Small systems are a very active area of research and development due to improved instrumentation that allows for spatial resolution in the range of sizes from one to 100 nm. In this size range, many physical and chemical properties change, which opens up new approaches to the study of substances and their practical application. This affects both traditional fields of knowledge and many other new fields including physics, chemistry, biology, etc. This book highlights new developments in statistical thermodynamics that answer the most important questions about the specifics of small systems - when one cannot apply equations or traditional thermodynamic models.

Fractal and Trans-scale Nature of Entropy: Towards a Geometrization of Thermodynamics develops a new vision for entropy in thermodynamics by proposing a new method to geometrize. It investigates how this approach can accommodate a large number of very different physical systems, going from combustion and turbulence towards cosmology. As an example, a simple interpretation of the Hawking entropy in black-hole physics is provided. In the life sciences, entropy appears as the driving element for the organization of systems. This book demonstrates this fact using simple pedagogical tools, thus showing that entropy cannot be interpreted as a basic measure of disorder.

A thorough exploration of the atomic structures and properties of the essential engineering interfaces—an invaluable resource for students, teachers, and professionals

The most up-to-date, accessible guide to solid-vapor, solid-liquid, and solid-solid phase transformations, this innovative book contains the only unified treatment of these three central engineering interfaces. Employing a simple nearest-neighbor broken-bond model, Interfaces in Materials focuses on metal alloys in a straightforward approach that can be easily extended to all types of interfaces and materials. Enhanced with nearly 300 illustrations, along with extensive references and suggestions for further reading, this book provides:

• A simple, cohesive approach to understanding the atomic structure and properties of interfaces formed between solid, liquid, and vapor phases
• Self-contained discussions of each interface—allowing separate study of each phase transformation
• A comparative look at the different interfaces, including atomic structure and crystallography; anisotropy, roughening, and melting; interfacial stability and segregation; continuous and ledge growth models; and atomistic modeling
• An analysis of nearest-neighbor broken-bond results against thermodynamic and kinetic descriptions of the interfaces
• Problem sets at the end of each chapter, emphasizing the key concepts detailed in the text

Spanning the fields of chemical, electrical and computer engineering, materials science, solid-state physics, and microscopy, Interfaces in Materials bridges a major gap in the literature of surface and interface science.

Physics on Your Feet (2nd Edition) is a significantly expanded collection of physics problems covering the broad range of topics in classical and modern physics that were, or could have been, asked at oral PhD exams at University of California at Berkeley. The questions are easy to formulate, but some of them can only be answered using an outside-of-the box approach. Detailed solutions are provided, from which the reader is guaranteed to learn a lot about the physicists' way of thinking. The book is also packed full of cartoons and dry humor to help take the edge off the stress and anxiety surrounding exams. This is a helpful guide for students preparing for their exams, as well as a resource for university lecturers looking for good instructive problems. No exams are necessary to enjoy the book!

This book is suitable to be used as a text in introducing graduate courses or advanced undergraduate courses on the equilibrium statistical mechanics of bulk phases, interfaces, thin films and associations colloids. Emphasis is placed on exactly solvable models or physically motivated approximate theories that offer revealing insights into the molecular origins of the behaviour of materials in equilibrium. Also emphasized are theoretically motivated semiempirical models that can be used in quantitative predictions of phase and interfacial behavior. The book is unique in its unified approach to the theory of phases and their interfaces and on the density functional theory that unification is based on.

* Physical chemists will find this book comprehensive. Topical reviews on all aspects of colloidal ordering and related phase transitions will be covered. It provides a good blend of experimental and theoretical investigations.
* Useful to materials scientists and chemical engineers, the book includes a discussion of stability, important from the point of view of applications of colloidal crystals.
* Physicists will be interested in the book, because it highlights the controversy over effective interparticle interaction in charged colloids.

Low Grade Heat Driven Multi-effect Distillation and Desalination describes the development of advanced multi-effect evaporation technologies that are driven by low grade sensible heat, including process waste heat in refineries, heat rejection from diesel generators or microturbines, and solar and geothermal energy. The technologies discussed can be applied to desalination in remote areas, purifying produced water in oil-and-gas industries, and to re-concentrate process liquor in refineries. This book is ideal for researchers, engineering scientists, graduate students, and industrial practitioners working in the desalination, petrochemical, and mineral refining sectors, helping them further understand the technologies and opportunities that relate to their respective industries. For researchers and graduate students, the core enabling ideas in the book will provide insights and open up new horizons in thermal engineering.

Clearly divided into three parts, this practical book begins by dealing with all fundamental aspects of calorimetry. The second part looks at the equipment used and new developments. The third and final section provides measurement guidelines in order to obtain the best results.
The result is optimized knowledge for users of this technique, supplemented with practical tips and tricks.

Prof. Newman is considered one of the great chemical engineers of his time. His reputation derives from his mastery of all phases of the subject matter, his clarity of thought, and his ability to reduce complex problems to their essential core elements. He has been teaching undergraduate and graduate core subject courses at the University of California, Berkeley (UC Berkeley), USA, since joining the faculty in 1966. His method is to write out, in long form, everything he expects to convey to his class on a subject on any given day. He has maintained and updated his lecture notes from notepad to computer throughout his career. This book is an exact reproduction of those notes. The book presents concepts needed to define single- and multi-component systems, starting with the Gibbs function. It helps readers derive concepts of entropy and temperature and the development of material properties of pure substances. It acquaints them with applications of thermodynamics, such as cycles, open systems, and phase transitions, and eventually leads them to concepts of multiple-component systems, in particular, chemical and phase equilibria. It clearly presents all concepts that are necessary for engineers.

This textbook provides an exposition of equilibrium thermodynamics and its applications to several areas of physics with particular attention to phase transitions and critical phenomena. The applications include several areas of condensed matter physics and include also a chapter on thermochemistry. Phase transitions and critical phenomena are treated according to the modern development of the field, based on the ideas of universality and on the Widom scaling theory. For each topic, a mean-field or Landau theory is presented to describe qualitatively the phase transitions. These theories include the van der Waals theory of the liquid-vapor transition, the Hildebrand-Heitler theory of regular mixtures, the Griffiths-Landau theory for multicritical points in multicomponent systems, the Bragg-Williams theory of order-disorder in alloys, the Weiss theory of ferromagnetism, the Neel theory of antiferromagnetism, the Devonshire theory for ferroelectrics and Landau-de Gennes theory of liquid crystals. This textbook is intended for students in physics and chemistry and provides a unique combination of thorough theoretical explanation and presentation of applications in both areas. Chapter summaries, highlighted essentials and problems with solutions enable a self sustained approach and deepen the knowledge.

Entropy - the key concept of thermodynamics, clearly explained and carefully illustrated. This book presents an accurate definition of entropy in classical thermodynamics which does not "put the cart before the horse" and is suitable for basic and advanced university courses in thermodynamics. Entropy is the most important and at the same time the most difficult term of thermodynamics to understand. Many students are discontent with its classical definition since it is either based on "temperature" and "heat" which both cannot be accurately defined without entropy, or since it includes concepts such as "molecular disorder" which does not fit in a macroscopic theory. The physicists Elliott Lieb and Jakob Yngvason have recently developed a new formulation of thermodynamics which is free of these problems. The Lieb-Yngvason formulation of classical thermodynamics is based on the concept of adiabatic accessibility and culminates in the entropy principle. The entropy principle represents the accurate mathematical formulation of the second law of thermodynamics. Temperature becomes a derived quantity whereas "heat" is no longer needed. This book makes the Lieb-Yngvason theory accessible to students. The presentation is supplemented by seven illustrative examples which explain the application of entropy and the entropy principle in practical problems in science and engineering.

This book is useful to engineers, researchers, entrepreneurs, and students in different branches of production, engineering, and systems sciences. The polytopic roadmaps are the guidelines inspired by the development stages of cognitive-intelligent systems, and expected to become powerful instruments releasing an abundance of new capabilities and structures for complex engineering systems implementation. The 4D approach developed in previous monographs and correlated with industry 4.0and Fourth Industrial Revolution is continued here toward higher dimensions approaches correlated with polytopic operations, equipment, technologies, industries, and societies. Methodology emphasizes the role of doubling, iteration, dimensionality, and cyclicality around the center, of periodic tables and of conservative and exploratory strategies. Partitions, permutations, classifications, and complexification, as polytopic chemistry, are the elementary operations analyzed. Multi-scale transfer, cyclic operations, conveyors, and assembly lines are the practical examples of operations and equipment. Polytopic flow sheets, online analytical processing, polytopic engineering designs, and reality-inspired engineering are presented. Innovative concepts such as Industry 5.0, polytopic industry, Society 5.0, polytopic society, cyber physical social systems, industrial Internet, and digital twins have been discussed. The general polytopic roadmaps, (GPTR), are proposed as universal guidelines and as common methodologies to synthesize the systemic thinking and capabilities for growing complexity projects implementation.

This is the first unified treatment of the properties of thermodynamically open and closed systems. It provides the theory and methodology that are necessary to understand nonlinear processes. The section on Classical Systems covers topics ranging from the evolution of probability to open and closed systems and non-Hamiltonian systems. The concluding section on Quantum Systems is equally detailed, treating the evolution of quantum systems, c-number fluctuations and operator fluctuations.
The material covered is applicable to weather systems, ocean currents, dye lasers and many other nonequilibrium systems. The text is also suitable for students in graduate course. Numerous physical chemical examples facilitate self-study.

Advances in Heat Transfer fills the information gap between regularly scheduled journals and university-level textbooks by providing in-depth review articles over a broader scope than in journals or texts. The articles, which serve as a broad review for experts in the field, will also be of great interest to non-specialists who need to keep up-to-date with the results of the latest research. This serial is essential reading for all mechanical, chemical and industrial engineers working in the field of heat transfer, graduate schools or industry.

Current Topics in Membranes is targeted toward scientists and researchers in biochemistry and molecular and cellular biology, providing the necessary membrane research to assist them in discovering the current state of a particular field and in learning where that field is heading. This volume presents an up to date presentation of current knowledge and problems in the field of thermal receptors. This is a rapidly evolving research area and the book contains important contributions from some of the leaders in the field.

This book highlights the practical aspects of computer modelling and simulation of complex dynamical systems for students. Mechanical systems are considered in the book as representative examples of dynamical systems. Wolfram SystemModeler, in combination with Learning Management System Sakai, is used as an instrument for studying features of various physical and technical phenomena and processes. Each of the presented virtual labs may be considered a stand-alone mini project to enable students to go through all the steps of mathematical modelling and computer simulation-from the problem statement to mathematical and physical analysis of the obtained result. The book is useful for teachers to organize the educational process, allowing gradual monitoring of the learning process and assessment of students' competencies. It also allows tutors to design individual educational trajectories for students to achieve educational properties. The subject of the book is an extension of activity started by the international team of authors within the InMotion project of the European programme ERASMUS+.

This is the first book of a series aiming at setting the basics for energy engineering. This book presents the fundamentals of heat and mass transfer with a step-by-step approach, based on material and energy balances. While the topic of heat and mass transfer is an old subject, the way the book introduces the concepts, linking them strongly to the real world and to the present concerns, is particular. The scope of the different developments keeps in mind a practical energy engineering view.

Whether in a solar thermal power plant or at the heart of a nuclear reactor, convection is an important mode of energy transfer. This mode is unique; it obeys specific rules and correlations that constitute one of the bases of equipment-sizing equations. In addition to standard aspects of convention, this book examines transfers at very high temperatures where, in order to ensure the efficient transfer of energy for industrial applications, it is becoming necessary to use particular heat carriers, such as molten salts, liquid metals or nanofluids. With modern technologies, these situations are becoming more frequent, requiring appropriate consideration in design calculations. Energy Transfers by Convection also studies the sizing of electronic heat sinks used to ensure the dissipation of heat and thus the optimal operation of circuit boards used in telecommunications, audio equipment, avionics and computers.

Modern thermodynamics is a unique but still not a logically self-consistent field of knowledge. It has a proven universal applicability and significance but its actual potential is still latent. The development of the foundations of thermodynamics was in effect non-stop but absolutely no one has any idea about this. This book is the first of its kind that will motivate researchers to build up a logically consistent field of thermodynamics. It greatly appreciates the actual depth and potential of thermodynamics which might also be of interest to readers in history and philosophy of scientific research. The book presents the life stories of the protagonists in detail and allows readers to cast a look at the whole scene of the field by showcasing a significant number of their colleagues whose works have fittingly complemented their achievements. It also tries to trigger a detailed analysis of the reasons why the actual work in this extremely important field has in effect gone astray. It comprises five chapters and introduces three scientists in the first two chapters, which are specifically devoted to the Scandinavian achievements in macroscopic thermodynamics. These introductions are novel and call for a detailed reconsideration of the field. The third chapter acquaints the readers with their fourth colleague in Germany who was working on the proper link between the macroscopic thermodynamics, kinetics, and the atomistic representation of matter. The fourth chapter brings in their fifth colleague in the United States who could formally infer the famous formula S = k * ln(W), ingeniously guessed by Ludwig Boltzmann, and thus clarify the physical sense of the entropy notion. The last chapter summarizes the above-mentioned discourses.

This textbook concerns thermal properties of bulk matter and is aimed at advanced undergraduate or first-year graduate students in a range of programs in science or engineering. It provides an intermediate level presentation of statistical thermodynamics for students in the physical sciences (chemistry, nanosciences, physics) or related areas of applied science/engineering (chemical engineering, materials science, nanotechnology engineering), as they are areas in which statistical mechanical concepts play important roles. The book enables students to utilize microscopic concepts to achieve a better understanding of macroscopic phenomena and to be able to apply these concepts to the types of sub-macroscopic systems encountered in areas of nanoscience and nanotechnology.

Written to introduce readers to molecular descriptions of thermodynamics, chemical systems, and biomolecules, Statistical Thermodynamics discusses the aspects of statistical thermodynamics of most use and interest to chemistry students. Topics include: probability; energy and interactions; statistical mechanics; harmonic oscillators; ideal gas; imperfect gas; heat capacities of gas; rubber elasticity; conformation of polymers; surface adsorption; law of mass action; Ising model; and more. Rich with illustrations and tables to illuminate rather difficult concepts, the text equips students with the ability to apply the method to their own systems.

Thermal physics deals with collections of large numbers of particles - typically 10 to the 23rd power or so. Examples include the air in a balloon, the water in a lake, the electrons in a chunk of metal, and the photons given off by the sun. We can't possibly follow every detail of the motions of so many particles. So in thermal physics we assume that these motions are random, and we use the laws of probability to predict how the material as a whole ought to behave. Alternatively, we can measure the bulk properties of a material, and from these infer something about the particles it is made of. This book will give you a working understanding of thermal physics, assuming that you have already studied introductory physics and calculus. You will learn to apply the general laws of energy and entropy to engines, refrigerators, chemical reactions, phase transformations, and mixtures. You will also learn to use basic quantum physics and powerful statistical methods to predict in detail how temperature affects molecular speeds, vibrations of solids, electrical and magnetic behaviors, emission of light, and exotic low-temperature phenomena. The problems and worked examples explore applications not just within physics but also to engineering, chemistry, biology, geology, atmospheric science, astrophysics, cosmology, and everyday life.

"Introductory Statistical Thermodynamics" is a text for an introductory one-semester course in statistical thermodynamics for upper-level undergraduate and graduate students in physics and engineering. The book offers a high level of detail in derivations of all equations and results. This information is necessary for students to grasp difficult concepts in physics that are needed to move on to higher level courses. The text is elementary, self contained, and mathematically well-founded, containing a number of problems with detailed solutions to help students to grasp the more difficult theoretical concepts.

Beginning chapters place an emphasis on quantum mechanics
Includes problems with detailed solutions and a number of detailed theoretical derivations at the end of each chapter
Provides a high level of detail in derivations of all equations and results

The accurate measurement of temperature is a vital parameter in many fields of engineering and scientific practice. Responding to emerging trends, this classic reference has been fully revised to include coverage of the latest instrumentation and measurement methods.

Featuring:

• Brand new chapters on computerised temperature measuring systems and temperature measurement in medicine.

• Sections on noise thermometers, the development of photoelectric and two-wave pyrometers and the latest IEC (International Electrotechnical Commission) standards

• Coverage of fibre optic thermometers, imaging of temperature fields and measurement in hazardous areas.

• Examination of virtual instruments, fuzzy logic in temperature measurement and new methods for thermometer calibration.

Practising instrument engineers, graduate students and researchers in the fields of mechanical, electrical and electronic engineering will welcome this balanced approach to both the theory and practice of temperature measurement.

The use of thermodynamics in biological research can be equated to an energy book-keeping system. While the structure and function of a molecule is important, it is equally important to know what drives the energy force. These methods look to answer: What are the sources of energy that drive the function? Which of the pathways are of biological significance? As the base of macromolecular structures continues to expand through powerful techniques of molecular biology, such as X-ray crystal data and spectroscopy methods, the importance of tested and reliable methods for answering these questions will continue to expand as well. This volume presents sophisticated methods for estimating the thermodynamic parameters of specific protein-protein, protein-DNA and small molecule interactions.

* Elucidates the relationships between structure and energetics and their applications to molecular design, aiding researchers in the design of medically important molecules * Provides a "must-have" methods volume that keeps MIE buyers and online subscribers up-to-date with the latest research * Offers step-by-step lab instructions, including necessary equipment, from a global research community