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Books > Science & Mathematics > Physics > Thermodynamics & statistical physics > Thermodynamics
Presenting classical thermodynamics as a concise and discrete whole, "Mere Thermodynamics" is a perfect tool for teaching a notoriously difficult subject. Accomplished teacher Don S. Lemons introduces the physical theory's concepts and methods and uses them to solve problems from a broad range of physics. He illustrates, at a gentle pace, not only the fundamentals of the subject but also advanced topics such as the relationship between the second law of thermodynamics and entropy. He highlights the intellectual structure and history of the discipline and explores the logical consequences of each of the famous three laws. Lemons explains and develops the first two laws and their corollaries, the methods and applications of thermodynamics, and the third law, as well as non-fluid variables, equilibrium and stability, and two-phase systems. The book features end-of-chapter practice problems, an appendix of worked problems, a glossary of terms, and an annotated bibliography.
This Brief describes and analyzes flow and heat transport over a liquid-saturated porous bed. The porous bed is saturated by a liquid layer and heating takes place from a section of the bottom. The effect on flow patterns of heating from the bottom is shown by calculation, and when the heating is sufficiently strong, the flow is affected through the porous and upper liquid layers. Measurements of the heat transfer rate from the heated section confirm calculations. General heat transfer laws are developed for varying porous bed depths for applications to process industry needs, environmental sciences, and materials processing. Addressing a topic of considerable interest to the research community, the brief features an up-to-date literature review of mixed convection energy transport in fluid superposed porous layers.
This introduction to random walks on infinite graphs gives particular emphasis to graphs with polynomial volume growth. It offers an overview of analytic methods, starting with the connection between random walks and electrical resistance, and then proceeding to study the use of isoperimetric and Poincare inequalities. The book presents rough isometries and looks at the properties of a graph that are stable under these transformations. Applications include the 'type problem': determining whether a graph is transient or recurrent. The final chapters show how geometric properties of the graph can be used to establish heat kernel bounds, that is, bounds on the transition probabilities of the random walk, and it is proved that Gaussian bounds hold for graphs that are roughly isometric to Euclidean space. Aimed at graduate students in mathematics, the book is also useful for researchers as a reference for results that are hard to find elsewhere.
This Brief describes six basic models of buoyancy-driven convection in a fluid layer: three configurations of internally heated convection and three configurations of Rayleigh-Benard convection. The author discusses the main quantities that characterize heat transport in each model, along with the constraints on these quantities. This presentation is the first to place the various models in a unified framework, and similarities and differences between the cases are highlighted. Necessary and sufficient conditions for convective motion are given. For the internally heated cases only, parameter-dependent lower bounds on the mean fluid temperature are proven, and results of past simulations and laboratory experiments are summarized and reanalyzed. The author poses several open questions for future study.
Combustion is a fascinating phenomenon coupling complex chemistry to transport mechanisms and nonlinear fluid dynamics. This book provides an up-to-date and comprehensive presentation of the nonlinear dynamics of combustion waves and other non-equilibrium energetic systems. The major advances in this field have resulted from analytical studies of simplified models performed in close relation with carefully controlled laboratory experiments. The key to understanding the complex phenomena is a systematic reduction of the complexity of the basic equations. Focusing on this fundamental approach, the book is split into three parts. Part I provides physical insights for physics-oriented readers, Part II presents detailed technical analysis using perturbation methods for theoreticians, and Part III recalls the necessary background knowledge in physics, chemistry and fluid dynamics. This structure makes the content accessible to newcomers to the physics of unstable fronts in flows, whilst also offering advanced material for scientists who wish to improve their knowledge.
Rich with examples and applications, this textbook provides a coherent and self-contained introduction to ergodic theory, suitable for a variety of one- or two-semester courses. The authors' clear and fluent exposition helps the reader to grasp quickly the most important ideas of the theory, and their use of concrete examples illustrates these ideas and puts the results into perspective. The book requires few prerequisites, with background material supplied in the appendix. The first four chapters cover elementary material suitable for undergraduate students - invariance, recurrence and ergodicity - as well as some of the main examples. The authors then gradually build up to more sophisticated topics, including correlations, equivalent systems, entropy, the variational principle and thermodynamical formalism. The 400 exercises increase in difficulty through the text and test the reader's understanding of the whole theory. Hints and solutions are provided at the end of the book.
This book reflects the resurgence of interest in the quantum properties of black holes, culminating most recently in controversial discussions about firewalls. On the thermodynamic side, it describes how new developments allowed the inclusion of pressure/volume terms in the first law, leading to a new understanding of black holes as chemical systems, experiencing novel phenomena such as triple points and reentrant phase transitions. On the quantum-information side, the reader learns how basic arguments undergirding quantum complementarity have been shown to be flawed; and how this suggests that a black hole may surround itself with a firewall: a violent and chaotic region of highly excited states. In this thorough and pedagogical treatment, Robert Mann traces these new developments from their roots to our present-day understanding, highlighting their relationships and the challenges they present for quantum gravity.
Learn classical thermodynamics alongside statistical mechanics with this fresh approach to the subjects. Molecular and macroscopic principles are explained in an integrated, side-by-side manner to give students a deep, intuitive understanding of thermodynamics and equip them to tackle future research topics that focus on the nanoscale. Entropy is introduced from the get-go, providing a clear explanation of how the classical laws connect to the molecular principles, and closing the gap between the atomic world and thermodynamics. Notation is streamlined throughout, with a focus on general concepts and simple models, for building basic physical intuition and gaining confidence in problem analysis and model development. Well over 400 guided end-of-chapter problems are included, addressing conceptual, fundamental, and applied skill sets. Numerous worked examples are also provided together with handy shaded boxes to emphasize key concepts, making this the complete teaching package for students in chemical engineering and the chemical sciences.
This second edition of the important introductory text for earth scientists has been thoroughly revised and extended. It is required reading for all those interested in learning about the quantitative description of geological problems. It contains chapters on heat flow, sedimentary basin modeling, the mechanics of continental deformation, PT path modeling, geomorphology, mass transfer and more. The book is aimed at the field oriented geologist who wants to begin by learning about the quantitative description of problems. The new edition features yet more illustrations and maps as well as almost 100 corrections of scientific problems.
A tubular heat exchanger exemplifies many aspects of the challenge in designing a pressure vessel. High or very low operating pressures and temperatures, combined with sharp temperature gradients, and large differences in the stiffnesses of adjoining parts, are amongst the legion of conditions that behoove the attention of the heat exchanger designer. Pitfalls in mechanical design may lead to a variety of operational problems, such as tube-to-tubesheet joint failure, flanged joint leakage, weld cracks, tube buckling, and flow induced vibration. Internal failures, such as pass partition bowing or weld rip-out, pass partition gasket rib blow-out, and impingement actuated tube end erosion are no less menacing. Designing to avoid such operational perils requires a thorough grounding in several disciplines of mechanics, and a broad understanding of the inter relationship between the thermal and mechanical performance of heat exchangers. Yet, while there are a number of excellent books on heat ex changer thermal design, comparable effort in mechanical design has been non-existent. This apparent void has been filled by an assortment of national codes and industry standards, notably the "ASME Boiler and Pressure Vessel Code" and the "Standards of Tubular Exchanger Manufacturers Association. " These documents, in conjunction with scattered publications, form the motley compendia of the heat exchanger designer's reference source. The subject matter clearly beckons a methodical and comprehensive treatment. This book is directed towards meeting this need.
Written by distinguished physics educator David Goodstein, this fresh introduction to thermodynamics, statistical mechanics, and the study of matter is ideal for undergraduate courses. The textbook looks at the behavior of thermodynamic variables and examines partial derivatives - the essential language of thermodynamics. It also explores states of matter and the phase transitions between them, the ideal gas equation, and the behavior of the atmosphere. The origin and meaning of the laws of thermodynamics are then discussed, together with Carnot engines and refrigerators, and the notion of reversibility. Later chapters cover the partition function, the density of states, and energy functions, as well as more advanced topics such as the interactions between particles and equations for the states of gases of varying densities. Favoring intuitive and qualitative descriptions over exhaustive mathematical derivations, the textbook uses numerous problems and worked examples to help readers get to grips with the subject.
The Scottish mathematician and natural philosopher Sir John Leslie (1766-1832) had set out at the end of the eighteenth century to explore the nature of heat radiation, which he felt was a 'dubious and neglected' area of physics. Leslie's inquiry, published in 1804, details his many experiments, notably the use of two self-devised instruments: Leslie's cube and his differential thermometer. Establishing several basic laws of heat radiation and rejuvenating the debate about the physical composition of heat, Leslie's work gained him the Rumford medal of the Royal Society in 1805. Nevertheless, the same publication jeopardised his chances of obtaining an academic position at Edinburgh. A single, allegedly atheistic endnote, supporting David Hume's views on causation, prompted protests by the local clergymen when his candidature for the chair of mathematics was under consideration. Leslie secured the professorship, however, and remained with the university until his death.
Originally published in 1936 as the second instalment of McKenzie's School Certificate series, this book explains the physical properties of heat. The text is accompanied by multiple photographs, drawings and diagrams to illustrate key points, and every chapter concludes with several questions for students to reinforce the chapter content. This book will be of value to anyone with an interest in the history of science education in Britain.
In this book the author presents selected challenges of thermal-hydraulics modeling of two-phase flows in minichannels with change of phase. These encompass the common modeling of flow boiling and flow condensation using the same expression. Approaches to model these two respective cases show, however, that experimental data show different results to those obtained by methods of calculation of heat transfer coefficient for respective cases. Partially that can be devoted to the fact that there are non-adiabatic effects present in both types of phase change phenomena which modify the pressure drop due to friction, responsible for appropriate modelling. The modification of interface shear stresses between flow boiling and flow condensation in case of annular flow structure may be considered through incorporation of the so called blowing parameter, which differentiates between these two modes of heat transfer. On the other hand, in case of bubbly flows, the generation of bubbles also modifies the friction pressure drop by the influence of heat flux. Presented are also the results of a peculiar M-shape distribution of heat transfer coefficient specific to flow boiling in minichannels. Finally, some attention is devoted to mathematical modeling of dryout phenomena. A five equation model enabling determination of the dryout location is presented, where the mass balance equations for liquid film, droplets and gas are supplemented by momentum equations for liquid film and two-phase core.
Superconductors have been known about since the turn ofthe century. Recently there has been a renewed interest with the discovery of the new, high-Tc materials since 1986 1]. These compounds become superconducting at much warmer temperatures than any pre viously known. In fact, many of tthem superconduct at temperatures above the boiling point of liquid nitrogen, making the observation of the transition both accessible and inexpensive. It was obvious immediately that these materials could have a tremendous technological impact, or lead to further materials with even higher transitions. For this reason there has been an intense effort by scientists in both academia and industry to study these materials. The scientificand industrial communitieshope to learn what makes these materials work. For, learning how these materials work not only increases mankind's overall knowledge of his world, but could make some person or company quite successful if the information were used and developed correctly."
First published in 1901, and originally delivered as lectures in the Philosophical Hall in Leeds earlier that year, this book discusses the practical and historical problems faced by those wishing to measure heat energy. Griffiths, who dealt with the problem extensively during his career, gives a brief historical survey of this problem and details various experiments performed by scientists such as Joule, Rowland and Regnault, as well as the application of such findings in both a scientific and industrial setting. This book will be of value to anyone with an interest in the history of science and scientific education.
This book introduces the detonation phenomenon in explosives. It is ideal for engineers and graduate students with a background in thermodynamics and fluid mechanics. The material is mostly qualitative, aiming to illustrate the physical aspects of the phenomenon. Classical idealized theories of detonation waves are presented first. These permit detonation speed, gas properties ahead of and behind the detonation wave, and the distribution of fluid properties within the detonation wave itself to be determined. Subsequent chapters describe in detail the real unstable structure of a detonation wave. One-, two-, and three-dimensional computer simulations are presented along with experimental results using various experimental techniques. The important effects of confinement and boundary conditions and their influence on the propagation of a detonation are also discussed. The final chapters cover the various ways detonation waves can be formed and provide a review of the outstanding problems and future directions in detonation research.
This book is a unique, multidisciplinary effort to apply rigorous thermodynamics fundamentals, a disciplined scholarly approach, to problems of sustainability, energy, and resource uses. Applying thermodynamic thinking to problems of sustainable behavior is a significant advantage in bringing order to ill-defined questions with a great variety of proposed solutions, some of which are more destructive than the original problem. The articles are pitched at a level accessible to advanced undergraduates and graduate students in courses on sustainability, sustainable engineering, industrial ecology, sustainable manufacturing, and green engineering. The timeliness of the topic, and the urgent need for solutions make this book attractive to general readers and specialist researchers as well. Top international figures from many disciplines, including engineers, ecologists, economists, physicists, chemists, policy experts and industrial ecologists among others make up the impressive list of contributors.
The Mechanics and Thermodynamics of Continua presents a unified treatment of continuum mechanics and thermodynamics that emphasises the universal status of the basic balances and the entropy imbalance. These laws are viewed as fundamental building blocks on which to frame theories of material behaviour. As a valuable reference source, this book presents a detailed and complete treatment of continuum mechanics and thermodynamics for graduates and advanced undergraduates in engineering, physics and mathematics. The chapters on plasticity discuss the standard isotropic theories and, in addition, crystal plasticity and gradient plasticity.
First published in 1927 as the second edition of a 1925 original, this book was intended as a general introduction to the principles of thermodynamics for university students involved in the physical sciences. Birtwistle gives a brief overview of the history of science relating to heat and the conservation of energy as well as practical examples to back up salient points in his explanation of key ideas. This book will be of value to anyone with an interest in the history of science.
Striving to explore the subject in as simple a manner as possible, this book helps readers understand the elusive concept of entropy. Innovative aspects of the book include the construction of statistical entropy from desired properties, the derivation of the entropy of classical systems from purely classical assumptions, and a statistical thermodynamics approach to the ideal Fermi and ideal Bose gases. Derivations are worked through step-by-step and important applications are highlighted in over 20 worked examples. Around 50 end-of-chapter exercises test readers' understanding. The book also features a glossary giving definitions for all essential terms, a time line showing important developments, and list of books for further study. It is an ideal supplement to undergraduate courses in physics, engineering, chemistry and mathematics.
Twentyfour years have gone by since the publication of K. Lohner and H. MOiler's comprehen sive work "Gemischbildung und Verbrennung im Ottomotor" in 1967 1.1]. Naturally, the field of mixture formation and combustion in the spark-ignition engine has wit nessed great technological advances and many new findings in the intervening years, so that the time seemed ripe for presenting a summary of recent research and developments. There fore, I gladly took up the suggestion of the editors of this series of books, Professor Dr. H. List and Professor Dr. A. Pischinger, to write a book summarizing the present state of the art. A center of activity of the Institute of Internal-Combustion Engines and Automotive Engineering at the Vienna Technical University, which I am heading, is the field of mixture formation -there fore, many new results that have been achieved in this area in collaboration with the respective industry have been included in this volume. The basic principles of combustion are discussed only to that extent which seemed necessary for an understanding of the effects of mixture formation. The focal point of this volume is the mixture formation in spark-ignition engines, covering both the theory and actual design of the mixture formation units and appropriate intake manifolds. Also, the related measurement technology is explained in this work."
Given that thermodynamics books are not a rarity on the market, why would an additional one be useful? The answer is simple: at any level, thermodynamics is usually taught as a somewhat abstruse discipline where many students get lost in a maze of difficult concepts. However, thermodynamics is not as intricate a subject as most people feel. This book fills a niche between elementary textbooks and mathematically oriented treatises, and provides readers with a distinct approach to the subject. As indicated by the title, this book explains thermodynamic phenomena and concepts in physical terms before proceeding to focus on the requisite mathematical aspects. It focuses on the effects of pressure, temperature and chemical composition on thermodynamic properties and places emphasis on rapidly evolving fields such as amorphous materials, metastable phases, numerical simulations of microsystems and high-pressure thermodynamics. Topics like redox reactions are dealt with in less depth, due to the fact that there is already much literature available. Without requiring a background in quantum mechanics, this book also illustrates the main practical applications of statistical thermodynamics and gives a microscopic interpretation of temperature, pressure and entropy. This book is perfect for undergraduate and graduate students who already have a basic knowledge of thermodynamics and who wish to truly understand the subject and put it in a broader physical perspective. The book is aimed not at theoretical physicists, but rather at practitioners with a variety of backgrounds from physics to biochemistry for whom thermodynamics is a tool which would be better used if better understood.
This undergraduate textbook provides a statistical mechanical foundation to the classical laws of thermodynamics via a comprehensive treatment of the basics of classical thermodynamics, equilibrium statistical mechanics, irreversible thermodynamics, and the statistical mechanics of non-equilibrium phenomena.This timely book has a unique focus on the concept of entropy, which is studied starting from the well-known ideal gas law, employing various thermodynamic processes, example systems and interpretations to expose its role in the second law of thermodynamics. This modern treatment of statistical physics includes studies of neutron stars, superconductivity and the recently developed fluctuation theorems. It also presents figures and problems in a clear and concise way, aiding the student's understanding.
An understanding of statistical thermodynamic molecular theory is fundamental to the appreciation of molecular solutions. This complex subject has been simplified by the authors with down-to-earth presentations of molecular theory. Using the potential distribution theorem (PDT) as the basis, the text provides a discussion of practical theories in conjunction with simulation results. The authors discuss the field in a concise and simple manner, illustrating the text with useful models of solution thermodynamics and numerous exercises. Modern quasi-chemical theories that permit statistical thermodynamic properties to be studied on the basis of electronic structure calculations are given extended development, as is the testing of those theoretical results with ab initio molecular dynamics simulations. The book is intended for students taking up research problems of molecular science in chemistry, chemical engineering, biochemistry, pharmaceutical chemistry, nanotechnology and biotechnology. |
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