Conjugated polymers have important technological applications, including solar cells and light emitting devices. They are also active components in many important biological processes. In recent years there have been significant advances in our understanding of these systems, owing to both improved experimental measurements and the development of advanced computational techniques. The aim of this book is to describe and explain the electronic and optical properties of conjugated polymers. It focuses on the three key roles of electron-electron interactions, electron-nuclear coupling, and disorder in determining the character of the electronic states, and it relates these properties to experimental observations in real systems. A number of important optical and electronic processes in conjugated polymers are also described. The second edition has a more extended discussion of excitons in conjugated polymers. There is also a new chapter on the static and dynamical localization of excitons.

This monograph is devoted to an entirely new branch of nonlinear physics - solitary intrinsic states, or autosolitons, which form in a broad class of physical, chemical and biological dissipative systems. Autosolitons are often observed as highly nonequilibrium regions in slightly nonequilibrium systems, in many ways resembling ball lightning which occurs in the atmosphere. We develop a new approach to problems of self-organization and turbulence, treating these phenomena as a result of spontaneous formation and subsequent evolution of autosolitons. Scenarios of self-organization involve sophisticated interactions between autosolitons, whereas turbulence is regarded as a pattern of autosolitons which appear and disappear at random in different parts of the system. This monograph is the first attempt to provide a comprehensive summary of the theory of autosolitons as developed by the authors over the years of research. The monograph is comprised of three more or less autonomous parts. Part I deals with the physical nature and experimental studies of autosolitons and self organization in various physical systems: semiconductor and gas plasma, heated gas mixture, semiconductor structures, composite superconductors, optical and magnetic media, systems with uniformly generated combustion matter, distributed gas-discharge and electronic systems. We discuss feasibility of autosolitons in the form of highly nonequilibrium regions in slightly nonequilibrium gases and semiconductors, "hot" and "cold" regions in semiconductor and gas plasmas, static, pulsating and traveling combustion fronts."

Over the years enormous effort was invested in proving ergodicity, but for a number of reasons, con?dence in the fruitfulness of this approach has waned. - Y. Ben-Menahem and I. Pitowsky [1] Abstract The basic motivation behind the present text is threefold: To give a new explanation for the emergence of thermodynamics, to investigate the interplay between quantum mechanics and thermodynamics, and to explore possible ext- sions of the common validity range of thermodynamics. Originally, thermodynamics has been a purely phenomenological science. Early s- entists (Galileo, Santorio, Celsius, Fahrenheit) tried to give de?nitions for quantities which were intuitively obvious to the observer, like pressure or temperature, and studied their interconnections. The idea that these phenomena might be linked to other ?elds of physics, like classical mechanics, e.g., was not common in those days. Such a connection was basically introduced when Joule calculated the heat equ- alent in 1840 showing that heat was a form of energy, just like kinetic or potential energy in the theory of mechanics. At the end of the 19th century, when the atomic theory became popular, researchers began to think of a gas as a huge amount of bouncing balls inside a box.

Researchers, postgraduate and undergraduate students of high energy physics

This book presents solutions to problems that are total and based on thinking about how and why humans have organized themselves. It discusses how to avoid the now well-documented Holocene Extinction, propelled by climate change, wars, resource depletion, desertification, degrading knowledge quality, famine, and deterioration of societies overall. It explains why we cannot respond effectively with hedonistic, incompetent, corrupt, and anarchistic "liberal democracy" and why neither personality cult regimes can suffice.  The book offers a model of an organic social structure embodying a collective consciousness of communitarianism and Platonic-style ethos. Putting an emphasis on the re-establishment of Classical Greek virtue, it offers solutions to resolve identity politics, alienation, and meritocracy. While doing so, the author opposes the "everyone is equal" ideology to govern the section of policymakers, instead circumscribing "rights" in terms of responsibilities, prioritizing education and training to carry forth the ethos of valuing truth above materialism, and developing Durkheim's social brain via a new discipline, "sociointelligence". The book goes on to explain how underpinning these elements is a comprehensive elucidation of often misunderstood words like "liberty", "freedom", "authoritarianism", and "democracy". All of these areas are arranged and combined in uniquely describing the organic society the author deems necessary to avoid human extinction. As a result, the book presents a “new organicity�, where the emerging transhumanism seeks to transcend hydrocarbon-based life with humanly-constructed life. This book will appeal to students, researchers, and scholars of political science, philosophy, and the social sciences interested in a better understanding of complexity, democratic theory, Holocene Extinction, organic thinking, and meritocratic societies. 

The book describes the thermodynamics, fluid dynamics, and working principle of the Ranque Hilsch Vortex Tube. Although vortex tubes have been around for a long time, different explications of their fundamental physics and operation can be found in literature and on the internet. This volume investigates the working principle based on thermodynamics and fluid dynamics. It provides full explication of these parameters in one single work along with results of new investigations not published elsewhere. In addition, the book features a wealth of illustrations on various aspects of the vortex tube that make it easy to read and understand.

This textbook presents the classical treatment of the problems of heat transfer in an exhaustive manner with due emphasis on understanding of the physics of the problems. This emphasis will be especially visible in the chapters on convective heat transfer. Emphasis is also laid on the solution of steady and unsteady two-dimensional heat conduction problems. Another special feature of the book is a chapter on introduction to design of heat exchangers and their illustrative design problems. A simple and understandable treatment of gaseous radiation has been presented. A special chapter on flat plate solar air heater has been incorporated that covers mathematical modeling of the air heater. The chapter on mass transfer has been written looking specifically at the needs of the students of mechanical engineering. The book includes a large number and variety of solved problems with supporting line diagrams. A number of application-based examples have been incorporated where applicable. The end-of-chapter exercise problems are supplemented with stepwise answers. Though the book has been primarily designed to serve as a complete textbook for undergraduate and graduate students of mechanical engineering, it will also be useful for students of chemical, aerospace, automobile, production, and industrial engineering streams. The book fully covers the topics of heat transfer coursework and can also be used as an excellent reference for students preparing for competitive graduate examinations.

This thesis presents the first experimental calibration of the top-quark Monte-Carlo mass. It also provides the top-quark mass-independent and most precise top-quark pair production cross-section measurement to date. The most precise measurements of the top-quark mass obtain the top-quark mass parameter (Monte-Carlo mass) used in simulations, which are partially based on heuristic models. Its interpretation in terms of mass parameters used in theoretical calculations, e.g. a running or a pole mass, has been a long-standing open problem with far-reaching implications beyond particle physics, even affecting conclusions on the stability of the vacuum state of our universe. In this thesis, this problem is solved experimentally in three steps using data obtained with the compact muon solenoid (CMS) detector. The most precise top-quark pair production cross-section measurements to date are performed. The Monte-Carlo mass is determined and a new method for extracting the top-quark mass from theoretical calculations is presented. Lastly, the top-quark production cross-sections are obtained - for the first time - without residual dependence on the top-quark mass, are interpreted using theoretical calculations to determine the top-quark running- and pole mass with unprecedented precision, and are fully consistently compared with the simultaneously obtained top-quark Monte-Carlo mass.

The nonequilibrium behavior of nanoscopic and biological systems, which are typically strongly fluctuating, is a major focus of current research. Lately, much progress has been made in understanding such systems from a thermodynamic perspective. However, new theoretical challenges emerge when the fluctuating system is additionally subject to time delay, e.g. due to the presence of feedback loops. This thesis advances this young and vibrant research field in several directions. The first main contribution concerns the probabilistic description of time-delayed systems; e.g. by introducing a versatile approximation scheme for nonlinear delay systems. Second, it reveals that delay can induce intriguing thermodynamic properties such as anomalous (reversed) heat flow. More generally, the thesis shows how to treat the thermodynamics of non-Markovian systems by introducing auxiliary variables. It turns out that delayed feedback is inextricably linked to nonreciprocal coupling, information flow, and to net energy input on the fluctuating level.

Density functional theory (DFT) has blossomed in the past few decades into a powerful tool that is used by experimentalists and theoreticians alike. This book highlights the extensive contributions that the DFT-based OLCAO method has made to progress in this field, and it demonstrates its competitiveness for performing ab initio calculations on large and complex models of practical systems. A brief historical account and introduction to the elements of the theory set the stage for discussions on semiconductors, insulators, crystalline metals and alloys, complex crystals, non-crystalline solids and liquids, microstructure containing systems and those containing impurities, defects, and surfaces, biomolecular systems, and the technique of ab initio core level spectroscopy calculation.

This book provides analytical and numerical methods for the estimation of dimension characteristics (Hausdorff, Fractal, Caratheodory dimensions) for attractors and invariant sets of dynamical systems and cocycles generated by smooth differential equations or maps in finite-dimensional Euclidean spaces or on manifolds. It also discusses stability investigations using estimates based on Lyapunov functions and adapted metrics. Moreover, it introduces various types of Lyapunov dimensions of dynamical systems with respect to an invariant set, based on local, global and uniform Lyapunov exponents, and derives analytical formulas for the Lyapunov dimension of the attractors of the Henon and Lorenz systems. Lastly, the book presents estimates of the topological entropy for general dynamical systems in metric spaces and estimates of the topological dimension for orbit closures of almost periodic solutions to differential equations.

A Practical Approach to Chemical Engineering for Non-Chemical Engineers is aimed at people who are dealing with chemical engineers or those who are involved in chemical processing plants. The book demystifies complicated chemical engineering concepts through daily life examples and analogies. It contains many illustrations and tables that facilitate quick and in-depth understanding of the concepts handled in the book. By studying this book, practicing engineers (non-chemical), professionals, technicians and other skilled workers will gain a deeper understanding of what chemical engineers say and ask for. The book is also useful for engineering students who plan to get into chemical engineering and want to know more on the topic and any related jargon.

This book explores the role of exaptation in diverse areas of life, with examples ranging from biology to economics, social sciences and architecture. The concept of exaptation, introduced in evolutionary biology by Gould and Vrba in 1982, describes the possibility that already existing traits can be exploited for new purposes throughout the evolutionary process. Edited by three active scholars in the fields of biology, physics and economics, the book presents an interdisciplinary collection of expert viewpoints illustrating the importance of exaptation for interpreting current reality in various fields of investigation. Using the lenses of exaptation, the contributing authors show how to view the overall macroscopic landscape as comprising many disciplines, all working in unity within a single complex system. This book is the first to discuss exaptation in both hard and soft disciplines and highlights the role of this concept in understanding the birth of innovation by identifying key elements and ideas. It also offers a comprehensive guide to the emerging interdisciplinary field of exaptation, provides didactic explanations of the basic concepts, and avoids excessive jargon and heavy formalism. Its target audience includes graduate students in physics, biology, mathematics, economics, psychology and architecture; it will also appeal to established researchers in the humanities who wish to explore or enter this new science-driven interdisciplinary field.

This book presents different thermodynamic approaches in the area of constitutive theory: thermodynamics of irreversible processes, rational thermodynamics, and extended thermodynamics. These different approaches are analyzed with respect to their presuppositions, as well as to their results, and each method is applied to several important examples. In many cases these examples are archetypes for numerous technologically important materials; i.e. complex materials having an internal structure. Some of the examples dealt with in this book are liquid crystals, colloid suspensions, ans fiber suspensions. The book well serves students and researchers who have basic knowledge in continuum mechanics and thermodynamics. It provides a systematic overview of the vast field of thermodynamic constitutive theory, beginning from a historical perspective and concluding with outstanding questions in recent research.

This book is based on the analogy between contact mechanics and fracture mechanics as proposed by the author about twenty years ago. It starts with a chapter devoted to the surface energy and tension of solids and surface thermodynamics, which is followed by a chapter on elastic recall. The methods of Muskhelichvili and Hankel transforms for the resolution of plane and axisymmetric problems are studied. Then the essential conepts of fracture mechanics are presented with emphasis on the thermodynamic aspect of the problem. The reader will find complete analytical results and detailed calculations for cracks submitted to pressure distributions and the Dugdale model, as well as a chapter on contact mechanics. The contact and adherence of rough solids is also studied. This book is intended for advanced students and researchers working in the fields of fracture mechanics or adhesion.

This book presents a selection of the talks resulting from research carried out by different groups at the Centre de Recerca Matematica and presented at the International Congress on Industrial and Applied Mathematics, held in Valencia in 2019. The various chapters describe a wide variety of topics: cancer modelling, carbon capture by adsorption, nanoscale diffusion and complex systems to predict earthquakes. These mathematical studies were specifically aided via collaborations with biomedical engineers, physicists and chemists. The book is addressed to researchers in all of these areas as well as in general mathematical modelling.

This book comprises selected papers from the International Conference on Numerical Heat Transfer and Fluid Flow (NHTFF 2018), and presents the latest developments in computational methods in heat and mass transfer. It also discusses numerical methods such as finite element, finite difference, and finite volume applied to fluid flow problems. Providing a good balance between computational methods and analytical results applied to a wide variety of problems in heat transfer, transport and fluid mechanics, the book is a valuable resource for students and researchers working in the field of heat transfer and fluid dynamics.

Existing texts on the statistical mechanics of liquids treat only spherical molecules. However, nearly all fluids of practical interest are composed of non-spherical molecules that are often dipolar or exhibit other kinds of electrostatic forces. This book describes the statistical mechanical theory of fluids of non-spherical molecules and its application to the calculation of physical properties, and is a sequel to Theory of Molecular Fluids. Volume 1: Fundamentals by C.G. Gray and K.E. Gubbins. The emphasis is on the new phenomena that arise due to the non-spherical nature of the intermolecular forces, such as new phase transitions, structural features and dielectric effects. It contains chapters on the thermodynamic properties of pure and mixed fluids, surface properties, X-ray and neutron diffraction structure factors, dielectric properties and spectroscopic properties. The book is aimed at beginning graduate students and research workers in chemistry, physics, materials science and engineering.

Analytical Mechanics for Relativity and Quantum Mechanics is an innovative and mathematically sound treatment of the foundations of analytical mechanics and the relation of classical mechanics to relativity and quantum theory. It is intended for use at the introductory graduate level. A distinguishing feature of the book is its integration of special relativity into teaching of classical mechanics. After a thorough review of the traditional theory, Part II of the book introduces extended Lagrangian and Hamiltonian methods that treat time as a transformable coordinate rather than the fixed parameter of Newtonian physics. Advanced topics such as covariant Langrangians and Hamiltonians, canonical transformations, and Hamilton-Jacobi methods are simplified by the use of this extended theory. And the definition of canonical transformation no longer excludes the Lorenz transformation of special relativity.
This is also a book for those who study analytical mechanics to prepare for a critical exploration of quantum mechanics. Comparisons to quantum mechanics appear throughout the text. The extended Hamiltonian theory with time as a coordinate is compared to Dirac's formalism of primary phase space constraints. The chapter on relativistic mechanics shows how to use covariant Hamiltonian theory to write the Klein-Gordon and Dirac equations. The chapter on Hamilton-Jacobi theory includes a discussion of the closely related Bohm hidden variable model of quantum mechanics. Classical mechanics itself is presented with an emphasis on methods, such as linear vector operators and dyadics, that will familiarize the student with similar techniques in quantum theory. Several of the current fundamental problems in theoretical physics - the development of quantum information technology, and the problem of quantizing the gravitational field, to name two - require a rethinking of the quantum-classical connection.
Graduate students preparing for research careers will find a graduate mechanics course based on this book to be an essential bridge between their undergraduate training and advanced study in analytical mechanics, relativity, and quantum mechanics.
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This book presents in a progressive way the techniques used in the proof of the hydrodynamic behavior of interacting particle systems. It starts with introductory material on independent particles and goes all the way to nongradient systems, covering the entropy and the relative entropy methods, asymmetric processes from which hyperbolic equations emerge, the equilibrium fluctuations and the large deviations theory for short-range stochastic dynamics. It reviews, in appendices, some tools of Markov process theory and derives estimates on the spectral gap of reversible, conservative generators. The book is self-contained and can be read by graduate students in mathematics or mathematical physics with standard probability background. It can be used as a support for a graduate on stochastic processes.

This wide-ranging book introduces information as a key concept not only in physics, from quantum mechanics to thermodynamics, but also in the neighboring sciences and in the humanities. The central part analyzes dynamical processes as manifestations of information flows between microscopic and macroscopic scales and between systems and their environment. Quantum mechanics is interpreted as a reconstruction of mechanics based on fundamental limitations of information processing on the smallest scales. These become particularly manifest in quantum chaos and in quantum computing. Covering subjects such as causality, prediction, undecidability, chaos, and quantum randomness, the book also provides an information-theoretical view of predictability. More than 180 illustrations visualize the concepts and arguments. The book takes inspiration from the author's graduate-level topical lecture but is also well suited for undergraduate studies and is a valuable resource for researchers and professionals.

This book presents the results of scientific research performed over the past two decades by the authors. The book discusses some issues of separated laminar flows that are of great practical interest for the development of new technologies using microchannel flows, where separation zones can form. Of particular interest is the complex mechanism of flow separation with superimposed high external turbulence. The challenges of finding the optimal location for the cavities and fins on heat exchange surfaces are also considered. This is an important fundamental and practical problem when creating new schemes of efficient heat exchangers in various power plants. A wide class of problems of turbulent flow in tubes with flow separation is considered. These data will be useful in engineering estimates of the thermal-hydraulic efficiency of various heat transfer intensifiers. This book focuses on the analysis of thermal characteristics of separated flows, as well as the possibility of controlling the intensity of heat exchange processes, from the point of view of both their intensification and their suppression.

The pendulum is a unique physical system which exhibits remarkably varied and complex behavior under many different conditions. It is also a system which, in its many manifestations, has left a significant imprint on human thought and culture. Using graphs, figures, and narrative to explain scientific ideas and models, Gregory Baker gives a lucid account of the physics of the pendulum, showing the reader how the context of the pendulum progresses over four centuries from that of a simple system of classical physics, to that of a chaotic system, and eventually to that of a modern quantum system. He also describes its fascinating presence in cultural history, from its role in timekeeping and measurements of the earth to its importance as a literary symbol of doom.
Seven 'tales', detailing different important facets of the pendulum, show the exciting diversity of the science of the pendulum, and its untold significance in the history of human intellectual development.

This book is intended as reference material for students and professors interested in air pollution modeling at the graduate level as well as researchers and professionals involved in developing and utilizing air pollution models. Current developments in air pollution modeling are explored as a series of contributions from researchers at the forefront of their field. This newest contribution on air pollution modeling and its application is focused on local, urban, regional and intercontinental modeling; emission modeling and processing; data assimilation and air quality forecasting; model assessment and evaluation; aerosol transformation. Additionally, this work also examines the relationship between air quality and human health and the effects of climate change on air quality. This work is a collection of selected papers presented at the 37th International Technical Meeting on Air Pollution Modeling and its Application, held in Hamburg, Germany, September 23-27, 2019.

Quantum information theory is a branch of science at the frontier of physics, mathematics, and information science, and offers a variety of solutions that are impossible using classical theory. This book provides a detailed introduction to the key concepts used in processing quantum information and reveals that quantum mechanics is a generalisation of classical probability theory. The second edition contains new sections and entirely new chapters: the hot topic of multipartite entanglement; in-depth discussion of the discrete structures in finite dimensional Hilbert space, including unitary operator bases, mutually unbiased bases, symmetric informationally complete generalized measurements, discrete Wigner function, and unitary designs; the Gleason and Kochen-Specker theorems; the proof of the Lieb conjecture; the measure concentration phenomenon; and the Hastings' non-additivity theorem. This richly-illustrated book will be useful to a broad audience of graduates and researchers interested in quantum information theory. Exercises follow each chapter, with hints and answers supplied.