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Books > Science & Mathematics > Physics > Thermodynamics & statistical physics > Thermodynamics
Schlieren and shadowgraph techniques are basic and valuable tools in various scientific and engineering disciplines. They allow us to see the invisible: the optical inhomogeneities in transparent media like air, water, and glass that otherwise cause only ghostly distortions of our normal vision. These techniques are discussed briefly in many books and papers, but there is no up-to-date complete treatment of the subject before now. The book is intended as a practical guide for those who want to use these methods, as well as a resource for a broad range of disciplines where scientific visualization is important. The colorful 400-year history of these methods is covered in an extensive introductory chapter accessible to all readers.
`Non-equilibrium Thermodynamics and Statistical Mechanics: Foundations and Applications' builds from basic principles to advanced techniques, and covers the major phenomena, methods, and results of time-dependent systems. It is a pedagogic introduction, a comprehensive reference manual, and an original research monograph. Uniquely, the book treats time-dependent systems by close analogy with their static counterparts, with most of the familiar results of equilibrium thermodynamics and statistical mechanics being generalized and applied to the non-equilibrium case. The book is notable for its unified treatment of thermodynamics, hydrodynamics, stochastic processes, and statistical mechanics, for its self-contained, coherent derivation of a variety of non-equilibrium theorems, and for its quantitative tests against experimental measurements and computer simulations. Systems that evolve in time are more common than static systems, and yet until recently they lacked any over-arching theory. 'Non-equilibrium Thermodynamics and Statistical Mechanics' is unique in its unified presentation of the theory of non-equilibrium systems, which has now reached the stage of quantitative experimental and computational verification. The novel perspective and deep understanding that this book brings offers the opportunity for new direction and growth in the study of time-dependent phenomena. 'Non-equilibrium Thermodynamics and Statistical Mechanics' is an invaluable reference manual for experts already working in the field. Research scientists from different disciplines will find the overview of time-dependent systems stimulating and thought-provoking. Lecturers in physics and chemistry will be excited by many fresh ideas and topics, insightful explanations, and new approaches. Graduate students will benefit from its lucid reasoning and its coherent approach, as well as from the chem12physof mathematical techniques, derivations, and computer algorithms.
This unique book provides a fundamental introduction to all aspects of modern plasma chemistry. The book describes mechanisms and kinetics of chemical processes in plasma, plasma statistics, thermodynamics, fluid mechanics, and electrodynamics, as well as all major electric discharges applied in plasma chemistry. The book considers most of the major applications of plasma chemistry from electronics to thermal coatings, from treatment of polymers to fuel conversion and hydrogen production, and from plasma metallurgy to plasma medicine. The book can be helpful to engineers, scientists, and students interested in plasma physics, plasma chemistry, plasma engineering, and combustion, as well as in chemical physics, lasers, energy systems, and environmental control. The book contains an extensive database on plasma kinetics and thermodynamics as well as a lot of convenient numerical formulas for practical calculations related to specific plasma-chemical processes and applications. The book contains a large number of problems and concept questions that are helpful in university courses related to plasma, lasers, combustion, chemical kinetics, statistics and thermodynamics, and high-temperature and high-energy fluid mechanics.
This is a textbook on thermodynamics of materials for junior/senior undergraduate students and first-year graduate students as well as a reference book for researchers who would like to refresh their understanding of thermodynamics. The textbook employs a plain language to explain the thermodynamic concepts and quantities. It embraces the mathematical beauty and rigor of Gibbs thermodynamics through the fundamental equation of thermodynamics from which all thermodynamic properties of a material can be derived. However, a reader with basic first-year undergraduate calculus skills will be able to get through the book without difficulty. One unique feature of this textbook is the descriptions of the step-by-step procedures for computing all the thermodynamic properties from the fundamental equation of thermodynamics and all the thermodynamic energies from a set of common, experimentally measurable thermodynamic properties, supplemented with ample numerical examples. Another unique feature of this textbook is its emphasis on the concept of chemical potential and its applications to phase equilibria in single component systems and binary solutions, chemical reaction equilibria, and lattice and electronic defects in crystals. The concept of chemical potential is introduced at the very beginning of the book together with temperature and pressure. It avoids or minimizes the use of terms such as molar Gibbs free energy, partial molar Gibbs free energy, or Gibbs potential because molar Gibbs free energy or partial molar Gibbs free energy is precisely the chemical potential of a material or a component. It is the chemical potential that determines the stability of chemical species, compounds, and phases and their tendency to chemically react to form new species, transform to new physical state, and migrate from one spatial location to another. Therefore, it is the chemical potential differences or gradients that drive essentially all materials processes of interest. A reader after finishing reading the book is expected to not only achieve a high-level fundamental understanding of thermodynamics but also acquire the analytical skills of applying thermodynamics to determining materials equilibrium and driving forces for materials processes.
Das Buch behandelt die wesentlichen Aspekte der numerischen Simulation von Verbrennungsprozessen. Dazu gehAren die Grundlagen zur mathematischen Beschreibung der Verbrennung, die Modellierung der Turbulenz, AnsAtze zur BerA1/4cksichtigung der Turbulenz-Chemie-Interaktion, numerische LAsungsverfahren und moderne, hoch effiziente Methoden zur Konvergenzbeschleunigung. In seiner umfassenden Darstellung liegt der besondere Nutzen dieses Buchs. Das Buch ist geeignet fA1/4r Studierende des Maschinenbaus, der Verfahrenstechnik und Luft- und Raumfahrttechnik ebenso wie fA1/4r Wissenschaftler und fA1/4r Ingenieure in der industriellen Praxis. Es stellt sowohl fA1/4r den Programmentwickler als auch fA1/4r den Nutzer kommerzieller Simulationsprogramme ein wichtiges Hilfsmittel dar.
The experimental discovery of the fractional quantum Hall effect (FQHE) at the end of 1981 by Tsui, Stormer and Gossard was absolutely unexpected since, at this time, no theoretical work existed that could predict new struc tures in the magnetotransport coefficients under conditions representing the extreme quantum limit. It is more than thirty years since investigations of bulk semiconductors in very strong magnetic fields were begun. Under these conditions, only the lowest Landau level is occupied and the theory predicted a monotonic variation of the resistivity with increasing magnetic field, depending sensitively on the scattering mechanism. However, the ex perimental data could not be analyzed accurately since magnetic freeze-out effects and the transitions from a degenerate to a nondegenerate system complicated the interpretation of the data. For a two-dimensional electron gas, where the positive background charge is well separated from the two dimensional system, magnetic freeze-out effects are barely visible and an analysis of the data in the extreme quantum limit seems to be easier. First measurements in this magnetic field region on silicon field-effect transistors were not successful because the disorder in these devices was so large that all electrons in the lowest Landau level were localized. Consequently, models of a spin glass and finally of a Wigner solid were developed and much effort was put into developing the technology for improving the quality of semi conductor materials and devices, especially in the field of two-dimensional electron systems."
Thermodynamics has benefited from nearly 100 years of parallel development with quantum mechanics. As a result, thermal physics has been considerably enriched in concepts, technique and purpose, and now has a dominant role in the developments of physics, chemistry and biology. This unique book explores the meaning and application of these developments using quantum theory as the starting point. The book links thermal physics and quantum mechanics in a natural way. Concepts are combined with interesting examples, and entire chapters are dedicated to applying the principles to familiar, practical and unusual situations. Together with end-of-chapter exercises, this book gives advanced undergraduate and graduate students a modern perception and appreciation for this remarkable subject.
The main object of this advanced textbook is modelling and simulation of energetic processes by bond graphs. But even without knowledge of this powerful method, it can be used to a certain extent as an introduction to simulation in thermodynamics.
Thermodynamics: Fundamentals and Applications is a 2005 text for a first graduate course in Chemical Engineering. The focus is on macroscopic thermodynamics; discussions of modeling and molecular situations are integrated throughout. Underpinning this text is the knowledge that while thermodynamics describes natural phenomena, those descriptions are the products of creative, systematic minds. Nature unfolds without reference to human concepts of energy, entropy, or fugacity. Natural complexity can be organized and studied by thermodynamics methodology. The power of thermodynamics can be used to advantage if the fundamentals are understood. This text's emphasis is on fundamentals rather than modeling. Knowledge of the basics will enhance the ability to combine them with models when applying thermodynamics to practical situations. While the goal of an engineering education is to teach effective problem solving, this text never forgets the delight of discovery, the satisfaction of grasping intricate concepts, and the stimulation of the scholarly atmosphere.
Sir James Prescott Joule (1818-1889) became one of the most significant physicists of the nineteenth century, although his original interest in science was as a hobby and for practical business purposes. The son of a brewer, he began studying heat while investigating how to increase the efficiency of electric motors. His discovery of the relationship between heat and energy contributed to the discovery of the conservation of energy and the first law of thermodynamics. Volume 1 of Joule's scientific papers was published in 1884. It is organised chronologically and reveals the range of Joule's interests and the development of his thought. The topics of the papers include the measurement of heat, voltaic batteries, electromagnets, specific heat, meteorology and thermodynamics. Joule's careful experiments in these areas were fundamental to the development of significant areas of twentieth-century physics, although he was slow to gain recognition from his contemporaries.
In this first biography of the physicist Sir James Prescott Joule (1818-1889), his friend and collaborator Osborne Reynolds (1842-1912), Professor of Engineering at Owens College, Manchester, is keen to show how Joule, the son of a prosperous Salford brewer, was an 'ordinary' boy, enjoying regular walking trips to Snowdon, the Peaks and the Lakes; at the same time, he was greatly influenced by two years of tuition by John Dalton. His later experiments, observations and published papers are discussed and quoted at length. Reynolds stresses the influence Joule's work on heat and thermodynamics had on his contemporaries, but also that this 'amateur' scientist was often so far ahead of his time that his work was misunderstood or dismissed. Since publication of this book in 1892, only one other biography of Joule has appeared, and so it remains a vital source of first-hand information on his life and work.
Sir James Prescott Joule (1818-1889) became one of the most significant physicists of the nineteenth century, although his original interest in science was as a hobby and for practical business purposes. The son of a brewer, he began studying heat while investigating how to increase the efficiency of electric motors. His discovery of the relationship between heat and energy contributed to the discovery of the conservation of energy and the first law of thermodynamics. Volume 2 of his collected papers, published in 1887, contains those which he co-authored with other noted physicists, such as Scoresby, Playfair and William Thomson, later Lord Kelvin. Because he was based in Manchester, and was not an academic, Joule's work was at first ignored by the scientific establishment, but Thomson's approval helped him gain acceptance. His joint work with Thomson on thermodynamics was fundamental to the development of significant areas of twentieth-century physics.
This graduate-level text gives a self-contained exposition of fundamental topics in equilibrium and nonequilibrium statistical thermodynamics. The text follows a balanced approach between the macroscopic (thermodynamic) and microscopic (statistical) points of view. The first half of the book deals with equilibrium thermodynamics and statistical mechanics. In addition to standard subjects, the reader will find a detailed account of broken symmetries, critical phenomena and the renormalization group, as well as an introduction to numerical methods. The second half of the book is devoted to nonequilibrium phenomena, first following a macroscopic approach, with hydrodynamics as an important example. Kinetic theory receives a thorough treatment through analysis of the Boltzmann-Lorentz model and the Boltzmann equation. The book concludes with general nonequilibrium methods such as linear response, projection method and the Langevin and Fokker-Planck equations, including numerical simulations. This advanced textbook will be of interest to graduate students and researchers in physics.
Statistical mechanics attempts to explain the behaviour of macroscopic physical systems in terms of the mechanical properties of their constituents. Although it is one of the fundamental theories of physics, it has received little attention from philosophers of science. Nevertheless, it raises philosophical questions of fundamental importance on the nature of time, chance and reduction. Most philosophical issues in this domain relate to the question of the reduction of thermodynamics to statistical mechanics. This book addresses issues inherent in this reduction: the time-asymmetry of thermodynamics and its absence in statistical mechanics; the role and essential nature of chance and probability in this reduction when thermodynamics is non-probabilistic; and how, if at all, the reduction is possible. Compiling contributions on current research by experts in the field, this is an invaluable survey of the philosophy of statistical mechanics for academic researchers and graduate students interested in the foundations of physics.
Develop a fundamental understanding of heat transfer analysis techniques as applied to earth based spacecraft with this practical guide. Written in a tutorial style, this essential text provides a how-to manual tailored for those who wish to understand and develop spacecraft thermal analyses. Providing an overview of basic heat transfer analysis fundamentals such as thermal circuits, limiting resistance, MLI, environmental thermal sources and sinks, as well as contemporary space based thermal technologies, and the distinctions between design considerations inherent to room temperature and cryogenic temperature applications, this is the perfect tool for graduate students, professionals and academic researchers.
Professor Buchdahl presents a systematic exposition of classical thermodynamics, against a background of general physical theory and on a purely phenomenological (i.e. non-statistical) level. Although particular attention is paid to the meaning of the various concepts introduced, Professor Buchdahl is not afraid of making simplifications where these are likely to enhance the reader's understanding of the subject and the relationships between the principal and ancillary laws. The emphasis throughout is on meaning and physical significance. Specific applications of the general theory are discussed in two final chapters. This book, first published in 1966, is intended for the student who has taken a first course in analytical, though not axiomatic, development of the subject. It will supplement rather than replace, the many familiar introductory treatments of thermodynamics.
The new edition of this highly regarded textbook provides a detailed overview of the most important characterization techniques for solar cells and a discussion of their advantages and disadvantages. It describes in detail all aspects of solar cell function, the physics behind every single step, as well as all the issues to be considered when improving solar cells and their efficiency. The text is now complete with examples of how the appropriate characterization techniques enable the distinction between several potential limitation factors, describing how quantities that have been introduced theoretically in earlier chapters become experimentally accessible. With exercises after each chapter to reinforce the newly acquired knowledge and requiring no more than standard physics knowledge, this book enables students and professionals to understand the factors driving conversion efficiency and to apply this to their own solar cell development.
Presenting classical thermodynamics as a concise and discrete whole, "Mere Thermodynamics" is a perfect tool for teaching a notoriously difficult subject. Accomplished teacher Don S. Lemons introduces the physical theory's concepts and methods and uses them to solve problems from a broad range of physics. He illustrates, at a gentle pace, not only the fundamentals of the subject but also advanced topics such as the relationship between the second law of thermodynamics and entropy. He highlights the intellectual structure and history of the discipline and explores the logical consequences of each of the famous three laws. Lemons explains and develops the first two laws and their corollaries, the methods and applications of thermodynamics, and the third law, as well as non-fluid variables, equilibrium and stability, and two-phase systems. The book features end-of-chapter practice problems, an appendix of worked problems, a glossary of terms, and an annotated bibliography.
This book summarizes the most recent theoretical, computational and experimental results dealing with homogeneous turbulence dynamics. A large class of flows is covered: flows governed by anisotropic production mechanisms (e.g. shear flows) and flows without production but dominated by waves (e.g. homogeneous rotating or stratified turbulence). Compressible turbulent flows are also considered. In each case, main trends are illustrated using computational and experimental results, while both linear and nonlinear theories and closures are discussed. Details about linear theories (e.g. Rapid Distortion Theory and variants) and nonlinear closures (e.g. EDQNM) are provided in dedicated chapters, following a fully unified approach. The emphasis is on homogeneous flows, including several interactions (rotation, stratification, shear, shock waves, acoustic waves, and more) which are pertinent to many applications fields - from aerospace engineering to astrophysics and Earth sciences.
This unique book provides a fundamental introduction to all aspects of modern plasma chemistry. The book describes mechanisms and kinetics of chemical processes in plasma, plasma statistics, thermodynamics, fluid mechanics, and electrodynamics, as well as all major electric discharges applied in plasma chemistry. The book considers most of the major applications of plasma chemistry from electronics to thermal coatings, from treatment of polymers to fuel conversion and hydrogen production, and from plasma metallurgy to plasma medicine. The book can be helpful to engineers, scientists, and students interested in plasma physics, plasma chemistry, plasma engineering, and combustion, as well as in chemical physics, lasers, energy systems, and environmental control. The book contains an extensive database on plasma kinetics and thermodynamics as well as a lot of convenient numerical formulas for practical calculations related to specific plasma-chemical processes and applications. The book contains a large number of problems and concept questions that are helpful in university courses related to plasma, lasers, combustion, chemical kinetics, statistics and thermodynamics, and high-temperature and high-energy fluid mechanics.
Der Lehrbuch-Klassiker stellt die physikalischen und theoretischen Gesetzmassigkeiten der Fluidmechanik dar. Anwendungsbeispiele, die weitgehend auf dem Impulssatz aufbauen, vermitteln ein vertieftes Verstandnis, Losungswege sind ausfuhrlich aufgezeigt. Wegen der grossen Nachfrage wurde das Werk in der Reihe Klassiker der Technik" neu aufgelegt. Der Band ist ein einzigartiges, bewahrtes Lehrbuch zum Thema und zugleich nutzliches Nachschlagewerk fur den Praktiker."
Das Fachbuch Verbrennung vermittelt einen UEberblick uber die Grundlagen von Verbrennungsprozessen und tragt zu einem Verstandnis ihrer Auswirkungen auf praktische Anwendungen bei. In den ersten Kapiteln finden sich die physikalisch-chemischen Grundlagen. Anhand verschiedener laminarer Flammentypen werden die Wechselwirkungen zwischen chemischer Reaktionskinetik, molekularen Transportprozessen und Stroemung beschrieben. Bei der Behandlung turbulenter Verbrennungsprozesse werden aktuelle Verfahren zur Beschreibung der Kopplung zwischen chemischer Reaktion und turbulentem Stroemungsfeld verwendet. Anwendungen sind das Motorklopfen und die Schadstoffbildung. Die dritte Auflage wurde im Hinblick auf die aktuelle Forschung erweitert und aktualisiert.
This is a comprehensive discussion of complexity as it arises in physical, chemical and biological systems, as well as in mathematical models of nature. The aim of this book is to illustrate the ways in which complexity manifests itself and to introduce a sequence of increasingly sharp mathematical methods for the classification of complex behavior. This book will be of interest to graduate students and researchers in physics (nonlinear dynamics, fluid dynamics, solid-state, cellular automata, stochastic processes, statistical mechanics and thermodynamics), mathematics (dynamical systems, ergodic and probability theory), information and computer science (coding, information theory and algorithmic complexity), electrical engineering and theoretical biology.
Heat flux or thermal flux is the rate of heat energy transfer through a given surface. In this book, the authors present topical research in the study of the processes, measurement techniques and applications of heat flux. Topics discussed include measuring heat flux and heat transfer coefficients; the science and application of heat flux biocalorimetry; measuring the thermal conductivity and the heat flux of soil as a function of air pressure; the net heat flux in the Mediterranean Sea; simulation of heat flux transport in the edge plasma of small size diverter tokamak and meridional heat fluxes in the North Indian Ocean. |
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