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Books > Science & Mathematics > Physics > Thermodynamics & statistical physics > Thermodynamics
This book is dedicated to the recent developments in RET with the aim to explore polyatomic gas, dense gas and mixture of gases in non-equilibrium. In particular we present the theory of dense gases with 14 fields, which reduces to the Navier-Stokes Fourier classical theory in the parabolic limit. Molecular RET with an arbitrary number of field-variables for polyatomic gases is also discussed and the theory is proved to be perfectly compatible with the kinetic theory in which the distribution function depends on an extra variable that takes into account a molecule's internal degrees of freedom. Recent results on mixtures of gases with multi-temperature are presented together with a natural definition of the average temperature. The qualitative analysis and in particular, the existence of the global smooth solution and the convergence to equilibrium are also studied by taking into account the fact that the differential systems are symmetric hyperbolic. Applications to shock and sound waves are analyzed together with light scattering and heat conduction and the results are compared with experimental data. Rational extended thermodynamics (RET) is a thermodynamic theory that is applicable to non-equilibrium phenomena. It is described by differential hyperbolic systems of balance laws with local constitutive equations. As RET has been strictly related to the kinetic theory through the closure method of moment hierarchy associated to the Boltzmann equation, the applicability range of the theory has been restricted within rarefied monatomic gases. The book represents a valuable resource for applied mathematicians, physicists and engineers, offering powerful models for potential applications like satellites reentering the atmosphere, semiconductors and nano-scale phenomena.
The third edition of Engineering Flow and Heat Exchange is the most practical textbook available on the design of heat transfer and equipment. This book is an excellent introduction to real-world applications for advanced undergraduates and an indispensable reference for professionals. The book includes comprehensive chapters on the different types and classifications of fluids, how to analyze fluids, and where a particular fluid fits into a broader picture. This book includes various a wide variety of problems and solutions - some whimsical and others directly from industrial applications. Numerous practical examples of heat transfer Different from other introductory books on fluids Clearly written, simple to understand, written for students to absorb material quickly Discusses non-Newtonian as well as Newtonian fluids Covers the entire field concisely Solutions manual with worked examples and solutions provided
This textbook explains completely the general and statistical thermodynamics. It begins with an introductory statistical mechanics course, deriving all the important formulae meticulously and explicitly, without mathematical short cuts. The main part of the book deals with the careful discussion of the concepts and laws of thermodynamics, van der Waals, Kelvin and Claudius theories, ideal and real gases, thermodynamic potentials, phonons and all the related aspects. To elucidate the concepts introduced and to provide practical problem solving support, numerous carefully worked examples are of great value for students. The text is clearly written and punctuated with many interesting anecdotes. This book is written as main textbook for upper undergraduate students attending a course on thermodynamics.
This book explores the Energy Minimization Multi-scale (EMMS) theory and the drag model for heterogeneous gas-solid fluidized flows. The results show that the cluster density plays a critical role with regard to drag. A novel cluster model is proposed and indicates that the profile of cluster density is single-peaked with the maximum value located at solid concentrations of 0.1~0.15. The EMMS theory is improved with the cluster model and an accurate drag model is developed. The model's universality is achieved by investigating the relationship between the heterogeneity and flow patterns. The drag model is subsequently verified numerically and experimentally.
This thesis studies the general heat conduction law, irreversible thermodynamics and the size effect of thermal conductivity exhibited in nanosystems from the perspective of recently developed thermomass theory. The derivation bridges the microscopic phonon Boltzmann equation and macroscopic continuum mechanics. Key concepts such as entropy production, temperature and the Onsager reciprocal relation are revisited in the case of non-Fourier heat conduction. Lastly, useful expressions are extracted from the picture of phonon gas dynamics and are used to successfully predict effective thermal conductivity in nanosystems.
This book presents a new economic theory developed from physical and biological principles. It explains how technology, social systems and economic values are intimately related to resources. Many people have recognized that mainstream (neoclassical) economic theories are not consistent with physical laws and often not consistent with empirical patterns, but most feel that economic activities are too complex to be described by a simple and coherent mathematical theory. While social systems are indeed complex, all life systems, including social systems, satisfy two principles. First, all systems need to extract resources from the external environment to compensate for their consumption. Second, for a system to be viable, the amount of resource extraction has to be no less than the level of consumption. From these two principles, we derive a quantitative theory of major factors in economic activities, such as fixed cost, variable cost, discount rate, uncertainty and duration. The mathematical theory enables us to systematically measure the effectiveness of different policies and institutional structures at varying levels of resource abundance and cost.The theory presented in this book shows that there do not exist universally optimal policies or institutional structures. Instead, the impacts of different policies or social structures have to be measured within the context of existing levels of resource abundance. As the physical costs of extracting resources rise steadily, many policy assumptions adopted in mainstream economic theories, and workable in times of cheap and abundant energy supplies and other resources, need to be reconsidered. In this rapidly changing world, the theory presented here provides a solid foundation for examining the long-term impacts of today's policy decisions.
This textbook presents an exposition of stochastic dynamics and irreversibility. It comprises the principles of probability theory and the stochastic dynamics in continuous spaces, described by Langevin and Fokker-Planck equations, and in discrete spaces, described by Markov chains and master equations. Special concern is given to the study of irreversibility, both in systems that evolve to equilibrium and in nonequilibrium stationary states. Attention is also given to the study of models displaying phase transitions and critical phenomena both in thermodynamic equilibrium and out of equilibrium. These models include the linear Glauber model, the Glauber-Ising model, lattice models with absorbing states such as the contact process and those used in population dynamic and spreading of epidemic, probabilistic cellular automata, reaction-diffusion processes, random sequential adsorption and dynamic percolation. A stochastic approach to chemical reaction is also presented.The textbook is intended for students of physics and chemistry and for those interested in stochastic dynamics. It provides, by means of examples and problems, a comprehensive and detailed explanation of the theory and its applications.
This comprehensive and carefully edited volume presents a variety of experimental methods used in Shock Waves research. In 14 self contained chapters this 9th volume of the "Shock Wave Science and Technology Reference Library" presents the experimental methods used in Shock Tubes, Shock Tunnels and Expansion Tubes facilities. Also described is their set-up and operation. The uses of an arc heated wind tunnel and a gun tunnel are also contained in this volume. Whenever possible, in addition to the technical description some typical scientific results obtained using such facilities are described. Additionally, this authoritative book includes techniques for measuring physical properties of blast waves and laser generated shock waves. Information about active shock wave laboratories at different locations around the world that are not described in the chapters herein is given in the Appendix, making this book useful for every researcher involved in shock/blast wave phenomena.
This textbook offers original and new approaches to the teaching of electrochemical concepts, principles and applications. Throughout the text the authors provide a balanced coverage of the thermodynamic and kinetic processes at the heart of electrochemical systems. The first half of the book outlines fundamental concepts appropriate to undergraduate students and the second half gives an in-depth account of electrochemical systems suitable for experienced scientists and course lecturers. Concepts are clearly explained and mathematical treatments are kept to a minimum or reported in appendices. This book features: - Questions and answers for self-assessment - Basic and advanced level numerical descriptions - Illustrated electrochemistry applications This book is accessible to both novice and experienced electrochemists and supports a deep understanding of the fundamental principles and laws of electrochemistry.
This Brief describes six basic models of buoyancy-driven convection in a fluid layer: three configurations of internally heated convection and three configurations of Rayleigh-Benard convection. The author discusses the main quantities that characterize heat transport in each model, along with the constraints on these quantities. This presentation is the first to place the various models in a unified framework, and similarities and differences between the cases are highlighted. Necessary and sufficient conditions for convective motion are given. For the internally heated cases only, parameter-dependent lower bounds on the mean fluid temperature are proven, and results of past simulations and laboratory experiments are summarized and reanalyzed. The author poses several open questions for future study.
Two-Phase Flow in Refrigeration Systems presents recent developments from the authors' extensive research programs on two-phase flow in refrigeration systems. This book covers advanced mass and heat transfer and vapor compression refrigeration systems and shows how the performance of an automotive air-conditioning system is affected through results obtained experimentally and theoretically, specifically with consideration of two-phase flow and oil concentration. The book is ideal for university postgraduate students as a textbook, researchers and professors as an academic reference book, and by engineers and designers as handbook.
Based on the simulations developed in research groups over the past years, Introduction to Quasi-dimensional Simulation of Spark Ignition Engines provides a compilation of the main ingredients necessary to build up a quasi-dimensional computer simulation scheme. Quasi-dimensional computer simulation of spark ignition engines is a powerful but affordable tool which obtains realistic estimations of a wide variety of variables for a simulated engine keeping insight the basic physical and chemical processes involved in the real evolution of an automotive engine. With low computational costs, it can optimize the design and operation of spark ignition engines as well as it allows to analyze cycle-to-cycle fluctuations. Including details about the structure of a complete simulation scheme, information about what kind of information can be obtained, and comparisons of the simulation results with experiments, Introduction to Quasi-dimensional Simulation of Spark Ignition Engines offers a thorough guide of this technique. Advanced undergraduates and postgraduates as well as researchers in government and industry in all areas related to applied physics and mechanical and automotive engineering can apply these tools to simulate cyclic variability, potentially leading to new design and control alternatives for lowering emissions and expanding the actual operation limits of spark ignition engines
Superconductors have been known about since the turn ofthe century. Recently there has been a renewed interest with the discovery of the new, high-Tc materials since 1986 1]. These compounds become superconducting at much warmer temperatures than any pre viously known. In fact, many of tthem superconduct at temperatures above the boiling point of liquid nitrogen, making the observation of the transition both accessible and inexpensive. It was obvious immediately that these materials could have a tremendous technological impact, or lead to further materials with even higher transitions. For this reason there has been an intense effort by scientists in both academia and industry to study these materials. The scientificand industrial communitieshope to learn what makes these materials work. For, learning how these materials work not only increases mankind's overall knowledge of his world, but could make some person or company quite successful if the information were used and developed correctly."
This first volume provides the basic matters needed for understanding the thermophysical properties of metallic liquids and for developing reliable models to accurately predict the thermophysical properties of almost all metallic elements in the liquid state, together with methods for quantitative assessment of models/equations. The authors also review the structure of metallic liquids, which is based on the theory of liquids, followed by density, volume expansivity, thermodynamic properties (evaporation enthalpy, vapour pressure, heat capacity), sound velocity, surface tension,viscosity, diffusion, and electrical and thermal conductivities. Finally, the essential points of methods used for measuring these experimental data are presented.
This book presents recent developments in our systematic studies of hydrodynamics and heat and mass transfer in laminar free convection, accelerating film boiling and condensation of Newtonian fluids, as well as accelerating film flow of non-Newtonian power-law fluids (FFNF). These new developments provided in this book are (i) novel system of analysis models based on the developed New Similarity Analysis Method; (ii) a system of advanced methods for treatment of gas temperature- dependent physical properties, and liquid temperature- dependent physical properties; (iii) the organically combined models of the governing mathematical models with those on treatment model of variable physical properties; (iv) rigorous approach of overcoming a challenge on accurate solution of three-point boundary value problem related to two-phase film boiling and condensation; and (v) A pseudo-similarity method of dealing with thermal boundary layer of FFNF for greatly simplifies the heat-transfer analysis and numerical calculation. A system of practical application equations on heat and mass transfer are provided in each chapter, which are formulated based on the rigorous numerical solutions with consideration of variable physical properties. In addition, in the second edition, other new research developments are further included on resolving an even big challenge associated with investigations of laminar free film condensation of vapour-gas mixture. They involve the novel methods for treatment of concentration- and temperature- dependent physical properties of vapour-gas mixture, and for rigorous solution of interfacial vapour saturation temperature, which have lead to rigorous analysis and calculation results on two-phase film flow velocity, temperature, and concentration fields, as well as condensate heat and mass transfer.
This book reflects the resurgence of interest in the quantum properties of black holes, culminating most recently in controversial discussions about firewalls. On the thermodynamic side, it describes how new developments allowed the inclusion of pressure/volume terms in the first law, leading to a new understanding of black holes as chemical systems, experiencing novel phenomena such as triple points and reentrant phase transitions. On the quantum-information side, the reader learns how basic arguments undergirding quantum complementarity have been shown to be flawed; and how this suggests that a black hole may surround itself with a firewall: a violent and chaotic region of highly excited states. In this thorough and pedagogical treatment, Robert Mann traces these new developments from their roots to our present-day understanding, highlighting their relationships and the challenges they present for quantum gravity.
Fundamental Aspects of Plasma Chemical Physics: Transport develops basic and advanced concepts of plasma transport to the modern treatment of the Chapman-Enskog method for the solution of the Boltzmann transport equation. The book invites the reader to consider actual problems of the transport of thermal plasmas with particular attention to the derivation of diffusion- and viscosity-type transport cross sections, stressing the role of resonant charge-exchange processes in affecting the diffusion-type collision calculation of viscosity-type collision integrals. A wide range of topics is then discussed including (1) the effect of non-equilibrium vibrational distributions on the transport of vibrational energy, (2) the role of electronically excited states in the transport properties of thermal plasmas, (3) the dependence of transport properties on the multitude of Saha equations for multi-temperature plasmas, and (4) the effect of the magnetic field on transport properties. Throughout the book, worked examples are provided to clarify concepts and mathematical approaches. This book is the second of a series of three published by the Bari group on fundamental aspects of plasma chemical physics. The first book, Fundamental Aspects of Plasma Chemical Physics: Thermodynamics, is dedicated to plasma thermodynamics; and the third, Fundamental Aspects of Plasma Chemical Physics: Kinetics, deals with plasma kinetics.
Is the heat and mass transfer intensification defined as a new paradigm of process engineering, or is it just a common and old idea, renamed and given the current taste? Where might intensification occur? How to achieve intensification? How the shape optimization of thermal and fluidic devices leads to intensified heat and mass transfers? To answer these questions, Heat & Mass Transfer Intensification and Shape Optimization: A Multi-scale Approach clarifies the definition of the intensification by highlighting the potential role of the multi-scale structures, the specific interfacial area, the distribution of driving force, the modes of energy supply and the temporal aspects of processes. A reflection on the methods of process intensification or heat and mass transfer enhancement in multi-scale structures is provided, including porous media, heat exchangers, fluid distributors, mixers and reactors. A multi-scale approach to achieve intensification and shape optimization is developed and clearly explained. Providing readers with a tool box of reflections, techniques, methods, supported by literature reviews, Heat & Mass Transfer Intensification and Shape Optimization: A Multi-scale Approach will be a key guide for students, a teaching aid for lecturers and a source of inspiration for future research subjects.
This book introduces the core concepts of the shock wave physics of condensed matter, taking a continuum mechanics approach to examine liquids and isotropic solids. The text primarily focuses on one-dimensional uniaxial compression in order to show the key features of condensed matter's response to shock wave loading. The first four chapters are specifically designed to quickly familiarize physical scientists and engineers with how shock waves interact with other shock waves or material boundaries, as well as to allow readers to better understand shock wave literature, use basic data analysis techniques, and design simple 1-D shock wave experiments. This is achieved by first presenting the steady one-dimensional strain conservation laws using shock wave impedance matching, which insures conservation of mass, momentum and energy. Here, the initial emphasis is on the meaning of shock wave and mass velocities in a laboratory coordinate system. An overview of basic experimental techniques for measuring pressure, shock velocity, mass velocity, compression and internal energy of steady 1-D shock waves is then presented. In the second part of the book, more advanced topics are progressively introduced: thermodynamic surfaces are used to describe equilibrium flow behavior, first-order Maxwell solid models are used to describe time-dependent flow behavior, descriptions of detonation shock waves in ideal and non-ideal explosives are provided, and lastly, a select group of current issues in shock wave physics are discussed in the final chapter.
A tubular heat exchanger exemplifies many aspects of the challenge in designing a pressure vessel. High or very low operating pressures and temperatures, combined with sharp temperature gradients, and large differences in the stiffnesses of adjoining parts, are amongst the legion of conditions that behoove the attention of the heat exchanger designer. Pitfalls in mechanical design may lead to a variety of operational problems, such as tube-to-tubesheet joint failure, flanged joint leakage, weld cracks, tube buckling, and flow induced vibration. Internal failures, such as pass partition bowing or weld rip-out, pass partition gasket rib blow-out, and impingement actuated tube end erosion are no less menacing. Designing to avoid such operational perils requires a thorough grounding in several disciplines of mechanics, and a broad understanding of the inter relationship between the thermal and mechanical performance of heat exchangers. Yet, while there are a number of excellent books on heat ex changer thermal design, comparable effort in mechanical design has been non-existent. This apparent void has been filled by an assortment of national codes and industry standards, notably the "ASME Boiler and Pressure Vessel Code" and the "Standards of Tubular Exchanger Manufacturers Association. " These documents, in conjunction with scattered publications, form the motley compendia of the heat exchanger designer's reference source. The subject matter clearly beckons a methodical and comprehensive treatment. This book is directed towards meeting this need.
This second edition of the important introductory text for earth scientists has been thoroughly revised and extended. It is required reading for all those interested in learning about the quantitative description of geological problems. It contains chapters on heat flow, sedimentary basin modeling, the mechanics of continental deformation, PT path modeling, geomorphology, mass transfer and more. The book is aimed at the field oriented geologist who wants to begin by learning about the quantitative description of problems. The new edition features yet more illustrations and maps as well as almost 100 corrections of scientific problems.
This textbook takes an interdisciplinary approach to the subject of thermodynamics and is therefore suitable for undergraduates in chemistry, physics and engineering courses. The book is an introduction to phenomenological thermodynamics and its applications to phase transitions and chemical reactions, with some references to statistical mechanics. It strikes the balance between the rigorousness of the Callen text and phenomenological approach of the Atkins text. The book is divided in three parts. The first introduces the postulates and laws of thermodynamics and complements these initial explanations with practical examples. The second part is devoted to applications of thermodynamics to phase transitions in pure substances and mixtures. The third part covers thermodynamic systems in which chemical reactions take place. There are some sections on more advanced topics such as thermodynamic potentials, natural variables, non-ideal mixtures and electrochemical reactions, which make this book of suitable also to post-graduate students.
Thermodynamics is the science that describes the behavior of matter at the macroscopic scale, and how this arises from individual molecules. As such, it is a subject of profound practical and fundamental importance to many science and engineering fields. Despite extremely varied applications ranging from nanomotors to cosmology, the core concepts of thermodynamics such as equilibrium and entropy are the same across all disciplines. A Conceptual Guide to Thermodynamics serves as a concise, conceptual and practical supplement to the major thermodynamics textbooks used in various fields. Presenting clear explanations of the core concepts, the book aims to improve fundamental understanding of the material, as well as homework and exam performance. Distinctive features include: *Terminology and Notation Key: A universal translator that addresses the myriad of conventions, terminologies, and notations found across the major thermodynamics texts. *Content Maps: Specific references to each major thermodynamic text by section and page number for each new concept that is introduced. *Helpful Hints and Don t Try Its: Numerous useful tips for solving problems, as well as warnings of common student pitfalls. *Unique Explanations: Conceptually clear, mathematically fairly simple, yet also sufficiently precise and rigorous. A more extensive set of reference materials, including older and newer editions of the major textbooks, as well as a number of less commonly used titles, is available online at http://www.conceptualthermo.com. Undergraduate and graduate students of chemistry, physics, engineering, geosciences and biological sciences will benefit from this book, as will students preparing for graduate school entrance exams and MCATs. |
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