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Books > Science & Mathematics > Physics > Thermodynamics & statistical physics
In the high energy gas flows, associating high velocities and high
temperatures, physical and chemical processes such as molecular
vibrational excitation, dissociation, ionisation or various
reactions take palce and deeply influence the structure of the
flows. The characteristic times of these processes have the same
order of magnitude as aerodynamic characteristic times so that
these reactive media are generally in thermodynamic and chemical
non-equilibrium. This book presents a general introductory study of
these media. In the first part their fundamental statistical
aspects are described, starting from their discrete structure and
taking into account the interactions between elementary particles:
the transport phenomena, relaxation and kinetics as well as their
coupling are thus analysed and illustrated by many examples. The
second part deals with the macroscopic re-entry bodies. Finally the
experimental aspects of these flows, their simulations in shock
tube and shock tunnel are described as well as their application,
particularly in the aero- spatial domain.
Analytical Mechanics for Relativity and Quantum Mechanics is an
innovative and mathematically sound treatment of the foundations of
analytical mechanics and the relation of classical mechanics to
relativity and quantum theory. It is intended for use at the
introductory graduate level. A distinguishing feature of the book
is its integration of special relativity into teaching of classical
mechanics. After a thorough review of the traditional theory, Part
II of the book introduces extended Lagrangian and Hamiltonian
methods that treat time as a transformable coordinate rather than
the fixed parameter of Newtonian physics. Advanced topics such as
covariant Langrangians and Hamiltonians, canonical transformations,
and Hamilton-Jacobi methods are simplified by the use of this
extended theory. And the definition of canonical transformation no
longer excludes the Lorenz transformation of special relativity.
Quantum information- the subject- is a new and exciting area of
science, which brings together physics, information theory,
computer science and mathematics. Quantum Information- the book- is
based on two successful lecture courses given to advanced
undergraduate and beginning postgraduate students in physics. The
intention is to introduce readers at this level to the fundamental,
but offer rather simple, ideas behind ground-breaking developments
including quantum cryptography, teleportation and quantum
computing. The text is necessarily rather mathematical in style,
but the mathematics nowhere allowed priority over the key physical
ideas. My aim throughout was to be as complete and self- contained
but to avoid, as far as possible, lengthy and formal mathematical
proofs. Each of the eight chapters is followed by about forty
exercise problems with which the reader can test their
understanding and hone their skills. These will also provide a
valuable resource to tutors and lectures.
The pendulum is a unique physical system which exhibits remarkably
varied and complex behavior under many different conditions. It is
also a system which, in its many manifestations, has left a
significant imprint on human thought and culture. Using graphs,
figures, and narrative to explain scientific ideas and models,
Gregory Baker gives a lucid account of the physics of the pendulum,
showing the reader how the context of the pendulum progresses over
four centuries from that of a simple system of classical physics,
to that of a chaotic system, and eventually to that of a modern
quantum system. He also describes its fascinating presence in
cultural history, from its role in timekeeping and measurements of
the earth to its importance as a literary symbol of doom.
This book discusses the study and analysis of the physical aspects of social systems and models, inspired by the analogy with familiar models of physical systems and possible applications of statistical physics tools. Unlike the traditional analysis of the physics of macroscopic many-body or condensed matter systems, which is now an established and mature subject, the upsurge in the physical analysis and modelling of social systems, which are clearly many-body dynamical systems, is a recent phenomenon. Though the major developments in sociophysics have taken place only recently, the earliest attempts of proposing "Social Physics" as a discipline are more than one and a half centuries old. Various developments in the mainstream physics of condensed matter systems have inspired and induced the recent growth of sociophysical analysis and models. In spite of the tremendous efforts of many scientists in recent years, the subject is still in its infancy and major challenges are yet to be taken up. An introduction to these challenges is the main motivation for this book.
This hands-on guide is primarily intended to be used in
undergraduate laboratories in the physical sciences and
engineering. It assumes no prior knowledge of statistics. It
introduces the necessary concepts where needed, with key points
illustrated with worked examples and graphic illustrations. In
contrast to traditional mathematical treatments it uses a
combination of spreadsheet and calculus-based approaches, suitable
as a quick and easy on-the-spot reference. The emphasis throughout
is on practical strategies to be adopted in the laboratory.
This book focuses on the characteristics of optical radiation, or a spectrum, emitted by various plasmas. In plasma, the same atomic species can produce quite different spectra, or colors depending on the nature of the plasma. This book gives a theoretical framework, by which a particular spectrum can be interpreted correctly and coherently. The uniqueness of the book lies in its comprehensive treatment of the intensity distribution of spectral lines and the population density distribution among the atomic levels, in plasma. It is intended to provide beginners with a good perspective of the field, laying out the physics in an extremely clear manner, starting from an elementary level. A very useful feature of the book is the asterisked sections and chapters which can be skipped by readers, who only wish to gain a quick and basic introduction to plasma spectroscopy. It will also be very useful to researchers working actively in the field, acting as a guide for carrying out experiments and interpreting experimental observations.
As an introductory account of the theory of phase transitions and critical phenomena, Elements of Phase Transitions and Critical Phenomena reflects lectures given by the authors to graduate students at their departments and is thus classroom-tested to help beginners enter the field. Most parts are written as self-contained units and every new concept or calculation is explained in detail without assuming prior knowledge of the subject. The book significantly enhances and revises a Japanese version which is a bestseller in the Japanese market and is considered a standard textbook in the field. It contains new pedagogical presentations of field theory methods, including a chapter on conformal field theory, and various modern developments hard to find in a single textbook on phase transitions. Exercises are presented as the topics develop, with solutions found at the end of the book, making the text useful for self-teaching, as well as for classroom learning.
One of the questions about which humanity has often wondered is the arrow of time. Why does temporal evolution seem irreversible? That is, we often see objects break into pieces, but we never see them reconstitute spontaneously. This observation was first put into scientific terms by the so-called second law of thermodynamics: entropy never decreases. However, this law does not explain the origin of irreversibly; it only quantifies it. Kinetic theory gives a consistent explanation of irreversibility based on a statistical description of the motion of electrons, atoms, and molecules. The concepts of kinetic theory have been applied to innumerable situations including electronics, the production of particles in the early universe, the dynamics of astrophysical plasmas, quantum gases or the motion of small microorganisms in water, with excellent quantitative agreement. This book presents the fundamentals of kinetic theory, considering classical paradigmatic examples as well as modern applications. It covers the most important systems where kinetic theory is applied, explaining their major features. The text is balanced between exploring the fundamental concepts of kinetic theory (irreversibility, transport processes, separation of time scales, conservations, coarse graining, distribution functions, etc.) and the results and predictions of the theory, where the relevant properties of different systems are computed.
The book contains 9 chapters out of which Chapters (1-2) deals with the "Point Estimation", (3) Interval estimation, (4-5) Test of hypothesis, (6) Sequential statistics, (7) Decision theory, (8) Linear estimation and (9) Theory of ordered statistics.
It was not until 1971 that the authority for defining scientific units, the General Conference of Weights and Measures got around to defining the unit that is the basis of chemistry (the mole, or the quantity of something). Yet for all this tardiness in putting the chemical sciences on a sound quantitative basis, chemistry is an old and venerable subject and one naturally asks the question, why? Well, the truth is that up until the mid-1920s, many physicists did not believe in the reality of molecules. Indeed, it was not until after the physics community had accepted Ernest Rutherford's 1913 solar-system-like model of the atom, and the quantum mechanical model of the coupling of electron spins in atoms that physicists started to take seriously the necessity of explaining the chemical changes that chemists had been observing, investigating and recording since the days of the alchemists.
The book provides an integrated energy/exergy analysis method to identify the energy utilization issues and systematically propose the cost-effective energy-saving and CO2 mitigation/capture solution. There is a strong market needs on energy-saving and greenhouse gas (GHG) reduction. CO2 mitigation/capture will achieve economic benefit of fuel, power, and carbon tax saving as well as environmental GHG reduction. The book is a professional book for energy-saving and GHG gas mitigation technology in oil & gas, oil refining, and chemical industry. It is an integrated technical book that combines energy utilization theory and practical method, including: thermodynamic analysis for unit operation and process units; energy and exergy calculation for various process streams and utilities; three-link energy/exergy analysis model; energy/exergy balance of equipment, process units, and entire plant; approach and technology of energy saving; optimization of pipeline and equipment; pinch energy-saving technology and its application; CO2 capture and utilization with 8 case studies incorporated for all different scenarios; key energy-saving technologies such gas turbine, FCCU regeneration CO combustion and energy recovery, flue gas turbine system optimization, low-grade heat recovery and utilization. The book is intended for engineers and professional personnel who are working in process engineering, EPC companies, chemical and petrochemical plants, refineries, oil & gas production facilities, power generation plant. It can also be a professional reference or textbook for undergraduate or graduate-level university students and teaching personnel of chemical, energy, and process engineering faculties of universities.
Thermodynamics is fundamental to university and college curricula in chemistry, physics, engineering and many life sciences around the world. It is also notoriously difficult for students to understand, learn and apply. What makes this book different, and special, is the clarity of the text. The writing style is fluid, natural and lucid, and everything is explained in a logical and transparent manner. Thermodynamics is a deep, and important, branch of science, and this book does not make it "easy". But it does make it intelligible. This book introduces a new, 'Fourth Law' of Thermodynamics' based on the notion of Gibbs free energy, which underpins almost every application of thermodynamics and which the authors claim is worthy of recognition as a 'law'. The last four chapters bring thermodynamics into the twenty-first century, dealing with bioenergetics (how living systems capture and use free energy), macromolecule assembly (how proteins fold), and macromolecular aggregation (how, for example, virus capsids assemble). This is of great current relevance to students of biochemistry, biochemical engineering and pharmacy, and is covered in very few other texts on thermodynamics. The book also contains many novel and effective examples, such as the explanation of why friction is irreversible, the proof of the depression of the freezing point, and the explanation of the biochemical standard state.
High speed catamaran and multihull high speed marine vessel have become very popular in the last two decades. The catamaran has become the vessel of choice for the majority of high speed ferry operators worldwide. There have been significant advances in structural materials, and structural design has been combined with higher power density and fuel efficient engines to deliver ferries of increasing size. The multihull has proven itself to be a suitable configuration for active power projection across oceans as well as for coastal patrol and protection, operating at high speedd for insertion or retrieval with a low energy capability. At present there is no easily accessible material covering the combination of hydrodynamics, aerodynamics, and design issues including structures, powering and propulsion for these vehicles. Coverage in High Speed Catamarans and Multihulls includes an introduction to the history, evolution, and development of catamarans, followed by a theoretical calculation of wave resistance in shallow and deep water, as well as the drag components of the multihull. A discussion of vessel concept design describing design characteristics, empirical regression for determination of principal dimensions in preliminary design, general arrangement, and methods is also included. The book concludes with a discussion of experimental future vehicles currently in development including the small waterplane twin hull vessels, wave piercing catamarans, planing catamarans, tunnel planing catamarans and other multihull vessels.
Nonlinear Time Series Analysis with R provides a practical guide to emerging empirical techniques allowing practitioners to diagnose whether highly fluctuating and random appearing data are most likely driven by random or deterministic dynamic forces. It joins the chorus of voices recommending 'getting to know your data' as an essential preliminary evidentiary step in modelling. Time series are often highly fluctuating with a random appearance. Observed volatility is commonly attributed to exogenous random shocks to stable real-world systems. However, breakthroughs in nonlinear dynamics raise another possibility: highly complex dynamics can emerge endogenously from astoundingly parsimonious deterministic nonlinear models. Nonlinear Time Series Analysis (NLTS) is a collection of empirical tools designed to aid practitioners detect whether stochastic or deterministic dynamics most likely drive observed complexity. Practitioners become 'data detectives' accumulating hard empirical evidence supporting their modelling approach. This book is targeted to professionals and graduate students in engineering and the biophysical and social sciences. Its major objectives are to help non-mathematicians - with limited knowledge of nonlinear dynamics - to become operational in NLTS; and in this way to pave the way for NLTS to be adopted in the conventional empirical toolbox and core coursework of the targeted disciplines. Consistent with modern trends in university instruction, the book makes readers active learners with hands-on computer experiments in R code directing them through NLTS methods and helping them understand the underlying logic (please see www.marco.bittelli.com). The computer code is explained in detail so that readers can adjust it for use in their own work. The book also provides readers with an explicit framework - condensed from sound empirical practices recommended in the literature - that details a step-by-step procedure for applying NLTS in real-world data diagnostics.
A multitude of processes in hydrology and environmental engineering are either random or entail random components which are characterized by random variables. These variables are described by frequency distributions. This book provides an overview of different systems of frequency distributions, their properties, and applications to the fields of water resources and environmental engineering. A variety of systems are covered, including the Pearson system, Burr system, and systems commonly applied in economics, such as the D'Addario, Dagum, Stoppa, and Esteban systems. The latter chapters focus on the Singh system and the frequency distributions deduced from Bessel functions, maximum entropy theory, and the transformations of random variables. The final chapter introduces the genetic theory of frequency distributions. Using real-world data, this book provides a valuable reference for researchers, graduate students, and professionals interested in frequency analysis.
This book contains an extensive illustration of use of finite difference method in solving the boundary value problem numerically. A wide class of differential equations has been numerically solved in this book. Starting with differential equations of elementary functions like hyperbolic, sine and cosine, we have solved those of special functions like Hermite, Laguerre and Legendre. Those of Airy function, of stationary localised wavepacket, of the quantum mechanical problem of a particle in a 1D box, and the polar equation of motion under gravitational interaction have also been solved. Mathematica 6.0 has been used to solve the system of linear equations that we encountered and to plot the numerical data. Comparison with known analytic solutions showed nearly perfect agreement in every case. On reading this book, readers will become adept in using the method.
Solid Fuels and Heavy Hydrocarbon Liquids: Thermal Characterisation and Analysis, Second Edition integrates the developments that have taken place since publication of the first edition in 2006. This updated material includes new insights that help unify the thermochemical reactions of biomass and coal, as well as new developments in analytical techniques, including new applications in size exclusion chromatography, several mass spectrometric techniques, and new applications of nuclear magnetic spectroscopy to the characterization of heavy hydrocarbon liquids The topics covered are essential for the energy and fuels research community, including academics, students, and research engineers working in the power, oil and gas, and renewable energy industries.
Kinetic theory provides a microscopic description of many observable, macroscopic processes and has a wide range of important applications in physics, astronomy, chemistry, and engineering. This powerful, theoretical framework allows a quantitative treatment of many non-equilibrium phenomena such as transport processes in classical and quantum fluids. This book describes in detail the Boltzmann equation theory, obtained in both traditional and modern ways. Applications and generalizations describing non-equilibrium processes in a variety of systems are also covered, including dilute and moderately dense gases, particles in random media, hard sphere crystals, condensed Bose-Einstein gases, and granular materials. Fluctuation phenomena in non-equilibrium fluids, and related non-analyticities in the hydrodynamic equations are also discussed in some detail. A thorough examination of many topics concerning time dependent phenomena in material systems, this book describes both current knowledge as well as future directions of the field.
This textbook introduces the molecular side of physical chemistry. It offers students and practitioners a new approach to the subject by presenting numerous applications and solved problems that illustrate the concepts introduced for varied and complex technical situations. The book offers a balance between theory, tools, and practical applications. The text aims to be a practical manual for solving engineering problems in industries where processes depend on the chemical composition and physical properties of matter. The book is organized into three main topics: (I) the molecular structure of matter, (II) molecular models in thermodynamics, and (III) transport phenomena and mechanisms. Part I presents methods of analysis of the molecular behavior in a given system, while the following parts use these methods to study the equilibrium states of a material system and to analyze the processes that can take place when the system is in a state of non-equilibrium, in particular the transport phenomena. Molecular Physical Chemistry for Engineering Applications is designed for upper-level undergraduate and graduate courses in physical chemistry for engineers, applied physical chemistry, transport phenomena, colloidal chemistry, and transport/transfer processes. The book will also be a valuable reference guide for engineers, technicians, and scientists working in industry. Offers modeling techniques and tools for solving exercises and practical cases; Provides solutions and conclusions so students can follow results more closely; Step-by-step problem solving enables students to understand how to approach complex issues.
This book presents sensemaking strategies to support security planning and design. Threats to security are becoming complex and multifaceted and increasingly challenging traditional notions of security. The security landscape is characterized as 'messes' and 'wicked problems' that proliferate in this age of complexity. Designing security solutions in the face of interconnectedness, volatility and uncertainty, we run the risk of providing the right answer to the wrong problem thereby resulting in unintended consequences. Sensemaking is the activity that enables us to turn the ongoing complexity of the world into a "situation that is comprehended explicitly in words and that serves as a springboard into action" (Weick, Sutcliffe, Obstfeld, 2005). It is about creating an emerging picture of our world through data collection, analysis, action, and reflection. The importance of sensemaking to security is that it enables us to plan, design and act when the world as we knew it seems to have shifted. Leveraging the relevant theoretical grounding and thought leadership in sensemaking, key examples are provided, thereby illustrating how sensemaking strategies can support security planning and design. This is a critical analytical and leadership requirement in this age of volatility, uncertainty, complexity and ambiguity that characterizes the security landscape. This book is useful for academics, graduate students in global security, and government and security planning practitioners.
Simulating for a crisis is far more than creating a simulation of a crisis situation. In order for a simulation to be useful during a crisis, it should be created within the space of a few days to allow decision makers to use it as quickly as possible. Furthermore, during a crisis the aim is not to optimize just one factor, but to balance various, interdependent aspects of life. In the COVID-19 crisis, decisions had to be made concerning e.g. whether to close schools and restaurants, and the (economic) consequences of a 3 or 4-week lock-down had to be considered. As such, rather than one simulation focusing on a very limited aspect, a framework allowing the simulation of several different scenarios focusing on different aspects of the crisis was required. Moreover, the results of the simulations needed to be easily understandable and explainable: if a simulation indicates that closing schools has no effect, this can only be used if the decision makers can explain why this is the case. This book describes how a simulation framework was created for the COVID-19 crisis, and demonstrates how it was used to simulate a wide range of scenarios that were relevant for decision makers at the time. It also discusses the usefulness of the approach, and explains the decisions that had to be made along the way as well as the trade-offs. Lastly, the book examines the lessons learned and the directions for the further development of social simulation frameworks to make them better suited to crisis situations, and to foster a more resilient society.
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