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Books > Science & Mathematics > Physics > Thermodynamics & statistical physics > Thermodynamics
Scheck's textbook starts with a concise introduction to classical thermodynamics, including geometrical aspects. Then a short introduction to probabilities and statistics lays the basis for the statistical interpretation of thermodynamics. Phase transitions, discrete models and the stability of matter are explained in great detail.Thermodynamics has a special role in theoretical physics. Due to the general approach of thermodynamics the field has as a bridging function between several areas like the theory of condensed matter, elementary particle physics, astrophysics and cosmology. The classical thermodynamics describes predominantly averaged properties of matter, reaching from few particle systems and state of matter to stellar objects. Statistical Thermodynamics covers the same fields, but explores them in greater depth and unifies classical statistical mechanics with quantum theory of multiple particle systems. The content is presented as two tracks: the fast track for master students, providing the essentials, and the intensive track for all wanting to get in depth knowledge of the field. Clearly labelled material and sections guide students through the preferred level of treatment. Numerous problems and worked examples will provide successful access to Statistical Physics and Thermodynamics.
This book provides analytical solutions to a number of classical problems in transport processes, i.e. in fluid mechanics, heat and mass transfer. Expanding computing power and more efficient numerical methods have increased the importance of computational tools. However, the interpretation of these results is often difficult and the computational results need to be tested against the analytical results, making analytical solutions a valuable commodity. Furthermore, analytical solutions for transport processes provide a much deeper understanding of the physical phenomena involved in a given process than do corresponding numerical solutions. Though this book primarily addresses the needs of researchers and practitioners, it may also be beneficial for graduate students just entering the field.
This book discusses the current direction of the research approach to extreme biomimetics through biological materials-inspired chemistry and its applications in modern technology and medicine. It is a resource covering topics of extreme (psychrophilic and thermopilic) biomineralization, solvothermal and hydrothermal chemistry of metal oxides and nanostructured composites, and bioinspired materials science in a diverse areas. The authors review the current advances in the extreme biomimetics research field and describe various approaches introduced and explored by their respective laboratories. * Details the basic principles of extreme biomimetics approach for design of new materials and applications; * Includes numerous examples of the hierarchical organization of hydrothermally or psychrophilically obtained biocomposites, structural bioscaffolds, biosculpturing, biomimetism, and bioinspiration as tools for the design of innovative materials; * Describes and details the principles of extreme biomimetics with respect to metallization of chemically and thermally stable biopolymers.
This book provides a detailed analysis of absorption refrigeration systems, covering single effect to multi-effect systems and their applications. Both the first and second laws of thermodynamics are discussed in relation to refrigeration systems to show how system performance differs from one law to another. Comparative energy and exergy analyses and assessments of single effect, double effect, triple effect and quadruple effect absorption refrigeration system are performed to illustrate the impact of an increase in the number of effects on system performance. In particular, the second law (exergy) formulation for absorption refrigeration systems, rarely discussed by other works, is covered in detail. Integrated Absorption Refrigeration Systems will help researchers, students and instructors in the formulation of energy and exergy efficiency equations for absorption refrigeration systems.
The book offers a comprehensive report on the design and optimization of a thermochemical heat storage system for use in buildings. It combines theoretical and experimental work, with a special emphasis on model-based methods. It describes the numerical modeling of the heat exchanger, which allows recovery of about two thirds of the waste heat from both solar and thermal energy. The book also provides readers with a snapshot of current research on thermochemical storage systems, and an in-depth review of the most important concepts and methods in thermal management modeling. It represents a valuable resource for students, engineers and researchers interested in thermal energy storage processes, as well as for those dealing with modeling and 3D simulations in the field of energy and process engineering.
This book presents the fundamentals of irreversible thermodynamics for nonlinear transport processes in gases and liquids, as well as for generalized hydrodynamics extending the classical hydrodynamics of Navier, Stokes, Fourier, and Fick. Together with its companion volume on nonrelativistic contexts, it provides a comprehensive picture of the relativistic covariant kinetic theory of gases and relativistic hydrodynamics of gases.Relativistic theories of macroscopic irreversible processes must strictly conform to the thermodynamic laws at every step and in all approximations that enter their derivation from the mechanical principles. Upholding this as the inviolable tenet, the author develops theories of irreversible transport processes in fluids (gases or liquids). They apply regardless of whether the processes are near to or far removed from equilibrium, or whether they are linear or nonlinear with respect to macroscopic fluxes or thermodynamic forces. The irreversible covariant Boltzmann as well as the covariant form of the Boltzmann-Nordheim-Uehling-Uhlenbeck equation is used for deriving theories of irreversible transport equations and generalized hydrodynamic equations for either classical gases or quantum gases. They all conform rigorously to the tenet. All macroscopic observables described by the so-formulated theories therefore are likewise expected to strictly obey the tenet.
This book is about the mechanisms of wealth creation, or what we like to think of as evolutionary "progress." The massive circular flow of goods and services between producers and consumers is not a perpetual motion machine; it has been dependent for the past 150 years on energy inputs from a finite storage of fossil fuels. In this book, you will learn about the three key requirements for wealth creation, and how this process acts according to physical laws, and usually after some part of the natural wealth of the planet has been exploited in an episode of "creative destruction." Knowledge and natural capital, particularly energy, will interact to power the human wealth engine in the future as it has in the past. Will it sputter or continue along the path of evolutionary progress that we have come to expect? Can the new immaterial wealth of information and ideas, which makes up the so-called knowledge economy, replace depleted natural wealth? These questions have no simple answers, but this masterful book will help you to understand the grand challenge of our time. Praise for Energy, Complexity and Wealth Maximization: "... people who run the modern world (politicians, economists and lawyers) have a very poor grasp of how it really works because they do not understand the fundamentals of energy, exergy and entropy ... those decision-makers would greatly benefit from reading this book ..." - Vaclav Smil, Distinguished Professor Emeritus, University of Manitoba "... A grandiose design; impressive, worth reading and reflecting!" - Prof. Dr. Ernst Ulrich von Weizacker, Founder of Wuppertal Institute; Co-President of the Club of Rome, Former Member of the German Bundestag, co-chair of the UN's Resource Panel "... The book is a must read for concerned citizens and decision makers across the globe." - RK Pachauri, Founder and Executive Vice Chairman, The Energy and Resources Institute (TERI) and ex-chair, International Panel on Climate Change (IPCC)
This book provides detailed calculated values for the thermal radiative and thermodynamic functions of black-body radiation in finite spectral ranges. The results are presented in tabular form. The areas of thermal power generation, infrared medical diagnostics, solar power and nuclear generation, and astrophysics are included. A range of the thermal radiative and thermodynamic functions are calculated by the authors in the finite frequency/wavenumber/wavelength intervals at different temperatures. This book also contains the tables of the chromaticity coordinates and RGB parameters calculated for different color spaces (Rec.709 (HDTV), sRGB, Adobe RGB). A number of the optimization problems is formulated and solved for various thermal black-body radiative and thermodynamic functions in a finite range of frequencies.
This first volume discusses fluid mechanical concepts and their applications to ideal and viscous processes. It describes the fundamental hydrostatics and hydrodynamics, and includes an almanac of flow problems for ideal fluids. The book presents numerous exact solutions of flows in simple configurations, each of which is constructed and graphically supported. It addresses ideal, potential, Newtonian and non-Newtonian fluids. Simple, yet precise solutions to special flows are also constructed, namely Blasius boundary layer flows, matched asymptotics of the Navier-Stokes equations, global laws of steady and unsteady boundary layer flows and laminar and turbulent pipe flows. Moreover, the well-established logarithmic velocity profile is criticised.
In the past decades, the scan rate range of calorimeters has been extended tremendously at the high end, from approximately 10 up to 10 000 000 DegreesC/s and more. The combination of various calorimeters and the newly-developed Fast Scanning Calorimeters (FSC) now span 11 orders of magnitude, by which many processes can be mimicked according to the time scale(s) of chemical and physical transitions occurring during cooling, heating and isothermal stays in case heat is exchanged. This not only opens new areas of research on polymers, metals, pharmaceuticals and all kinds of substances with respect to glass transition, crystallization and melting phenomena, it also enables in-depth study of metastability and reorganization of samples on an 1 to 1000 ng scale. In addition, FSC will become a crucial tool for understanding and optimization of processing methods at high speeds like injection molding. The book resembles the state-of-the art in Thermal Analysis & Calorimetry and is an excellent starting point for both experts and newcomers in the field.
This book provides a practical study of modern heat pipe engineering, discussing how it can be optimized for use on a wider scale. An introduction to operational and design principles, this book offers a review of heat and mass transfer theory relevant to performance, leading into and exploration of the use of heat pipes, particularly in high-heat flux applications and in situations in which there is any combination of non-uniform heat loading, limited airflow over the heat generating components, and space or weight constraints. Key implementation challenges are tackled, including load-balancing, materials characteristics, operating temperature ranges, thermal resistance, and operating orientation. With its presentation of mathematical models to calculate heat transfer limitations and temperature gradient of both high- and low-temperature heat pipes, the book compares calculated results with the available experimental data. It also includes a series of computer programs developed by the author to support presented data, aid design, and predict performance.
This book describes recent technological developments in next generation nuclear reactors that have created renewed interest in nuclear process heat for industrial applications. The author's discussion mirrors the industry's emerging focus on combined cycle Next Generation Nuclear Plants' (NGNP) seemingly natural fit in producing electricity and process heat for hydrogen production. To utilize this process heat, engineers must uncover a thermal device that can transfer the thermal energy from the NGNP to the hydrogen plant in the most performance efficient and cost effective way possible. This book is written around that vital quest, and the author describes the usefulness of the Intermediate Heat Exchanger (IHX) as a possible solution. The option to transfer heat and thermal energy via a single-phase forced convection loop where fluid is mechanically pumped between the heat exchangers at the nuclear and hydrogen plants is presented, and challenges associated with this tactic are discussed. As a second option, heat pipes and thermosyphons, with their ability to transport very large quantities of heat over relatively long distance with small temperature losses, are also examined.
This is a comprehensive textbook designed for graduate and advanced undergraduate students. Both authors rely on more than 20 years of teaching experience in renowned Physics Engineering courses to write this book addressing the students' needs. Kinetics and Spectroscopy of Low Temperature Plasmas derives in a full self-consistent way the electron kinetic theory used to describe low temperature plasmas created in the laboratory with an electrical discharge, and presents the main optical spectroscopic diagnostics used to characterize such plasmas. The chapters with the theoretical contents make use of a deductive approach in which the electron kinetic theory applied to plasmas with basis on the electron Boltzmann equation is derived from the basic concepts of Statistical and Plasma Physics. On the other hand, the main optical spectroscopy diagnostics used to characterize experimentally such plasmas are presented and justified from the point of view of the Atomic and Molecular Physics. Low temperature plasmas (LTP) are partially ionized gases with a broad use in many technological applications such as microelectronics, light sources, lasers, biology and medicine. LTPs lead to the production of atomic and molecular excited states, chemically reactive radicals, and activated surface sites, which are in the origin, among others, of the deposition of thin films, advanced nanotechnology products, solar cells, highly efficient combustion motors, and treatment of cancer cells.
In this book the author presents a general formalism of nonequilibrium thermodynamics with complex information flows induced by interactions among multiple fluctuating systems. The author has generalized stochastic thermodynamics with information by using a graphical theory. Characterizing nonequilibrium dynamics by causal networks, he has obtained a novel generalization of the second law of thermodynamics with information that is applicable to quite a broad class of stochastic dynamics such as information transfer between multiple Brownian particles, an autonomous biochemical reaction, and complex dynamics with a time-delayed feedback control. This study can produce further progress in the study of Maxwell's demon for special cases. As an application to these results, information transmission and thermodynamic dissipation in biochemical signal transduction are discussed. The findings presented here can open up a novel biophysical approach to understanding information processing in living systems.
This monograph presents a systematic analysis of bubble system mathematics, using the mechanics of two-phase systems in non-equilibrium as the scope of analysis. The author introduces the thermodynamic foundations of bubble systems, ranging from the fundamental starting points to current research challenges. This book addresses a range of topics, including description methods of multi-phase systems, boundary and initial conditions as well as coupling requirements at the phase boundary. Moreover, it presents a detailed study of the basic problems of bubble dynamics in a liquid mass: growth (dynamically and thermally controlled), collapse, bubble pulsations, bubble rise and breakup. Special emphasis is placed on bubble dynamics in turbulent flows. The analysis results are used to write integral equations governing the rate of vapor generation (condensation) in non-equilibrium flows, thus creating a basis for solving a number of practical problems. This book is the first to present a comprehensive theory of boiling shock with applications to problems of critical discharge and flashing under the fast decompression conditions. Reynolds' analogy was the key to solving a number of problems in subcooled forced-flow boiling, the theoretical results of which led to easy-to-use design formulas. This book is primarily aimed at graduate and post-graduate students specializing in hydrodynamics or heat and mass transfer, as well as research expert focused on two-phase flow. It will also serve as a comprehensive reference book for designers working in the field of power and aerospace technology.
This book provides a systematic and comprehensive description of high-entropy alloys (HEAs). The authors summarize key properties of HEAs from the perspective of both fundamental understanding and applications, which are supported by in-depth analyses. The book also contains computational modeling in tackling HEAs, which help elucidate the formation mechanisms and properties of HEAs from various length and time scales.
This book highlights new developments in the field of building pathology and rehabilitation, taking an in-depth look into current approaches to the surveying of buildings and the study of defect diagnosis, prognosis and remediation. Including a number of real-world case studies and a detailed set of references for further reading, the book will appeal to a wide readership of scientists, practitioners, students and lecturers.
This thesis represents the first systematic description of the two-phase flow problem. Two-phase flows of volatile fluids in confined geometries driven by an applied temperature gradient play an important role in a range of applications, including thermal management, such as heat pipes, thermosyphons, capillary pumped loops and other evaporative cooling devices. Previously, this problem has been addressed using a piecemeal approach that relied heavily on correlations and unproven assumptions, and the science and technology behind heat pipes have barely evolved in recent decades. The model introduced in this thesis, however, presents a comprehensive physically based description of both the liquid and the gas phase. The model has been implemented numerically and successfully validated against the available experimental data, and the numerical results are used to determine the key physical processes that control the heat and mass flow and describe the flow stability. One of the key contributions of this thesis work is the description of the role of noncondensables, such as air, on transport. In particular, it is shown that many of the assumptions used by current engineering models of evaporative cooling devices are based on experiments conducted at atmospheric pressures, and these assumptions break down partially or completely when most of the noncondensables are removed, requiring a new modeling approach presented in the thesis. Moreover, Numerical solutions are used to motivate and justify a simplified analytical description of transport in both the liquid and the gas layer, which can be used to describe flow stability and determine the critical Marangoni number and wavelength describing the onset of the convective pattern. As a result, the results presented in the thesis should be of interest both to engineers working in heat transfer and researchers interested in fluid dynamics and pattern formation.
This book examines the performance of oscillating water column (OWC) wave energy converters. It discusses the influence of humid air inside the chamber and changes in the seabed, and also investigates the role of wave energy converters in coastal protection. The authors use a real gas model to describe the thermodynamics of the air-water vapour mixture inside the chamber, and the compression and expansion process during the wave cycle. Further, they present an alternative formulation with new perspectives on the adiabatic process of the gaseous phase, including a modified adiabatic index, and subsequent modified thermodynamic state variables such as enthalpy, entropy and specific heat. The book also develops a numerical model using computational fluid dynamics to simulate OWC characteristics in open sea, and studies the performance of a linear turbine using an actuator disk model. It then compares the results from both cases to find an agreement between the analytical and numerical models when humidity is inserted in the gaseous phase. Introducing new concepts to studies of wave energy to provide fresh perspectives on energy extraction and efficiency problems, the book is a valuable resource for researchers and industrial companies involved in thermal energy and coastal engineering. It is also of interest to undergraduate and postgraduate students, as it broadens their view of wave energy.
This book presents a new algorithm to calculate fluid flow and heat transfer of laminar mixed convection. It provides step-by-step tutorial help to learn quickly how to set up the theoretical and numerical models of laminar mixed convection, to consider the variable physical properties of fluids, to obtain the system of numerical solutions, to create a series of formalization equations for the convection heat transfer by using a curve-fitting approach combined with theoretical analysis and derivation. It presents the governing ordinary differential equations of laminar mixed convection, equivalently transformed by an innovative similarity transformation with the description of the related transformation process. A system of numerical calculations of the governing ordinary differential equations is presented for the water laminar mixed convection. A polynomial model is induced for convenient and reliable treatment of variable physical properties of liquids. The developed formalization equations of mixed convection heat transfer coefficient have strong theoretical and practical value for heat transfer applications because they are created based on a better consideration of variable physical properties of fluids, accurate numerical solutions and rigorous formalization equations combined with rigorous theoretical derivation. This book is suitable for scientific researchers, engineers, professors, master and PhD students of fluid mechanics and convection heat and mass transfer.
This book presents a collection of recent research works intended to assist in the effective management of service loss. It develops and evaluates methodologies for the assessment of defects and failures, and proposes methodologies for preventing and mitigating building defects. As such, the book will appeal to a broad readership of scientists, practitioners, students and lecturers.
This book presents a collection of recent research on building diagnosis techniques related to construction pathology, hygrothermal behavior and durability, and diagnostic techniques. It highlights recent advances and new developments in the field of building physics, building anomalies in materials and components, new techniques for improved energy efficiency analysis, and diagnosis techniques such as infrared thermography. This book will be of interest to a wide readership of professionals, scientists, students, practitioners, and lecturers.
This book presents research advances in automotive AC systems using an interdisciplinary approach combining both thermal science, and automotive engineering. It covers a variety of topics, such as: control strategies, optimization algorithms, and diagnosis schemes developed for when automotive air condition systems interact with powertrain dynamics. In contrast to the rapid advances in the fields of building HVAC and automotive separately, an interdisciplinary examination of both areas has long been neglected. The content presented in this book not only reveals opportunities when interaction between on-board HVAC and powertrain is considered, but also provides new findings to achieve performance improvement using model-based methodologies.
This book presents the fundamentals of irreversible thermodynamics for nonlinear transport processes in gases and liquids, as well as for generalized hydrodynamics extending the classical hydrodynamics of Navier, Stokes, Fourier, and Fick. Together with its companion volume on relativistic theories, it provides a comprehensive picture of the kinetic theory formulated from the viewpoint of nonequilibrium ensembles in both nonrelativistic and, in Vol. 2, relativistic contexts. Theories of macroscopic irreversible processes must strictly conform to the thermodynamic laws at every step and in all approximations that enter their derivation from the mechanical principles. Upholding this as the inviolable tenet, the author develops theories of irreversible transport processes in fluids (gases or liquids) on the basis of irreversible kinetic equations satisfying the H theorem. They apply regardless of whether the processes are near to or far removed from equilibrium, or whether they are linear or nonlinear with respect to macroscopic fluxes or thermodynamic forces. Both irreversible Boltzmann and generalized Boltzmann equations are used for deriving theories of irreversible transport equations and generalized hydrodynamic equations, which rigorously conform to the tenet. All observables described by the so-formulated theories therefore also strictly obey the tenet.
This book describes the latest research on producing functional particles using spray processes. The authors detail micro level elementary processes and phase boundaries, process analysis scaling and modeling, and macro level process functions and particle properties. They include numerical simulations and particulars of experiments for deriving process conditions for particle production. |
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