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Books > Science & Mathematics > Physics > Thermodynamics & statistical physics > Thermodynamics
The principal message of this book is that thermodynamics and statistical mechanics will benefit from replacing the unfortunate, misleading and mysterious term "entropy" with a more familiar, meaningful and appropriate term such as information, missing information or uncertainty. This replacement would facilitate the interpretation of the "driving force" of many processes in terms of informational changes and dispel the mystery that has always enshrouded entropy.It has been 140 years since Clausius coined the term "entropy"; almost 50 years since Shannon developed the mathematical theory of "information" - subsequently renamed "entropy". In this book, the author advocates replacing "entropy" by "information", a term that has become widely used in many branches of science.The author also takes a new and bold approach to thermodynamics and statistical mechanics. Information is used not only as a tool for predicting distributions but as the fundamental cornerstone concept of thermodynamics, held until now by the term "entropy".The topics covered include the fundamentals of probability and information theory; the general concept of information as well as the particular concept of information as applied in thermodynamics; the re-derivation of the Sackur-Tetrode equation for the entropy of an ideal gas from purely informational arguments; the fundamental formalism of statistical mechanics; and many examples of simple processes the "driving force" for which is analyzed in terms of information.
The principal message of this book is that thermodynamics and statistical mechanics will benefit from replacing the unfortunate, misleading and mysterious term "entropy" with a more familiar, meaningful and appropriate term such as information, missing information or uncertainty. This replacement would facilitate the interpretation of the "driving force" of many processes in terms of informational changes and dispel the mystery that has always enshrouded entropy.It has been 140 years since Clausius coined the term "entropy"; almost 50 years since Shannon developed the mathematical theory of "information" - subsequently renamed "entropy". In this book, the author advocates replacing "entropy" by "information", a term that has become widely used in many branches of science.The author also takes a new and bold approach to thermodynamics and statistical mechanics. Information is used not only as a tool for predicting distributions but as the fundamental cornerstone concept of thermodynamics, held until now by the term "entropy".The topics covered include the fundamentals of probability and information theory; the general concept of information as well as the particular concept of information as applied in thermodynamics; the re-derivation of the Sackur-Tetrode equation for the entropy of an ideal gas from purely informational arguments; the fundamental formalism of statistical mechanics; and many examples of simple processes the "driving force" for which is analyzed in terms of information.
In this unique book, Arieh Ben-Naim invites the reader to experience the joy of appreciating something which has eluded understanding for many years -- entropy and the Second Law of Thermodynamics. The book has a two-pronged message: first, that the Second Law is not "infinitely incomprehensible" as commonly stated in textbooks of thermodynamics but can, in fact, be comprehended through sheer common sense; and second, that entropy is not a mysterious quantity that has "resisted understanding" but a simple, familiar and easily comprehensible concept. Written in an accessible style, the book guides the reader through an abundance of dice games and examples from everyday life. The author paves the way for readers to discover for themselves what entropy is, how it changes, and most importantly, why it always changes in one direction in a spontaneous process.
This book provides a solid foundation in the principles of heat and mass transfer and shows how to solve problems by applying modern methods. The basic theory is developed systematically, exploring in detail the solution methods to all important problems. The revised second edition incorporates state-of-the-art findings on heat and mass transfer correlations. The book will be useful not only to upper- and graduate-level students, but also to practicing scientists and engineers. Many worked-out examples and numerous exercises with their solutions will facilitate learning and understanding, and an appendix includes data on key properties of important substances.
This book offers an easy to read, all-embracing history of thermodynamics. It describes the long development of thermodynamics, from the misunderstood and misinterpreted to the conceptually simple and extremely useful theory that we know today. Coverage identifies not only the famous physicists who developed the field, but also engineers and scientists from other disciplines who helped in the development and spread of thermodynamics as well.
This book is an introductory text on fundamental aspects of combustion including thermodynamics, heat and mass transfer and chemical kinetics which are used to systematically derive the basic concepts of combustion. Apart from the fundamental aspects, many of the emerging topics in the field like microscale combustion, combustion dynamics, oxy-fuel combustion and combustion diagnostics are also covered in the book. This would help the beginners in the subject to get initiated to the state of the art topics. Key Features: Coverage of the essential aspects of combustion engineering suitable for both beginners and practicing professionals Topics like entropy generation, microscale combustion, combustion diagnostics, second law-based analysis exclusive to the title Balanced treatment of thermodynamics, transport phenomena and chemical kinetics Discussion on state of the art techniques in combustion diagnostics Illustrates combustion of gaseous, liquid and solid fuels along with emission of pollutants and greenhouse gases
Chemical Thermodynamics for Industry presents the latest developments in applied thermodynamics and highlights the role of thermodynamics in the chemical industry. Written by leading experts in the field, Chemical Thermodynamics for Industry covers the latest developments in traditional areas such as calorimetry, microcalorimetry, transport properties, crystallization, adsorption, electrolyte systems and transport fuels, It highlights newly established areas such as multiphase modeling, reactive distillation, non-equilibrium thermodynamics and spectro-calorimetry. It also explores new ways of treating old technologies as well as new and potentially important areas such as ionic liquids, new materials, ab-initia quantum chemistry, nano-particles, polymer recycling, clathrates and the economic value of applied thermodynamics. This book is aimed not only at those working in a specific area of chemical thermodynamics but also at the general chemist, the prospective researcher and those involved in funding chemical research.
This textbook concerns thermal properties of bulk matter and is aimed at advanced undergraduate or first-year graduate students in a range of programs in science or engineering. It provides an intermediate level presentation of statistical thermodynamics for students in the physical sciences (chemistry, nanosciences, physics) or related areas of applied science/engineering (chemical engineering, materials science, nanotechnology engineering), as they are areas in which statistical mechanical concepts play important roles. The book enables students to utilize microscopic concepts to achieve a better understanding of macroscopic phenomena and to be able to apply these concepts to the types of sub-macroscopic systems encountered in areas of nanoscience and nanotechnology.
The utilization of refrigeration and cryogenics contributes to high-quality preservation and processing of foods, in environmental protection, and in case of emergencies. Refrigerating and cryogenic engineering enhance progress in machine-building and automation of manufacturing processes, while refrigeration and cryogenics are increasingly used in construction. Refrigerating engineering is the backbone of the air-conditioning industry.
For almost 20 years the author has conducted research on both macroscopic and molecular theories. The results of his investigation, which can be found in this work, are that irreversible thermodynamics and kinetic theory of matter are not separable especially for nonlinear irreversible processes occurring in systems removed far from equilibrium and thus must be examined together in a mutually consistent manner. Includes coverage of such topics as mass and momentum conservation law, bilinear and quadratic forms for entropy production, viscous phenomena, boundary conditions for velocities and much more.
Thermal Conductivity: Thermal Conductivity of LooseFill Materials by a RadialHeatFlow Method (D.R. Flynn). The Probe Method for Measurement of Thermal Conductivity (A.E. Wechsler). Electrical Resistivity: Methods for Electrical Resistivity Measurement Applicable to Medium and Good Electrical Conductors (B. Cales, P. Abelard). Thermal Diffusivity: Modulated Electron Beam Thermal Diffusivity Equipment (R. De Conink). The Apparatus for Measurement of Thermophysical Properties of Liquids by AC HotWire Technique (L.P. Phylippov et al.). Specific Heat: Practical Modulation Calorimetry (Y.A. Kraftmakher). The Application of Differential Scanning Calorimetry to the Measurement of Specific Heat (M.J. Richardson). Thermal Expansion: Methods of Measuring Thermal Expansion (R.K. Kirby). The Review of Certified Thermophysical Property SRMs. Fourteen additonal articles. Index.
Geostationary or equatorial synchronous satellites are a daily reminder of our space efforts during the past two decades. The nightly television satellite weather picture, the intercontinental telecommunications of television transmissions and telephone conversations, and the establishrnent of educational programs in remote regions on Earth are constant reminders of the presence of these satellites. As used here, the term 'geo stationary' must be taken loosely because, in the long run, the satellites will not remain 'stationary' with respect to an Earth-fixed reference frame. This results from the fact that these satellites, as is true for all satellites, are incessantly subject to perturbations other than the central-body attraction of the Earth. Among the more predominant pertur bations are: the ellipticity of the Earth's equator, the Sun and Moon, and solar radiation pressure. Higher harmonics of the Earth's potential and tidal effects also influence satellite motion, but they are of second order when compared to the predominant perturbations. This volume deals with the theory of geostationary satellites. It consists of seven chapters. Chapter 1 provides a general discussion including a brief history of geostationary satellites and their practical applications. Chapter 2 describes the Earth's gravitational potential field and the methodology of solving the geostationary satellite problem. Chapter 3 treats the effect of Earth's equatorial ellipticity (triaxiality) on a geostationary satellite. Chapter 4 deals with the effects of the Sun and Moon on the satellite's motion while Chapter 5 presents the combined influences of the Sun, Moon and solar radiation pressure. Chapter 6 describes various station-keeping techniques which may be used to make geostationary satellites practically stationary. Finally, Chapter 7 describes the verification of the theory developed in Chapters 3, 4 and 5 by utilizing the Early Bird synchronous satellite observed data as well as its numerically integrated results.
Thermodynamics and Statistical Mechanics provides undergraduate chemistry students with a grounding in both classical and statistical thermodynamics. Thermodynamic quantities and relationships are introduced and developed in a coherent way, enabling students to apply thermodynamic analysis to chemical problems with confidence. Each stage in the development is well illustrated with examples. The text aims to help students understand energy, its different forms and transformations, and the key role of entropy, as applied to chemical systems, addressing questions such as: (i) How much work is performed, and how much heat transfer occurs, during chemical processes and reactions, and how do they depend on temperature? (ii) How is it possible for endothermic processes to occur spontaneously, and will a given reaction occur spontaneously? (iii) What determines the equilibrium between phases? (iv) How do temperature and pressure affect equilibrium? (v) What is the meaning of entropy? (vi) How are macroscopic thermodynamic properties related to microscopic energy levels? Ideal for the needs of undergraduate chemistry students, Tutorial Chemistry Texts is a major series consisting of short, single topic or modular texts concentrating on the fundamental areas of chemistry taught in undergraduate science courses. Each book provides a concise account of the basic principles underlying a given subject, embodying an independent-learning philosophy and including worked examples.
This volume discusses the advances in numerical heat transfer modeling by applying high-performance computing resources, striking a balance between generic fundamentals, specific fundamentals, generic applications, and specific applications.
Statistical Thermodynamics and Properties of Matter is written with the advanced undergraduate and graduate student in mind. Its aim is to familiarize the student with the approach that a physicist would take, for example, when tackling problems related to quantum mechanics or thermodynamics.
Thermodynamics is used increasingly in ecology to understand the system properties of ecosystems because it is a basic science that describes energy transformation from a holistic view. In the last decade, many contributions to ecosystem theory based on thermodynamics have been published, therefore an important step toward integrating these theories and encouraging a more wide spread use of them is to present them in one volume.
In this invaluable book, macroscopic irreversible thermodynamics is presented in its realm and its splendor by appealing to the notion of internal variables of state. This applies to both fluids and solids with or without microstructures of mechanical or electromagnetic origin. This unmatched richness of essentially nonlinear behaviors is the result of the use of modern mathematical techniques such as convex analysis in a clear-cut framework which allows one to put under the umbrella of "irreversible thermodynamics" behaviors which until now have been commonly considered either not easily covered, or even impossible to incorporate into such a framework.The book is intended for all students and researchers whose main concern is the rational modeling of complex and/or new materials with physical and engineering applications, such as those accounting for coupled-field, hysteresis, fracture, nonlinear-diffusion, and phase-transformation phenomena.
This book serves as an introduction to cryocooler technology and describes the principle applications of cryocoolers across a broad range of fields. It covers the specific requirements of these applications, and describes how the advantages and disadvantages of different cryocooler systems are taken into consideration. For example, Stirling coolers tend to be used only in space applications because of their high coefficient of performance, low weight and proven reliability, whilst Gifford-McMahon coolers are used for ground applications, such as in cryopumps and MRI shield cooling applications. Joule-Thomson cryocoolers are used in missile technology because of the fast cool down requirements. The cryocooler field is fast developing and the number of applications are growing because of the increasing costs of the cryogens such as Helium and Neon. The first chapter of the book introduces the different types of cryocoolers, their classification, working principles, and their design aspects, and briefly mentions some of the applications of these systems. This introductory chapter is followed by a number of contributions from prominent international researchers, each describing a specific field of application, the cooling requirements and the cryocooler systems employed. These areas of application include gas liquefaction, space technology, medical science, dilution refrigerators, missile systems, and physics research including particle accelerators. Each chapter describes the cooling requirements based on the end use, the approximate cooling load calculations, the criteria for cryocooler selection, the arrangement for cryocooler placement, the connection of the cooler to the object to be cooled, and includes genuine case studies. Intended primarily for researchers working on cryocoolers, the book will also serve as an introduction to cryocooler technology for students, and a useful reference for those using cryocooler systems in any area of application.
This book represents a detailed and systematic account of the basic
principles, developments and applications of the theory of
nucleation. The book has four parts, which are devoted to the thermodynamics of nucleation, the kinetics of nucleation, the effect of various factors on nucleation and the application of the theory to other processes, which involve nucleation. The first two parts describe in detail the two basic approaches in nucleation theory - the thermodynamic and the kinetic ones. They contain derivations of the basic and most important formulae of the theory and discuss their limitations and possibilities for improvement. The third part deals with some of the factors that can affect nucleation and is a natural continuation of the first two chapters. The last part is devoted to the application of the theory to processes of practical importance such as melt crystallization and polymorphic transformation, crystal growth and growth of thin solid films, size distribution of droplets and crystallites in condensation and crystallization. The book is not just an account of the status quo in nucleation theory - throughout the book there are a number of new results as well as extensions and generalisations of existing ones.
Der Grundkurs Theoretische Physik deckt in 7 Banden alle fur das Diplom und fur Bachelor/Master-Studiengange massgeblichen Gebiete ab. Jeder Band vermittelt das im jeweiligen Semester notwendige theoretisch-physikalische Rustzeug. UEbungsaufgaben mit ausfuhrlichen Loesungen dienen der Vertiefung des Stoffs. Der 4. Band behandelt die Gebiete Thermodynamik und Relativitatstheorie. Fur die Neuauflage wurde er grundlegend uberarbeitet und um 24 Aufgaben erganzt. Durch die zweifarbige Gestaltung ist der Stoff jetzt noch ubersichtlicher gegliedert.
Atmospheric and climatological studies are becoming more and more
important in day-to-day living. Winds and ocean current owe their
existence to the thermodynamic imbalances that arise from the
differential heating of the Earth and air by the sun. Accounting
for heat exchanges with the atmosphere and ocean is essential in
any predictive model of the ocean and/or atmosphere. Thermodynamic
feedback processes in the atmosphere and ocean are critical to
understanding the overall stability of the Earth's climate and
climate change. Water and its phase changes make the thermodynamics
of the atmosphere and ocean uniquely interesting and
challenging.
Heat pipes today find many applications, in areas such as electronics cooling, diecasting and injection moulding, heat recovery and energy conservation, de-icing, and manufacturing process temperature control. "Heat Pipe Technology: Theory, Applications and Prospects" contains the proceedings of an important international gathering of those at the cutting edge of research in the field, with representatives of more than 20 countries. In addition to the finest technical papers, a particularly valuable feature is the inclusion of a series of regional surveys portraying the latest developments worldwide. The inherent characteristics of heat pipes (passiveness, absence of moving parts, high thermal efficiency) suggest for them an increasingly major role in the evolution of new thermal engineering systems in the years ahead. This volume will undoubtedly be an important resource for researchers worldwide in heat pipe technology.
This book discusses all three formalisms used in the study of finite temperature field theory, namely the imaginary time formalism, the closed time formalism and thermofield dynamics. Applications of the formalisms are worked out in detail. Gauge field theories and symmetry restoration at finite temperature are among the practical examples discussed in depth. The question of gauge dependence of the effective potential and the Nielsen identities are explained. The nonrestoration of some symmetries at high temperature (such as supersymmetry) and theories on nonsimply connected space-times are also described thoroughly. Other topics include (1+1)- and (2+1)-dimensional field theories at finite temperature and phase transitions, derivative expansion, linear response theory and the question of infrared divergences at finite temperature. In addition, examples of nonequilibrium phenomena are discussed with the disoriented chiral condensates as an illustration.This book is a very useful tool for graduate students, teachers and researchers in theoretical physics. |
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