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Books > Science & Mathematics > Chemistry > Physical chemistry > Quantum & theoretical chemistry
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Micellar Solutions and Microemulsions - Structure, Dynamics, and Statistical Thermodynamics (Paperback, Softcover reprint of the original 1st ed. 1990)
Loot Price: R1,530
Discovery Miles 15 300
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Micellar Solutions and Microemulsions - Structure, Dynamics, and Statistical Thermodynamics (Paperback, Softcover reprint of the original 1st ed. 1990)
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During the last decade there has been a renewed interest in
research on supramolecular assemblies in solutions, such as
micelles and microemulsions, not only because of their extensive
applications in industries dealing with catalysts, detergency,
biotechnology, and enhanced oil recovery, but also due to the
development of new and more powerful experimental and theoretical
tools for probing the microscopic behavior of these systems.
Prominent among the array of the newly available experimental
techniques are photon correlation spectroscopy, small-angle neutron
and X-ray scattering, and neutron spin-echo and nuclear magnetic
resonance spectroscopies. On the theoretical side, the
traditionally emphasized thermodynamic approach to the study of the
phase behavior of self-assembled systems in solutions is gradually
being replaced by statistical mechanical studies of semi-micro
scopic and microscopic models of the assemblies. Since the
statistical mechanical approach demands as its starting point the
microscopic struc tural information of the self-assembled system,
the experimental determina tion of the structures of micelles and
microemulsions becomes of paramount interest. In this regard the
scattering techniques mentioned above have played an important role
in recent years and will continue to do so in the future. In
applying the scattering techniques to the supramolecular species in
solution, one cannot often regard the solution to be ideal. This is
because the inter-aggregate interaction is often long-ranged since
it is coulombic in nature and the interparticle correlations are
thus appreciable."
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