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Books > Science & Mathematics > Physics > Thermodynamics & statistical physics > Thermodynamics
The idea of a workshop devoted to the static and dynamic properties of liquids arose from two smaller meetings on the same topic held at the Interfaculty Reactor Institute, Delft, The Netherlands in 1985 and 1987, and from the LAM conference (International Conference on Liquid and Amorphous Metals) held at Garmisch Partenkirchen, FRG, in 1986. The object of the Workshop was to bring together experimentalists, theoreticians and people working on computer simulations in or der to learn about developments in the microscopic behaviour of liquids. Approx imately 35 scientists from Austria, France, Israel, Italy, Sweden, The Netherlands, the United Kingdom, the Federal Republic of Germany and Yugoslavia gathered at the Hotel "Libertas", Dubrovnik, in Yugoslavia, June 27-30, 1988 to hear ten in vited talks and nineteen contributed papers on a wide range of subjects, including generalized hydrodynamics, mode coupling theory, liquids at surfaces, extraction of effective potentials, and the glass transition. The most numerous were the papers dealing with computer simulation, and then those on supercooled liquids and the glass transition. The number of experimental results was relatively small, which points to difficulties in this kind of research (evaluation of experimental data). The workshop closed with an expanded round-table discussion of the main themes of the meeting, with an emphasis on the likely trend of investigations in the future. This discussion is summarized at the end of this volume.
During the last decade there has been a renewed interest in research on supramolecular assemblies in solutions, such as micelles and microemulsions, not only because of their extensive applications in industries dealing with catalysts, detergency, biotechnology, and enhanced oil recovery, but also due to the development of new and more powerful experimental and theoretical tools for probing the microscopic behavior of these systems. Prominent among the array of the newly available experimental techniques are photon correlation spectroscopy, small-angle neutron and X-ray scattering, and neutron spin-echo and nuclear magnetic resonance spectroscopies. On the theoretical side, the traditionally emphasized thermodynamic approach to the study of the phase behavior of self-assembled systems in solutions is gradually being replaced by statistical mechanical studies of semi-micro scopic and microscopic models of the assemblies. Since the statistical mechanical approach demands as its starting point the microscopic struc tural information of the self-assembled system, the experimental determina tion of the structures of micelles and microemulsions becomes of paramount interest. In this regard the scattering techniques mentioned above have played an important role in recent years and will continue to do so in the future. In applying the scattering techniques to the supramolecular species in solution, one cannot often regard the solution to be ideal. This is because the inter-aggregate interaction is often long-ranged since it is coulombic in nature and the interparticle correlations are thus appreciable."
What is thermodynamics? What does statistical physics teach us? In the pages of this slim book, we confront the answers. The reader will discover that where thermodynami cs provi des a 1 arge scal e, macroscopi c theory of the ef fects of temperature on physical systems, statistical mechanics provides the microscopic analysis of these effects which, invariably, are the results of thermal disorder. A number of systems in nature undergo dramatic changes in aspect and in their properties when subjected to changes in ambient temperature or pres sure, or when electric or magnetic fields are applied. The ancients already knew that a liquid, a solid, or a gas can represent different states of the same matter. But what is meant by "state"? It is here that the systematic study of magnetic materials has provided one of the best ways of examining this question, which is one of the principal concerns of statistical physics (alias "statistical mechanics") and of modern thermodynamics."
Universality is one of the fascinating features of condensed matter physies: it is the property whereby systems of radieally different composition and structure ex- hibit similar behavior. In the mid-1960s the word entered usage to express the fact that the equations of state of several substances could be mapped onto one another near the critical point: critieal universality. Renormalization group theory in the early 1970s provided both an explanation and a sharper definition of universality. Systems with similar behavior - universality classes - correspond to the same fixed point of a renormalization group transformation. A number of brilliant con- tributions showed how the same concepts could be applied to non-thermodynamie systems, such as the statisties of self-avoiding walks or of connected clusters on a lattice. A few years later it was realized that chaotie dynamieal systems mayaiso exhibit some degree of universality, the paradigmatic example being the period doubling cascade in the iterated maps of the unit interval into itself.
This work marks a stage in the evolution of a scientific and technical field which has been developed by the Commissariat a l'Energie Atomique (CEA) over several decades. Many members of the staff of the CEA have won re nown in this field, and their work has brought it to the high degree of excel lence for which it is internationally recognized today. These scientists had to consider every aspect of the field, as it concerned: modeling, which has recourse to fluid thermodynamics, molecular phys ics, and chemistry; numerical evaluation, which relies on mathematical analysis and data processing; and experiments in the firing area, which require specific stress generators and instrumentation. Whilst this book is a testament to the activity and success of staff of the CEA, it also reviews a number ofthe advances made in the discipline. How ever, it is not intended to be an exhaustive account of those advances; it is assumed that the reader can, if desired, consult the standard monographs, and more recent, more specialized works (notably W.C. Davis and W. Fickett, and C.L. Mader). The history of the discipline is interesting in itself, and also as an illustra tion of the causes which lead to progress in a coherent body of scientific work. I should like to make some comments on this progress, of which there is a fascinating summary in the introduction, and which will figure largely throughout the work."
At first glance it may seem presumptuous to want to add yet another to the numerous books on Differential Thermal Analysis (DT A). Thermoanalytical methods have been in use for some time, as shown by the more than five thousand publications containing DT A or TG curves listed by SMOTHERS and CHIANG in the bibliography to their handbook and abstracted in the several volumes of Thermal Analysis Abstracts (TAA), edited by J. P. REDFERN for the International Con federation for Thermal Analysis (ICT A). Every three years the proceed ings of ICT A meetings are published, bringing the latest results of thermoanalytic research. There is also the Scifax DT A Data Index, edited by R. C. MACKENZIE (1962) and modeled on the ASTM pattern card index (used for X-ray investigations), a compilation of the DT A data for several hundred minerals, and inorganic and organic materials. The theoretical foundations of thermogravimetry and DT A have been described in detail by LEHMANN, DAS and PAETSCH (1953), R. C. MACKENZIE (1957, 1970), DUVAL (1963), WENDLANDT (1964), GARN (1965), F. PAULIK et al. (1966), SMOTHERS and CHIANG (1966), and KEATTCH (1969). Thermoanalytical results are strongly influenced by various factors relative to preparation and equipment (see 1-2. 4 of this study). This is the reason why we frequently find, in these books as well as in the Scifax-Card catalog, contradictory data on the same substance."
Fundamentals of Continuum Mechanics of Soils provides a long-needed general scheme for the study of the important yet problematic material of soil. It closes the gap between two disciplines, soil mechanics and con- tinuum mechanics, showing that the familiar concepts of soil mechanics evolve directly from continuum mechanics. It confirms concepts such as pore pressures, cohesion and dependence of the shear stress on consolidation, and rejects the view that continuum mechanics cannot be applied to a material such as soil. The general concepts of continuum mechanics, field equations and constitutive equations are discussed. It is shown how the theory of mixtures evolves from these equations and how, along with energetics and irrevers- ible thermodynamics, it can be applied to soils. The discussion also sheds light on some aspects of mechanics of materials, especially compressible materials. Examples are the introduction of the Hencky measure of strain, the requirement of dual constitutive equations, and the dependence of the spent internal energy on the stored internal energy. Researchers in engineering mechanics and material sciences may find that the results of experiments on soils can be generalized and extended to other materials. The book is a reference text for students familiar with the fundamentals of mechanics, for scholars of soil engineering, and for soil scientists. It is also suitable as an advanced undergraduate course in soil mechanics.
This book consists of two parts, the first dealing with dissipative structures and the second with the structure and physics of chaos. The first part was written by Y. Kuramoto and the second part by H. Mori. Throughout the book, emphasis is laid on fundamental concepts and methods rather than applications, which are too numerous to be treated here. Typical physical examples, however, including nonlinear forced oscilla tors, chemical reactions with diffusion, and Benard convection in horizontal fluid layers, are discussed explicitly. Our consideration of dissipative structures is based on a phenomenolog ical reduction theory in which universal aspects of the phenomena under consideration are emphasized, while the theory of chaos is developed to treat transport phenomena, such as the mixing and diffusion of chaotic orbits, from the viewpoint of the geometrical phase space structure of chaos. The title of the original, Japanese version of the book is Sanitsu Kozo to Kaosu (Dissipative Structures and Chaos). It is part of the Iwanami Koza Gendai no Butsurigaku (Iwanami Series on Modern Physics). The first Japanese edition was published in March 1994 and the second in August 1997. We are pleased that this book has been translated into English and that it can now have an audience outside of Japan. We would like to express our gratitude to Glenn Paquette for his English translation, which has made this book more understandable than the original in many respects."
This book brings together data from Czechoslovakia on vapor pressures, data from England on critical properties, and data from America on physical properties of organic and organometallic compounds to provide a basic reference book for engineers and scientists involved with research and design in the chemical and petroleum industries. We would like to acknowledge Jaroslav Dykyj, Milan Repas, and Josef Svo boda of Czechoslovakia for providing the material on Antoine constants and Douglas Ambrose of the University of London for providing the material on critical properties. Stanislaw Malanowski pointed out and made available the sources of data from Eastern Europe. Richard Stephenson translated and correlated the data in tabular form. We would like to thank Dr. Matej Andras of the Slovenska Literarna Agentura for granting permission to use the data from Czechoslovakia and Dr. Marjan Bace of Elsevier Science Publishing Co., Inc., who encouraged preparation of this manuscript and handled the publishing arrangements. Particular thanks go to Mary Stephenson for typing the entire camera-ready copy. Richard M. Stephenson University of Connecticut Storrs, Connecticut Stanislaw Malanowski Institute of Physical Chemistry Warsaw, Poland vii Introduction All scientific and engineering calculations are dependent on the availability of thennodynamic and physical property data for the materials or systems in question. This dependency is particularly true in engineering design, which relies almost exclusively on computers for accurate data to produce meaningful final designs."
The result of two decades spent developing and refining the phase-integral method to a high level of precision, the authors have applied this method to problems in various fields of theoretical physics. The problems treated are of a mathematical nature, but have important physical applications. This book will thus be of great use to research workers in various branches of theoretical physics, where the problems can be reduced to one-dimensional second-order differential equations of the Schrodinger type for which phase-integral solutions are required. Includes contributions from notable scientists who have already made use of the authors'technique."
It seemed appropriate to arrange a meeting of teachers of thermodynamics in the United Kingdom, a meeting held in the pleasant surroundings of Emmanuel College, Cambridge, in Sept mber, 1984. This volume records the ideas put forward by authors, the discussion generated and an account of the action that discussion has initiated. Emphasis was placed on the Teaching of Thermodynamics to degree-level students in their first and second years. The meeting, a workshop for practitioners in which all were expected to take part, was remarkably well supported. This was notable in the representation of essentially every UK university and polytechnic engaged in teaching engineering thermodynamics and has led to a stimulating spread of ideas. By intention, the emphasis for attendance was put on teachers of engineering concerned with thermodynamics, both mechanical and chemical engineering disciplines. Attendance from others was encouraged but limited as follows: non-engineering acad emics, 10%, industrialists, 10%. The record of attendance, which will also provide addresses for direct correspondance, will show the broad cover achieved. I am indeed grateful for the attendance of those outside the engineering departments who in many cases brought a refreshing approach to discussions of the 'how' and 'why' of teaching thermodynamics. It was also notable that many of those speaking from the polytechnics had a more original approach to the teaching of thermodynamics than those from conventional universities. The Open University however brought their own special experience to bear."
Since the petroleum crisis in the 1970s, a lot of effort to save energy was made in industry, and remarkable achievements have been made. In the research and development concerning thermal energy, however, it was clar ified that one of the most important problems was manufacturing con densing systems with smaller size and higher performance. To solve this problem we need a method which synthesizes selections_ of the type of con denser, cooling tube and its arrangement, assessment of fouling on the cooling surfaces, consideration of transient characteristics of a condenser, etc. The majority of effort, however, has been to devise a surface element which enhances the heat transfer coefficient in condensation of a single or multicomponent vapor. Condensation phenomena are complexly affected by a lot of physical property values, and accordingly the results of theo retical research are expressed with several dimensionless parameters. On the other hand, the experimental research is limited to those with some specified cooling surfaces and some specified working fluids. Hence, the basic research of condensation is necessary for criticizing the enhancement effect as well as for an academic interest."
One of the major achievements in computational fluid dynamics has been the development of numerical methods for simulating compressible flows, combining higher-order accuracy in smooth regions with a sharp, oscillation-free representation of embedded shocks methods and now known as "high-resolution schemes." Together with introductions from the editors written from the modern vantage point this volume collects in one place many of the most significant papers in the development of high-resolution schemes as occured at ICASE.
This book addresses several of the foundational problems in thermophysics, i. e. thermodynamics and statistical mechanics. It is an interdisciplinary work in that it examines the philosophical underpinning of scientific models and theories; it also refines the analysis of the problems at hand and delineates the place occupied by various scientific models in a generalized philosophical landscape. Hence, our philosophical - or theoretical - inquiry focuses sharply on the concept of models; and our empirical - or laboratory - evidence is sought in the model-building activities of scientists who have tried to confront the epistemological problems arising in the thermophysical sciences. Primarily for researchers and students in physics, philosophy of science, and mathematics, our book aims at informing the readers - with all the in dispensable technical details made readily available - about the nature of the foundational problems, how these problems are approached with the help of various mathematical models, and what the philosophical implications of such models and approaches involve. Some familiarity with elementary ther mophysics and/or with introductory-level philosophy of science may help, but neither is a prerequisite. The logical and mathematical background re quired for the book are introduced in the Appendices. Upon using the Subject Index, the readers may easily locate the concepts and theorems needed for understanding various parts of the book. The Citation Index lists the authors of the contributions we discuss in detail."
In the decades the of the formation of structures past subject spontaneous in far from has into a branch of - systems equilibrium major physics grown search with ties to It has become evident that strong neighboring disciplines. a diverse of can be understood within a common mat- phenomena range matical framework which has been called nonlinear of continuous dynamics This name the close to the field of nonlinear systems. emphasizes relationship of with few of freedom which has evolved into a dynamics systems degrees mature in the recent features mathematically subject past. Many dynamical of continuous be described reduction few can a to a systems actually through of freedom and of the latter of continue to degrees properties type systems of continuous the inspire study systems. The of this book is to demonstrate the numerous goal through examples that exist for the of nonlinear the opportunities study phenomena through tools of mathematical and use of common analyses dynamical interpretations. Instead of overview of the a providing comprehensive rapidly evolving field, the contributors to this book are to communicate to a wide scientific trying audience the of what have learnt about the formation of essence they spon- neous structures in continuous and about the dissipative systems competition between order and chaos that characterizes these It is that systems. hoped the book will be even to those scientists whose not helpful are disciplines the authors.
Fluid flows that transfer heat and mass often involve drops and bubbles, particularly if there are changes of phase in the fluid in the formation or condensation of steam, for example. Such flows pose problems for the chemical and mechanical engineer significantly different from those posed by single-phase flows. This book reviews the current state of the field and will serve as a reference for researchers, engineers, teachers, and students concerned with transport phenomena. It begins with a review of the basics of fluid flow and a discussion of the shapes and sizes of fluid particles and the factors that determine these. The discussion then turns to flows at low Reynolds numbers, including effects due to phase changes or to large radial inertia. Flows at intermediate and high Reynolds numbers are treated from a numerical perspective, with reference to experimental results. The next chapter considers the effects of solid walls on fluid particles, treating both the statics and dynamics of the particle-wall interaction and the effects of phase changes at a solid wall. This is followed by a discussion of the formation and breakup of drops and bubbles, both with and without phase changes. The last two chapters discuss compound drops and bubbles, primarily in three-phase systems, and special topics, such as transport in an electric field.
This concise and unified text reviews recent contributions to the principles of convective heat transfer for single and multi-phase systems. This valuable new edition has been updated throughout and contains new examples and problems.
This volume contains the proceedings of the Seventh International Conference on Phonon Scattering in Condensed Matter held August 3-7, 1992, at Cornell University in Ithaca, NY, USA. The preceding conferences were held at: St. Maxime and Paris (France) 1972, Nottingham (UK) 1975, Providence (USA) 1979, Stuttgart (Germany) 1983, Urbana (USA) 1986, and Heidelberg (Germany) 1989. The Heidelberg conference was held jointly with the Third International Con ference on Phonon Physics. The next conference, to be held in August, 1995, in Sapporo, Japan, and hosted by Professor T. Nakayama and his colleagues, will also be such a joint conference. This conference was attended by 227 scientists from 27 countries, and covered all aspects of phonon scattering in condensed matter, ranging from the more traditional topics of thermal conductivity, Kapitza resistance, and ballistic phonon propagation to the recently added topics, such as electron-phonon interaction in high-T c superconductors, the use of phonons in particle detection, and phonons in confined geometries. The 207 papers arranged in 11 chapters in this volume are a cross section of the present activities in the quite obviously vibrant field of phonons and their interactions."
Statistical thermodynamics and the related domains of statistical physics and quantum mechanics are very important in many fields of research, including plasmas, rarefied gas dynamics, nuclear systems, lasers, semiconductors, superconductivity, ortho- and para-hydrogen, liquid helium, and so on. Statistical Thermodynamics: Understanding the Properties of Macroscopic Systems provides a detailed overview of how to apply statistical principles to obtain the physical and thermodynamic properties of macroscopic systems. Intended for physics, chemistry, and other science students at the graduate level, the book starts with fundamental principles of statistical physics, before diving into thermodynamics. Going further than many advanced textbooks, it includes Bose-Einstein, Fermi-Dirac statistics, and Lattice dynamics as well as applications in polaron theory, electronic gas in a magnetic field, thermodynamics of dielectrics, and magnetic materials in a magnetic field. The book concludes with an examination of statistical thermodynamics using functional integration and Feynman path integrals, and includes a wide range of problems with solutions that explain the theory.
Convective heat tranfer is the result of fluid flowing between objects of different temperatures. Thus it may be the objective of a process (as in refrigeration) or it may be an incidental aspect of other processes. This monograph reviews in a concise and unified manner recent contributions to the principles of convective heat transfer for single- and multi-phase systems: It summarizes the role of the fundamental mechanism, discusses the governing differential equations, describes approximation schemes and phenomenological models, and examines their solutions and applications. After a review of the basic physics and thermodynamics, the book divides the subject into three parts. Part 1 deals with single-medium transfer, specifically with intraphase transfers in single-phase flows and with intramedium transfers in two-phase flows. Part 2 deals with fluid-solid transfer processes, both in cases where the interface is small and in cases where it is large, as well as liquid-liquid transfer processes. Part 3 considers three media, addressing both liquid-solid-solid and gas-liquid-solid systems.
Macroscopic physics provides us with a great variety of pattern-forming systems displaying propagation phenomena, from reactive fronts in combustion, to wavy structures in convection and to shear flow instabilities in hydrodynamics. These proceedings record progress in this rapidly expanding field. The contributions have the following major themes: - The problems of velocity selection and front morphology of propagating interfaces in multiphase media, with emphasis on recent theoretical and experimental results on dendritic crystal growth, Saffman-Taylor fingering, directional solidification and chemical waves. - The "unfolding" of large-scale, low-frequency behavior in weakly confined homogeneous systems driven far from equilibrium, and more specifically, the envelope approach to the mathematical description of textures in different cases: steady cells, propagating waves, structural defects, and phase instabilities. - The implications of the presence of global downstream transport in open flows for the nature, convective or absolute, of shear flow instabilities, with applications to real boundary layer flows or shear layers, as reported in contributions covering experimental situations of fundamental and/or engineering interest.
The development of the modern theory of metals and alloys has coincided with great advances in quantum-mechanical many-body theory, in electronic structure calculations, in theories of lattice dynamics and of the configura tional thermodynamics of crystals, in liquid-state theory, and in the theory of phase transformations. For a long time all these different fields expanded quite independently, but now their overlap has become sufficiently large that they are beginning to form the basis of a comprehensive first-principles the ory of the cohesive, structural, and thermodynamical properties of metals and alloys in the crystalline as well as in the liquid state. Today, we can set out from the quantum-mechanical many-body Hamiltonian of the system of electrons and ions, and, following the path laid out by generations of the oreticians, we can progress far enough to calculate a pressure-temperature phase diagram of a metal or a composition-temperature phase diagram of a binary alloy by methods which are essentially rigorous and from first prin ciples. This book was written with the intention of confronting the materials scientist, the metallurgist, the physical chemist, but also the experimen tal and theoretical condensed-matter physicist, with this new and exciting possibility. Of course there are limitations to such a vast undertaking as this. The selection of the theories and techniques to be discussed, as well as the way in which they are presented, are necessarily biased by personal inclination and personal expertise."
Speech by Toyosaburo Taniguchi Dr. Kubo, Chairman, Distinguished Guests, and Friends, I am very happy, pleased and honored to be here this evening with so many distinguished guests, friends, and scholars from within this country and from different parts of the world. The Taniguchi Foundation wishes to extend a warm and sincere welcome to the many participants of the Ninth International Symposium on the Theory of Condensed Matter, which se ries was inaugurated eight years ago through the strenuous efforts of Dr. Ryogo Kubo, who is gracing us today with his presence. We are deeply indebted to Dr. Kubo, Dr. Suzuki, and their associates, who havE' spent an enormous amount of time and effort to make this particular symposium possible. We are convinced that the foundation should not be considered as what makes our symposium a success. The success is entirely due, I feel, to the continuous efforts of the Organizing Committee and of all those who have lent their support to this program. In this sense, your words of praise about the symposium, if any, should be directed to all of them. So far, I have met in person a total of 62 participants in this Division from 12 countries: Argentina, Belgium, Canada, Denmark, the Federal Republic of Germany, France, Ireland, Israel, Rumania, Switzerland, the United Kingdom, and the United States of America, with 133 participants from Japan. Those friends I have been privileged to make, I shall always treasure."
B. Coleman, M.E. Gurtin: Thermodynamics and wave propagation in Elastic and Viscoelastic media.- L. De Vito: Sui fondamenti della meccanica di sistemi continui (II).- G. Fichera: Problemi elastostatici con ambigue condizioni al contorno.- G. Grioli: Sistemi a trasformazioni reversibili.- W. Noll: the foundations of mechanics.- R.A. Toupin: Elasticity and electromagnetic.- C.C. Wang: Subfluids.
Mon but n'a jamais be de m'occuper des ces matieres comme physicien, mais seulement comme /ogicien ... F. REECH, 1856 I do not think it possible to write the history of a science until that science itself shall have been understood, thanks to a clear, explicit, and decent logical structure. The exuberance of dim, involute, and undisciplined his torical essays upon classical thermodynamics reflects the confusion of the theory itself. Thermodynamics, despite its long history, has never had the benefit of a magisterial synthesis like that which EULER gave to hydro dynamics in 1757 or that which MAXWELL gave to electromagnetism in 1873; the expositions in the works of discovery in thermodynamics stand a pole apart from the pellucid directness of the notes in which CAUCHY presented his creation and development of the theory of elasticity from 1822 to 1845. Thermodynamics was born in obscurity and disorder, not to say confusion, and there the common presentations of it have remained. With this tractate I aim to provide a simple logical structure for the classical thermodynamics of homogeneous fluid bodies. Like any logical structure, it is only one of many possible ones. I think it is as simple and pretty as can be." |
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