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Anomalous Relaxation in Colloidal Systems (Hardcover, 1st ed. 2022)
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Anomalous Relaxation in Colloidal Systems (Hardcover, 1st ed. 2022)
Series: Springer Theses
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The thesis presents a systematic study of the Mpemba effect in a
colloidal system with a micron-sized particle diffusing in a water
bath. While the Mpemba effect, where a system's thermal relaxation
time is a non-monotonic function of the initial temperature, has
been observed in water since Aristotle's era, the underlying
mechanism of the effect is still unknown. Recent studies indicate
that the effect is not limited to water and has been studied both
experimentally and numerically in a wide variety of systems. By
carefully designing a double-well potential using feedback-based
optical tweezers, the author demonstrates that an initially hot
system can sometimes cool faster than an initially warm system. The
author also presents the first observation in any system of another
counterintuitive effect-the inverse Mpemba effect-where the colder
of the two samples reaches the thermal equilibrium at a hot
temperature first. The results for both the observations agree with
theoretical predictions based on the Fokker-Planck equation. The
experiments reveal that, for carefully chosen conditions, a strong
version of both of the effects are observed where a system can
relax to the bath temperature exponentially faster than under
typical conditions.
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