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Books > Science & Mathematics > Physics > Thermodynamics & statistical physics > Thermodynamics
This monograph disentangles the law of motive force, a fundamental law of nature that can be accommodated as an addition to the existing laws of thermodynamics. This unmistakable and remarkable tendency of nature is equally applicable to all other branches of studies. The law of motive force was discovered in 1989 by the author of this book, Professor Pramanick, who reports here various applications of the law in the area ofthermodynamics, heat transfer, fluid mechanics and solid mechanics and shows how, by applying the law of motive force, it is possible to solve analytically century old unsolved problems. This book offers a comprehensive account of the law of motive force and its relation to other laws and principles such as the generalized conservation principle, variational formulation, Fermat s principle, Bejan s constructal law, entropy generation minimization, Bejan s method of intersecting asymptotes and equipartition principle. Furthermore, the author addresses here some interrelated fundamental problems of contemporary interest, especially to thermodynamicists and provides exact solutions to these problems, by combining analytical methods, physical reasoning and the proposed law of motive force. This book is a must-read for both students and researchers in exact as well as non-exact sciences and at the same time, a pleasant learning experience for any novice. The first chapter proposes the law of motive force and establishes its relation to the other laws and principles such as the generalized conservation principle, variational formulation, Fermat s principle, Bejan s constructal law, entropy generation minimization, Bejan s method of intersecting asymptotes and equipartition principle. The second chapter presents Schmidt s intuitive criterion for fin design by employing the law of motive force alone. The third chapter provides an elegant solution to a classically unsolved fundamental issue of thermal science, the generalization of Pohlhausen s problem of heat transfer from a flat plate, by applying the law of motive force. The fourth chapter is a theoretical excursus of hydraulic jump for the first time deploying the law of motive force. The fifth chapter inculcates the law of motive force to establish the dendritic structure of nature with reference to a thermoelectric device. In the light of law of motive force the sixth and last chapter finally integrates finite-time thermodynamics with Bejan s constructal law.
Gets right to the point with step-by-step guidance on solving physics problems. Covers all topics in standard general physics courses in the same sequence. Keeps learning about physics fun and engaging through the story of dinosaurs being tested on their knowledge for a final challenge (deflecting an asteroid headed to Earth!). Enables the reader to quickly flip through and locate steps needed for a particular problem. Includes tons of easy to follow diagrams and worked solutions.
The term transport phenomena is used to describe processes in which mass, momentum, energy and entropy move about in matter. Advances in Transport Phenomena provide state-of-the-art expositions of major advances by theoretical, numerical and experimental studies from a molecular, microscopic, mesoscopic, macroscopic or megascopic point of view across the spectrum of transport p- nomena, from scientific enquiries to practical applications. The annual review series intends to fill the information gap between regularly published journals and university-level textbooks by providing in-depth review articles over a broader scope than in journals. The authoritative articles, contributed by international- leading scientists and practitioners, establish the state of the art, disseminate the latest research discoveries, serve as a central source of reference for fundamentals and applications of transport phenomena, and provide potential textbooks to senior undergraduate and graduate students. The series covers mass transfer, fluid mechanics, heat transfer and thermo- namics. The 2009 volume contains the four articles on biomedical, environmental and nanoscale transports. The editorial board expresses its appreciation to the c- tributing authors and reviewers who have maintained the standard associated with Advances in Transport Phenomena. We also would like to acknowledge the efforts of the staff at Springer who have made the professional and attractive pr- entation of the volume. Serial Editorial Board Editor-in-Chief Professor L. Q. Wang The University of Hong Kong, Hong Kong; lqwang@hku. hk Editors Professor A. R. Balakrishnan Indian Institute of Technology Madras, India Professor A.
This volume is a compilation of carefully selected questions at the PhD qualifying exam level, including many actual questions from Columbia University, University of Chicago, MIT, State University of New York at Buffalo, Princeton University, University of Wisconsin and the University of California at Berkeley over a twenty-year period. Topics covered in this book include the laws of thermodynamics, phase changes, Maxwell-Boltzmann statistics and kinetic theory of gases.This latest edition has been updated with more problems and solutions and the original problems have also been modernized, excluding outdated questions and emphasizing those that rely on calculations. The problems range from fundamental to advanced in a wide range of topics on thermodynamics and statistical physics, easily enhancing the student's knowledge through workable exercises. Simple-to-solve problems play a useful role as a first check of the student's level of knowledge whereas difficult problems will challenge the student's capacity on finding the solutions.
Calculations in Chemical Kinetics for Undergraduates aims to restore passion for problem solving and applied quantitative skills in undergraduate chemistry students. Avoiding complicated chemistry jargon and providing hints and step wise explanations in every calculation problem, students are able to overcome their fear of handling mathematically applied problems in physical chemistry. This solid foundation in their early studies will enable them to connect fundamental theoretical chemistry to real experimental applications as graduates. Additional Features Include: Contains quantitative problems from popular physical chemistry references. Provides step by step explanations are given in every calculation problem. Offers hints to certain problems as "points to note" to enable student comprehension. Includes solutions for all questions and exercises. This book is a great resource for undergraduate chemistry students however, the contents are rich and useful to even the graduate chemist that has passion for applied problems in physical chemistry of reaction Kinetics.
The simulation of turbulent reacting flows, connected with environmental protection and the design of chemical and mechanical processes, is increasingly important. Statistical Mechanics of Turbulent Flows presents a modern overview of basic ways to calculate such flows. It discusses the fundamental problems related to the use of basic equations and their modifications. Special emphasis is placed on the discussion of very promising statistical methods which provide solutions to these problems by models for the underlying stochastic physics of turbulent reacting flows. Their foundations and important new developments up through current challenges are systematically explained. Students and researchers in atmospheric sciences and oceanography, mechanical and chemical engineering and applied mathematics and physics may use Statistical Mechanics of Turbulent Flows as a guide to solve many problems related, e.g. to the assessment of complex atmospheric chemistry, chemical reactor processes, turbulent combustion, and multi-phase flows.
- It provides a rigorous mathematical and physical basis to techniques that are often introduced on empirical basis - While the book covers a broad range of techniques, it starts at a basic theoretical level. This gives the book a strong foundation and makes it accessible to students from various backgrounds. - Has a computational focus unlike many competing titles
The revised second edition of this practical book reviews the fundamentals of cryogenic liquid behaviour in small and large scale storage systems. The text is based on research findings on the convective and evaporative behaviour of cryogenic fluids, aimed at improving the design, construction and operation of low-loss cryogenic liquid storage systems, with a view to minimising cost and improving operational safety. Since the first edition was published in 2006, the breadth of cryogenic applications and the modelling of cryogenic fluid dynamics (CFD) have expanded in several directions. In this second edition, most chapters have been extended to introduce discussions of these new applications and their safety and energy economy. These include advances in the modelling of CFD required in, for example, the design of miniature cryocoolers and condensers and reboilers, large-scale cryogenic liquid mixture properties and their stability, and the understanding that hazards and safety problems in the public domain increase with the scaling up of cryogenic systems. With helpful summaries at the end of each chapter, the book is an essential reference for anyone working on the design and operation of cryogenic liquid storage and transportation systems.
- A brief and accessible introduction to a complex topic - Contains a thorough treatment of the motions of heavenly bodies than conventional elementary mechanics texts. - Provides a wealth of end-of-chapter exercises to test understanding
"Fundamental Aspects of Plasma Chemical Physics: Transport "develops basic and advanced concepts of plasma transport to the modern treatment of the Chapman-Enskog method for the solution of the Boltzmann transport equation. The book invites the reader to consider actual problems of the transport of thermal plasmas with particular attention to the derivation of diffusion- and viscosity-type transport cross sections, stressing the role of resonant charge-exchange processes in affecting the diffusion-type collision calculation of viscosity-type collision integrals. A wide range of topics is then discussed including (1) the effect of non-equilibrium vibrational distributions on the transport of vibrational energy, (2) the role of electronically excited states in the transport properties of thermal plasmas, (3) the dependence of transport properties on the multitude of Saha equations for multi-temperature plasmas, and (4) the effect of the magnetic field on transport properties. Throughout the book, worked examples are provided to clarify concepts and mathematical approaches. This book is the second of a series of three published by the Bari group on fundamental aspects of plasma chemical physics. The first book, "Fundamental Aspects of Plasma Chemical Physics: Thermodynamics," is dedicated to plasma thermodynamics; and the third, "Fundamental Aspects of Plasma Chemical Physics: Kinetics," deals with plasma kinetics.
This textbook provides an accessible introduction to various energy transformation technologies and their influences on the environment. Here the energy transformation is understood as any physical process induced by humans, in which energy is intentionally transformed from one form to another. This book provides an accessible introduction to the subject: covering the theory, principles of design, operation, and efficiency of the systems in addition to discerning concepts such as energy, entropy, exergy, efficiency, and sustainability. It is not assumed that readers have any previous exposure to such concepts as laws of thermodynamics, entropy, exergy, fluid mechanics or heat transfer, and is therefore an ideal textbook for advanced undergraduate students. Key features: Represents a complete source of information on sustainable energy transformation systems and their externalities. Includes all existing and major emerging technologies in the field. Chapters include numerous examples and problems for further learning opportunities.
This textbook provides an accessible introduction to various energy transformation technologies and their influences on the environment. Here the energy transformation is understood as any physical process induced by humans, in which energy is intentionally transformed from one form to another. This book provides an accessible introduction to the subject: covering the theory, principles of design, operation, and efficiency of the systems in addition to discerning concepts such as energy, entropy, exergy, efficiency, and sustainability. It is not assumed that readers have any previous exposure to such concepts as laws of thermodynamics, entropy, exergy, fluid mechanics or heat transfer, and is therefore an ideal textbook for advanced undergraduate students. Key features: Represents a complete source of information on sustainable energy transformation systems and their externalities. Includes all existing and major emerging technologies in the field. Chapters include numerous examples and problems for further learning opportunities.
Discusses advances in the computation of phase diagrams Offers expanded treatment of eutectic solidification with practical examples and new coverage of ternary phase diagrams, covering the concepts of orthoequilibrium and paraequilibrium Updates discussion of bainite transformation to reflect current opinions Includes new case studies covering grain refiners in aluminium alloys, additive manufacturing, thin film growth, important aerospace Al-Li alloys, and quenched and partitioned steels, and metastable austenitic stainless steels. Each chapter now begins with a list of key concepts, includes simpler illustrative exercises with relevance to real practical applications, and references to scientific publications updated to reflect experimental and computational advances in metallurgy
This volume is a compilation of carefully selected questions at the PhD qualifying exam level, including many actual questions from Columbia University, University of Chicago, MIT, State University of New York at Buffalo, Princeton University, University of Wisconsin and the University of California at Berkeley over a twenty-year period. Topics covered in this book include the laws of thermodynamics, phase changes, Maxwell-Boltzmann statistics and kinetic theory of gases.This latest edition has been updated with more problems and solutions and the original problems have also been modernized, excluding outdated questions and emphasizing those that rely on calculations. The problems range from fundamental to advanced in a wide range of topics on thermodynamics and statistical physics, easily enhancing the student's knowledge through workable exercises. Simple-to-solve problems play a useful role as a first check of the student's level of knowledge whereas difficult problems will challenge the student's capacity on finding the solutions.
Presents a clear path to developing quantitative multi-phase and multi-component phase field models for solidification and other phase transformation kinetics based on practical grand potential functional Derives explicitly and discusses the quantitative nature of the model formulations through matched interface asymptotic analysis Explores a framework for quantitative treatment of rapid solidification to control solute trapping and solute drag dynamics
This book is devoted to the problems of oxidation chemical reactions and addresses bimodal reaction sequences. Chemical reactions of oxidation, occurring under certain conditions and in multicomponent systems are complex processes. The process of the oxidation essentially changes in the presence and contact of the solid substances with reactants. The role of solid substances and the appearance of this phenomenon in oxidation reaction are discussed. The reader will understand the "driving forces" of this phenomenon and apply it in practice. Written for chemists, physicists, biologists and engineers working in the domain of oxidation reactions. Key Selling Features: Covers the historical background, modern state of the art, and perspectives in investigations of the coupling between heterogeneous and homogeneous reactions Discusses the feasible pathways of the coupling of heterogeneous and homogeneous reactions in oxidation in man-made and natural chemical systems Addresses the abundance, peculiarities and mechanisms of the bimodal reaction sequences in oxidation with dioxygen in recent decades Discusses the existence of the bimodal reaction sequences in chemical systems investigations in atmospheric chemistry and heterogeneous photocatalysis Presented in a simple concise style, accessible for both specialists and non-specialists
This book focuses on mixed crystals formed by molecular substances. The emphasis lies on the elucidation of the structural and thermodynamic properties of two-component systems. Thanks to the fact that the research efforts have been directed to a number of families of chemically coherent substances, rather than to a collection of isolated systems, the knowledge of mixed crystals has substantially increased. This is reflected by the discovery of several empirical relationships between thermodynamic properties, crystallographic properties, and also between thermodynamic mixing properties and exothermodynamic parameters, such as the structural mismatch between the components of the binary systems. This book is a benchmark for material scientists and a unique starting point for anyone interested in mixed crystals.
Exactly solvable models are very important in physics. They are important not just from a theoretical point of view but also from the experimentalist's perspective because in such cases theoretical results and experimental results can be compared without ambiguity. This 1999 book is about an important class of exactly solvable models in physics. The subject area is the Bethe-ansatz approach for a number of one-dimensional models, and the setting up of equations within this approach to determine the thermodynamics of these systems. It is a topic that crosses the boundaries between condensed matter physics, mathematics and field theory. The derivation and application of thermodynamic Bethe-ansatz equations for one-dimensional models are explained in detail. This technique is indispensable for physicists studying the low-temperature properties of one-dimensional substances. This book, written by one of the top physicists in this field, and the originator of much of the work in the subject, will be of great interest to theoretical condensed matter physicists.
This thesis establishes a multifaceted extension of the deterministic control framework that has been a workhorse of nonequilibrium statistical mechanics, to stochastic, discrete, and autonomous control mechanisms. This facilitates the application of ideas from stochastic thermodynamics to the understanding of molecular machines in nanotechnology and in living things. It also gives a scale on which to evaluate the nonequilibrium energetic efficiency of molecular machines, guidelines for designing effective synthetic machines, and a perspective on the engineering principles that govern efficient microscopic energy transduction far from equilibrium. The thesis also documents the author's design, analysis, and interpretation of the first experimental demonstration of the utility of this generally applicable method for designing energetically-efficient control in biomolecules. Protocols designed using this framework systematically reduced dissipation, when compared to naive protocols, in DNA hairpins across a wide range of experimental unfolding speeds and between sequences with wildly different physical characteristics.
In this book basic and some more advanced thermodynamics and phase as well as stability diagrams relevant for diffusion studies are introduced. Following, Fick s laws of diffusion, atomic mechanisms, interdiffusion, intrinsic diffusion, tracer diffusion and the Kirkendall effect are discussed. Short circuit diffusion is explained in detail with an emphasis on grain boundary diffusion.Recent advances in the area of interdiffusion will be introduced. Interdiffusion in multi-component systems is also explained. Many practical examples will be given, such that researches working in this area can learn the practical evaluation of various diffusion parameters from experimental results. Large number of illustrations and experimental results are used to explain the subject. This book will be appealing for students, academicians, engineers and researchers in academic institutions, industry research and development laboratories."
This book tells the story of the power generation gas turbine from the perspective of one of the leading companies in the field over a period of nearly 100 years, written by an engineer. Especially in times of imminent global economic crises it appears to be worthwhile to reflect on real economic values based on engineering ingenuity and enduring management of technological leadership. Though the book is primarily designed as a technical history of the BBC/ABB/Alstom power generation gas turbines, its scope is sufficiently broad to cover general development trends, including parallel competitor activities. A special benefit is the historical breakdown to the gas turbine component level, so that the book actually outlines the development of axial compressors from early beginnings, the progress in combustion technology towards extraordinary low emission values and that of axial turbines with special emphasis on early turbine cooling innovations. The sheer length of certain engineering developments over several decades allows interesting historic observations and deductions on inherent business mechanisms, the effects of technology preparations and organisational consequences. A look into the mirror of the past provides revelations on the impact of far-reaching business decisions. 2017 Winner of the Historian Engineer Award of the ASME (American Society of Mechanical Engineers
Experts of fluid dynamics agree that turbulence is nonlinear and nonlocal. Because of a direct correspondence, nonlocality also implies fractionality. Fractional dynamics is the physics related to fractal (geometrical) systems and is described by fractional calculus. Up-to-present, numerous criticisms of linear and local theories of turbulence have been published. Nonlinearity has established itself quite well, but so far only a very small number of general nonlocal concepts and no concrete nonlocal turbulent flow solutions were available. This book presents the first analytical and numerical solutions of elementary turbulent flow problems, mainly based on a nonlocal closure. Considerations involve anomalous diffusion (Levy flights), fractal geometry (fractal- , bi-fractal and multi-fractal model) and fractional dynamics. Examples include a new 'law of the wall' and a generalization of Kraichnan's energy-enstrophy spectrum that is in harmony with non-extensive and non-equilibrium thermodynamics (Tsallis thermodynamics) and experiments. Furthermore, the presented theories of turbulence reveal critical and cooperative phenomena in analogy with phase transitions in other physical systems, e.g., binary fluids, para-ferromagnetic materials, etc.; the two phases of turbulence identifying the laminar streaks and coherent vorticity-rich structures. This book is intended, apart from fluids specialists, for researchers in physics, as well as applied and numerical mathematics, who would like to acquire knowledge about alternative approaches involved in the analytical and numerical treatment of turbulence.
Multi-phase flows are part of our natural environment such as tornadoes, typhoons, air and water pollution and volcanic activities as well as part of industrial technology such as power plants, combustion engines, propulsion systems, or chemical and biological industry. The industrial use of multi-phase systems requires analytical and numerical strategies for predicting their behavior. .In its fourth extended edition the successful monograph package Multiphase Flow Daynmics contains theory, methods and practical experience for describing complex transient multi-phase processes in arbitrary geometrical configurations, providing a systematic presentation of the theory and practice of numerical multi-phase fluid dynamics. In the present third volume methods for describing of the thermal interactions in multiphase dynamics are provided. In addition a large number of valuable experiments is collected and predicted using the methods introduced in this monograph. In this way the accuracy of the methods is revealed to the reader. This fourth edition includes various updates, extensions, improvements and corrections. "The literature in the field of multiphase flows is numerous. Therefore, it is very important to have a comprehensive and systematic overview including useful numerical methods. The volumes have the character of a handbook and accomplish this function excellently. The models are described in detail and a great number of comprehensive examples and some cases useful for testing numerical solutions are included. These two volumes are very useful for scientists and practicing engineers in the fields of technical thermodynamics, chemical engineering, fluid mechanics, and for mathematicians with interest in technical problems. Besides, they can give a good overview of the dynamically developing, complex field of knowledge to students. This monograph is highly recommended, BERND PLATZER, ZAAM In the present third volume methods for describing of the thermal interactions in multiphase dynamics are provided. In addition a large number of valuable experiments is collected and predicted using the methods introduced in this monograph. In this way the accuracy of the methods is revealed to the reader. This fourth edition includes various updates, extensions, improvements and corrections. "The literature in the field of multiphase flows is numerous. Therefore, it is very important to have a comprehensive and systematic overview including useful numerical methods. The volumes have the character of a handbook and accomplish this function excellently. The models are described in detail and a great number of comprehensive examples and some cases useful for testing numerical solutions are included. These two volumes are very useful for scientists and practicing engineers in the fields of technical thermodynamics, chemical engineering, fluid mechanics, and for mathematicians with interest in technical problems. Besides, they can give a good overview of the dynamically developing, complex field of knowledge to students. This monograph is highly recommended, BERND PLATZER, ZAAM
Scheck's textbook starts with a concise introduction to classical thermodynamics, including geometrical aspects. Then a short introduction to probabilities and statistics lays the basis for the statistical interpretation of thermodynamics. Phase transitions, discrete models and the stability of matter are explained in great detail.Thermodynamics has a special role in theoretical physics. Due to the general approach of thermodynamics the field has as a bridging function between several areas like the theory of condensed matter, elementary particle physics, astrophysics and cosmology. The classical thermodynamics describes predominantly averaged properties of matter, reaching from few particle systems and state of matter to stellar objects. Statistical Thermodynamics covers the same fields, but explores them in greater depth and unifies classical statistical mechanics with quantum theory of multiple particle systems. The content is presented as two tracks: the fast track for master students, providing the essentials, and the intensive track for all wanting to get in depth knowledge of the field. Clearly labelled material and sections guide students through the preferred level of treatment. Numerous problems and worked examples will provide successful access to Statistical Physics and Thermodynamics. |
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