Written to introduce readers to molecular descriptions of thermodynamics, chemical systems, and biomolecules, Statistical Thermodynamics discusses the aspects of statistical thermodynamics of most use and interest to chemistry students. Topics include: probability; energy and interactions; statistical mechanics; harmonic oscillators; ideal gas; imperfect gas; heat capacities of gas; rubber elasticity; conformation of polymers; surface adsorption; law of mass action; Ising model; and more. Rich with illustrations and tables to illuminate rather difficult concepts, the text equips students with the ability to apply the method to their own systems.

Written by distinguished physics educator David Goodstein, this fresh introduction to thermodynamics, statistical mechanics, and the study of matter is ideal for undergraduate courses. The textbook looks at the behavior of thermodynamic variables and examines partial derivatives - the essential language of thermodynamics. It also explores states of matter and the phase transitions between them, the ideal gas equation, and the behavior of the atmosphere. The origin and meaning of the laws of thermodynamics are then discussed, together with Carnot engines and refrigerators, and the notion of reversibility. Later chapters cover the partition function, the density of states, and energy functions, as well as more advanced topics such as the interactions between particles and equations for the states of gases of varying densities. Favoring intuitive and qualitative descriptions over exhaustive mathematical derivations, the textbook uses numerous problems and worked examples to help readers get to grips with the subject.

This book provides a simple and well-structured course followed by an innovative collection of exercises and solutions that will enrich a wide range of courses as part of the undergraduate physics curriculum. It will also be useful for first-year graduate students who are preparing for their qualifying exams. The book is divided into four main themes at the boundary of classical and modern physics: atomic physics, matter-radiation interaction, blackbody radiation, and thermodynamics. Each chapter starts with a thorough and well-illustrated review of the core material, followed by plenty of original exercises that progress in difficulty, replete with clear, step-by-step solutions. This book will be invaluable for undergraduate course instructors who are looking for a source of original exercises to enhance their classes, while students that want to hone their skills will encounter challenging and stimulating problems.

Provides unified coverage of computational heat transfer and fluid dynamics. Covers basic concepts and then applies computational methods for problem analysis and solution. Contains new chapters on mesh generation and computer modeling of turbulent flow. Includes ANSYS, STAR CCM+, and COMSOL CFD code and tutorials in the appendix. Includes a Solutions Manual for instructor use.

This graduate textbook describes atomic-level kinetics (mechanisms and rates) of thermal energy storage, transport (conduction, convection, and radiation), and transformation (various energy conversions) by principal energy carriers. The approach combines the fundamentals of molecular orbitals-potentials, statistical thermodynamics, computational molecular dynamics, quantum energy states, transport theories, solid-state and fluid-state physics, and quantum optics. The textbook presents a unified theory, over fine-structure/molecular-dynamics/Boltzmann/macroscopic length and time scales, of heat transfer kinetics in terms of transition rates and relaxation times, and its modern applications, including nano- and microscale size effects. Numerous examples, illustrations, and homework problems with answers that enhance learning are included. This new edition includes applications in energy conversion (including chemical bond, nuclear, and solar), expanded examples of size effects, inclusion of junction quantum transport, and discussion of graphene and its phonon and electronic conductances. New appendix coverage of Phonon Contributions Seebeck Coefficient and Monte Carlo Methods are also included.

This introductory textbook for standard undergraduate courses in thermodynamics has been completely rewritten to explore a greater number of topics, more clearly and concisely. Starting with an overview of important quantum behaviours, the book teaches students how to calculate probabilities in order to provide a firm foundation for later chapters. It introduces the ideas of classical thermodynamics and explores them both in general and as they are applied to specific processes and interactions. The remainder of the book deals with statistical mechanics. Each topic ends with a boxed summary of ideas and results, and every chapter contains numerous homework problems, covering a broad range of difficulties. Answers are given to odd-numbered problems, and solutions to even-numbered problems are available to instructors at www.cambridge.org/9781107694927.

This is the first biography of Julian Schwinger, one of the great theoretical physicists of the twentieth century. A long-time colleague and collaborator of Richard Feynman, he was the joint winner with Feynman of the 1965 Nobel Prize for Physics for their work on quantum electrodynamics. However his contribution extended far beyond this, and his life and achievements are chronicled in this book.

Striving to explore the subject in as simple a manner as possible, this book helps readers understand the elusive concept of entropy. Innovative aspects of the book include the construction of statistical entropy from desired properties, the derivation of the entropy of classical systems from purely classical assumptions, and a statistical thermodynamics approach to the ideal Fermi and ideal Bose gases. Derivations are worked through step-by-step and important applications are highlighted in over 20 worked examples. Around 50 end-of-chapter exercises test readers' understanding. The book also features a glossary giving definitions for all essential terms, a time line showing important developments, and list of books for further study. It is an ideal supplement to undergraduate courses in physics, engineering, chemistry and mathematics.

At the heart of many fields - physics, chemistry, engineering - lies thermodynamics. While this science plays a critical role in determining the boundary between what is and is not possible in the natural world, it occurs to many as an indecipherable black box, thus making the subject a challenge to learn. Two obstacles contribute to this situation, the first being the disconnect between the fundamental theories and the underlying physics and the second being the confusing concepts and terminologies involved with the theories. While one needn't confront either of these two obstacles to successfully use thermodynamics to solve real problems, overcoming both provides access to a greater intuitive sense of the problems and more confidence, more strength, and more creativity in solving them. This book offers an original perspective on thermodynamic science and history based on the three approaches of a practicing engineer, academician, and historian. The book synthesises and gathers into one accessible volume a strategic range of foundational topics involving the atomic theory, energy, entropy, and the laws of thermodynamics.

This book presents the derivation of the fluctuation theorems with divergent entropy production and their application to fundamental problems in statistical physics. It explores the two basic aspects of the fluctuation theorems: i) Applicability in extreme situations with divergent entropy production, concluding that the fluctuation theorems remain valid under the notion of absolute irreversibility, and ii) utility in the investigation of classical enigmas in the framework of statistical physics, i.e., Gibbs and Loschmidt paradoxes. The book offers readers an overview of the research in fundamental statistical physics. Firstly it briefly but skillfully reviews the modern development of fluctuation theorems to found the key theme of the book. Secondly it concisely discusses historical issues of statistical physics in chronological order, along with the key literature in the field. They help readers easily follow the key developments in the fundamental research of statistical physics.

This book represents a journey through the history of science in regards to the concept of time, specifically, the question as to whether it is absolute, relative, or irreversible. The best-known contribution, or at least the most popular one, came from Einstein. He took the illusion that time was universal, a concept dating back, essentially, to Galileo and Newton, and shattered it, both within and without the scientific community. Thermodynamics teaches us that time has a preferential direction, i.e., forward, and is irreversible, as shown by Prigogine and his theories on dissipative structures and complex systems. Time is not only an "external spectator" to what happens, but assiduously takes part in making it happen. The concept of thermodynamics shows us how time is linked with environmental issues, as creator and destroyer. The author explores the relationships of cause and effect and how it can help in measuring the various eras of the planet, as well as understanding the beings that inhabit it. This book will be a valuable read for students, researchers, and interested laypersons alike.

This is the first biography of Julian Schwinger, one of the great theoretical physicists of the twentieth century. A long-time colleague and collaborator of Richard Feynman, he was the joint winner with Feynman of the 1965 Nobel Prize for Physics for their work on quantum electrodynamics. However his contribution extended far beyond this, and his life and achievements are chronicled in this book.

This book looks at global atmospheric processes from a physical standpoint using available current and past observational data taken from measurements of relevant atmospheric parameters. It describes various aspects of the current atmospheric state and its future evolution, focusing primarily on the energetic balance of the Earth and atmosphere, and taking into consideration the multi-faceted global equilibrium between these two systems, carbon, and water. The analysis presented in this book restricts itself to those objects and processes that allow us to obtain reliable conclusions and numerical estimations, in contrast to current climate models with much larger numbers of parameters for describing the same problems. As a result, in spite of the roughness of numerical parameters, the book unveils a reliable and transparent physical picture of energetic phenomena in the global atmosphere. In particular, it shows that approximately only one-fourth of atmospheric water returns from the atmosphere to the Earth in the form of free molecules. It was shown that the contemporary warming of our planet has an anthropogenic character, and that the average global temperature increases due to an increase of the concentration of atmospheric CO2 molecules, via an increase in atmospheric moisture, as well as an increase in the amount of aerosols in the atmosphere. Accumulation of atmospheric carbon dioxide plays a subsidiary role in this process and gives approximately one-third in a change of the global temperature, while an increase in the amount of atmospheric water by as little as only 0.3% per year explains the observed warming of the Earth. The book shows how the greenhouse instability of the atmosphere evidently has its origins in the Eocene epoch, presenting an analysis of the influence of various types of global energetic processes on the climate that differs from the official stance on these problems.

This essential provides an overview of the changes in our climate, their causes and their consequences. Today, humanity's energy needs are largely met in ways that are harmful to the climate. The alternative to this, solar energy, would satisfy our needs thousands of times over. But this option is far too little used for mainly economic reasons. This essential then discusses the energy converters that can be used to make solar energy available. Some other modern energy sources, such as nuclear power, are either inadequate, still utopian, or otherwise environmentally harmful. An outlook shows that our energy problem could easily be solved with economic reason by global use of solar energy. The climate could thus still be stabilized in time. This book is a translation of the original German 1st edition Unser Klima und das Energieproblem by Klaus Stierstadt, published by Springer Fachmedien Wiesbaden GmbH, part of Springer Nature in 2020. The translation was done with the help of artificial intelligence (machine translation by the service DeepL.com). A subsequent human revision was done primarily in terms of content, so that the book will read stylistically differently from a conventional translation. Springer Nature works continuously to further the development of tools for the production of books and on the related technologies to support the authors.

Best known for his theory of electromagnetism, James Clerk Maxwell (1831 79) was Cambridge University's first Cavendish Professor of Experimental Physics. Albert Einstein described his work as 'the most profound and the most fruitful that physics has experienced since the time of Newton'. He carried out brilliant work in thermodynamics and statistical mechanics, laying the foundation for the kinetic theory of gases. This book, published originally in 1871, summarises his work in this field. It includes the 'Maxwell relations' that still feature in every standard text on thermodynamics. It also outlines his famous thought experiment, later named Maxwell's 'demon'. This idea, which appeared to contradict the second law of thermodynamics, would inspire scientific debate well into the twentieth century. More recently, it has sparked developments in the new sciences of nanotechnology and quantum computing.

This textbook facilitates students' ability to apply fundamental principles and concepts in classical thermodynamics to solve challenging problems relevant to industry and everyday life. It also introduces the reader to the fundamentals of statistical mechanics, including understanding how the microscopic properties of atoms and molecules, and their associated intermolecular interactions, can be accounted for to calculate various average properties of macroscopic systems. The author emphasizes application of the fundamental principles outlined above to the calculation of a variety of thermodynamic properties, to the estimation of conversion efficiencies for work production by heat interactions, and to the solution of practical thermodynamic problems related to the behavior of non-ideal pure fluids and fluid mixtures, including phase equilibria and chemical reaction equilibria. The book contains detailed solutions to many challenging sample problems in classical thermodynamics and statistical mechanics that will help the reader crystallize the material taught. Class-tested and perfected over 30 years of use by nine-time Best Teaching Award recipient Professor Daniel Blankschtein of the Department of Chemical Engineering at MIT, the book is ideal for students of Chemical and Mechanical Engineering, Chemistry, and Materials Science, who will benefit greatly from in-depth discussions and pedagogical explanations of key concepts. Distills critical concepts, methods, and applications from leading full-length textbooks, along with the author's own deep understanding of the material taught, into a concise yet rigorous graduate and advanced undergraduate text; Enriches the standard curriculum with succinct, problem-based learning strategies derived from the content of 50 lectures given over the years in the Department of Chemical Engineering at MIT; Reinforces concepts covered with detailed solutions to illuminating and challenging homework problems.

This is a textbook on thermodynamics of materials for junior/senior undergraduate students and first-year graduate students as well as a reference book for researchers who would like to refresh their understanding of thermodynamics. The textbook employs a plain language to explain the thermodynamic concepts and quantities. It embraces the mathematical beauty and rigor of Gibbs thermodynamics through the fundamental equation of thermodynamics from which all thermodynamic properties of a material can be derived. However, a reader with basic first-year undergraduate calculus skills will be able to get through the book without difficulty. One unique feature of this textbook is the descriptions of the step-by-step procedures for computing all the thermodynamic properties from the fundamental equation of thermodynamics and all the thermodynamic energies from a set of common, experimentally measurable thermodynamic properties, supplemented with ample numerical examples. Another unique feature of this textbook is its emphasis on the concept of chemical potential and its applications to phase equilibria in single component systems and binary solutions, chemical reaction equilibria, and lattice and electronic defects in crystals. The concept of chemical potential is introduced at the very beginning of the book together with temperature and pressure. It avoids or minimizes the use of terms such as molar Gibbs free energy, partial molar Gibbs free energy, or Gibbs potential because molar Gibbs free energy or partial molar Gibbs free energy is precisely the chemical potential of a material or a component. It is the chemical potential that determines the stability of chemical species, compounds, and phases and their tendency to chemically react to form new species, transform to new physical state, and migrate from one spatial location to another. Therefore, it is the chemical potential differences or gradients that drive essentially all materials processes of interest. A reader after finishing reading the book is expected to not only achieve a high-level fundamental understanding of thermodynamics but also acquire the analytical skills of applying thermodynamics to determining materials equilibrium and driving forces for materials processes.

This book introduces the concepts of physical chemistry of polymers in a format targeted for a blended-learning approach. It provides a basis to bridge polymer chemistry, which targets microscopic chain structures, and polymer engineering, which targets macroscopic material properties and functions. Topics covered are single chain statistics, multi-chain interactions, and chain dynamics, both from a viewpoint of structure, properties (mostly mechanical ones), and their interrelation. In all that, the author encourages the reader to think conceptually. Explains complex facts through simplifying models, diagrams, and illustrations Accessible to chemists, chemical engineers, materials scientists, and physicists Tailored content for an interactive blended-learning format

This thesis establishes a multifaceted extension of the deterministic control framework that has been a workhorse of nonequilibrium statistical mechanics, to stochastic, discrete, and autonomous control mechanisms. This facilitates the application of ideas from stochastic thermodynamics to the understanding of molecular machines in nanotechnology and in living things. It also gives a scale on which to evaluate the nonequilibrium energetic efficiency of molecular machines, guidelines for designing effective synthetic machines, and a perspective on the engineering principles that govern efficient microscopic energy transduction far from equilibrium. The thesis also documents the author's design, analysis, and interpretation of the first experimental demonstration of the utility of this generally applicable method for designing energetically-efficient control in biomolecules. Protocols designed using this framework systematically reduced dissipation, when compared to naive protocols, in DNA hairpins across a wide range of experimental unfolding speeds and between sequences with wildly different physical characteristics.

Survival of the fittest" is a tautology, because those that are "fit" are the ones that survive, but to survive, a species must be "fit". Modern evolutionary theory avoids the problem by defining fitness as reproductive success, but the complexity of life that we see today could not have evolved based on selection that favors only reproductive ability. There is nothing inherent in reproductive success alone that could result in higher forms of life. Evolution from a Thermodynamic Perspective presents a non-circular definition of fitness and a thermodynamic definition of evolution. Fitness means maximization of power output, necessary to survive in a competitive world. Evolution is the "storage of entropy". "Entropy storage" means that solar energy, instead of dissipating as heat in the Earth, is stored in the structure of living organisms and ecosystems. Part one explains this in terms comprehensible to a scientific audience beyond biophysicists and ecosystem modelers. Part two applies thermodynamic theory in non-esoteric language to sustainability of agriculture, and to conservation of endangered species. While natural systems are stabilized by feedback, agricultural systems remain in a mode of perpetual growth, pressured by balance of trade and by a swelling population. The constraints imposed by thermodynamic laws are being increasingly felt as economic expansion destabilizes resource systems on which expansion depends.

This open access book introduces and explains machine learning (ML) algorithms and techniques developed for statistical inferences on a complex process or system and their applications to simulations of chemically reacting turbulent flows. These two fields, ML and turbulent combustion, have large body of work and knowledge on their own, and this book brings them together and explain the complexities and challenges involved in applying ML techniques to simulate and study reacting flows. This is important as to the world's total primary energy supply (TPES), since more than 90% of this supply is through combustion technologies and the non-negligible effects of combustion on environment. Although alternative technologies based on renewable energies are coming up, their shares for the TPES is are less than 5% currently and one needs a complete paradigm shift to replace combustion sources. Whether this is practical or not is entirely a different question, and an answer to this question depends on the respondent. However, a pragmatic analysis suggests that the combustion share to TPES is likely to be more than 70% even by 2070. Hence, it will be prudent to take advantage of ML techniques to improve combustion sciences and technologies so that efficient and "greener" combustion systems that are friendlier to the environment can be designed. The book covers the current state of the art in these two topics and outlines the challenges involved, merits and drawbacks of using ML for turbulent combustion simulations including avenues which can be explored to overcome the challenges. The required mathematical equations and backgrounds are discussed with ample references for readers to find further detail if they wish. This book is unique since there is not any book with similar coverage of topics, ranging from big data analysis and machine learning algorithm to their applications for combustion science and system design for energy generation.

This open access book describes the theory of transformation thermotics and its extended theories for the active control of macroscopic thermal phenomena of artificial systems, which is in sharp contrast to classical thermodynamics comprising the four thermodynamic laws for the passive description of macroscopic thermal phenomena of natural systems. This monograph consists of two parts, i.e., inside and outside metamaterials, and covers the basic concepts and mathematical methods, which are necessary to understand the thermal problems extensively investigated in physics, but also in other disciplines of engineering and materials. The analyses rely on models solved by analytical techniques accompanied by computer simulations and laboratory experiments. This monograph can not only be a bridge linking three first-class disciplines, i.e., physics, thermophysics, and materials science, but also contribute to interdisciplinary development.

The Mechanics and Thermodynamics of Continua presents a unified treatment of continuum mechanics and thermodynamics that emphasizes the universal status of the basic balances and the entropy imbalance. These laws are viewed as fundamental building blocks on which to frame theories of material behavior. As a valuable reference source, this book presents a detailed and complete treatment of continuum mechanics and thermodynamics for graduates and advanced undergraduates in engineering, physics, and mathematics. The chapters on plasticity discuss the standard isotropic theories and, in addition, crystal plasticity and gradient plasticity.

This textbook presents the classical treatment of the problems of heat transfer in an exhaustive manner with due emphasis on understanding of the physics of the problems. This emphasis will be especially visible in the chapters on convective heat transfer. Emphasis is also laid on the solution of steady and unsteady two-dimensional heat conduction problems. Another special feature of the book is a chapter on introduction to design of heat exchangers and their illustrative design problems. A simple and understandable treatment of gaseous radiation has been presented. A special chapter on flat plate solar air heater has been incorporated that covers mathematical modeling of the air heater. The chapter on mass transfer has been written looking specifically at the needs of the students of mechanical engineering. The book includes a large number and variety of solved problems with supporting line diagrams. A number of application-based examples have been incorporated where applicable. The end-of-chapter exercise problems are supplemented with stepwise answers. Though the book has been primarily designed to serve as a complete textbook for undergraduate and graduate students of mechanical engineering, it will also be useful for students of chemical, aerospace, automobile, production, and industrial engineering streams. The book fully covers the topics of heat transfer coursework and can also be used as an excellent reference for students preparing for competitive graduate examinations.

The Surface Wettability Effect on Phase Change collects high level contributions from internationally recognised scientists in the field. It thoroughly explores surface wettability, with topics spanning from the physics of phase change, physics of nucleation, mesoscale modeling, analysis of phenomena such drop evaporation, boiling, local heat flux at triple line, Leidenfrost, dropwise condensation, heat transfer enhancement, freezing, icing. All the topics are treated by discussing experimental results, mathematical modeling and numerical simulations. In particular, the numerical methods look at direct numerical simulations in the framework of VOF simulations, phase-field simulations and molecular dynamics. An introduction to equilibrium and non-equilibrium thermodynamics of phase change, wetting phenomena, liquid interfaces, numerical simulation of wetting phenomena and phase change is offered for readers who are less familiar in the field. This book will be of interest to researchers, academics, engineers, and postgraduate students working in the area of thermofluids, thermal management, and surface technology.