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Books > Science & Mathematics > Physics > Thermodynamics & statistical physics > Thermodynamics
This is the second edition of the book "Thermodynamics of Fluids under Flow," which was published in 2000 and has now been corrected, expanded and updated. This is a companion book to our other title Extended irreversible thermodynamics (D. Jou, J. Casas-Vazquez and G. Lebon, Springer, 4th edition 2010), and of the textbook Understanding non-equilibrium thermodynamics (G. Lebon, D. Jou and J. Casas-Vazquez, Springer, 2008. The present book is more specialized than its counterpart, as it focuses its attention on the non-equilibrium thermodynamics of flowing fluids, incorporating non-trivial thermodynamic contributions of the flow, going beyond local equilibrium theories, i.e., including the effects of internal variables and of external forcing due to the flow. Whereas the book's first edition was much more focused on polymer solutions, with brief glimpses into ideal and real gases, the present edition covers a much wider variety of systems, such as: diluted and concentrated polymer solutions, polymer blends, laminar and turbulent superfluids, phonon hydrodynamics and heat transport in nanosystems, nuclear collisions, far-from-equilibrium ideal gases, and molecular solutions. It also deals with a variety of situations, emphasizing the non-equilibrium flow contribution: temperature and entropy in flowing ideal gases, shear-induced effects on phase transitions in real gases and on polymer solutions, stress-induced migration and its application to flow chromatography, Taylor dispersion, anomalous diffusion in flowing systems, the influence of the flow on chemical reactions, and polymer degradation. The new edition is not only broader in scope, but more educational in character, and with more emphasis on applications, in keeping with our times. It provides many examples of how a deeper theoretical understanding may bring new and more efficient applications, forging links between theoretical progress and practical aims. This updated version expands on the trusted content of its predecessor, making it more interesting and useful for a larger audience.
The contributions to this volume review the mathematical description of complex phenomena from both a deterministic and stochastic point of view. The interface between theoretical models and the understanding of complexity in engineering, physics and chemistry is explored. The reader will find information on neural networks, chemical dissipation, fractal diffusion, problems in accelerator and fusion physics, pattern formation and self-organisation, control problems in regions of insta- bility, and mathematical modeling in biology.
The concept of phase space plays a decisive role in the study of the transition from classical to quantum physics. This is particularly the case in areas such as nonlinear dynamics and chaos, geometric quantization and the study of the various semi-classical theories, which are the setting of the present volume. Much of the content is devoted to the study of the Wigner distribution. This volume gives the first complete survey of the progress made by both mathematicians and physicists. It will serve as an excellent reference for further research.
The pedagogically presented lectures deal with viscoelastic behaviour of fluids, the compatibility of rheological theories with nonequilibrium thermodynamics, fluids under shear, and polymer behaviour in solution and in biological systems. The main aims of the book are to stress the importance of the study of rheological systems for statistical physics and nonequilibrium thermodynamics and to present recent results in rheological modelling. The book will be a valuable source for both students and researchers.
This volume contains a series of six lecture courses presented by some of the leading exponents in the field of low-temperature physics. Special emphasis is given to theoretical and experimental advances in our understanding of 3He, heavy fermion systems and high-Tc superconductivity. The book provide an ideal basis for graduate courses in low-temperature physics.
Despite scientific evidence that business-as-usual is unsustainable, there is a huge and widespread inertia to 'greening' the planet. Warming to Ecocide considers climate change from a thermodynamic perspective and asks whether market-driven organisations have carried us to the point of no return through the flawed economics of endless growth. Warming to Ecocide begins by exploring the thermodynamic origins of climate change. It demonstrates that equilibrium thermodynamics can provide full explanations for the basic processes of life such as photosynthesis and metabolism, and that non-equilibrium thermodynamics is close to providing an explanation for how life started. Armed with a solid appreciation of the power of thermodynamics, the second half of Warming to Ecocide discusses whether multinational corporations have convinced the public that climate change is insignificant and thereby neutered any all attempts by governments to espouse environmentally-friendly policies. It then goes on to offer strategies whereby mankind may avoid propelling the global average temperature above the pre-industrial level by more than 2 DegreesC, which scientists view as a threshold presaging catastrophic run-away processes.
Combined for researchers and graduate students the articles from the Sitges Summer School together form an excellent survey of the applications of neural-network theory to statistical mechanics and computer-science biophysics. Various mathematical models are presented together with their interpretation, especially those to do with collective behaviour, learning and storage capacity, and dynamical stability.
to increase the use of direct contact processes, the National Science Foundation sup ported a workshop on direct contact heat transfer at the Solar Energy Research Insti tute in the summer of 1985. We served as organizers for this workshop, which em phasized an area of thermal engineering that, in our opinion, has great promise for the future, but has not yet reached the point of wide-spread commercial application. Hence, a summary of the state of knowledge at this point is timely. The workshop had a dual objective: 1. To summarize the current state of knowledge in such a form that industrial practi tioners can make use of the available information. 2. To indicate the research and development needed to advance the state-of-the-art, indicating not only what kind of research is needed, but also the industrial poten tial that could be realized if the information to be obtained through the proposed research activities were available.
Materials sciences relate the macroscopic properties of materials to their microscopic structure and postulate the need for holistic multiscale research. The investigation of shape memory alloys is a prime example in this regard. This particular class of materials exhibits strong coupling of temperature, strain and stress, determined by solid state phase transformations of their metallic lattices. The present book presents a collection of simulation studies of this behaviour. Employing conceptually simple but comprehensive models, the fundamental material properties of shape memory alloys are qualitatively explained from first principles. Using contemporary methods of molecular dynamics simulation experiments, it is shown how microscale dynamics may produce characteristic macroscopic material properties. The work is rooted in the materials sciences of shape memory alloys and covers thermodynamical, micro-mechanical and crystallographical aspects. It addresses scientists in these research fields and their students.
Entransy in Phase-Change Systems summarizes recent developments in the area of entransy, especially on phase-change processes. This book covers new developments in the area including the great potential for energy saving for process industries, decreasing carbon dioxide emissions, reducing energy bills and improving overall efficiency of systems. This concise volume is an ideal book for engineers and scientists in energy-related industries.
Large-scale winds and currents tend to balance Coriolis and pressure gradient forces. The time evolution of these winds and currents is the subject of the quasi-geostrophic theory. Chapter 1 presents concepts and equations of classical inertial fluid mechanics. Chapter 2 deals with the equations of thermodynamics that close the governing equations of the fluids. Then, the motion is reformulated in a uniformly rotating reference frame. Chapter 3 deals with the shallow-water model and the homogeneous model of wind-driven circulation. The chapter also describes a classical application of the Ekman layer to the atmosphere. Chapter 4 considers the two-layer model, as an introduction to baroclinic flows, together with the concept of available potential energy. Chapter 5 takes into account continuously stratified flows in the ocean and in the atmosphere.
The domain of non-extensive thermostatistics has been subject to intensive research over the past twenty years and has matured significantly. Generalised Thermostatistics cuts through the traditionalism of many statistical physics texts by offering a fresh perspective and seeking to remove elements of doubt and confusion surrounding the area. The book is divided into two parts - the first covering topics from conventional statistical physics, whilst adopting the perspective that statistical physics is statistics applied to physics. The second developing the formalism of non-extensive thermostatistics, of which the central role is played by the notion of a deformed exponential family of probability distributions. Presented in a clear, consistent, and deductive manner, the book focuses on theory, part of which is developed by the author himself, but also provides a number of references towards application-based texts. Written by a leading contributor in the field, this book will provide a useful tool for learning about recent developments in generalized versions of statistical mechanics and thermodynamics, especially with respect to self-study. Written for researchers in theoretical physics, mathematics and statistical mechanics, as well as graduates of physics, mathematics or engineering. A prerequisite knowledge of elementary notions of statistical physics and a substantial mathematical background are required.
The study of thermodynamics is often limited to classical thermodynamics where minimal laws and concepts lead to a wealth of equations and applications. The resultant equations best describe systems at equilibrium with no temporal or s- tial parameters. The equations do, however, often provide accurate descriptions for systems close to equilibrium. . Statistical thermodynamics produces the same equilibrium information starting with the microscopic properties of the atoms or molecules in the system that correlates with the results from macroscopic classical thermodynamics. Because both these disciplines develop a wealth of information from a few starting postulates, e. g. , the laws of thermodyamics, they are often introduced as independent disciplines. However, the concepts and techniques dev- oped for these disciplines are extremely useful in many other disciplines. This book is intended to provide an introduction to these disciplines while revealing the connections between them. Chemical kinetics uses the statistics and probabilities developed for statistical thermodynamics to explain the evolution of a system to equilibrium. Irreversible thermodynamics, which is developed from the equations of classical thermodyn- ics, centers on distance-dependent forces, and time-dependent ?uxes. The force ?ux equations of irreversible thermodynamics lead are generated from the intensive and extensive variables of classical thermodynamics. These force ?ux equations lead, in turn, to transport equations such as Fick's ?rst law of diffusion and the Nernst Planck equation for electrochemical transport. The book illustrates the concepts using some simple examples.
Hydrogen in Intermetallics I is the first of two volumes aiming to provide atutorial introduction to the general topic of hydrogen in intermetallic compounds and alloys. In the present volume, a series of chapters, each written by two experts in the field, gives a comprehensive review of thefollowing areas: -preparation of intermetallics and their hydrides on a laboratory and industrial scale; - thermodynamic properties; -crystal and magnetic structure; - electronic properties; - heat of formation models; - magnetism and superconductivity.
In this volume the author gives a detailed presentation of his theory of multiphase mixtures with structure. The book also addresses students, and in addition encourages further research. Based on the concept of averaging the field equations, conservation and balance equations are developed. A material deformation postulate leads to structured mixtures. The resulting model is compared with those in use elsewhere. The final chapters are devoted to constitutive theory and constitutive equations. In particular, two-phase mixtures are treated in some detail.
An understanding of statistical thermodynamic molecular theory is fundamental to the appreciation of molecular solutions. This complex subject has been simplified by the authors with down-to-earth presentations of molecular theory. Using the potential distribution theorem (PDT) as the basis, the text provides a discussion of practical theories in conjunction with simulation results. The authors discuss the field in a concise and simple manner, illustrating the text with useful models of solution thermodynamics and numerous exercises. Modern quasi-chemical theories that permit statistical thermodynamic properties to be studied on the basis of electronic structure calculations are given extended development, as is the testing of those theoretical results with ab initio molecular dynamics simulations. The book is intended for students taking up research problems of molecular science in chemistry, chemical engineering, biochemistry, pharmaceutical chemistry, nanotechnology and biotechnology.
This unique book provides a fundamental introduction to all aspects of modern plasma chemistry. The book describes mechanisms and kinetics of chemical processes in plasma, plasma statistics, thermodynamics, fluid mechanics, and electrodynamics, as well as all major electric discharges applied in plasma chemistry. The book considers most of the major applications of plasma chemistry from electronics to thermal coatings, from treatment of polymers to fuel conversion and hydrogen production, and from plasma metallurgy to plasma medicine. The book can be helpful to engineers, scientists, and students interested in plasma physics, plasma chemistry, plasma engineering, and combustion, as well as in chemical physics, lasers, energy systems, and environmental control. The book contains an extensive database on plasma kinetics and thermodynamics as well as a lot of convenient numerical formulas for practical calculations related to specific plasma-chemical processes and applications. The book contains a large number of problems and concept questions that are helpful in university courses related to plasma, lasers, combustion, chemical kinetics, statistics and thermodynamics, and high-temperature and high-energy fluid mechanics.
Computational Fluid Dynamics has now grown into a multidisciplinary activity with considerable industrial applications. The papers in this volume bring out the current status and future trends in CFD very effectively. They cover numerical techniques for solving Euler and Navier-Stokes equations and other models of fluid flow, along with a number of papers on applications. Besides the 88 contributed papers by research workers from all over the world, the book also includes 6 invited lectures from distinguished scientists and engineers.
This monograph presents an integrated perspective of the wide range of phenomena and processes applicable to the study of transport of species in porous materials. In order to formulate the entire range of porous media and their uses, this book gives the basics of continuum mechanics, thermodynamics, seepage and consolidation and diffusion, including multiscale homogenization methods. The particular structure of the book has been chosen because it is essential to be aware of the true properties of porous materials particularly in terms of nano, micro and macro mechanisms. This book is of pedagogical and practical importance to the fields covered by civil, environmental, nuclear and petroleum engineering and also in chemical physics and geophysics as it relates to radioactive waste disposal, geotechnical engineering, mining and petroleum engineering and chemical engineering.
This companion provides a collection of frequently needed numerical data as a convenient desk-top or pocket reference for atmospheric scientists as well as a concise source of information for others interested in this matter. The material contained in this book was extracted from the recent and the past scientific literature; it covers essentially all aspects of atmospheric chemistry. The data are presented primarily in the form of annotated tables while any explanatory text is kept to a minimum. In this condensed form of presentation, the volume may serve also as a supplement to many textbooks used in teaching the subject at various universities. Peter Warneck, a physical chemist specializing in atmospheric chemistry, received the diploma in 1954 and the doctorate in 1956 at the university in Bonn, Germany. In 1959, following several postdoctoral assignments, he joined the GCA Corporation in Bedford, Massachusetts, where he explored elementary processes in the atmospheres of the earth and other planets. He returned to Germany in 1970 to head the chemical kinetics group in the Air Chemistry Division of the Max-Planck-Institute for Chemistry in Mainz. In 1974 he also became professor of physical chemistry at the university in Mainz. In 1991, following German reunification, Warneck was appointed the founding director of the new Institute for Tropospheric Research in Leipzig. He served in this position parallel to his activities in Mainz until official retirement. Warneck s research included laboratory studies of chemical mechanisms and photochemistry as well as the development of analytical techniques for field measurements. Since 1990, his interests are focused on chemical reactions in clouds. Jonathan Williams is an atmospheric chemist. He received his BSc in Chemistry and French and his Ph.D. in Environmental Science from the University of East Anglia, England. Between 1995-1997 he worked as a postdoctoral researcher at the NOAA Aeronomy laboratory in Boulder, USA, and from 1998 to present as a member of staff at the Max Planck Institute for Chemistry, Mainz, Germany. He has participated in many international field measurement campaigns on aircraft, ships and at ground stations. Dr Williams is currently an editor on three atmospheric chemistry journals. His present research involves investigating the chemistry of reactive organic species in the atmosphere, in particular over forested ecosystems and in the marine boundary layer. Dr Williams leads a research group focussed specifically on Volatile Organic Compounds (VOC) at the Max Planck Institute and in 2008 he was made an honorary Reader at the University of East Anglia, UK."
This book contains the edited proceedings of the 2nd Internat- ional Conference on Computationa1 Methods and Experimental Meas- urements held on board the QE2 liner from 27th June to 2nd Ju1y 1984. The meeting was sponsored by the International Society for Computationa1 Methods in Engineering and the Department of Civi1 Engineering, Southampton University and organized by the Computationa1 Mechanics Institute of Southampton, England. The QE2 provided an ideal environment for the international meeting and one that was equa11y convenient for the USA and European re- searchers and offered a 10cation propitious to the interchange of ideas and c10se contact between participants. This book covers a wide range of different topics in Computat- iona1 Methods and Experimental Measurements with the main empha- sis on the re1ationships between experimental and ana1ytica1 5- utions. The first section deals with fluid dynamics problems and a 1arge number of app1ications. Section 2 considers geophysica1 fluid dynamics and describes some atmospheric models and their re1ated problems. Water resources are dealt with in Section 3 which describes some app1ications of porous media f10w and sur- face water mode11ing. Wave interaction problems are described in Section 4 and Section 5 considers some important heat transfer app1ications. Other sections - 6 & 7 - study problems re1ated to stress analysis and structura1 app1ications. Vibration pro- blems are becoming of fundamental importance in engineering and part of the Conference Proceedings - Section 8 - are dedicated to the study of experimental and computational models.
This volume collects contributions to the workshop on "Turbulence Modeling and Vortex Dynamics, Istanbul," where engineers, physicists, and mathematicians discussed the statistical description of turbulence. They cover practical aspects as well as rigorous mathematics. This book will be a source of reference for many years for those working in this most fascinating field of scientific modeling.
On June 19th 1999, the European Ministers of Education signed the Bologna Dec laration, with which they agreed that the European university education should be uniformized throughout Europe and based on the two cycle bachelor master's sys tem. The Institute for Theoretical Physics at Utrecht University quickly responded to this new challenge and created an international master's programme in Theoret ical Physics which started running in the summer of 2000. At present, the master's programme is a so called prestige master at Utrecht University, and it aims at train ing motivated students to become sophisticated researchers in theoretical physics. The programme is built on the philosophy that modern theoretical physics is guided by universal principles that can be applied to any sub?eld of physics. As a result, the basis of the master's programme consists of the obligatory courses Statistical Field Theory and Quantum Field Theory. These focus in particular on the general concepts of quantum ?eld theory, rather than on the wide variety of possible applica tions. These applications are left to optional courses that build upon the ?rm concep tual basis given in the obligatory courses. The subjects of these optional courses in clude, for instance, Strongly Correlated Electrons, Spintronics, Bose Einstein Con densation, The Standard Model, Cosmology, and String Theory.
This book provides a solid foundation in the principles of heat and mass transfer and shows how to solve problems by applying modern methods. The basic theory is developed systematically, exploring in detail the solution methods to all important problems. The revised second edition incorporates state-of-the-art findings on heat and mass transfer correlations. The book will be useful not only to upper- and graduate-level students, but also to practicing scientists and engineers. Many worked-out examples and numerous exercises with their solutions will facilitate learning and understanding, and an appendix includes data on key properties of important substances.
ThisvolumeisacollectionofarticlesoriginallypublishedonaSpecialIssueoftheAstrophysicsandSpaceScienceJournal. It is intended to give a comprehensive overview of the current state of knowledge in solar and stellar modelling, with the aim of comparing and extending what we know from the detailed solar modelling, made possible by the helioseismic tools and by the recent analysis of the solar spectrum, to the modelling and understanding of generic stellar structures and their evolution. Particular emphasis is devoted to the role of the input physics, and its relevant uncertainties, in the construction of stellar models and in the resulting predictions for general observable quantities. Issues related to convection, overshoot, diffusion and settling of helium and heavy elements, rotation, chemical composition and magnetic eld are extensively discussed. Large space is dedicated to the application of helio- and asteroseismic techniques as tools to prove the theory of the evolution and the structure of the stars. Comments on prospects for future improvements and re nements of the theoretical models are given, focusing on the possibility of getting ever more precise helioseismic and asteroseismic observations from ground and space. The articles included in this volume are the results of the HELAS-NA5 workshop 'Synergies between solar and stellar modelling' held in Rome from 22nd to 26th of June 2009, which was an unique occasion to gather the solar and the stellar physics communities to discuss the urgent questions risen by recent photometric and spectroscopic observational results. |
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