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Books > Science & Mathematics > Physics > Thermodynamics & statistical physics
One common characteristics of a complex system is its ability to
withstand major disturbances and the capacity to rebuild itself.
Understanding how such systems demonstrate resilience by absorbing
or recovering from major external perturbations requires both
quantitative foundations and a multidisciplinary view on the
topic.
This book studies the collision, coalescence and deposition of nanoparticles in stagnation flames. With the help of synthesis experiments, in-situ laser diagnostics and molecular dynamics simulations, it investigates the growth of nanoparticles in flames and their deposition in boundary layers at a macroscopic flow field scale, as well as particle and molecular scale issues such as the interaction force between particles, how the collision rate is enhanced by attractive forces, and how the nano-scale coalescence process is influenced by the high surface curvature - all of which are crucial to understanding nanoparticle transport phenomena at high temperatures. The book also reports on a novel in-situ laser diagnostics phenomenon called phase-selective laser-induced breakdown spectroscopy and related applications for tracing gas-to-particle transitions and measuring local particle volume fractions in nano-aerosols.
In this volume we continue the logical development of the work begun in Volume I, and the equilibrium theory now becomes a very special case of the exposition presented here. Once a departure is made from equilibrium, however, the problems become deeper and more subtle-and unlike the equilibrium theory, many aspects of nonequilibrium phenomena remain poorly understood. For over a century a great deal of effort has been expended on the attempt to develop a comprehensive and sensible description of nonequilibrium phenomena and irreversible processes. What has emerged is a hodgepodge of ad hoc constructs that do little to provide either a firm foundation, or a systematic means for proceeding to higher levels of understanding with respect to ever more complicated examples of nonequilibria. Although one should rightfully consider this situation shameful, the amount of effort invested testifies to the degree of difficulty of the problems. In Volume I it was emphasized strongly that the traditional exposition of equilibrium theory lacked a certain cogency which tended to impede progress with extending those considerations to more complex nonequilibrium problems. The reasons for this were adduced to be an unfortunate reliance on ergodicity and the notions of kinetic theory, but in the long run little harm was done regarding the treatment of equilibrium problems. On the nonequilibrium level the potential for disaster increases enormously, as becomes evident already in Chapter 1.
"The first volume might be especially useful for specialists in its subject, but it also contains good expositions for nonspecialists." Acta Sci. Math. (Szeged) Contents: Notes on Subfactors and Statistical Mechanics (V F R Jones); Polynomial Invariants in Knot Theory (L H Kauffman); Algebras of Loops on Surfaces, Algebras of Knots, and Quantization (V G Turaev); Quantum Groups (L Faddeev et al.); Introduction to the Yang-Baxter Equation (M Jimbo); Integrable Systems Related to Braid Groups and Yang-Baxter Equation (T Kohno); The Yang-Baxter Relation: A New Tool for Knot Theory (Y Akutsu et al.); Akutsu-Wadati Link Polynomials from Feynman-Kauffman Diagrams (M-L Ge et al.); Quantum Field Theory and the Jones Polynomial (E Witten)
This two-volume work provides a comprehensive study of the statistical mechanics of lattice models. It introduces readers to the main topics and the theory of phase transitions, building on a firm mathematical and physical basis. Volume 1 contains an account of mean-field and cluster variation methods successfully used in many applications in solid-state physics and theoretical chemistry, as well as an account of exact results for the Ising and six-vertex models and those derivable by transformation methods.
Most of the interesting and difficult problems in statistical mechanics arise when the constituent particles of the system interact with each other with pair or multipartiele energies. The types of behaviour which occur in systems because of these interactions are referred to as cooperative phenomena giving rise in many cases to phase transitions. This book and its companion volume (Lavis and Bell 1999, referred to in the text simply as Volume 1) are princi pally concerned with phase transitions in lattice systems. Due mainly to the insights gained from scaling theory and renormalization group methods, this subject has developed very rapidly over the last thirty years. ' In our choice of topics we have tried to present a good range of fundamental theory and of applications, some of which reflect our own interests. A broad division of material can be made between exact results and ap proximation methods. We have found it appropriate to inelude some of our discussion of exact results in this volume and some in Volume 1. Apart from this much of the discussion in Volume 1 is concerned with mean-field theory. Although this is known not to give reliable results elose to a critical region, it often provides a good qualitative picture for phase diagrams as a whole. For complicated systems some kind of mean-field method is often the only tractable method available. In this volume our main concern is with scaling theory, algebraic methods and the renormalization group."
Chaos and nonlinear dynamics initially developed as a new emergent field with its foundation in physics and applied mathematics. The highly generic, interdisciplinary quality of the insights gained in the last few decades has spawned myriad applications in almost all branches of science and technology-and even well beyond. Wherever quantitative modeling and analysis of complex, nonlinear phenomena is required, chaos theory and its methods can play a key role. This volume concentrates on reviewing the most relevant contemporary applications of chaotic nonlinear systems as they apply to the various cutting-edge branches of engineering. The book covers the theory as applied to robotics, electronic and communication engineering (for example chaos synchronization and cryptography) as well as to civil and mechanical engineering, where its use in damage monitoring and control is explored). Featuring contributions from active and leading research groups, this collection is ideal both as a reference and as a 'recipe book' full of tried and tested, successful engineering applications
This book is based on the premise that the entropy concept, a fundamental element of probability theory as logic, governs all of thermal physics, both equilibrium and nonequilibrium. The variational algorithm of J. Willard Gibbs, dating from the 19th Century and extended considerably over the following 100 years, is shown to be the governing feature over the entire range of thermal phenomena, such that only the nature of the macroscopic constraints changes. Beginning with a short history of the development of the entropy concept by Rudolph Clausius and his predecessors, along with the formalization of classical thermodynamics by Gibbs, the first part of the book describes the quest to uncover the meaning of thermodynamic entropy, which leads to its relationship with probability and information as first envisioned by Ludwig Boltzmann. Recognition of entropy first of all as a fundamental element of probability theory in mid-twentieth Century led to deep insights into both statistical mechanics and thermodynamics, the details of which are presented here in several chapters. The later chapters extend these ideas to nonequilibrium statistical mechanics in an unambiguous manner, thereby exhibiting the overall unifying role of the entropy.
Observation, Prediction and Simulation of Phase Transitions in Complex Fluids presents an overview of the phase transitions that occur in a variety of soft-matter systems: colloidal suspensions of spherical or rod-like particles and their mixtures, directed polymers and polymer blends, colloid--polymer mixtures, and liquid-forming mesogens. This modern and fascinating branch of condensed matter physics is presented from three complementary viewpoints. The first section, written by experimentalists, emphasises the observation of basic phenomena (by light scattering, for example). The second section, written by theoreticians, focuses on the necessary theoretical tools (density functional theory, path integrals, free energy expansions). The third section is devoted to the results of modern simulation techniques (Gibbs ensemble, free energy calculations, configurational bias Monte Carlo). The interplay between the disciplines is clearly illustrated. For all those interested in modern research in equilibrium statistical mechanics.
This book presents the theory of periodic conjugate heat transfer in a detailed way. The effects of thermophysical properties and geometry of a solid body on the commonly used and experimentally determined heat transfer coefficient are analytically presented from a general point of view. The main objective of the book is a simplified description of the interaction between a solid body and a fluid as a boundary value problem of the heat conduction equation for the solid body. At the body surface, the true heat transfer coefficient is composed of two parts: the true mean value resulting from the solution of the steady state heat transfer problem and a periodically variable part, the periodic time and length to describe the oscillatory hydrodynamic effects. The second edition is extended by (i) the analysis of stability boundaries in helium flow at supercritical conditions in a heated channel with respect to the interaction between a solid body and a fluid; (ii) a periodic model and a method of heat transfer simulation in a fluid at supercritical pressure and (iii) a periodic quantum-mechanical model for homogeneous vapor nucleation in a fluid with respect to nanoscale effects.
This work introduces a new method for analysing measured signals: nonlinear mode decomposition, or NMD. It justifies NMD mathematically, demonstrates it in several applications and explains in detail how to use it in practice. Scientists often need to be able to analyse time series data that include a complex combination of oscillatory modes of differing origin, usually contaminated by random fluctuations or noise. Furthermore, the basic oscillation frequencies of the modes may vary in time; for example, human blood flow manifests at least six characteristic frequencies, all of which wander in time. NMD allows us to separate these components from each other and from the noise, with immediate potential applications in diagnosis and prognosis. Mat Lab codes for rapid implementation are available from the author. NMD will most likely come to be used in a broad range of applications.
This textbook concerns thermal properties of bulk matter and is aimed at advanced undergraduate or first-year graduate students in a range of programs in science or engineering. It provides an intermediate level presentation of statistical thermodynamics for students in the physical sciences (chemistry, nanosciences, physics) or related areas of applied science/engineering (chemical engineering, materials science, nanotechnology engineering), as they are areas in which statistical mechanical concepts play important roles. The book enables students to utilize microscopic concepts to achieve a better understanding of macroscopic phenomena and to be able to apply these concepts to the types of sub-macroscopic systems encountered in areas of nanoscience and nanotechnology.
This book consists of peer-reviewed articles and reviews presented as lectures at the Sixth International Symposium on Thermal Engineering and Sciences for Cold Regions in Darmstadt, Germany. It addresses all relevant aspects of thermal physics and engineering in cold regions, such as the Arctic regions. These environments present many unique freezing and melting phenomena and the relevant heat and mass transfer processes are of basic importance with respect to both the technological applications and the natural context in which they occur. Intended for physicists, engineers, geoscientists, climatologists and cryologists alike, these proceedings cover topics such as: ice formation and decay, heat conduction with phase change, convection with freezing and melting, thermal properties at low temperature, frost heave and permafrost, climate impact in cold regions, thermal design of structures, bio-engineering in cold regions, and many more.
Thermodiffusion describes the coupling between a temperature gradient and a resulting mass flux. Traditionally, the focus has been on simple fluids, and it is now extending to more complex systems such as electrolytes, polymers, colloidal dispersions and magnetic fluids. This book widens the scope even further by including applications in ionic solids. Written as a set of tutorial reviews, it will be useful to experts, nonspecialist researchers and postgraduate students alike.
This book presents recent findings on the global existence, the uniqueness and the large-time behavior of global solutions of thermo(vis)coelastic systems and related models arising in physics, mechanics and materials science such as thermoviscoelastic systems, thermoelastic systems of types II and III, as well as Timoshenko-type systems with past history. Part of the book is based on the research conducted by the authors and their collaborators in recent years. The book will benefit interested beginners in the field and experts alike.
This book focuses on the nonlinear dynamics based on the vector fields with univariate quadratic functions. This book is a unique monograph for two-dimensional quadratic nonlinear systems. It provides different points of view about nonlinear dynamics and bifurcations of the quadratic dynamical systems. Such a two-dimensional dynamical system is one of simplest dynamical systems in nonlinear dynamics, but the local and global structures of equilibriums and flows in such two-dimensional quadratic systems help us understand other nonlinear dynamical systems, which is also a crucial step toward solving the Hilbert's sixteenth problem. Possible singular dynamics of the two-dimensional quadratic systems are discussed in detail. The dynamics of equilibriums and one-dimensional flows in two-dimensional systems are presented. Saddle-sink and saddle-source bifurcations are discussed, and saddle-center bifurcations are presented. The infinite-equilibrium states are switching bifurcations for nonlinear systems. From the first integral manifolds, the saddle-center networks are developed, and the networks of saddles, source, and sink are also presented. This book serves as a reference book on dynamical systems and control for researchers, students, and engineering in mathematics, mechanical, and electrical engineering.
This superb text describes a novel and powerful method for allowing
design engineers to firstly model a linear problem in heat
conduction, then build a solution in an explicit form and finally
obtain a numerical solution. It constitutes a modelling and
calculation tool based on a very efficient and systemic
methodological approach.
Materials sciences relate the macroscopic properties of materials to their microscopic structure and postulate the need for holistic multiscale research. The investigation of shape memory alloys is a prime example in this regard. This particular class of materials exhibits strong coupling of temperature, strain and stress, determined by solid state phase transformations of their metallic lattices. The present book presents a collection of simulation studies of this behaviour. Employing conceptually simple but comprehensive models, the fundamental material properties of shape memory alloys are qualitatively explained from first principles. Using contemporary methods of molecular dynamics simulation experiments, it is shown how microscale dynamics may produce characteristic macroscopic material properties. The work is rooted in the materials sciences of shape memory alloys and covers thermodynamical, micro-mechanical and crystallographical aspects. It addresses scientists in these research fields and their students.
This book, based on a selection of invited presentations from a topical workshop, focusses on time-variable oscillations and their interactions. The problem is challenging, because the origin of the time variability is usually unknown. In mathematical terms, the oscillations are non-autonomous, reflecting the physics of open systems where the function of each oscillator is affected by its environment. Time-frequency analysis being essential, recent advances in this area, including wavelet phase coherence analysis and nonlinear mode decomposition, are discussed. Some applications to biology and physiology are described. Although the most important manifestation of time-variable oscillations is arguably in biology, they also crop up in, e.g. astrophysics, or for electrons on superfluid helium. The book brings together the research of the best international experts in seemingly very different disciplinary areas.
This book addresses the problem of multi-agent systems, considering that it can be interpreted as a generalized multi-synchronization problem. From manufacturing tasks, through encryption and communication algorithms, to high-precision experiments, the simultaneous cooperation between multiple systems or agents is essential to successfully carrying out different modern activities, both in academy and industry. For example, the coordination of multiple assembler robots in manufacturing lines. These agents need to synchronize. The first two chapters of the book describe the synchronization of dynamical systems, paying special attention to the synchronization of non-identical systems. Following, the third chapter presents an interesting application of the synchronization phenomenon for state estimation. Subsequently, the authors fully address the multi-agent problem interpreted as multi-synchronization. The final chapters introduce the reader to a more complex problem, the synchronization of systems governed by partial differential equations, both of integer and fractional order. The book aimed at graduates, postgraduate students and researchers closely related to the area of automatic control. Previous knowledge of linear algebra, classical and fractional calculus is requested, as well as some fundamental notions of graph theory.
"Great progress has been made in electrical science, chiefly in Germany, by cultivators of the theory of action at a distance. The valuable electrical measurements of W. Weber are interpreted by him according to this theory, and the electromagnetic speculation which was originated by Gauss, and carried on by Weber, Riemann, F. and C. Neumann, Lorenz, etc. , is founded on the theory of action at a distance, but depending either directly on the relative velocity of the particles, or on the gradual propagation of something, whether potential or force, from the one particle to the other. The great success which these eminent men have attained in the application of mathematics to electrical phenomena, gives, as is natural, additional weight to their theoretical speculations, so that those who, as students of electricity, turn to them as the greatest authorities in mathematical electricity, would probably imbibe, along with their mathematical methods, their physical hypothesis. These physical hypotheses, however, are entirely alien from the way of looking at things which I adopt, and one object which I have in view is that some of those who wish to study electricity may, by reading this treatise, come to see that there is another way of treating the subject, which is no less fitted to explain the phenomena, and which, though in some parts it may appear less definite, corresponds, as I think, more faithfuHy with our actual knowledge, both in what it affirms and in what it leaves undecided.
The book describes in a simple and practical way what non-equilibrium thermodynamics is and how it can add to engineering fields. It explains how to describe proper equations of transport, more precise than used so far, and how to use them to understand the waste of energy resources in central unit processes in the industry. It introduces the entropy balance as an additional equation to use, to create consistent thermodynamic models, and a systematic method for minimizing energy losses that are connected with transport of heat, mass, charge, momentum and chemical reactions. Readership: Senior undergraduate and graduate students in physics, chemistry, chemical engineering and mechanical engineering.
Key features Major concepts in thermal physics are introduced cohesively through computational and mathematical treatments. Computational examples in Python programming language guide students on how to simulate and visualize thermodynamic principles and processes for themselves.
This is a collection of articles written by mathematicians and physicists, designed to describe the state of the art in climate models with stochastic input. Mathematicians will benefit from a survey of simple models, while physicists will encounter mathematically relevant techniques at work.
This thesis explores several interdisciplinary topics at the border of theoretical physics and biology, presenting results that demonstrate the power of methods from statistical physics when applied to neighbouring disciplines. From birth-death processes in switching environments to discussions on the meaning of quasi-potential landscapes in high-dimensional spaces, this thesis is a shining example of the efficacy of interdisciplinary research. The fields advanced in this work include game theory, the dynamics of cancer, and invasion of mutants in resident populations, as well as general contributions to the theory of stochastic processes. The background material provides an intuitive introduction to the theory and applications of stochastic population dynamics, and the use of techniques from statistical physics in their analysis. The thesis then builds on these foundations to address problems motivated by biological phenomena. |
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