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Books > Science & Mathematics > Physics > Thermodynamics & statistical physics
Ring polymers are one of the last big mysteries in polymer physics, and this thesis tackles the problem of describing their behaviour when interacting in dense solutions and with complex environments and reports key findings that help shed light on these complex issues. The systems investigated are not restricted to artificial polymer systems, but also cover biologically inspired ensembles, contributing to the broad applicability and interest of the conclusions reached. One of the most remarkable findings is the unambiguous evidence that rings inter-penetrate when in dense solutions; here this behaviour is shown to lead to the emergence of a glassy state solely driven by the topology of the constituents. This novel glassy state is unconventional in its nature and, thanks to its universal properties inherited from polymer physics, will attract the attention of a wide range of physicists in the years to come.
This book represents a detailed and systematic account of the basic
principles, developments and applications of the theory of
nucleation. The book has four parts, which are devoted to the thermodynamics of nucleation, the kinetics of nucleation, the effect of various factors on nucleation and the application of the theory to other processes, which involve nucleation. The first two parts describe in detail the two basic approaches in nucleation theory - the thermodynamic and the kinetic ones. They contain derivations of the basic and most important formulae of the theory and discuss their limitations and possibilities for improvement. The third part deals with some of the factors that can affect nucleation and is a natural continuation of the first two chapters. The last part is devoted to the application of the theory to processes of practical importance such as melt crystallization and polymorphic transformation, crystal growth and growth of thin solid films, size distribution of droplets and crystallites in condensation and crystallization. The book is not just an account of the status quo in nucleation theory - throughout the book there are a number of new results as well as extensions and generalisations of existing ones.
This is a thoroughly revised version of the original book published in 1986. About half of the contents of the previous version remain essentially unchanged, and one quarter has been rewritten and updated. The rest consists of completely new and extended material. Recent research has focussed on new materials made through "molecular engineering," and computational materials science through ab initio electron structure calculations. Another trend is the ever growing interdisciplinary aspect of both basic and applied materials science. There is an obvious need for reviews that link well established results to the modern approaches. One purpose of this book is to provide such an overview in a specific field of materials science, namely thermophysical phenomena that are intimately connected with the lattice vibrations of solids. This includes, e.g., elastic properties and electrical and thermal transport. Furthermore, this book attempts to present the results in such a form that the reader can clearly see their domain of applicability, for instance if and how they depend on crystal structure, defects, applied pressure, crystal anisotropy etc. The level and presentation is such that the results can be immediately used in research. Graduate students in condensed matter physics, metallurgy,
inorganic chemistry or geophysical materials will benefit from this
book as will theoretical physicists and scientists in industrial
research laboratories.
The book provides an introduction to the methods of quantum statistical mechanics used in quantum optics and their application to the quantum theories of the single-mode laser and optical bistability. The generalized representations of Drummond and Gardiner are discussed together with the more standard methods for deriving Fokker--Planck equations. Particular attention is given to the theory of optical bistability formulated in terms of the positive P-representation, and the theory of small bistable systems. This is a textbook at an advanced graduate level. It is intended as a bridge between an introductory discussion of the master equation method and problems of current research.
This book presents a solution for direct and inverse heat conduction problems, discussing the theoretical basis for the heat transfer process and presenting selected theoretical and numerical problems in the form of exercises with solutions. The book covers one-, two- and three dimensional problems which are solved by using exact and approximate analytical methods and numerical methods. An accompanying CD-Rom includes computational solutions of the examples and extensive FORTRAN code.
Conversion of Coal-Fired Power Plant to Cogeneration and Combined-Cycle presents the methodology, calculation procedures and tools used to support enterprise planning for adapting power stations to cogeneration and combined-cycle forms. The authors analyze the optimum selection of the structure of heat exchangers in a 370 MW power block, the structure of heat recovery steam generators and gas turbines. Conversion of Coal-Fired Power Plant to Cogeneration and Combined-Cycle also addresses the problems of converting existing power plants to dual-fuel gas-steam combined-cycle technologies coupled with parallel systems. Conversion of Coal-Fired Power Plant to Cogeneration and Combined-Cycle is an informative monograph written for researchers, postgraduate students and policy makers in power engineering.
Atmospheric and climatological studies are becoming more and more
important in day-to-day living. Winds and ocean current owe their
existence to the thermodynamic imbalances that arise from the
differential heating of the Earth and air by the sun. Accounting
for heat exchanges with the atmosphere and ocean is essential in
any predictive model of the ocean and/or atmosphere. Thermodynamic
feedback processes in the atmosphere and ocean are critical to
understanding the overall stability of the Earth's climate and
climate change. Water and its phase changes make the thermodynamics
of the atmosphere and ocean uniquely interesting and
challenging.
Complexity science has been a source of new insight in physical and social systems and has demonstrated that unpredictability and surprise are fundamental aspects of the world around us. This book is the outcome of a discussion meeting of leading scholars and critical thinkers with expertise in complex systems sciences and leaders from a variety of organizations, sponsored by the Prigogine Center at The University of Texas at Austin and the Plexus Institute, to explore strategies for understanding uncertainty and surprise. Besides contributions to the conference, it includes a key digest by the editors as well as a commentary by the late nobel laureate Ilya Prigogine, "Surprises in half of a century." The book is intended for researchers and scientists in complexity science, as well as for a broad interdisciplinary audience of both practitioners and scholars. It will well serve those interested in the research issues and in the application of complexity science to physical and social systems.
Computer science and physics have been closely linked since the
birth of modern computing. In recent years, an interdisciplinary
area has blossomed at the junction of these fields, connecting
insights from statistical physics with basic computational
challenges. Researchers have successfully applied techniques from
the study of phase transitions to analyze NP-complete problems such
as satisfiability and graph coloring. This is leading to a new
understanding of the structure of these problems, and of how
algorithms perform on them.
This book is dedicated to the recent developments in RET with the aim to explore polyatomic gas, dense gas and mixture of gases in non-equilibrium. In particular we present the theory of dense gases with 14 fields, which reduces to the Navier-Stokes Fourier classical theory in the parabolic limit. Molecular RET with an arbitrary number of field-variables for polyatomic gases is also discussed and the theory is proved to be perfectly compatible with the kinetic theory in which the distribution function depends on an extra variable that takes into account a molecule's internal degrees of freedom. Recent results on mixtures of gases with multi-temperature are presented together with a natural definition of the average temperature. The qualitative analysis and in particular, the existence of the global smooth solution and the convergence to equilibrium are also studied by taking into account the fact that the differential systems are symmetric hyperbolic. Applications to shock and sound waves are analyzed together with light scattering and heat conduction and the results are compared with experimental data. Rational extended thermodynamics (RET) is a thermodynamic theory that is applicable to non-equilibrium phenomena. It is described by differential hyperbolic systems of balance laws with local constitutive equations. As RET has been strictly related to the kinetic theory through the closure method of moment hierarchy associated to the Boltzmann equation, the applicability range of the theory has been restricted within rarefied monatomic gases. The book represents a valuable resource for applied mathematicians, physicists and engineers, offering powerful models for potential applications like satellites reentering the atmosphere, semiconductors and nano-scale phenomena.
The primary goal of the book is to present the ideas and research findings of active researchers such as physicists, economists, mathematicians and financial engineers working in the field of "Econophysics," who have undertaken the task of modeling and analyzing systemic risk, network dynamics and other topics. Of primary interest in these studies is the aspect of systemic risk, which has long been identified as a potential scenario in which financial institutions trigger a dangerous contagion mechanism, spreading from the financial economy to the real economy. This type of risk, long confined to the monetary market, has spread considerably in the recent past, culminating in the subprime crisis of 2008. As such, understanding and controlling systemic risk has become an extremely important societal and economic challenge. The Econophys-Kolkata VI conference proceedings are dedicated to addressing a number of key issues involved. Several leading researchers in these fields report on their recent work and also review contemporary literature on the subject.
Within the framework of Jaynes' "Predictive Statistical Mechanics,"
this book presents a detailed derivation of an ensemble formalism
for open systems arbitrarily away from equilibrium. This involves a
large systematization and extension of the fundamental works and
ideas of the outstanding pioneers Gibbs and Boltzmann, and of
Bogoliubov, Kirkwood, Green, Mori, Zwanzig, Prigogine and Zubarev,
among others.
Heat pipes today find many applications, in areas such as electronics cooling, diecasting and injection moulding, heat recovery and energy conservation, de-icing, and manufacturing process temperature control. "Heat Pipe Technology: Theory, Applications and Prospects" contains the proceedings of an important international gathering of those at the cutting edge of research in the field, with representatives of more than 20 countries. In addition to the finest technical papers, a particularly valuable feature is the inclusion of a series of regional surveys portraying the latest developments worldwide. The inherent characteristics of heat pipes (passiveness, absence of moving parts, high thermal efficiency) suggest for them an increasingly major role in the evolution of new thermal engineering systems in the years ahead. This volume will undoubtedly be an important resource for researchers worldwide in heat pipe technology.
In this book, the authors give an up-to-date account of thermoluminescence (TL) and other thermally stimulated phenomena. Although most recent experimental results of TL in different materials are described in some detail, the main emphasis in the present book is on general processes, and the approach is more theoretical. Thus the details of the possible processes which can take place during the excitation of the sample, and during its heating, are carefully analysed. The methods for analysing TL glow curves are critically discussed, and recommendations as to their application are made. Also discussed is the expected behavior of these phenomena as functions of the experimental parameters, for example, dose of excitation. The consequences of the main applications of TL (for example, radiation dosimetry) are also discussed in detail as are the similarities and dissimilarities of other thermally stimulated phenomena, and the simultaneous measurements of the latter and TL.
Kinetic Theory of granular Gases provides an introduction to the rapidly developing theory of dissipative gas dynamics as it has been developed mainly during the past decade. The book is aimed at readers from the advanced undergraduate level onwards and leads up to the present state of research. The text is self-contained, in the sense that no mathematical or physical knowledge is required that goes beyond standard undergraduate physics courses. The material is adequate for a one-semester course and contains chapter summaries as well as exercises with detailed solutions. Special emphasis is put on a microscopically consistent description of pairwise particle collisions which leads to an impact-velocity dependent coefficient of restitution. The description of the many-particle system, based on the Boltzmann equation, starts with the derivation of the velocity distribution function, followed by the investigation of self-diffusion and Brownian motion. Using hydrodynamical methods, transport processes and self-organized structure formulation are studies. An appendix gives a brief introduction to event-driven molecular dynamics. A second appendix describes a novel mathematical technique for the derivation of the kinetic properties which allows for the application of computer algebra. The book is accompanied by a web page where the molecular dynamics program as well as the computer-algebra programs are provided.
This book draws on the latest research to discuss the history and development of high-entropy alloys and ceramics in bulk, film, and fiber form. High-entropy materials have recently been developed using the entropy of mixing and entropy of configuration of materials, and have proven to exhibit unique properties superior to those of conventional materials. The field of high-entropy alloys was born in 2004, and has since been developed for both scientific and engineering applications. Although there is extensive literature, this field is rapidly transforming. This book highlights the cutting edge of high-entropy materials, including their fundamentals and applications. Above all, it reflects two major milestones in their development: the equi-atomic ratio single-phase high-entropy alloys; and the non-equi-atomic ratio dual-phase high-entropy alloys.
This book presents the latest advances in ultrafast science, including both ultrafast optical technology and the study of ultrafast phenomena. It covers picosecond, femtosecond, and attosecond processes relevant to applications in physics, chemistry, biology, and engineering. Ultrafast technology has a profound impact in a wide range of applications, amongst them biomedical imaging, chemical dynamics, frequency standards, material processing, and ultrahigh-speed communications. This book summarizes the results presented at the 19th International Conference on Ultrafast Phenomena and provides an up-to-date view of this important and rapidly advancing field.
This book is concerned with the prediction of thermodynamic and transport properties of gases and liquids. The prediction of such properties is essential for the solution of many problems encountered in chemical and process engineering as well as in other areas of science and technology. The book aims to present the best of those modern methods which are capable of practical application. It begins with basic scientific principles and formal results which are subsequently developed into practical methods of prediction. Numerous examples, supported by a suite of computer programmes, illustrate applications of the methods. The book is aimed primarily at the student market (for both undergraduate and taught postgraduate courses) but it will also be useful for those engaged in research and for chemical and process engineering professionals.
This book is concerned with the prediction of thermodynamic and transport properties of gases and liquids. The prediction of such properties is essential for the solution of many problems encountered in chemical and process engineering as well as in other areas of science and technology. The book aims to present the best of those modern methods which are capable of practical application. It begins with basic scientific principles and formal results which are subsequently developed into practical methods of prediction. Numerous examples, supported by a suite of computer programmes, illustrate applications of the methods. The book is aimed primarily at the student market (for both undergraduate and taught postgraduate courses) but it will also be useful for those engaged in research and for chemical and process engineering professionals.
What do combustion engines, fusion reactors, weather forecast, ocean ?ows, our sun, and stellar explosions in outer space have in common? Of course, the physics and the length and time scales are vastly di?erent in all cases, but it is alsowellknownthatinallofthem,onsomerelevantlengthscales,thematerial ?ows that govern the dynamical and/or secular evolution of the systems are chaotic and often unpredictable: they are said to be turbulent. In fact, the term "turbulence" is used for an enormous variety of p- nomena in very di?erent ?elds, including geophysics, astrophysics, and - gineering. Unfortunately, these communities do not talk to each other too often. Therefore, back in 2005, we organized a workshop on "Interdis- plinary Aspects of Turbulence" at the Ringberg Castle in the Bavarian Alps, to discuss topics such as the basic concepts of turbulence, the di?- ent approaches of modelling and simulations used in the various areas, and also possible tests. This workshop was a great success and the proceedings can be found on the Internet (www.mpa-garching.mpg.de/mpa/publications/ proceedings/proceedings-en.html) as well as pdf-?les of several of the talks presented (www.mpa-garching. mpg.de/hydro/Turbulence/).
This book deals with models and model-building in classical and quantum physics; it relies on logic and the philosophy of science as well as on modern mathematics. The reader will also find vistas into the history of ideas. The philosophical analysis is based on the separation of syntax and semantics, which is at the root of Kolmogorov's theory of probability; recursive functions and algorithmic complexity are used to discuss entropy and randomness. Basic concepts are discussed, together with concrete physical models for phase transitions, scaling, renormalization semigroups, and the irreversible approach to equilibrium. The book is intended for mathematicians, physicists and philosophers of science, both researchers and graduate students.
This is a graduate level monographic textbook in the field of Computational Intelligence. It presents a modern dynamical theory of the computational mind, combining cognitive psychology, artificial and computational intelligence, and chaos theory with quantum consciousness and computation. The book introduces to human and computational mind, comparing and contrasting main themes of cognitive psychology, artificial and computational intelligence.
This thesis discusses in detail the measurement of the polarizations of all S-wave vector quarkonium states in LHC proton-proton collisions with the CMS detector. Heavy quarkonium states constitute an ideal laboratory to study non-perturbative effects of quantum chromodynamics and to understand how quarks bind into hadrons. The experimental results are interpreted through an original phenomenological approach, which leads to a coherent picture of quarkonium production cross sections and polarizations within a simple model, dominated by one single color-octet production mechanism. These findings provide new insights into the dynamics of heavy quarkonium production at the LHC, an important step towards a satisfactory understanding of hadron formation within the standard model of particle physics.
Evolution is a critical challenge for many areas of science, technology and development of society. The book reviews general evolutionary facts such as origin of life and evolution of the genome and clues to evolution through simple systems. Emerging areas of science such as "systems biology" and "bio-complexity" are founded on the idea that phenomena need to be understood in the context of highly interactive processes operating at different levels and on different scales. This is where physics meets complexity in nature, and where we must begin to learn about complexity if we are to understand it. Similarly, there is an increasingly urgent need to understand and predict the evolutionary behavior of highly interacting man-made systems, in areas such as communications and transport, which permeate the modern world. The same applies to the evolution of human networks such as social, political and financial systems, where technology has tended to vastly increase both the complexity and speed of interaction, which is sometimes effectively instantaneous. The book contains reviews on such diverse areas as evolution experiments with microorganisms, the origin and evolution of viruses, evolutionary dynamics of genes and environment in cancer development, aging as an evolution-facilitating program, evolution of vision and evolution of financial markets.
Metaphors, generalizations and unifications are natural and desirable ingredients of the evolution of scientific theories and concepts. Physics, in particular, obviously walks along these paths since its very beginning. This book focuses on nonextensive statistical mechanics, a current generalization of Boltzmann-Gibbs (BG) statistical mechanics, one of the greatest monuments of contemporary physics. Conceived more than 130 years ago by Maxwell, Boltzmann and Gibbs, the BG theory exhibits uncountable - some of them impressive - successes in physics, chemistry, mathematics, and computational sciences, to name a few. Presently, more than two thousand publications, by over 1800 scientists around the world, have been dedicated to the nonextensive generalization. Remarkable applications have emerged, and its mathematical grounding is by now relatively well established. A pedagogical introduction to its concepts - nonlinear dynamics, extensivity of the nonadditive entropy, global correlations, generalization of the standard CLT's, among others - is presented in this book as well as a selection of paradigmatic applications in various sciences together with diversified experimental verifications of some of its predictions.
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