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Books > Science & Mathematics > Physics > Thermodynamics & statistical physics > Thermodynamics
This book covers aspects of multiphase flow and heat transfer during phase change processes, focusing on boiling and condensation in microscale channels. The authors present up-to-date predictive methods for flow pattern, void fraction, pressure drop, heat transfer coefficient and critical heat flux, pointing out the range of operational conditions that each method is valid. The first four chapters are dedicated on the motivation to study multiphase flow and heat transfer during phase change process, and the three last chapters are focused on the analysis of heat transfer process during boiling and condensation. During the description of the models and predictive methods, the trends are discussed and compared with experimental findings.
Capitalism is under attack. Defenders say that capitalism has raised billions of people from poverty. But a central activity of capitalism today, Wall Street style, is speculation (gambling), using other people's money, and privatizing the profits while socializing the debts. Skeptics argue that capitalism has redistributed the wealth of the planet in favor of a very few, meanwhile leaving the planet in bad shape and leaving billions of people out in the cold. Wealth is now extremely mal-distributed, opportunity is far from equal, and upward social mobility has declined significantly in recent decades. This book reviews the evidence and arguments pro and con in considerable detail. The evidence is mixed. The main virtue of capitalism is its emphasis on competition as a driver of innovation and, thus, of economic growth. It is true that economic growth has accelerated in recent centuries, and it is true that billions of people have been lifted from poverty. But it is not necessarily true that intense "winner take all" competition in the marketplace is the explanation for growth. Neoclassical economic theory posits that self-interest is the primary motive for all economic decisions, leaving little room for cooperation and even less for altruism. The theory applies to an unrealistic "model" of human behavior, known as Homo economicus or "economic man", whose characteristic activity is buying or selling. The reason for using the adjective word "social" - as in socialism" or "social service" or "social democracy" -- is, essentially, to deny those postulates of standard economic theory. Real humans are not rational utility maximizers (whatever that is) and very often do things that are not in their own personal best interests. This can happen because other interests, such as family loyalty, professional, religious, or patriotic duty, may take precedence. Real people rarely behave like Homo economicus, who has rivals but no friends. He (or she) does not trust anyone, hence cannot cooperate with others, and can never create, or live in, a viable social system (or marriage). Yet social systems, ranging from families and tribes to firms, cities, and nations do (and must) exist or civilization cannot exist. A viable social system must not allow "winner takes all". It must reallocate some of the societal wealth being created by competitive activities to support the young, the old and the weak, because all of those people have equal rights, if not the same luck or the same skills. Both competition and cooperation have important roles to play. A hybrid capitalism involving both is the only viable solution. The book ends with a specific suggestion, namely Universal Basic Income, or UBI.
This monograph focuses on the science of combustion, exploring its technological, social, and philosophical aspects. Presented here is a systematic overview of the field, with up-to-date treatments of topics of central importance: diffusion flames, deflagrations, detonations, flammability, and explosions. Special emphasis is given to turbulent combustion so that the many different approaches to this multifaceted subject can be exposed and categorized in a systematic manner. The author offers his projections for future developments, including identification of outstanding research areas. This book is a concise and penetrating overview of the field of combustion history and research, and will be of interest to motivated non-specialists interested in more than a facile exploration of the subject.
This textbook provides comprehensive information on general and statistical thermodynamics. It begins with an introductory statistical mechanics course, deriving all the important formulae meticulously and explicitly, without mathematical shortcuts. In turn, the main part of the book focuses on in-depth discussions of the concepts and laws of thermodynamics, van der Waals, Kelvin and Claudius theories, ideal and real gases, thermodynamic potentials, phonons and all related aspects. To elucidate the concepts introduced and to provide practical problem-solving support, numerous carefully worked-out examples are included. The text is clearly written and punctuated with a number of interesting anecdotes. The book also provides alternative solutions to problems and second equivalent explanations of important physical concepts. This second edition has been expanded to cover the foundations of superconductivity with new chapters on Cooper pairs, the Bogoliubov transformation, and superconductivity. It is suitable as a main thermodynamics textbook for upper-undergraduate students and provides extensive coverage, allowing instructors to 'pick and choose' the elements that best match their class profile.
This book describes various forms of solar energy conversion techniques in a unified way. The physical framework used to describe the various conversions is endoreversible thermodynamics, a recently developed subset of irreversible thermodynamics . It thus studies situations which are not in equilibrium and in which therefore entropy is continuously created. Nevertheless the mathematics is simple, because the authors consider only stationary situations. Most undergraduate textbooks on thermodynamics emphasize equilibrium thermodynamics and reversible processes. No entropy is created and conversion efficiencies are maximal, equal to the Carnot efficiency. For irreversible conversion processes, the reader learns only that entropy production is positive and that conversion efficiency is lower than the Carnot efficiency. But how great the entropy creation is, and how low the efficiency, is usually not expressed. Endoreversible thermodynamics gives the opportunity to calculate explicit values for a broad class of these processes, including solar energy conversion, which is particularly suited to being described in this way. The book is intended for physicists and engineers interested in renewable energy and irreversible thermodynamics.
"an impressive text that addresses a glaring gap in the teaching of physical chemistry, being specifically focused on biologically-relevant systems along with a practical focus.... the ample problems and tutorials throughout are much appreciated." -Tobin R. Sosnick, Professor and Chair of Biochemistry and Molecular Biology, University of Chicago "Presents both the concepts and equations associated with statistical thermodynamics in a unique way that is at visual, intuitive, and rigorous. This approach will greatly benefit students at all levels." -Vijay S. Pande, Henry Dreyfus Professor of Chemistry, Stanford University "a masterful tour de force.... Barrick's rigor and scholarship come through in every chapter." -Rohit V. Pappu, Edwin H. Murty Professor of Engineering, Washington University in St. Louis This book provides a comprehensive, contemporary introduction to developing a quantitative understanding of how biological macromolecules behave using classical and statistical thermodynamics. The author focuses on practical skills needed to apply the underlying equations in real life examples. The text develops mechanistic models, showing how they connect to thermodynamic observables, presenting simulations of thermodynamic behavior, and analyzing experimental data. The reader is presented with plenty of exercises and problems to facilitate hands-on learning through mathematical simulation. Douglas E. Barrick is a professor in the Department of Biophysics at Johns Hopkins University. He earned his Ph.D. in biochemistry from Stanford University, and a Ph.D. in biophysics and structural biology from the University of Oregon.
This textbook concerns thermal properties of bulk matter and is aimed at advanced undergraduate or first-year graduate students in a range of programs in science or engineering. It provides an intermediate level presentation of statistical thermodynamics for students in the physical sciences (chemistry, nanosciences, physics) or related areas of applied science/engineering (chemical engineering, materials science, nanotechnology engineering), as they are areas in which statistical mechanical concepts play important roles. The book enables students to utilize microscopic concepts to achieve a better understanding of macroscopic phenomena and to be able to apply these concepts to the types of sub-macroscopic systems encountered in areas of nanoscience and nanotechnology.
Nobel laureate's brilliant attempt to develop a simple, unified standard method of dealing with all cases of statistical thermodynamics (classical, quantum, Bose-Einstein, Fermi-Dirac, etc.). Discussions of Nernst theorem, Planck's oscillator, fluctuations, the n-particle problem, problem of radiation, much more.
This book is intended to serve as a textbook for advanced undergraduate and graduate students as well as professionals engaged in application of thermo-fluid science to the study of combustion. The relevant thermo-chemistry and thermo-physical data required for this study are provided in the 6 appendices along with appropriate curve-fit coefficients. To facilitate gradual learning, two chapters are devoted to thermodynamics of pure and gaseous mixture substances, followed by one chapter each on chemical equilibrium and chemical kinetics. This material when coupled with a dedicated chapter on understanding of equations governing transport of momentum, heat and mass in the presence of chemical reactions provides adequate grounding to undertake analysis of practical combustion equipment, of premixed and diffusion flames as well as of solid particle and liquid droplet combustion. The learnings from the aforementioned chapters are taken to a uniquely strong chapter on application case studies, some of which have special relevance for developing countries.
The theory of thermodynamics has been one of the bedrocks of 19th-century physics, and thermodynamic problems have inspired Planck's quantum hypothesis. One hundred years later, in an era where we design increasingly sophisticated nanotechnologies, researchers in quantum physics have been 'returning to their roots', attempting to reconcile modern nanoscale devices with the theory of thermodynamics. This textbook explains how it is possible to unify the two opposite pictures of microscopic quantum physics and macroscopic thermodynamics in one consistent framework, proving that the ancient theory of thermodynamics still offers many remarkable insights into present-day problems. This textbook focuses on the microscopic derivation and understanding of key principles and concepts and their interrelation. The topics covered in this book include (quantum) stochastic processes, (quantum) master equations, local detailed balance, classical stochastic thermodynamics, (quantum) fluctuation theorems, strong coupling and non-Markovian effects, thermodynamic uncertainty relations, operational approaches, Maxwell's demon, and time-reversal symmetry, among other topics. The textbook also explores several practical applications of the theory in more detail, including single-molecule pulling experiments, quantum transport and thermoelectric effects in quantum dots, the micromaser, and related setups in quantum optics. The aim of this book is to inspire readers to investigate a plethora of modern nanoscale devices from a thermodynamic point of view, allowing them to address their dissipation, efficiency, reliability, and power based on a conceptually clear understanding about the microscopic origin of heat, entropy, and the second law. The book is accessible to graduate students, post-docs, and lecturers, but will also be of interest to all researchers striving for a deeper understanding of the laws of thermodynamics beyond their traditional realm of applicability.
This book focuses on theoretical thermotics, the theory of transformation thermotics and its extended theories for the active control of macroscopic thermal phenomena of artificial systems, which is in sharp contrast to classical thermodynamics comprising the four thermodynamic laws for the passive description of macroscopic thermal phenomena of natural systems. The book covers the basic concepts and mathematical methods, which are necessary to understand thermal problems extensively investigated in physics, but also in other disciplines of engineering and materials. The analyses rely on models solved by analytical techniques accompanied with computer simulations and laboratory experiments. This book serves both as a reference work for senior researchers and a study text for zero beginners.
This book is the second edition of Numerical methods for diffusion phenomena in building physics: a practical introduction originally published by PUCPRESS (2016). It intends to stimulate research in simulation of diffusion problems in building physics, by providing an overview of mathematical models and numerical techniques such as the finite difference and finite-element methods traditionally used in building simulation tools. Nonconventional methods such as reduced order models, boundary integral approaches and spectral methods are presented, which might be considered in the next generation of building-energy-simulation tools. In this reviewed edition, an innovative way to simulate energy and hydrothermal performance are presented, bringing some light on innovative approaches in the field.
This book offers a comprehensive overview of thermodynamics. It is divided into four parts, the first of which equips readers with a deeper understanding of the fundamental principles of thermodynamics of equilibrium states and of their evolution. The second part applies these principles to a series of generalized situations, presenting applications that are of interest both in their own right and in terms of demonstrating how thermodynamics, as a theory of principle, relates to different fields. In turn, the third part focuses on non-equilibrium configurations and the dynamics of natural processes. It discusses both discontinuous and continuous systems, highlighting the interference among non-equilibrium processes, and the nature of stationary states and of fluctuations in isolated systems. Lastly, part four introduces the relation between physics and information theory, which constitutes a new frontier in fundamental research. The book includes step-by-step exercises, with solutions, to help readers to gain a fuller understanding of the subjects, and also features a series of appendices providing useful mathematical formulae. Reflecting the content of modern university courses on thermodynamics, it is a valuable resource for students and young scientists in the fields of physics, chemistry, and engineering.
This thesis presents several related advances in the field of nonequilibrium quantum thermodynamics. The central result is an ingenious proof that the local temperature and voltage measurement in a nonequilibrium system of fermions exists and is unique, placing the concept of local temperature on a rigorous mathematical footing for the first time. As an intermediate step, a proof of the positivity of the Onsager matrix of linear response theory is given -- a statement of the second law of thermodynamics that had lacked an independent proof for 85 years. A new experimental method to measure the local temperature of an electron system using purely electrical techniques is also proposed, which could enable improvements to the spatial resolution of thermometry by several orders of magnitude. Finally, a new mathematically-exact definition for the local entropy of a quantum system in a nonequilibrium steady state is derived. Several different measures of the local entropy are discussed, relating to the thermodynamics of processes that a local observer with varying degrees of information about the microstates of the system could carry out, and it is shown that they satisfy a hierarchy of inequalities. Proofs of the third law of thermodynamics for generic open quantum systems are presented, taking into account the entropic contribution due to localized states. Appropriately normalized (per-state) local entropies are defined and are used to quantify the departure from local equilibrium.
This is the second edition of a well-received book. It provides an up-to-date, concise review of essential topics in the physics of matter, from atoms and molecules to solids, including elements of statistical mechanics. It features over 160 completely revised and enhanced figures illustrating the main physical concepts and the fundamental experimental facts, and discusses selected experiments, mainly in spectroscopy and thermodynamics, within the general framework of the adiabatic separation of the motions of electrons and nuclei. The book focuses on what can be described in terms of independent-particle models, providing the mathematical derivations in sufficient detail for readers to grasp the relevant physics involved. The final section offers a glimpse of more advanced topics, including magnetism and superconductivity, sparking readers' curiosity to further explore the latest developments in the physics of matter.
Kompakt und verstandlich fuhrt dieses Lehrbuch in die Grundlagen der theoretischen Physik ein. Dabei werden die ublichen Themen der Grundvorlesungen Mechanik, Elektrodynamik, Relativitatstheorie, Quantenmechanik , Thermodynamik und Statistik in einem Band zusammengefasst, um den Zusammenhang zwischen den einzelnen Teilgebieten besonders zu betonen. Ein Kapitel mit mathematischen Grundlagen der Physik erleichtert den Einstieg. Zahlreiche UEbungsaufgaben dienen der Vertiefung des Stoffes.
This textbook is an introduction to the Brownian motion of colloids and nano-particles, and the diffusion of molecules. One very appealing aspect of Brownian motion, as this book illustrates, is that the subject connects a broad variety of topics, including thermal physics, hydrodynamics, reaction kinetics, fluctuation phenomena, statistical thermodynamics, osmosis and colloid science. The book is based on a set of lecture notes that the authors used for an undergraduate course at the University of Utrecht, Netherland. It aims to provide more than a simplified qualitative description of the subject, without getting bogged down in difficult mathematics. Each chapter contains exercises, ranging from straightforward ones to more involved problems, addressing instances from (thermal motion in) chemistry, physics and life sciences. Exercises also deal with derivations or calculations that are skipped in the main text. The book offers a treatment of Brownian motion on a level appropriate for bachelor/undergraduate students of physics, chemistry, soft matter and the life sciences. PhD students attending courses and doing research in colloid science or soft matter will also benefit from this book.
Clearly written treament elucidates fundamental concepts and demonstrates their plausibility and usefulness. Language is informal, examples are vivid and lively, and the perspectivie is fresh. Based on lectures delivered to engineering students, this work will also be valued by scientists, engineers, technicians, businessmen, anyone facing energy challenges of the future.
This book comprises select proceedings of the International Conference on Future Learning Aspects of Mechanical Engineering (FLAME 2018). The book gives an overview of recent developments in the field of thermal and fluid engineering, and covers theoretical and experimental fluid dynamics, numerical methods in heat transfer and fluid mechanics, different modes of heat transfer, multiphase transport and phase change, fluid machinery, turbo machinery, and fluid power. The book is primarily intended for researchers and professionals working in the field of fluid dynamics and thermal engineering.
This book presents a new view of the mechanism of functional expression of ATP-driven motors (proteins or protein complexes). It is substantially different from the prevailing idea that the motor converts chemical energy to mechanical work. To facilitate understanding, the differences between the new and prevailing views are explained using many illustrations. The book is of interest to those who are not convinced of the notion of chemo-mechanical coupling. The claims presented are the following: The system, which comprises not only the motor but also water, does no mechanical work during the ATP hydrolysis cycle; a protein is moved or a protein in the complex is rotated by the entropic force generated by water. The highlight of the explanation in the book is that the mechanism of unidirectional rotation of the central shaft in F1-ATPase is discussed in detail on the basis of this new view. The hydration entropy of each subunit to which a specific chemical compound (ATP, ADP and Pi, Pi, or nothing) is bound, the hydration entropy of the 3 3 complex, and the dependence of the hydration entropy of F1-ATPase on the orientation of the subunit play essential roles.
In this book fluid mechanics and thermodynamics (F&T) are approached as interwoven, not disjoint fields. The book starts by analyzing the creeping motion around spheres at rest: Stokes flows, the Oseen correction and the Lagerstrom-Kaplun expansion theories are presented, as is the homotopy analysis. 3D creeping flows and rapid granular avalanches are treated in the context of the shallow flow approximation, and it is demonstrated that uniqueness and stability deliver a natural transition to turbulence modeling at the zero, first order closure level. The difference-quotient turbulence model (DQTM) closure scheme reveals the importance of the turbulent closure schemes' non-locality effects. Thermodynamics is presented in the form of the first and second laws, and irreversibility is expressed in terms of an entropy balance. Explicit expressions for constitutive postulates are in conformity with the dissipation inequality. Gas dynamics offer a first application of combined F&T. The book is rounded out by a chapter on dimensional analysis, similitude, and physical experiments.
All technologies depend on the availability of suitable materials. The progress of civilisation is often measured by the materials people have used, from the stone age to the silicon age. Engineers exploit the relationships between the structure, properties and manufacturing methods of a material to optimise their design and production for particular applications. Scientists seek to understand and predict those relationships. This short book sets out fundamental concepts that underpin the science of materials and emphasizes their relevance to mainstream chemistry, physics and biology. These include the thermodynamic stability of materials in various environments, quantum behaviour governing all matter, and active matter. Others include defects as the agents of change in crystalline materials, materials at the nanoscale, the emergence of new science at increasing length scales in materials, and man-made materials with properties determined by their structure rather than their chemistry. The book provides a unique insight into the essence of materials science at a level suitable for pre-university students and undergraduates of materials science. It will also be suitable for graduates in other subjects contemplating postgraduate study in materials science. Professional materials scientists will also find it stimulating and occasionally provocative.
Understand multiphase flows using multidisciplinary knowledge in physical principles, modelling theories, and engineering practices. This essential text methodically introduces the important concepts, governing mechanisms, and state-of-the-art theories, using numerous real-world applications, examples, and problems. Covers all major types of multiphase flows, including gas-solid, gas-liquid (sprays or bubbling), liquid-solid, and gas-solid-liquid flows. Introduces the volume-time-averaged transport theorems and associated Lagrangian-trajectory modelling and Eulerian-Eulerian multi-fluid modelling. Explains typical computational techniques, measurement methods and four representative subjects of multiphase flow systems. Suitable as a reference for engineering students, researchers, and practitioners, this text explores and applies fundamental theories to the analysis of system performance using a case-based approach.
In a comprehensive treatment of Statistical Mechanics from thermodynamics through the renormalization group, this book serves as the core text for a full-year graduate course in statistical mechanics at either the Masters or Ph.D. level. Each chapter contains numerous exercises, and several chapters treat special topics which can be used as the basis for student projects. The concept of scaling is introduced early and used extensively throughout the text. At the heart of the book is an extensive treatment of mean field theory, from the simplest decoupling approach, through the density matrix formalism, to self-consistent classical and quantum field theory as well as exact solutions on the Cayley tree. Proceeding beyond mean field theory, the book discusses exact mappings involving Potts models, percolation, self-avoiding walks and quenched randomness, connecting various athermal and thermal models. Computational methods such as series expansions and Monte Carlo simulations are discussed, along with exact solutions to the 1D quantum and 2D classical Ising models. The renormalization group formalism is developed, starting from real-space RG and proceeding through a detailed treatment of Wilson's epsilon expansion. Finally the subject of Kosterlitz-Thouless systems is introduced from a historical perspective and then treated by methods due to Anderson, Kosterlitz, Thouless and Young. Altogether, this comprehensive, up-to-date, and engaging text offers an ideal package for advanced undergraduate or graduate courses or for use in self study. |
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