This textbook provides an exposition of equilibrium thermodynamics and its applications to several areas of physics with particular attention to phase transitions and critical phenomena. The applications include several areas of condensed matter physics and include also a chapter on thermochemistry. Phase transitions and critical phenomena are treated according to the modern development of the field, based on the ideas of universality and on the Widom scaling theory. For each topic, a mean-field or Landau theory is presented to describe qualitatively the phase transitions. These theories include the van der Waals theory of the liquid-vapor transition, the Hildebrand-Heitler theory of regular mixtures, the Griffiths-Landau theory for multicritical points in multicomponent systems, the Bragg-Williams theory of order-disorder in alloys, the Weiss theory of ferromagnetism, the Neel theory of antiferromagnetism, the Devonshire theory for ferroelectrics and Landau-de Gennes theory of liquid crystals. This new edition presents expanded sections on phase transitions, liquid crystals and magnetic systems, for all problems detailed solutions are provided. It is intended for students in physics and chemistry and provides a unique combination of thorough theoretical explanation and presentation of applications in both areas. Chapter summaries, highlighted essentials and problems with solutions enable a self sustained approach and deepen the knowledge. It is intended for students in physics and chemistry and provides a unique combination of thorough theoretical explanation and presentation of applications in both areas. Chapter summaries, highlighted essentials and problems with solutions enable a self sustained approach and deepen the knowledge.

This book focuses on Creep in Ceramics. The book consists of two parts. In part A general knowledge of creep in ceramics is considered, while part B specifies creep in technologically important ceramics, namely creep in oxide ceramics, carnides and nitrides. While covering all relevant information regarding raw materials and characterization of creep in ceramics, the book also summarizes most recent innovations and developments in this field as a result of extensive literature search.

A text- and exercise book for physical chemistry students! This book deals with the fundamental aspects of physical chemistry taught at the undergraduate level in chemistry and the engineering sciences in a compact and practice-oriented form. Numerous problems and detailed solutions offer the possibility of an in-depth reflection of topics like chemical thermodynamics and kinetics, atomic structure and spectroscopy. Every chapter starts with a recapitulation of important background information, before leading over to representative exercises and problems. Detailed descriptions systematically present and explain the solutions to the problems, so that readers can carefully check their own solutions and get clear-cut introductions on how to approach similar problems systematically. The book addresses students at the (upper) undergraduate level, as well as tutors and teachers. It is a rich source of exercises for exam preparation and can be used alongside classical textbooks. Furthermore it can serve teachers and tutors for the conception of their lessons. Its well-thought-through presentation, structure and design make the book appeal to everybody who wants to succeed with the physical chemistry lessons and exercises.

This book is the first major work covering applications in thermal engineering and offering a comprehensive introduction to optimal control theory, which has applications in mechanical engineering, particularly aircraft and missile trajectory optimization. The book is organized in three parts: The first part includes a brief presentation of function optimization and variational calculus, while the second part presents a summary of the optimal control theory. Lastly, the third part describes several applications of optimal control theory in solving various thermal engineering problems. These applications are grouped in four sections: heat transfer and thermal energy storage, solar thermal engineering, heat engines and lubrication.Clearly presented and easy-to-use, it is a valuable resource for thermal engineers and thermal-system designers as well as postgraduate students.

This is the physical chemistry textbook for students with an affinity for computers! It offers basic and advanced knowledge for students in the second year of chemistry masters studies and beyond. In seven chapters, the book presents thermodynamics, chemical kinetics, quantum mechanics and molecular structure (including an introduction to quantum chemical calculations), molecular symmetry and crystals. The application of physical-chemical knowledge and problem solving is demonstrated in a chapter on water, treating both the water molecule as well as water in condensed phases. Instead of a traditional textbook top-down approach, this book presents the subjects on the basis of examples, exploring and running computer programs (Mathematica (R)), discussing the results of molecular orbital calculations (performed using Gaussian) on small molecules and turning to suitable reference works to obtain thermodynamic data. Selected Mathematica (R) codes are explained at the end of each chapter and cross-referenced with the text, enabling students to plot functions, solve equations, fit data, normalize probability functions, manipulate matrices and test physical models. In addition, the book presents clear and step-by-step explanations and provides detailed and complete answers to all exercises. In this way, it creates an active learning environment that can prepare students for pursuing their own research projects further down the road. Students who are not yet familiar with Mathematica (R) or Gaussian will find a valuable introduction to computer-based problem solving in the molecular sciences. Other computer applications can alternatively be used. For every chapter learning goals are clearly listed in the beginning, so that readers can easily spot the highlights, and a glossary in the end of the chapter offers a quick look-up of important terms.

This book provides a consistent scientific background to engineering calculation methods applicable to analyses of materials reaction-to-fire, as well as fire resistance of structures. Several new and unique formulas and diagrams which facilitate calculations are presented. It focuses on problems involving high temperature conditions and, in particular, defines boundary conditions in a suitable way for calculations. A large portion of the book is devoted to boundary conditions and measurements of thermal exposure by radiation and convection. The concepts and theories of adiabatic surface temperature and measurements of temperature with plate thermometers are thoroughly explained.Also presented is a renewed method for modeling compartment fires, with the resulting simple and accurate prediction tools for both pre- and post-flashover fires. The final chapters deal with temperature calculations in steel, concrete and timber structures exposed to standard time-temperature fire curves. Useful temperature calculation tools are included, and several examples demonstrate how the finite element code TASEF can be used to calculate temperature in various configurations. Temperature Calculation in Fire Safety Engineering is intended for researchers, students, teachers, and consultants in fire safety engineering. It is also suitable for others interested in analyzing and understanding fire, fire dynamics, and temperature development. Review questions and exercises are provided for instructor use.

Der Grundkurs Theoretische Physik deckt in 7 Banden alle fur das Diplom und fur Bachelor/Master-Studiengange massgeblichen Gebiete ab. Jeder Band vermittelt das im jeweiligen Semester notwendige theoretisch-physikalische Rustzeug. UEbungsaufgaben mit ausfuhrlichen Loesungen dienen der Vertiefung des Stoffs. Der 4. Band behandelt die Gebiete Thermodynamik und Relativitatstheorie. Fur die Neuauflage wurde er grundlegend uberarbeitet und um 24 Aufgaben erganzt. Durch die zweifarbige Gestaltung ist der Stoff jetzt noch ubersichtlicher gegliedert.

This authoritative but highly accessible book presents the reader with a powerful framework for understanding the critical role of the energy return on investment (EROI) in the survival and well-being of individuals, ecosystems, businesses, economies and nations. Growth and development are fundamental and ubiquitous processes at all scales, from individuals to food crops to national economies. While we are all familiar with the concepts of economic growth and living standards as measured by gross domestic product (GDP), we often take for granted the energy use that underpins GDP and our expectations for year-on-year growth. In this book, you will learn how these measures of "progress" are completely dependent on the balance that can be achieved between energy costs (inputs) and gains. Nothing is made or moved without an energy surplus, and it is the EROI of available energy sources more than any other single factor that determines the shape of civilization. Nearly all politics and economics assume that policy and market forces are the levers upon which future outcomes will hinge. However, this book presents many examples of historical and current events that can be explained much more clearly from an energetic perspective. In addition, a future scenario is developed that gives a central place to EROI in assessing the potential of governmental and private initiatives to substitute so-called renewable energy sources for diminishing stocks of fossil fuels. When cheap fossil fuels are no longer available in the abundance needed to mask economic problems and power business as usual, it will be EROI more than the plethora of "green" technologies that creates the boundary conditions for a sustainable future.

This book covers the parameterization of entry capsules, including Apollo capsules and planetary probes, and winged entry vehicles such as the Space Shuttle and lifting bodies. The aerodynamic modelling is based on a variety of panel methods that take shadowing into account, and it has been validated with flight and wind tunnel data of Apollo and the Space Shuttle. The shape optimization is combined with constrained trajectory analysis, and the multi-objective approach provides the engineer with a Pareto front of optimal shapes. The method detailed in Conceptual Shape Optimization of Entry Vehicles is straightforward, and the output gives the engineer insight in the effect of shape variations on trajectory performance. All applied models and algorithms used are explained in detail, allowing for reconstructing the design tool to the researcher's requirements. Conceptual Shape Optimization of Entry Vehicles will be of interest to both researchers and graduate students in the field of aerospace engineering, and to practitioners within the aerospace industry.

Scheck's textbook starts with a concise introduction to classical thermodynamics, including geometrical aspects. Then a short introduction to probabilities and statistics lays the basis for the statistical interpretation of thermodynamics. Phase transitions, discrete models and the stability of matter are explained in great detail.Thermodynamics has a special role in theoretical physics. Due to the general approach of thermodynamics the field has as a bridging function between several areas like the theory of condensed matter, elementary particle physics, astrophysics and cosmology. The classical thermodynamics describes predominantly averaged properties of matter, reaching from few particle systems and state of matter to stellar objects. Statistical Thermodynamics covers the same fields, but explores them in greater depth and unifies classical statistical mechanics with quantum theory of multiple particle systems. The content is presented as two tracks: the fast track for master students, providing the essentials, and the intensive track for all wanting to get in depth knowledge of the field. Clearly labelled material and sections guide students through the preferred level of treatment. Numerous problems and worked examples will provide successful access to Statistical Physics and Thermodynamics.

This book provides analytical solutions to a number of classical problems in transport processes, i.e. in fluid mechanics, heat and mass transfer. Expanding computing power and more efficient numerical methods have increased the importance of computational tools. However, the interpretation of these results is often difficult and the computational results need to be tested against the analytical results, making analytical solutions a valuable commodity. Furthermore, analytical solutions for transport processes provide a much deeper understanding of the physical phenomena involved in a given process than do corresponding numerical solutions. Though this book primarily addresses the needs of researchers and practitioners, it may also be beneficial for graduate students just entering the field.

This book discusses the current direction of the research approach to extreme biomimetics through biological materials-inspired chemistry and its applications in modern technology and medicine. It is a resource covering topics of extreme (psychrophilic and thermopilic) biomineralization, solvothermal and hydrothermal chemistry of metal oxides and nanostructured composites, and bioinspired materials science in a diverse areas. The authors review the current advances in the extreme biomimetics research field and describe various approaches introduced and explored by their respective laboratories. * Details the basic principles of extreme biomimetics approach for design of new materials and applications; * Includes numerous examples of the hierarchical organization of hydrothermally or psychrophilically obtained biocomposites, structural bioscaffolds, biosculpturing, biomimetism, and bioinspiration as tools for the design of innovative materials; * Describes and details the principles of extreme biomimetics with respect to metallization of chemically and thermally stable biopolymers.

This book provides a detailed analysis of absorption refrigeration systems, covering single effect to multi-effect systems and their applications. Both the first and second laws of thermodynamics are discussed in relation to refrigeration systems to show how system performance differs from one law to another. Comparative energy and exergy analyses and assessments of single effect, double effect, triple effect and quadruple effect absorption refrigeration system are performed to illustrate the impact of an increase in the number of effects on system performance. In particular, the second law (exergy) formulation for absorption refrigeration systems, rarely discussed by other works, is covered in detail. Integrated Absorption Refrigeration Systems will help researchers, students and instructors in the formulation of energy and exergy efficiency equations for absorption refrigeration systems.

The book offers a comprehensive report on the design and optimization of a thermochemical heat storage system for use in buildings. It combines theoretical and experimental work, with a special emphasis on model-based methods. It describes the numerical modeling of the heat exchanger, which allows recovery of about two thirds of the waste heat from both solar and thermal energy. The book also provides readers with a snapshot of current research on thermochemical storage systems, and an in-depth review of the most important concepts and methods in thermal management modeling. It represents a valuable resource for students, engineers and researchers interested in thermal energy storage processes, as well as for those dealing with modeling and 3D simulations in the field of energy and process engineering.

This book presents the fundamentals of irreversible thermodynamics for nonlinear transport processes in gases and liquids, as well as for generalized hydrodynamics extending the classical hydrodynamics of Navier, Stokes, Fourier, and Fick. Together with its companion volume on nonrelativistic contexts, it provides a comprehensive picture of the relativistic covariant kinetic theory of gases and relativistic hydrodynamics of gases.Relativistic theories of macroscopic irreversible processes must strictly conform to the thermodynamic laws at every step and in all approximations that enter their derivation from the mechanical principles. Upholding this as the inviolable tenet, the author develops theories of irreversible transport processes in fluids (gases or liquids). They apply regardless of whether the processes are near to or far removed from equilibrium, or whether they are linear or nonlinear with respect to macroscopic fluxes or thermodynamic forces. The irreversible covariant Boltzmann as well as the covariant form of the Boltzmann-Nordheim-Uehling-Uhlenbeck equation is used for deriving theories of irreversible transport equations and generalized hydrodynamic equations for either classical gases or quantum gases. They all conform rigorously to the tenet. All macroscopic observables described by the so-formulated theories therefore are likewise expected to strictly obey the tenet.

This book is about the mechanisms of wealth creation, or what we like to think of as evolutionary "progress." The massive circular flow of goods and services between producers and consumers is not a perpetual motion machine; it has been dependent for the past 150 years on energy inputs from a finite storage of fossil fuels. In this book, you will learn about the three key requirements for wealth creation, and how this process acts according to physical laws, and usually after some part of the natural wealth of the planet has been exploited in an episode of "creative destruction." Knowledge and natural capital, particularly energy, will interact to power the human wealth engine in the future as it has in the past. Will it sputter or continue along the path of evolutionary progress that we have come to expect? Can the new immaterial wealth of information and ideas, which makes up the so-called knowledge economy, replace depleted natural wealth? These questions have no simple answers, but this masterful book will help you to understand the grand challenge of our time. Praise for Energy, Complexity and Wealth Maximization: "... people who run the modern world (politicians, economists and lawyers) have a very poor grasp of how it really works because they do not understand the fundamentals of energy, exergy and entropy ... those decision-makers would greatly benefit from reading this book ..." - Vaclav Smil, Distinguished Professor Emeritus, University of Manitoba "... A grandiose design; impressive, worth reading and reflecting!" - Prof. Dr. Ernst Ulrich von Weizacker, Founder of Wuppertal Institute; Co-President of the Club of Rome, Former Member of the German Bundestag, co-chair of the UN's Resource Panel "... The book is a must read for concerned citizens and decision makers across the globe." - RK Pachauri, Founder and Executive Vice Chairman, The Energy and Resources Institute (TERI) and ex-chair, International Panel on Climate Change (IPCC)

This is a masterly exposition and an encyclopedic presentation of the theory of hyperbolic conservation laws. It illustrates the essential role of continuum thermodynamics in providing motivation and direction for the development of the mathematical theory while also serving as the principal source of applications. The reader is expected to have a certain mathematical sophistication and to be familiar with (at least) the rudiments of analysis and the qualitative theory of partial differential equations, whereas prior exposure to continuum physics is not required. The target group of readers would consist of (a) experts in the mathematical theory of hyperbolic systems of conservation laws who wish to learn about the connection with classical physics; (b) specialists in continuum mechanics who may need analytical tools; (c) experts in numerical analysis who wish to learn the underlying mathematical theory; and (d) analysts and graduate students who seek introduction to the theory of hyperbolic systems of conservation laws. This new edition places increased emphasis on hyperbolic systems of balance laws with dissipative source, modeling relaxation phenomena. It also presents an account of recent developments on the Euler equations of compressible gas dynamics. Furthermore, the presentation of a number of topics in the previous edition has been revised, expanded and brought up to date, and has been enriched with new applications to elasticity and differential geometry. The bibliography, also expanded and updated, now comprises close to two thousand titles. From the reviews of the 3rd edition: "This is the third edition of the famous book by C.M. Dafermos. His masterly written book is, surely, the most complete exposition in the subject." Evgeniy Panov, Zentralblatt MATH "A monumental book encompassing all aspects of the mathematical theory of hyperbolic conservation laws, widely recognized as the "Bible" on the subject." Philippe G. LeFloch, Math. Reviews

This book provides detailed calculated values for the thermal radiative and thermodynamic functions of black-body radiation in finite spectral ranges. The results are presented in tabular form. The areas of thermal power generation, infrared medical diagnostics, solar power and nuclear generation, and astrophysics are included. A range of the thermal radiative and thermodynamic functions are calculated by the authors in the finite frequency/wavenumber/wavelength intervals at different temperatures. This book also contains the tables of the chromaticity coordinates and RGB parameters calculated for different color spaces (Rec.709 (HDTV), sRGB, Adobe RGB). A number of the optimization problems is formulated and solved for various thermal black-body radiative and thermodynamic functions in a finite range of frequencies.

This first volume discusses fluid mechanical concepts and their applications to ideal and viscous processes. It describes the fundamental hydrostatics and hydrodynamics, and includes an almanac of flow problems for ideal fluids. The book presents numerous exact solutions of flows in simple configurations, each of which is constructed and graphically supported. It addresses ideal, potential, Newtonian and non-Newtonian fluids. Simple, yet precise solutions to special flows are also constructed, namely Blasius boundary layer flows, matched asymptotics of the Navier-Stokes equations, global laws of steady and unsteady boundary layer flows and laminar and turbulent pipe flows. Moreover, the well-established logarithmic velocity profile is criticised.

In the past decades, the scan rate range of calorimeters has been extended tremendously at the high end, from approximately 10 up to 10 000 000 DegreesC/s and more. The combination of various calorimeters and the newly-developed Fast Scanning Calorimeters (FSC) now span 11 orders of magnitude, by which many processes can be mimicked according to the time scale(s) of chemical and physical transitions occurring during cooling, heating and isothermal stays in case heat is exchanged. This not only opens new areas of research on polymers, metals, pharmaceuticals and all kinds of substances with respect to glass transition, crystallization and melting phenomena, it also enables in-depth study of metastability and reorganization of samples on an 1 to 1000 ng scale. In addition, FSC will become a crucial tool for understanding and optimization of processing methods at high speeds like injection molding. The book resembles the state-of-the art in Thermal Analysis & Calorimetry and is an excellent starting point for both experts and newcomers in the field.

This book provides a practical study of modern heat pipe engineering, discussing how it can be optimized for use on a wider scale. An introduction to operational and design principles, this book offers a review of heat and mass transfer theory relevant to performance, leading into and exploration of the use of heat pipes, particularly in high-heat flux applications and in situations in which there is any combination of non-uniform heat loading, limited airflow over the heat generating components, and space or weight constraints. Key implementation challenges are tackled, including load-balancing, materials characteristics, operating temperature ranges, thermal resistance, and operating orientation. With its presentation of mathematical models to calculate heat transfer limitations and temperature gradient of both high- and low-temperature heat pipes, the book compares calculated results with the available experimental data. It also includes a series of computer programs developed by the author to support presented data, aid design, and predict performance.

This book describes recent technological developments in next generation nuclear reactors that have created renewed interest in nuclear process heat for industrial applications. The author's discussion mirrors the industry's emerging focus on combined cycle Next Generation Nuclear Plants' (NGNP) seemingly natural fit in producing electricity and process heat for hydrogen production. To utilize this process heat, engineers must uncover a thermal device that can transfer the thermal energy from the NGNP to the hydrogen plant in the most performance efficient and cost effective way possible. This book is written around that vital quest, and the author describes the usefulness of the Intermediate Heat Exchanger (IHX) as a possible solution. The option to transfer heat and thermal energy via a single-phase forced convection loop where fluid is mechanically pumped between the heat exchangers at the nuclear and hydrogen plants is presented, and challenges associated with this tactic are discussed. As a second option, heat pipes and thermosyphons, with their ability to transport very large quantities of heat over relatively long distance with small temperature losses, are also examined.

This is a comprehensive textbook designed for graduate and advanced undergraduate students. Both authors rely on more than 20 years of teaching experience in renowned Physics Engineering courses to write this book addressing the students' needs. Kinetics and Spectroscopy of Low Temperature Plasmas derives in a full self-consistent way the electron kinetic theory used to describe low temperature plasmas created in the laboratory with an electrical discharge, and presents the main optical spectroscopic diagnostics used to characterize such plasmas. The chapters with the theoretical contents make use of a deductive approach in which the electron kinetic theory applied to plasmas with basis on the electron Boltzmann equation is derived from the basic concepts of Statistical and Plasma Physics. On the other hand, the main optical spectroscopy diagnostics used to characterize experimentally such plasmas are presented and justified from the point of view of the Atomic and Molecular Physics. Low temperature plasmas (LTP) are partially ionized gases with a broad use in many technological applications such as microelectronics, light sources, lasers, biology and medicine. LTPs lead to the production of atomic and molecular excited states, chemically reactive radicals, and activated surface sites, which are in the origin, among others, of the deposition of thin films, advanced nanotechnology products, solar cells, highly efficient combustion motors, and treatment of cancer cells.

In this book the author presents a general formalism of nonequilibrium thermodynamics with complex information flows induced by interactions among multiple fluctuating systems. The author has generalized stochastic thermodynamics with information by using a graphical theory. Characterizing nonequilibrium dynamics by causal networks, he has obtained a novel generalization of the second law of thermodynamics with information that is applicable to quite a broad class of stochastic dynamics such as information transfer between multiple Brownian particles, an autonomous biochemical reaction, and complex dynamics with a time-delayed feedback control. This study can produce further progress in the study of Maxwell's demon for special cases. As an application to these results, information transmission and thermodynamic dissipation in biochemical signal transduction are discussed. The findings presented here can open up a novel biophysical approach to understanding information processing in living systems.

This monograph presents a systematic analysis of bubble system mathematics, using the mechanics of two-phase systems in non-equilibrium as the scope of analysis. The author introduces the thermodynamic foundations of bubble systems, ranging from the fundamental starting points to current research challenges. This book addresses a range of topics, including description methods of multi-phase systems, boundary and initial conditions as well as coupling requirements at the phase boundary. Moreover, it presents a detailed study of the basic problems of bubble dynamics in a liquid mass: growth (dynamically and thermally controlled), collapse, bubble pulsations, bubble rise and breakup. Special emphasis is placed on bubble dynamics in turbulent flows. The analysis results are used to write integral equations governing the rate of vapor generation (condensation) in non-equilibrium flows, thus creating a basis for solving a number of practical problems. This book is the first to present a comprehensive theory of boiling shock with applications to problems of critical discharge and flashing under the fast decompression conditions. Reynolds' analogy was the key to solving a number of problems in subcooled forced-flow boiling, the theoretical results of which led to easy-to-use design formulas. This book is primarily aimed at graduate and post-graduate students specializing in hydrodynamics or heat and mass transfer, as well as research expert focused on two-phase flow. It will also serve as a comprehensive reference book for designers working in the field of power and aerospace technology.