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Books > Science & Mathematics > Physics > Thermodynamics & statistical physics
This monograph provides a comprehensive study about how a dilute gas described by the Boltzmann equation responds under extreme nonequilibrium conditions. This response is basically characterized by nonlinear transport equations relating fluxes and hydrodynamic gradients through generalized transport coefficients that depend on the strength of the gradients. In addition, many interesting phenomena (e.g. chemical reactions or other processes with a high activation energy) are strongly influenced by the population of particles with an energy much larger than the thermal velocity, what motivates the analysis of high-degree velocity moments and the high energy tail of the distribution function. The authors have chosen to focus on shear flows with simple geometries, both for single gases and for gas mixtures. This allows them to cover the subject in great detail. Some of the topics analyzed include: -Non-Newtonian or rheological transport properties, such as the
nonlinear shear viscosity and the viscometric functions. The text can be read as a whole or can be used as a resource for selected topics from specific chapters.
Data assimilation is a hugely important mathematical technique, relevant in fields as diverse as geophysics, data science, and neuroscience. This modern book provides an authoritative treatment of the field as it relates to several scientific disciplines, with a particular emphasis on recent developments from machine learning and its role in the optimisation of data assimilation. Underlying theory from statistical physics, such as path integrals and Monte Carlo methods, are developed in the text as a basis for data assimilation, and the author then explores examples from current multidisciplinary research such as the modelling of shallow water systems, ocean dynamics, and neuronal dynamics in the avian brain. The theory of data assimilation and machine learning is introduced in an accessible and unified manner, and the book is suitable for undergraduate and graduate students from science and engineering without specialized experience of statistical physics.
Low-Grade Thermal Energy Harvesting: Advances in Thermoelectrics, Materials, and Emerging Applications provides readers with fundamental and key concepts surrounding low-grade thermal energy conversion while also reviewing the latest research directions. The book covers the most promising and emerging technologies for low-grade heat recovery, harvesting and conversion, including wearable thermoelectrics and organic thermoelectrics. Each chapter includes key materials, principles, design and fabrication strategies for low-grade heat recovery. Special attention on emerging materials such as organic composites, 2D materials and nanomaterials are also included. The book emphasizes materials and device structures that enable the powering of wearable electronics and consumer electronics. The book is suitable for materials scientists and engineers in academia and R&D in manufacturing, industry, energy and electronics.
"Temperature and Humidity Independent Control (THIC) of Air-conditioning System" focuses on temperature and humidity independent control (THIC) systems, which represents a new concept and new approach for indoor environmental control. This book presents the main components of the THIC systems, including dehumidification devices, high-temperature cooling devices and indoor terminal devices. Other relevant issues, such as operation and control strategy and case studies, are also included. This book is intended for air-conditioning system designers and engineers as well as researchers working with indoor environments. Xiaohua Liu is an associate professor at the Building Energy Research Center, Tsinghua University, China. Yi Jiang is a member of the Chinese Academy of Engineering, the director of the Building Energy Research Center, Tsinghua University, China and the director of the China-USA Joint Research Center on Clean Energy. Tao Zhang is a Ph.D. candidate at the Building Energy Research Center, Tsinghua University, China.
This book sheds light on the large-scale engineering systems that shape and guide our everyday lives. It does this by bringing together the latest research and practice defining the emerging field of Complex Engineered Systems. Understanding, designing, building and controlling such complex systems is going to be a central challenge for engineers in the coming decades. This book is a step toward addressing that challenge.
This thesis is concerned with establishing a rigorous, modern theory of the stochastic and dissipative forces on crystal defects, which remain poorly understood despite their importance in any temperature dependent micro-structural process such as the ductile to brittle transition or irradiation damage. The author first uses novel molecular dynamics simulations to parameterise an efficient, stochastic and discrete dislocation model that allows access to experimental time and length scales. Simulated trajectories are in excellent agreement with experiment. The author also applies modern methods of multiscale analysis to extract novel bounds on the transport properties of these many body systems. Despite their successes in coarse graining, existing theories are found unable to explain stochastic defect dynamics. To resolve this, the author defines crystal defects through projection operators, without any recourse to elasticity. By rigorous dimensional reduction, explicit analytical forms are derived for the stochastic forces acting on crystal defects, allowing new quantitative insight into the role of thermal fluctuations in crystal plasticity.
This unique book gives a comprehensive account of new mathematical tools used to solve polygon problems. In the 20th and 21st centuries, many problems in mathematics, theoretical physics and theoretical chemistry - and more recently in molecular biology and bio-informatics - can be expressed as counting problems, in which specified graphs, or shapes, are counted. One very special class of shapes is that of polygons. These are closed, connected paths in space. We usually sketch them in two-dimensions, but they can exist in any dimension. The typical questions asked include "how many are there of a given perimeter?," "how big is the average polygon of given perimeter?," and corresponding questions about the area or volume enclosed. That is to say "how many enclosing a given area?" and "how large is an average polygon of given area?" Simple though these questions are to pose, they are extraordinarily difficult to answer. They are important questions because of the application of polygon, and the related problems of polyomino and polycube counting, to phenomena occurring in the natural world, and also because the study of these problems has been responsible for the development of powerful new techniques in mathematics and mathematical physics, as well as in computer science. These new techniques then find application more broadly. The book brings together chapters from many of the major contributors in the field. An introductory chapter giving the history of the problem is followed by fourteen further chapters describing particular aspects of the problem, and applications to biology, to surface phenomena and to computer enumeration methods.
This work tries to provide an elementary introduction to the notions of continuum limit and universality in statistical systems with a large number of degrees of freedom. The existence of a continuum limit requires the appearance of correlations at large distance, a situation that is encountered in second order phase transitions, near the critical temperature. In this context, we will emphasize the role of gaussian distributions and their relations with the mean field approximation and Landau's theory of critical phenomena. We will show that quasi-gaussian or mean-field approximations cannot describe correctly phase transitions in three space dimensions. We will assign this difficulty to the coupling of very different physical length scales, even though the systems we will consider have only local, that is, short range interactions. To analyze the unusual situation, a new concept is required: the renormalization group, whose fixed points allow understanding the universality of physical properties at large distance beyond mean-field theory. In the continuum limit, critical phenomena can be described by quantum field theories. In this framework, the renormalization group is directly related to the renormalization process, that is, the necessity to cancel the infinities that arise in straightforward formulations of the theory. We thus discuss the renormalization group in the context of various relevant field theories. This leads to proofs of universality and to efficient tools for calculating universal quantities in a perturbative framework. Finally, we construct a general functional renormalization group, which can be used when perturbative methods are inadequate.
This textbook explores the working principles of all kinds of turbomachines. The same theoretical framework is used to analyze the different machine types. The order in which the different kinds are treated is chosen by the possibility of gradually building up theoretical concepts. For each of the turbomachine kinds, a balance is sought between fundamental understanding and knowledge of practical aspects. Readers are invited through challenging exercises to consider how the theory applies to particular cases. This textbook appeals to senior undergraduate and graduate students in mechanical engineering and to professional engineers seeking to understand the operation of turbomachines. Readers will gain a fundamental understanding of turbomachines and will be able to make a reasoned choice of a turbomachine for a particular application.
In this volume we continue the logical development of the work begun in Volume I, and the equilibrium theory now becomes a very special case of the exposition presented here. Once a departure is made from equilibrium, however, the problems become deeper and more subtle-and unlike the equilibrium theory, many aspects of nonequilibrium phenomena remain poorly understood. For over a century a great deal of effort has been expended on the attempt to develop a comprehensive and sensible description of nonequilibrium phenomena and irreversible processes. What has emerged is a hodgepodge of ad hoc constructs that do little to provide either a firm foundation, or a systematic means for proceeding to higher levels of understanding with respect to ever more complicated examples of nonequilibria. Although one should rightfully consider this situation shameful, the amount of effort invested testifies to the degree of difficulty of the problems. In Volume I it was emphasized strongly that the traditional exposition of equilibrium theory lacked a certain cogency which tended to impede progress with extending those considerations to more complex nonequilibrium problems. The reasons for this were adduced to be an unfortunate reliance on ergodicity and the notions of kinetic theory, but in the long run little harm was done regarding the treatment of equilibrium problems. On the nonequilibrium level the potential for disaster increases enormously, as becomes evident already in Chapter 1.
This thesis presents pioneering experimental and numerical studies on three aspects of the combustion characteristics of lean premixed syngas/air flames, namely the laminar flame speed, extinction limit and flammability limit. It illustrates a new extinction exponent concept, which enriches the combustion theory. Above all, the book provides the following: a) a series of carefully measured data and theoretical analyses to reveal the intrinsic mechanisms of the fuel composition effect on the propagation and extinction of lean syngas/air flames; b) a mixing model and correlation to predict the laminar flame speed of multi-component syngas fuels, intended for engineering computations; c) a new "extinction exponent" concept to describe the critical effects of chemical kinetics on the extinction of lean premixed syngas/air flames; and d) the effects and mechanism of the dilution of incombustible components on lean premixed syngas/air flames and the preferential importance among the thermal, chemical and diffusion effects.
This two-volume work provides a comprehensive study of the statistical mechanics of lattice models. It introduces readers to the main topics and the theory of phase transitions, building on a firm mathematical and physical basis. Volume 1 contains an account of mean-field and cluster variation methods successfully used in many applications in solid-state physics and theoretical chemistry, as well as an account of exact results for the Ising and six-vertex models and those derivable by transformation methods.
Metaphors, generalizations and unifications are natural and desirable ingredients of the evolution of scientific theories and concepts. Physics, in particular, obviously walks along these paths since its very beginning. This book focuses on nonextensive statistical mechanics, a current generalization of Boltzmann-Gibbs (BG) statistical mechanics, one of the greatest monuments of contemporary physics. Conceived more than 130 years ago by Maxwell, Boltzmann and Gibbs, the BG theory exhibits uncountable - some of them impressive - successes in physics, chemistry, mathematics, and computational sciences, to name a few. Presently, more than two thousand publications, by over 1800 scientists around the world, have been dedicated to the nonextensive generalization. Remarkable applications have emerged, and its mathematical grounding is by now relatively well established. A pedagogical introduction to its concepts - nonlinear dynamics, extensivity of the nonadditive entropy, global correlations, generalization of the standard CLT's, among others - is presented in this book as well as a selection of paradigmatic applications in various sciences together with diversified experimental verifications of some of its predictions.
In the present volume numerous descriptions of Ram accelerators are presented. These descriptions provide good overview on the progress made and the present state of the Ram accelerator technology worldwide. In addition, articles describing light gas gun, ballistic range including a chapter dealing with shock waves in solids are given. Along with the technical description of considered facilities, samples of obtained results are also included. Each chapter is written by an expert in the described topic providing a comprehensive description of the discussed phenomena.
One common characteristics of a complex system is its ability to
withstand major disturbances and the capacity to rebuild itself.
Understanding how such systems demonstrate resilience by absorbing
or recovering from major external perturbations requires both
quantitative foundations and a multidisciplinary view on the
topic.
In this thesis, the author describes the development of a software framework to systematically construct a particular class of weakly coupled free fermionic heterotic string models, dubbed gauge models. In their purest form, these models are maximally supersymmetric (N = 4), and thus only contain superpartners in their matter sector. This feature makes their systematic construction particularly efficient, and they are thus useful in their simplicity. The thesis first provides a brisk introduction to heterotic strings and the spin-structure construction of free fermionic models. Three systematic surveys are then presented, and it is conjectured that these surveys are exhaustive modulo redundancies. Finally, the author presents a collection of metaheuristic algorithms for searching the landscape for models with a user-specified spectrum of phenomenological properties, e.g. gauge group and number of spacetime supersymmetries. Such algorithms provide the groundwork for extended generic free fermionic surveys.
Most of the interesting and difficult problems in statistical mechanics arise when the constituent particles of the system interact with each other with pair or multipartiele energies. The types of behaviour which occur in systems because of these interactions are referred to as cooperative phenomena giving rise in many cases to phase transitions. This book and its companion volume (Lavis and Bell 1999, referred to in the text simply as Volume 1) are princi pally concerned with phase transitions in lattice systems. Due mainly to the insights gained from scaling theory and renormalization group methods, this subject has developed very rapidly over the last thirty years. ' In our choice of topics we have tried to present a good range of fundamental theory and of applications, some of which reflect our own interests. A broad division of material can be made between exact results and ap proximation methods. We have found it appropriate to inelude some of our discussion of exact results in this volume and some in Volume 1. Apart from this much of the discussion in Volume 1 is concerned with mean-field theory. Although this is known not to give reliable results elose to a critical region, it often provides a good qualitative picture for phase diagrams as a whole. For complicated systems some kind of mean-field method is often the only tractable method available. In this volume our main concern is with scaling theory, algebraic methods and the renormalization group."
Chaos and nonlinear dynamics initially developed as a new emergent field with its foundation in physics and applied mathematics. The highly generic, interdisciplinary quality of the insights gained in the last few decades has spawned myriad applications in almost all branches of science and technology-and even well beyond. Wherever quantitative modeling and analysis of complex, nonlinear phenomena is required, chaos theory and its methods can play a key role. This volume concentrates on reviewing the most relevant contemporary applications of chaotic nonlinear systems as they apply to the various cutting-edge branches of engineering. The book covers the theory as applied to robotics, electronic and communication engineering (for example chaos synchronization and cryptography) as well as to civil and mechanical engineering, where its use in damage monitoring and control is explored). Featuring contributions from active and leading research groups, this collection is ideal both as a reference and as a 'recipe book' full of tried and tested, successful engineering applications
This book studies the collision, coalescence and deposition of nanoparticles in stagnation flames. With the help of synthesis experiments, in-situ laser diagnostics and molecular dynamics simulations, it investigates the growth of nanoparticles in flames and their deposition in boundary layers at a macroscopic flow field scale, as well as particle and molecular scale issues such as the interaction force between particles, how the collision rate is enhanced by attractive forces, and how the nano-scale coalescence process is influenced by the high surface curvature - all of which are crucial to understanding nanoparticle transport phenomena at high temperatures. The book also reports on a novel in-situ laser diagnostics phenomenon called phase-selective laser-induced breakdown spectroscopy and related applications for tracing gas-to-particle transitions and measuring local particle volume fractions in nano-aerosols.
Observation, Prediction and Simulation of Phase Transitions in Complex Fluids presents an overview of the phase transitions that occur in a variety of soft-matter systems: colloidal suspensions of spherical or rod-like particles and their mixtures, directed polymers and polymer blends, colloid--polymer mixtures, and liquid-forming mesogens. This modern and fascinating branch of condensed matter physics is presented from three complementary viewpoints. The first section, written by experimentalists, emphasises the observation of basic phenomena (by light scattering, for example). The second section, written by theoreticians, focuses on the necessary theoretical tools (density functional theory, path integrals, free energy expansions). The third section is devoted to the results of modern simulation techniques (Gibbs ensemble, free energy calculations, configurational bias Monte Carlo). The interplay between the disciplines is clearly illustrated. For all those interested in modern research in equilibrium statistical mechanics.
This book is based on the premise that the entropy concept, a fundamental element of probability theory as logic, governs all of thermal physics, both equilibrium and nonequilibrium. The variational algorithm of J. Willard Gibbs, dating from the 19th Century and extended considerably over the following 100 years, is shown to be the governing feature over the entire range of thermal phenomena, such that only the nature of the macroscopic constraints changes. Beginning with a short history of the development of the entropy concept by Rudolph Clausius and his predecessors, along with the formalization of classical thermodynamics by Gibbs, the first part of the book describes the quest to uncover the meaning of thermodynamic entropy, which leads to its relationship with probability and information as first envisioned by Ludwig Boltzmann. Recognition of entropy first of all as a fundamental element of probability theory in mid-twentieth Century led to deep insights into both statistical mechanics and thermodynamics, the details of which are presented here in several chapters. The later chapters extend these ideas to nonequilibrium statistical mechanics in an unambiguous manner, thereby exhibiting the overall unifying role of the entropy.
This book presents the theory of periodic conjugate heat transfer in a detailed way. The effects of thermophysical properties and geometry of a solid body on the commonly used and experimentally determined heat transfer coefficient are analytically presented from a general point of view. The main objective of the book is a simplified description of the interaction between a solid body and a fluid as a boundary value problem of the heat conduction equation for the solid body. At the body surface, the true heat transfer coefficient is composed of two parts: the true mean value resulting from the solution of the steady state heat transfer problem and a periodically variable part, the periodic time and length to describe the oscillatory hydrodynamic effects. The second edition is extended by (i) the analysis of stability boundaries in helium flow at supercritical conditions in a heated channel with respect to the interaction between a solid body and a fluid; (ii) a periodic model and a method of heat transfer simulation in a fluid at supercritical pressure and (iii) a periodic quantum-mechanical model for homogeneous vapor nucleation in a fluid with respect to nanoscale effects.
This work introduces a new method for analysing measured signals: nonlinear mode decomposition, or NMD. It justifies NMD mathematically, demonstrates it in several applications and explains in detail how to use it in practice. Scientists often need to be able to analyse time series data that include a complex combination of oscillatory modes of differing origin, usually contaminated by random fluctuations or noise. Furthermore, the basic oscillation frequencies of the modes may vary in time; for example, human blood flow manifests at least six characteristic frequencies, all of which wander in time. NMD allows us to separate these components from each other and from the noise, with immediate potential applications in diagnosis and prognosis. Mat Lab codes for rapid implementation are available from the author. NMD will most likely come to be used in a broad range of applications.
This book consists of peer-reviewed articles and reviews presented as lectures at the Sixth International Symposium on Thermal Engineering and Sciences for Cold Regions in Darmstadt, Germany. It addresses all relevant aspects of thermal physics and engineering in cold regions, such as the Arctic regions. These environments present many unique freezing and melting phenomena and the relevant heat and mass transfer processes are of basic importance with respect to both the technological applications and the natural context in which they occur. Intended for physicists, engineers, geoscientists, climatologists and cryologists alike, these proceedings cover topics such as: ice formation and decay, heat conduction with phase change, convection with freezing and melting, thermal properties at low temperature, frost heave and permafrost, climate impact in cold regions, thermal design of structures, bio-engineering in cold regions, and many more.
Thermodiffusion describes the coupling between a temperature gradient and a resulting mass flux. Traditionally, the focus has been on simple fluids, and it is now extending to more complex systems such as electrolytes, polymers, colloidal dispersions and magnetic fluids. This book widens the scope even further by including applications in ionic solids. Written as a set of tutorial reviews, it will be useful to experts, nonspecialist researchers and postgraduate students alike. |
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