Review articles by leading scientists in their fields are brought together in this volume to provide a comprehensive treatment of photoacoustic, photothermal and photochemical processes at surfaces and in thin films. The articles introduce the fields, review present knowledge and conclude with latest developments and future prospects. Topics covered include laser-induced desorption, ablation and surface damage; surface acoustic waves; photothermal and photoacoustic characterization of thin films and interfaces; depth profiling in the frequency and time domains; remote testing and nondestructive evaluation; materials characterization; and new theoretical approaches using fractals. The book will interest newcomers to photoacoustics, since it gives an overview of current research and details of experimental methods. It will also be a source of information for those already in the field due to its clear presentation of theory and experimental results. All relevant literature references in this rapidly expanding field are included.

The idea of a workshop devoted to the static and dynamic properties of liquids arose from two smaller meetings on the same topic held at the Interfaculty Reactor Institute, Delft, The Netherlands in 1985 and 1987, and from the LAM conference (International Conference on Liquid and Amorphous Metals) held at Garmisch Partenkirchen, FRG, in 1986. The object of the Workshop was to bring together experimentalists, theoreticians and people working on computer simulations in or der to learn about developments in the microscopic behaviour of liquids. Approx imately 35 scientists from Austria, France, Israel, Italy, Sweden, The Netherlands, the United Kingdom, the Federal Republic of Germany and Yugoslavia gathered at the Hotel "Libertas", Dubrovnik, in Yugoslavia, June 27-30, 1988 to hear ten in vited talks and nineteen contributed papers on a wide range of subjects, including generalized hydrodynamics, mode coupling theory, liquids at surfaces, extraction of effective potentials, and the glass transition. The most numerous were the papers dealing with computer simulation, and then those on supercooled liquids and the glass transition. The number of experimental results was relatively small, which points to difficulties in this kind of research (evaluation of experimental data). The workshop closed with an expanded round-table discussion of the main themes of the meeting, with an emphasis on the likely trend of investigations in the future. This discussion is summarized at the end of this volume.

Efficiency is one of the most frequently used terms in thermodynamics, and it indicates how well an energy conversion or process is accomplished. Efficiency is also one of the most frequently misused terms in thermodynamics and is often a source of misunderstanding. This is because efficiency is often used without being properly defined first. This book intends to provide a comprehensive evaluation of various efficiencies used for energy transfer and conversion systems including steady-flow energy devices (turbines, compressors, pumps, nozzles, heat exchangers, etc.), various power plants, cogeneration plants, and refrigeration systems. The book will cover first-law (energy based) and second-law (exergy based) efficiencies and provide a comprehensive understanding of their implications. It will help minimize the widespread misuse of efficiencies among students and researchers in energy field by using an intuitive and unified approach for defining efficiencies. The book will be particularly useful for a clear understanding of second law (exergy) efficiencies for various systems. It may serve as a reference book to the researchers in energy field. The definitions and concepts developed in the book will be explained through illustrative examples.

This volume comprises a selection of the best papers presented at the Eighth International Symposium on Applications of Laser Techniques to Fluid Mechanics, held in Lisbon in July 1996.
The papers describe novel ideas for instrumentation, instrumentation developments, results of measurements of wall-bounded flows, free flows and flames and flow and combustion in engines. The papers demonstrate the continuing interest in the development of an understanding of new methodologies and implementation in terms of new instrumentation.

Radio telescopes as well as communication antennas operate under the influence of gravity, temperature and wind. Among those, temperature influences may degrade the performance of a radio telescope through transient changes of the focus, pointing, path length and sensitivity, often in an unpredictable way. Thermal Design and Thermal Behaviour of Radio Telescopes and their Enclosures reviews the design and construction principles of radio telescopes in view of thermal aspects and heat transfer with the variable thermal environment; it explains supporting thermal model calculations and the application and efficiency of thermal protection and temperature control; it presents many measurements illustrating the thermal behaviour of telescopes in the environment of their observatory sites.

The book benefits scientists and radio/communication engineers, telescope designers and construction firms as well as telescope operators, observatory staff, but also the observing astronomer who is directly confronted with the thermal behaviour of a telescope.

This monograph treats, for the first time, major aspects of gas dynamics of nozzles from a general point of view. Its outstanding feature is the pre- sentation of the modern theory of gas flows and modern analytical and nu- merical methods, together with numerous examples of practical applications. At the same time, quite diverse physico-chemical processes, such as disso- ciation and recombination, relaxation of vibrational degrees of freedom, two-phase flows wi th phase trans formati ons and e 1 ectromagneti c i nf1 uences, are considered. The material is presented in such a way as to help the reader to use numer- ous methods and approaches, not only for the study of gas flows in nozzles, but also for the investigation of a wide variety of problems of physical gas dynamics in different areas of application. The number of applications which may benefit from the use of the methods and results presented in this book is constantly growing. Theoretical, numerical and analytical methods of physical gas dynamics of internal flows may be, and are nowadays, ap- plied to solving the problem of preventing pollution of the air basin with toxic substances. These methods make it possible to describe the formation and transformation of toxic components in the vapour generators of thermal power plants, internal combustion engines and various metallurgical instal- lations. The methods of physical gas dynamics may be used in meteorology and powder metallurgy to create ultradispersed media and predict their proper- ties.

Enrico Fermi s scientific work, noted for its originality and breadth, has had lasting consequences throughout modern science. Written by close colleagues as well as scientists whose fields were profoundly influenced by Fermi, the papers collected here constitute a tribute to him and his scientific legacy. They were commissioned on the occasion of his 100th birthday by the Italian Physical Society and confirm that Fermi was a rare combination of theorist, experimentalist, teacher, and inspiring colleague. The book is organized into three parts: three biographical overviews by close colleagues, replete with personal insights; fourteen analyses of Fermi's impact by specialists in their fields, spanning physics, chemistry, mathematics, and engineering; and a year-by-year chronology of Fermi s scientific endeavors. Written for a general scientific audience, Enrico Fermi: His Work and Legacy offers a highly readable source on the life of one of the 20th century's most distinguished scientists and a must for everybody interested in the history of modern science."

As a basis for printed property charts and tables, empirical multiparameter equa tions of state have been the most important source of accurate thermodynamic property data for more than 30 years now. However, due to increasing demands on the accuracy of thermodynamic property data in computerised calculations as well as the availability of appropriate software tools, and the ever increasing computer power, such formulations are nowadays becoming a valuable tool for everyday work. This development has substantially increased the number of scientists, engi neers, and students who are working with empirical multiparameter equations of state, and it continues to do so. Nevertheless, common knowledge on this kind of thermodynamic property models and on the ongoing progress in this scientific discipline is still very limited. Multiparameter equations of state do not belong to the topics which are taught intensively in thermodynamic courses in engineering and natural sciences and the books and articles where they are published mainly deal with the thermodynamic properties of certain substances rather than with the theoretical background of the used equations of state. In contrast to this, my concern mainly was to give a survey of the theoretical background of multiparameter equations of state both with regard to their application and their development."

Properties of systems with long range interactions are still poorly understood despite being of importance in most areas of physics. The present volume introduces and reviews the effort of constructing a coherent thermodynamic treatment of such systems by combining tools from statistical mechanics with concepts and methods from dynamical systems. Analogies and differences between various systems are examined by considering a large range of applications, with emphasis on Bose--Einstein condensates. Written as a set of tutorial reviews, the book will be useful for both the experienced researcher as well as the nonexpert scientist or postgraduate student.

During the last decade there has been a renewed interest in research on supramolecular assemblies in solutions, such as micelles and microemulsions, not only because of their extensive applications in industries dealing with catalysts, detergency, biotechnology, and enhanced oil recovery, but also due to the development of new and more powerful experimental and theoretical tools for probing the microscopic behavior of these systems. Prominent among the array of the newly available experimental techniques are photon correlation spectroscopy, small-angle neutron and X-ray scattering, and neutron spin-echo and nuclear magnetic resonance spectroscopies. On the theoretical side, the traditionally emphasized thermodynamic approach to the study of the phase behavior of self-assembled systems in solutions is gradually being replaced by statistical mechanical studies of semi-micro scopic and microscopic models of the assemblies. Since the statistical mechanical approach demands as its starting point the microscopic struc tural information of the self-assembled system, the experimental determina tion of the structures of micelles and microemulsions becomes of paramount interest. In this regard the scattering techniques mentioned above have played an important role in recent years and will continue to do so in the future. In applying the scattering techniques to the supramolecular species in solution, one cannot often regard the solution to be ideal. This is because the inter-aggregate interaction is often long-ranged since it is coulombic in nature and the interparticle correlations are thus appreciable."

This booklet is designed to bridge the gap between handbooks and technical literature and aims at graduate students or experienced readers. Commercial flow sheeting simulation software is increasingly available and is used in the early steps of process design in industry. As to this, more sophisticated and precise models based on activities instead of concentrations should be used. After an introductory chapter there is in Chapter 2 an intensive discussion of reactive phase equilibria of ionic and non-ionic solutes based on chemical potentials. Chapter 3 introduces to multicomponent diffusion and mass transfer. However, the main focus is on the reactive mass transfer on rigid and mobile surfaces where the interfacial reaction, molecular diffusion and adsorption layers are decisive. The respective extraction of zinc with a cation exchanger and of acetic acid with an anion exchanger is discussed as case studies. Since adsorption layers and surfactants have a major impact on liquid-liquid extraction efficiency, the final chapter reviews several tech niques which make use of polymeric species in an extractive process. A short review is also given on extraction apparatus and the hydrodynamics (hydraulic design, droplet populance balances) of columns. Much of the booklet is based on the PhD works of C. Czapla (2000), G. Modes (2000), H. Klocker (1996), T. Kronberger (1995), M. Marters (2000), M. Roos (2000), M. Traving (2000) and B. Wachter (1996) who I wish to thank for their fruitful contributions."

Speech by Toyosaburo Taniguchi Dr. Kubo, Chairman, Distinguished Guests, and Friends, I am very happy, pleased and honored to be here this evening with so many distinguished guests, friends, and scholars from within this country and from different parts of the world. The Taniguchi Foundation wishes to extend a warm and sincere welcome to the many participants of the Ninth International Symposium on the Theory of Condensed Matter, which se ries was inaugurated eight years ago through the strenuous efforts of Dr. Ryogo Kubo, who is gracing us today with his presence. We are deeply indebted to Dr. Kubo, Dr. Suzuki, and their associates, who havE' spent an enormous amount of time and effort to make this particular symposium possible. We are convinced that the foundation should not be considered as what makes our symposium a success. The success is entirely due, I feel, to the continuous efforts of the Organizing Committee and of all those who have lent their support to this program. In this sense, your words of praise about the symposium, if any, should be directed to all of them. So far, I have met in person a total of 62 participants in this Division from 12 countries: Argentina, Belgium, Canada, Denmark, the Federal Republic of Germany, France, Ireland, Israel, Rumania, Switzerland, the United Kingdom, and the United States of America, with 133 participants from Japan. Those friends I have been privileged to make, I shall always treasure."

Nonextensive statistical mechanics is now a rapidly growing field and a new stream in the research of the foundations of statistical mechanics. This generalization of the well-known Boltzmann--Gibbs theory enables the study of systems with long-range interactions, long-term memories or multi-fractal structures. This book consists of a set of self-contained lectures and includes additional contributions where some of the latest developments -- ranging from astro- to biophysics -- are covered. Addressing primarily graduate students and lecturers, this book will also be a useful reference for all researchers working in the field.

Providing the first comprehensive treatment, this book covers all aspects of the laser Doppler and phase Doppler measurement techniques, including light scattering from small particles, fundamental optics, system design, signal and data processing, tracer particle generation, and applications in single and two-phase flows. The book is intended as both a reference book for more experienced users as well as an instructional book for students. It provides ample material as a basis for a lecture course on the subject and represents one of the most comprehensive treatments of the phase Doppler technique to date. The book will serve as a valuable reference book in any fluid mechanics laboratory where the laser Doppler or phase Doppler techniques are used. This work reflects the authors' long practical experience in the development of the techniques and equipment, as the many examples confirm.

The present volume offers a state-of-the-art report on the various recent sci entific developments in the Theory of Porous Media (TPM) comprehending the basic theoretical concepts in continuum mechanics on porous and mul tiphasic materials as well as the wide range of experimental and numerical applications. Following this, the volume does not only address the sophisti cated reader but also the interested beginner in the area of Porous Media by presenting a collection of articles. These articles written by experts in the field concern the fundamental approaches to multiphasic and porous materials as well as various applications to engineering problems. In many branches of engineering just as in applied natural sciences like bio- and chemomechanics, one often has to deal with continuum mechanical problems which cannot be uniquely classified within the well-known disci plines of either "solid mechanics" or "fluid mechanics." These problems, characterized by the fact that they require a unified treatment of volumetri cally coupled solid-fluid aggregates; basically fall into the categories of either mixtures or porous media. Following this, there is a broad variety of problems ranging in this category as for example the investigation of reacting fluid mix tures or solid-fluid suspensions as well as the investigation of the coupled solid deformation and pore-fluid flow behaviour of liquid- and gas-saturated porous solid skeleton materials like geomaterials (soil, rock, concrete, etc. ), polymeric and metallic foams or biomaterials (hard and soft tissues, etc)."

This book contains the expanded lecture notes of the 32nd Saas-Fee Advanced Course. The three contributions present the central themes in modern research on the cold universe, ranging from cold objects at large distances to the physics of dust in cold clouds.

This book does not give a prediction of what the efficiency will be of the energy use of industrial processes in the future. However, it does give an exploration of limits to the efficiency of current processes and an indication of what might be achieved if new technologies can be developed. At the Department of Science, Technology and Society of Utrecht University research had been done to the opportunities for improvement of the energy efficiency in the short term since the 1980's. This had resulted in a comprehensive database on energy efficient measures. This database and a possible application are described in Chapter 3 of this book. The use of the database induced new research themes around efficiency improvement, e.g. concerning barriers for implementation of measures. It was around 1993 that I did a preliminary study to the potential for efficiency improvement in the long term. Historical analysis had shown us that the short term potential stayed constant over the years. It seemed to be replenished by the introduction of new technologies. This lead to the question whether there are limits to the efficiency, taking into account both thermodynamic considerations and ideas on the development and dissemination of new technologies.

This textbook covers the basic principles of statistical physics and thermodynamics. The text is pitched at the level equivalent to first-year graduate studies or advanced undergraduate studies. It presents the subject in a straightforward and lively manner. After reviewing the basic probability theory of classical thermodynamics, the author addresses the standard topics of statistical physics. The text demonstrates their relevance in other scientific fields using clear and explicit examples. Later chapters introduce phase transitions, critical phenomena and non-equilibrium phenomena.

Well-balanced and up-to-date introduction to the field of semiconductor optics, including transport phenomena in semiconductors. Starting with the theoretical fundamentals of this field the book develops, assuming a basic knowledge of solid-state physics. The application areas of the theory covered include semiconductor lasers, detectors, electro-optic modulators, single-electron transistors, microcavities and double-barrier resonant tunneling diodes. One hundred problems with hints for solution help the readers to deepen their knowledge.

In Statistical Physics one of the ambitious goals is to derive rigorously, from statistical mechanics, the thermodynamic properties of models with realistic forces. Elliott Lieb is a mathematical physicist who meets the challenge of statistical mechanics head on, taking nothing for granted and not being content until the purported consequences have been shown, by rigorous analysis, to follow from the premises. The present volume contains a selection of his contributions to the field, in particular papers dealing with general properties of Coulomb systems, phase transitions in systems with a continuous symmetry, lattice crystals, and entropy inequalities. It also includes work on classical thermodynamics, a discipline that, despite many claims to the contrary, is logically independent of statistical mechanics and deserves a rigorous and unambiguous foundation of its own. The articles in this volume have been carefully annotated by the editors.

This book involves application of the Calphad method for derivation of a self consistent thermodynamic database for the geologically important system Mg0- Fe0-Fe203-Alz03-Si02 at pressures and temperatures of Earth's upper mantle and the transition zone of that mantle for Earth. The created thermodynamic database reproduces phase relations at 1 bar and at pressures up to 30 GPa. The minerals are modelled by compound energy formalism, which gives realistic descriptions of their Gibbs energy and takes into account crystal structure data. It incorporates a detailed review of diverse types of experimental data which are used to derive the thermodynamic database: phase equilibria, calorimetric stud ies, and thermoelastic property measurements. The book also contains tables of thermodynamic properties at 1 bar (enthalpy and Gibbs energy of formation from the elements, entropy, and heat capacity, and equation of state data at pressures from 1 bar to 30 GPa. Mixing parameters of solid solutions are also provided by the book. Table of Contents Introduction to the Series . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . V Acknowledgments . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . VII Preface . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . IX Table of Contents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . XI Co-Authors . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . XIII Vitae of Co-Authors . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . XV CODATA Task Group on Geothermodynamic Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . XXIII Chapter 1. Thermodynamics and Modeling . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 1. 1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 1. 2 Thermodynamic Modeling . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 1. 3 Experimental Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 1. 4 Programs and Assessment. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 System and Phases . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5 1. 5 Chapter 2. Experimental Phase Equilibrium Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7 The Si02 System . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7 2. 1 2. 2 The Fe-0 System . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8 2. 3 The Fe-Si-0 System . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10 2. 4 The Mg0-Si0 System . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

The theory of thermoelasticity studies the interaction between thermal and mechan ical fields in elastic bodies. This theory is of interest both for the mathematical and technical point of view. Intense interest has been shown recently in this field owing to the great practical importance of dynamical effects in aeronautics, nu clear reactors, and its potential importance in cryogenic applications. This work is concerned mainly with basic problems of the theory of thermoelasticity. Ther moelasticity of polar materials and the theories of thermoelasticity with finite wave speeds are not considered here. The reader interested in these subjects will find a full account in the works of Nowacki [280], Chandrasekharaiah [60] and Ignaczak [195]. Our purpose in this work is to present a systematic treatment of some results established in the theory of thermoelasticity. On the whole, the subject matter is directed towards recent developments. Chapter 1 is concerned mainly with the development of the fundamental equa tions of the theory of thermoelasticity. The kinematics and primitive concepts associated with the basic principles are developed and emphasized only to the ex tent that they are needed in our treatment of the subject. Chapter 2 is devoted to a study of linear thermoelastic deformations for prestressed bodies. We have at tempted to isolate those conceptual and mathematical difficulties which arise over and above those inherent in the problems concerned with unstressed bodies.

Crystal growth, casting, soldering, welding, high-energy surface treatment, nuclear safety systems and geophysical flows are just a few examples where solidification and convection occur together. These processes are interactive on micro- and macroscales: flow affects the distribution of heat and species and hence the freezing process, while solidification evolves flow boundaries, as in crusting, for example, and hence can radically alter the convection. Mathematical modellers, experimentalists and applied scientists were invited to this colloquium with the aim of consolidating our understanding of such interactions, of identifying key outstanding issues, and of developing new approaches in this important area of fundamental research. Both invited and contributed papers focus on both fundamental and technologically relevant problems.

The simulation of technological and environmental flows is very important for many industrial developments. A major challenge related to their modeling is to involve the characteristic turbulence that appears in most of these flows. The traditional way to tackle this question is to use deterministic equations where the effects of turbulence are directly parametrized, i. e. , assumed as functions of the variables considered. However, this approach often becomes problematic, in particular if reacting flows have to be simulated. In many cases, it turns out that appropriate approximations for the closure of deterministic equations are simply unavailable. The alternative to the traditional way of modeling turbulence is to construct stochastic models which explain the random nature of turbulence. The application of such models is very attractive: one can overcome the closure problems that are inherent to deterministic methods on the basis of relatively simple and physically consistent models. Thus, from a general point of view, the use of stochastic methods for turbulence simulations seems to be the optimal way to solve most of the problems related to industrial flow simulations. However, it turns out that this is not as simple as it looks at first glance. The first question concerns the numerical solution of stochastic equations for flows of environmental and technological interest. To calculate industrial flows, 3 one often has to consider a number of grid cells that is of the order of 100 .

Modulation Calorimetry reviews modulation techniques for measuring specific heat, thermal expansivity, temperature derivative of resistance, thermopower, and spectral absorptance. Owing to the periodic nature of the temperature oscillations, high sensitivity and excellent temperature resolution are peculiar to all these methods. The monograph presents the various methods of the modulation and of measuring the temperature oscillations. Important applications of the modulation techniques for studying physical phenomena in solids and liquids are considered in depth (equilibrium point defects, phase transitions, superconductors, liquid crystals, biological materials, relaxation phenomena in specific heat, and more).