean space. Aimed at graduate students in mathematics, the book is also useful for researchers as a reference for results that are hard to find elsewhere.

This book presents a collection of essays that explore the life and works of Tatjana Afanassjewa (1876-1964), a Russian-Dutch physicist-mathematician. Readers will discover a scientist whose work on the foundations of thermodynamics significantly influenced the field itself as well as the philosophy of physics. This book highlights the philosophical consequences of her work in physics and mathematics and discusses historical aspects of her writings on the foundations of physics. In addition, it features English translations and critical reviews of key selections from her texts. First and foremost, the book highlights the numerous contributions that Afanassjewa made to the field. In particular, the authors examine her work on the foundations of thermodynamics and statistical physics, starting in the 1920s and extending to 1956, well after the untimely death of her husband in 1933. They also explore her almost entirely forgotten work on the didactics of mathematics. In addition, they discuss her influential collaboration with her husband, the Austrian physicist Paul Ehrenfest (1880-1933). The portrait that emerges is that of a highly original physicist and mathematician, whose legacy continues to influence scientists and philosophers today and whose lesser-known works deserve more attention than they have received. Readers will find a rich body of work that continues to this day to yield insights into the foundations of physics and mathematics.

This book contains the courses given at the Fifth School on Complex Systems held at Santiago, Chile, from 9th .to 13th December 1996. At this school met researchers working on areas related with recent trends in Complex Systems, which include dynamical systems, cellular automata, symbolic dynamics, spatial systems, statistical physics and thermodynamics. Scientists working in these subjects come from several areas: pure and applied mathematics, physics, biology, computer science and electrical engineering. Each contribution is devoted to one of the above subjects. In most cases they are structured as surveys, presenting at the same time an original point of view about the topic and showing mostly new results. The paper of Bruno Durand presents the state of the art on the relationships between the notions of surjectivity, injectivity and reversibility in cellular automata when finite, infinite or periodic configurations are considered, also he discusses decidability problems related with the classification of cellular automata as well as global properties mentioned above. The paper of Eric Goles and Martin Matamala gives a uniform presentation of simulations of Turing machines by cellular automata. The main ingredient is the encoding function which must be fixed for all Turing machine. In this context known results are revised and new results are presented.

This thesis demonstrates the potential of two platforms to explore experimentally the emerging field of quantum thermodynamics that has remained mostly theoretical so far. It proposes methods to define and measure work in the quantum regime. The most important part of the thesis focuses on hybrid optomechanical devices, evidencing that they are proper candidates to measure directly the fluctuations of work and the corresponding fluctuation theorem. Such devices could also give rise to the observation of mechanical lasing and cooling, based on mechanisms similar to a heat engine. The final part of the thesis studies how quantum coherence can improve work extraction in superconducting circuits. All the proposals greatly clarify the concept of work since they are based on measurable quantities in state of the art devices.

In the high energy gas flows, associating high velocities and high temperatures, physical and chemical processes such as molecular vibrational excitation, dissociation, ionisation or various reactions take palce and deeply influence the structure of the flows. The characteristic times of these processes have the same order of magnitude as aerodynamic characteristic times so that these reactive media are generally in thermodynamic and chemical non-equilibrium. This book presents a general introductory study of these media. In the first part their fundamental statistical aspects are described, starting from their discrete structure and taking into account the interactions between elementary particles: the transport phenomena, relaxation and kinetics as well as their coupling are thus analysed and illustrated by many examples. The second part deals with the macroscopic re-entry bodies. Finally the experimental aspects of these flows, their simulations in shock tube and shock tunnel are described as well as their application, particularly in the aero- spatial domain.
This book is intended for researchers and students that have acquired basic knowledge in thermodynamics, statistical physics and fluid mechanics. It must also interest the engineers engaged in research and industry related to the applications of the reactive flows, in particular in the aerospace field and, more generally, all the researchers trying to simulate and calculate complex reactive flows.

The principal objective of this book is to provide information needed to define human thermal behavior quantitatively. Human thermal physiology is defined using mathematical methods routinely employed by physicists and engineers, but seldom used by physiologists. Major sections of the book are devoted to blood flow, sweating, shivering, heat transfer within the body, and heat and mass transfer from skin and clothing to the environment. Simple algebraic models based on experimental data from a century of physiological investigation are developed for bodily processes. The book offers an invaluable source of information for physiologists and physical scientists interested in quantitative approaches to the fascinating field of human thermoregulation.

The accurate measurement of temperature is a vital parameter in many fields of engineering and scientific practice. Responding to emerging trends, this classic reference has been fully revised to include coverage of the latest instrumentation and measurement methods.

Featuring:

• Brand new chapters on computerised temperature measuring systems and temperature measurement in medicine.

• Sections on noise thermometers, the development of photoelectric and two-wave pyrometers and the latest IEC (International Electrotechnical Commission) standards

• Coverage of fibre optic thermometers, imaging of temperature fields and measurement in hazardous areas.

• Examination of virtual instruments, fuzzy logic in temperature measurement and new methods for thermometer calibration.

Energy is typically regarded as understandable, despite its multiple forms of storage and transfer. Entropy, however, is an enigma, in part because of the common view that it represents disorder. That view is flawed and hides entropy's connection with energy. In fact, macroscopic matter stores internal energy, and that matter's entropy is determined by how the energy is stored. Energy and entropy are intimately linked. Energy and Entropy: A Dynamic Duo illuminates connections between energy and entropy for students, teachers, and researchers. Conceptual understanding is emphasised where possible through examples, analogies, figures, and key points. Features: Qualitative demonstration that entropy is linked to spatial and temporal energy spreading, with equilibrium corresponding to the most equitable distribution of energy, which corresponds to maximum entropy Analysis of energy and entropy of matter and photons, with examples ranging from rubber bands, cryogenic cooling, and incandescent lamps to Hawking radiation of black holes Unique coverage of numerical entropy, the 3rd law of thermodynamics, entropic force, dimensionless entropy, free energy, and fluctuations, from Maxwell's demon to Brownian ratchets, plus attempts to violate the second law of thermodynamics

Functionality, Advancements and Industrial Applications of Heat Pipes introduces heat pipe technologies and highlights a variety of applications for passive thermal control. The book begins with a thorough analysis of heat pipe infrastructure, including principles of operation, temperature limits, reliability and lessons learned from worked examples and case studies. It also presents a concise design guideline for the assembly of heat pipes. The second part moves on to consider a variety of modern day applications for the heat pipe principles discussed, covering nuclear and solar thermal energy engineering facilities as well as applications in space, in the sea and in the air. A final section works through manufacturing elements of different types of heat pipe to ensure they are well maintained and remain fully operational. This section includes the cleaning of parts, the assembly of the heat pipe, an analysis of gas blockages and how to deal with them, as well as performance versification.

Complexity and Complex Thermoeconomic Systems describes the properties of complexity and complex thermo-economic systems as the consequence of formulations, definitions, tools, solutions and results consistent with the best performance of a system. Applying to complex systems contemporary advanced techniques, such as static optimization, optimal control, and neural networks, this book treats the systems theory as a science of general laws for functional integrities. It also provides a platform for the discussion of various definitions of complexity, complex hierarchical structures, self-organization examples, special references, and historical issues. This book is a valuable reference for scientists, engineers and graduated students in chemical, mechanical, and environmental engineering, as well as those in physics, ecology and biology, helping them better understand the complex thermodynamic systems and enhance their technical skills in research.

This multi-volume handbook is the most up-to-date and comprehensive reference work in the field of fractional calculus and its numerous applications. This fifth volume collects authoritative chapters covering several applications of fractional calculus in physics, including electrodynamics, statistical physics and physical kinetics, and quantum theory.

Illustrating the development of Brownian ratchets, from their foundations, to their role in the description of life at the molecular scale and in the design of artificial nano-machinery, this text will appeal to both advanced graduates and researchers entering the field. Providing a self-contained introduction to Brownian ratchets, devices which rectify microscopic fluctuations, Part I avoids technicalities and sets out the broad range of physical systems where the concept of ratchets is relevant. Part II supplies a single source for a complete and modern theoretical analysis of ratchets in regimes such as classical vs quantum and stochastic vs deterministic, and in Part III readers are guided through experimental developments in different physical systems, each highlighting a specific unique feature of ratchets. The thorough and systematic approach to the topic ensures that this book provides a complete guide to Brownian ratchets for newcomers and established researchers in physics, biology and biochemistry.

This thesis presents several related advances in the field of nonequilibrium quantum thermodynamics. The central result is an ingenious proof that the local temperature and voltage measurement in a nonequilibrium system of fermions exists and is unique, placing the concept of local temperature on a rigorous mathematical footing for the first time. As an intermediate step, a proof of the positivity of the Onsager matrix of linear response theory is given -- a statement of the second law of thermodynamics that had lacked an independent proof for 85 years. A new experimental method to measure the local temperature of an electron system using purely electrical techniques is also proposed, which could enable improvements to the spatial resolution of thermometry by several orders of magnitude. Finally, a new mathematically-exact definition for the local entropy of a quantum system in a nonequilibrium steady state is derived. Several different measures of the local entropy are discussed, relating to the thermodynamics of processes that a local observer with varying degrees of information about the microstates of the system could carry out, and it is shown that they satisfy a hierarchy of inequalities. Proofs of the third law of thermodynamics for generic open quantum systems are presented, taking into account the entropic contribution due to localized states. Appropriately normalized (per-state) local entropies are defined and are used to quantify the departure from local equilibrium.

This book presents the optimal auxiliary functions method and applies it to various engineering problems and in particular in boundary layer problems. The cornerstone of the presented procedure is the concept of "optimal auxiliary functions" which are needed to obtain accurate results in an efficient way. Unlike other known analytic approaches, this procedure provides us with a simple but rigorous way to control and adjust the convergence of the solutions of nonlinear dynamical systems. The optimal auxiliary functions are depending on some convergence-control parameters whose optimal values are rigorously determined from mathematical point of view. The capital strength of our procedure is its fast convergence, since after only one iteration, we obtain very accurate analytical solutions which are very easy to be verified. Moreover, no simplifying hypothesis or assumptions are made. The book contains a large amount of practical models from various fields of engineering such as classical and fluid mechanics, thermodynamics, nonlinear oscillations, electrical machines, and many more. The book is a continuation of our previous books "Nonlinear Dynamical Systems in Engineering. Some Approximate Approaches", Springer-2011 and "The Optimal Homotopy Asymptotic Method. Engineering Applications", Springer-2015.

- A brief and accessible introduction to a complex topic - Contains a thorough treatment of the motions of heavenly bodies than conventional elementary mechanics texts. - Provides a wealth of end-of-chapter exercises to test understanding

This book discusses the elementary ideas and tools needed for open quantum systems in a comprehensive manner. The emphasis is given to both the traditional master equation as well as the functional (path) integral approaches. It discusses the basic paradigm of open systems, the harmonic oscillator and the two-level system in detail. The traditional topics of dissipation and tunneling, as well as the modern field of quantum information, find a prominent place in the book. Assuming a basic background of quantum and statistical mechanics, this book will help readers familiarize with the basic tools of open quantum systems. Open quantum systems is the study of quantum dynamics of the system of interest, taking into account the effects of the ambient environment. It is ubiquitous in the sense that any system could be envisaged to be surrounded by its environment which could naturally exert its influence on it. Open quantum systems allows for a systematic understanding of irreversible processes such as decoherence and dissipation, of the essence in order to have a correct understanding of realistic quantum dynamics and also for possible implementations. This would be essential for a possible development of quantum technologies.

This book explains theoretical and technological aspects of amorphous drug formulations. It is intended for all those wishing to increase their knowledge in the field of amorphous pharmaceuticals. Conversion of crystalline material into the amorphous state, as described in this book, is a way to overcome limited water solubility of drug formulations, in this way enhancing the chemical activity and bioavailability inside the body. Written by experts from various fields and backgrounds, the book introduces to fundamental physical aspects (explaining differences between the ordered and the disordered solid states, the enhancement of solubility resulting from drugs amorphization, physical instability and how it can be overcome) as well as preparation and formulation procedures to produce and stabilize amorphous pharmaceuticals. Readers will thus gain a well-funded understanding and find a multi-faceted discussion of the properties and advantages of amorphous drugs and of the challenges in producing and stabilizing them. The book is an ideal source of information for researchers and students as well as professionals engaged in research and development of amorphous pharmaceutical products.

Defrosting for Air Source Heat Pumps: Research, Analysis and Methods presents a detailed analysis of the methods, processes and problems relating to defrosting, a necessary requirement to maintain the performance of ASHP units. Readers will gain a deeper understanding of control strategies and system design optimization methods that improve the performance and reliability of units. The book discusses the most recent experimental and numerical studies of reverse cycle defrosting and the most widely used defrosting method for ASHP. Techno-economic considerations are also presented, as is the outlook for the future. This book is a valuable resource for research students and academics of thermal energy and mechanical engineering, especially those focusing on defrosting for ASHP, heating, ventilation and energy efficiency, as well as engineers and professionals engaged in the development and management of heat pump machinery.

Nonextensive statistical mechanics is now a rapidly growing field and a new stream in the research of the foundations of statistical mechanics. This generalization of the well-known Boltzmann--Gibbs theory enables the study of systems with long-range interactions, long-term memories or multi-fractal structures. This book consists of a set of self-contained lectures and includes additional contributions where some of the latest developments -- ranging from astro- to biophysics -- are covered. Addressing primarily graduate students and lecturers, this book will also be a useful reference for all researchers working in the field.

This book continues the process of systematization of knowledge about convection. It is important to put the current knowledge on weakly and strongly stratified convection in order, and provide a comprehensive description of the marginal, weakly nonlinear and fully developed stages of convective flow in both cases. The book provides a short compendium of knowledge on the linear and weakly nonlinear limits of the Boussinesq convection, and a review of the theory on fully developed Boussinesq convection. The third chapter is devoted to a detailed derivation and a study of the three aforementioned stages of stratified (anelastic) convection, with a full solution in the marginal stage provided for the first time. Detailed and systematic explanations are given. The book is intended mainly as a textbook for courses on hydrodynamics and convective flows, for the use of lecturers and students; however, it also serves for the entire scientific community as a practical reference.

Measurements, Mechanisms, and Models of Heat Transport offers an interdisciplinary approach to the dynamic response of matter to energy input. Using a combination of fundamental principles of physics, recent developments in measuring time-dependent heat conduction, and analytical mathematics, this timely reference summarizes the relative advantages of currently used methods, and remediates flaws in modern models and their historical precursors. Geophysicists, physical chemists, and engineers will find the book to be a valuable resource for its discussions of radiative transfer models and the kinetic theory of gas, amended to account for atomic collisions being inelastic. This book is a prelude to a companion volume on the thermal state, formation, and evolution of planets. Covering both microscopic and mesoscopic phenomena of heat transport, Measurements, Mechanisms, and Models of Heat Transport offers both the fundamental knowledge and up-to-date measurements and models to encourage further improvem

This book is dedicated to the atmosphere of our planet, and discusses historical and contemporary achievements in meteorological science and technology for the betterment of society. The book explores many significant atmospheric phenomena and physical processes from the local to global scale, as well as from the perspective of short and long-term time scales, and links these processes to various applications in other scientific disciplines with linkages to meteorology. In addition to addressing general topics such as climate system dynamics and climate change, the book also discusses atmospheric boundary layer, atmospheric waves, atmospheric chemistry, optics/photometeors, electricity, atmospheric modeling and numeric weather prediction. Through its interdisciplinary approach, the book will be of interest to researchers, students and academics in meteorology and atmospheric science, environmental physics, climate change dynamics, air pollution and human health impacts of atmospheric aerosols.

First published in 1927 as the second edition of a 1925 original, this book was intended as a general introduction to the principles of thermodynamics for university students involved in the physical sciences. Birtwistle gives a brief overview of the history of science relating to heat and the conservation of energy as well as practical examples to back up salient points in his explanation of key ideas. This book will be of value to anyone with an interest in the history of science.