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Books > Science & Mathematics > Physics > Thermodynamics & statistical physics > Thermodynamics
This book presents the basic elements of theoretical physics in a highly accessible, captivating way for university students in the third year of a degree in physics. It covers analytical mechanics, thermodynamics and statistical physics, special and general relativity and non-relativistic quantum theory, fully developing the necessary mathematical methods beyond standard calculus. The central theme is scientific curiosity and the main focus is on the experimental meaning of all quantities and equations. Several recent verifications of General Relativity are presented, with emphasis on the physical effects - why they were predicted to exist and what signals they were seen to produce. Similarly, the basic reasons why superconductors have zero resistance and are perfect diamagnets are pinpointed. Quantum Eraser Experiments and Delayed Choice Experiments are described. Many statements of Quantum Theory are a challenge to common sense and some crucial predictions have often been considered hard to believe and have been tested experimentally. The book examines the EPR paradox, Bell states and teleportation. To show the beauty and richness of the subject, various topics from different areas of Physics are covered. These include: discrete quantum models and lattices (periodic and not), Casimir effect, Anyons, Fano Resonances, the Hanbury Brown and Twiss effect, the Aharonov-Bohm effect, the Meitner-Auger effect, Squeezed Light, the Rabi model, neutrino oscillations, aspects of Quantum Transport, Quantum Pumping, and Berry phases, black holes and cosmological problems.
This thesis presents pioneering experimental and numerical studies on three aspects of the combustion characteristics of lean premixed syngas/air flames, namely the laminar flame speed, extinction limit and flammability limit. It illustrates a new extinction exponent concept, which enriches the combustion theory. Above all, the book provides the following: a) a series of carefully measured data and theoretical analyses to reveal the intrinsic mechanisms of the fuel composition effect on the propagation and extinction of lean syngas/air flames; b) a mixing model and correlation to predict the laminar flame speed of multi-component syngas fuels, intended for engineering computations; c) a new "extinction exponent" concept to describe the critical effects of chemical kinetics on the extinction of lean premixed syngas/air flames; and d) the effects and mechanism of the dilution of incombustible components on lean premixed syngas/air flames and the preferential importance among the thermal, chemical and diffusion effects.
This thesis investigates the combustion chemistry of cyclohexane, methylcyclohexane, and ethylcyclohexane on the basis of state-of-the-art synchrotron radiation photoionization mass spectrometry experiments, quantum chemistry calculations, and extensive kinetic modeling. It explores the initial decomposition mechanism and distribution of the intermediates, proposes a novel formation mechanism of aromatics, and develops a detailed kinetic model to predict the three cycloalkanes' combustion properties under a wide range of conditions. Accordingly, the thesis provides an essential basis for studying much more complex cycloalkanes in transport fuels and has applications in engine and fuel design, as well as emission control.
This book introduces and discusses both the fundamental aspects and the measurability of applications of time-symmetric kinetic quantities, outlining the features that constitute the non-dissipative branch of non-equilibrium physics. These specific features of non-equilibrium dynamics have largely been ignored in standard statistical mechanics texts. This introductory-level book offers novel material that does not take the traditional line of extending standard thermodynamics to the irreversible domain. It shows that although stationary dissipation is essentially equivalent with steady non-equilibrium and ubiquitous in complex phenomena, non-equilibrium is not determined solely by the time-antisymmetric sector of energy-entropy considerations. While this should not be very surprising, this book provides timely, simple reminders of the role of time-symmetric and kinetic aspects in the construction of non-equilibrium statistical mechanics.
This book discusses the thermal-elastic mechanics problems of concrete rectangular thin plate. Using theoretical derivation combined with numerical examples, it explains in detail the analytical solution of the deflection, bending moment, thermal vibration and thermal buckling of concrete rectangular thin plate. To facilitate application, the book also includes deflection and bending moment calculation tables of concrete rectangular thin plate with four edges supported and with free boundary conditions.
This is a book about thermodynamics, not history, but it adopts a semi-historical approach in order to highlight different approaches to entropy. The book does not follow a rigid temporal order of events, nor it is meant to be comprehensive. It includes solved examples for a solid understanding. The division into chapters under the names of key players in the development of the field is not intended to separate these individual contributions entirely, but to highlight their different approaches to entropy. This structure helps to provide a different view-point from other text-books on entropy.
This monograph presents a comprehensive treatment of analytical solutions to problems in the area of non-equilibrium evaporation and condensation processes. The book covers, among others, topics such as systems of conversation equations for molecular fluxes of mass, momentum and energy within the Knudsen layer, spherical growth of vapor bubbles in volumes of highly superheated liquid. The target audience primarily comprises research experts in the field of thermodynamics and fluid dynamics, but the book may also be beneficial for graduate students alike.
This book presents a theoretical study of heat transfer due to laminar natural convection of nanofluids, using Al2O3-water nanofluid as an example. An innovative method of similarity transformation of velocity fields on laminar boundary layers is applied for the development of a mathematical governing model of natural convection with actual nanofluids, and a novel model of the nanofluid's variable thermophysical properties is derived by a mathematical analysis based on the developed model of variable physical properties of fluids combined with the model of the nanofluid's thermal conductivity and viscosity. Based on these, the physical property factors of nanofluids are produced, which leads to a simultaneous solution for deep investigations of hydrodynamics and heat transfer of nanofluid's natural convection. The book also proposes novel predictive formulae for the evaluation of heat transfer of Al2O3-water nanofluid's natural convection. The formulae have reliable theoretical and practical value because they are developed by rigorous theoretical analysis of heat transfer combined with full consideration of the effects of the temperature-dependent physical properties of nanofluids and the nanoparticle shape factor and concentration, as well as variations of fluid boundary temperatures. The conversion factors proposed help to turn the heat transfer coefficient and rate of fluid natural convection into those of nanofluid natural convection. Furthermore, several calculation examples are provided to demonstrate the heat transfer application of the proposed predictive formulae.
This book presents new methods of numerical modelling of tube heat exchangers, which can be used to perform design and operation calculations of exchangers characterized by a complex flow system. It also proposes new heat transfer correlations for laminar, transition and turbulent flows. A large part of the book is devoted to experimental testing of heat exchangers, and methods for assessing the indirect measurement uncertainty are presented. Further, it describes a new method for parallel determination of the Nusselt number correlations on both sides of the tube walls based on the nonlinear least squares method and presents the application of computational fluid dynamic (CFD) modeling to determine the air-side Nusselt number correlations. Lastly, it develops a control system based on the mathematical model of the car radiator and compares this with the digital proportional-integral-derivative (PID) controller. The book is intended for students, academics and researchers, as well as for designers and manufacturers of heat exchangers.
This book provides a general formalism for the calculation of the spectral correlation function for the fluctuating electromagnetic field. The procedure is applied to the radiative heat transfer and the van der Waals friction using both the semi-classical theory of the fluctuating electromagnetic field and quantum field theory. Applications of the radiative heat transfer and non-contact friction to scanning probe spectroscopy are presented. The theory gives a tentative explanation for the experimental non-contact friction data. The book explains that radiative heat transfer and the van der Waals friction are largely enhanced at short separations between the bodies due to the evanescent electromagnetic waves. Particular strong enhancement occurs if the surfaces of the bodies can support localized surface modes like surface plasmons, surface polaritons or adsorbate vibrational modes. An electromagnetic field outside a moving body can also be created by static charges which are always present on the surface of the body due to inhomogeneities, or due to a bias voltage. This electromagnetic field produces electrostatic friction which can be significantly enhanced if on the surface of the body there is a 2D electron or hole system or an incommensurate adsorbed layer of ions exhibiting acoustic vibrations.
This is the first book dedicated to solar gas turbines, providing fundamental knowledge and state-of-the-art developments in the field. A gas turbine is a heat engine in which a mixture of fuel and air is burned in a chamber that is an integral part of the flow circuit of the working fluid. The burnt gas mixture expands and turns the turbine, which can be connected to a generator for electricity production. Solar gas turbines offer an important alternative to conventional gas turbines driven by non-renewable, polluting fossil fuels such as diesel or natural gas. The book provides a comprehensive overview of the topic as well as numerous illustrations.
This third volume describes continuous bodies treated as classical (Boltzmann) and spin (Cosserat) continua or fluid mixtures of such bodies. It discusses systems such as Boltzmann continua (with trivial angular momentum) and Cosserat continua (with nontrivial spin balance) and formulates the balance law and deformation measures for these including multiphase complexities. Thermodynamics is treated in the spirit of Muller-Liu: it is applied to Boltzmann-type fluids in three dimensions that interact with neighboring fluids on two-dimensional contact surfaces and/or one-dimensional contact lines. For all these situations it formulates the balance laws for mass, momenta, energy, and entropy. Further, it introduces constitutive modeling for 3-, 2-, 3-d body parts for general processes and materially objective variable sets and their reduction to equilibrium and non-equilibrium forms. Typical (reduced) fluid spin continua are liquid crystals. Prominent nematic examples of these include the Ericksen-Leslie-Parodi (ELP) formulation, in which material particles are equipped with material unit vectors (directors). Nematic liquid crystals with tensorial order parameters of rank 1 to n model substructure behavior better, and for both classes of these, the book analyzes the thermodynamic conditions of consistency. Granular solid-fluid mixtures are generally modeled by complementing the Boltzmann laws with a balance of fluctuation (kinetic) energy of the particles. The book closes by presenting a full Reynolds averaging procedure that accounts for higher correlation terms e.g. a k-epsilon formulation in classical turbulence. However, because the volume fraction is an additional variable, the theory also incorporates 'k-epsilon equations' for the volume fraction.
This book presents a collection of recent contributions in the field of transport phenomena in multiphase systems, namely, heat and mass transfer. It discusses various topics related to the transport phenomenon in engineering (including state-of-the-art, theory and applications) and introduces some of the most important theoretical advances, computational developments and technological applications in multiphase systems domain, providing a self-contained key reference that is appealing to scientists, researchers and engineers alike. At the same time, these topics are relevant to a variety of scientific and engineering disciplines, such as chemical, civil, agricultural, and mechanical engineering.
The principal objective of this book is to provide information needed to define human thermal behavior quantitatively. Human thermal physiology is defined using mathematical methods routinely employed by physicists and engineers, but seldom used by physiologists. Major sections of the book are devoted to blood flow, sweating, shivering, heat transfer within the body, and heat and mass transfer from skin and clothing to the environment. Simple algebraic models based on experimental data from a century of physiological investigation are developed for bodily processes. The book offers an invaluable source of information for physiologists and physical scientists interested in quantitative approaches to the fascinating field of human thermoregulation.
Starting from a broad overview of heat transport based on the Boltzmann Transport Equation, this book presents a comprehensive analysis of heat transport in bulk and nanomaterials based on a kinetic-collective model (KCM). This has become key to understanding the field of thermal transport in semiconductors, and represents an important stride. The book describes how heat transport becomes hydrodynamic at the nanoscale, propagating very much like a viscous fluid and manifesting vorticity and friction-like behavior. It introduces a generalization of Fourier's law including a hydrodynamic term based on collective behavior in the phonon ensemble. This approach makes it possible to describe in a unifying way recent experiments that had to resort to unphysical assumptions in order to uphold the validity of Fourier's law, demonstrating that hydrodynamic heat transport is a pervasive type of behavior in semiconductors at reduced scales.
This book provides a detailed overview of the plasma fluidized bed. It is an innovative tool and generally combines plasma process with another efficient reactor, fluidized bed, providing an excellent method for particulate processes over conventional technology. The development and designs of typical types of plasma fluidized beds, mainly thermal plasma fluidized beds and non-thermal plasma fluidized beds are discussed. The influencing factors on the performance of plasma fluidized beds are analyzed in detail. The mechanism, i.e. the discharge characteristics, hydrodynamics, heat transfer and mass transfer are analyzed to offer a further insight of plasma fluidized beds. Applications of plasma fluidized beds for different areas, including metallurgy extraction, green energy process, environmental protection and advanced materials are presented. The book is a valuable reference for scientists, engineers and graduate students in chemical engineering and relative fields.
This book investigates the common nature of granular and active systems, which is rooted in their intrinsic out-of-equilibrium behavior, with the aim of finding minimal models able to reproduce and predict the complex collective behavior observed in experiments and simulations. Granular and active matter are among the most studied systems in out-of-equilibrium statistical physics. The book guides readers through the derivation of a fluctuating hydrodynamic description of granular and active matter by means of controlled and transparent mathematical assumptions made on a lattice model. It also shows how a macroscopic description can be provided from microscopic requirements, leading to the prediction of collective states such as cooling, swarming, clustering and the transitions among them. The analytical and numerical results shed new light on the physical connection between the local, microscopic properties of few particles and the macroscopic collective motion of the whole system.
These proceedings from the 37th International Workshop on Bayesian Inference and Maximum Entropy Methods in Science and Engineering (MaxEnt 2017), held in Sao Carlos, Brazil, aim to expand the available research on Bayesian methods and promote their application in the scientific community. They gather research from scholars in many different fields who use inductive statistics methods and focus on the foundations of the Bayesian paradigm, their comparison to objectivistic or frequentist statistics counterparts, and their appropriate applications. Interest in the foundations of inductive statistics has been growing with the increasing availability of Bayesian methodological alternatives, and scientists now face much more difficult choices in finding the optimal methods to apply to their problems. By carefully examining and discussing the relevant foundations, the scientific community can avoid applying Bayesian methods on a merely ad hoc basis. For over 35 years, the MaxEnt workshops have explored the use of Bayesian and Maximum Entropy methods in scientific and engineering application contexts. The workshops welcome contributions on all aspects of probabilistic inference, including novel techniques and applications, and work that sheds new light on the foundations of inference. Areas of application in these workshops include astronomy and astrophysics, chemistry, communications theory, cosmology, climate studies, earth science, fluid mechanics, genetics, geophysics, machine learning, materials science, medical imaging, nanoscience, source separation, thermodynamics (equilibrium and non-equilibrium), particle physics, plasma physics, quantum mechanics, robotics, and the social sciences. Bayesian computational techniques such as Markov chain Monte Carlo sampling are also regular topics, as are approximate inferential methods. Foundational issues involving probability theory and information theory, as well as novel applications of inference to illuminate the foundations of physical theories, are also of keen interest.
This monograph discusses the essential principles of the evaporationprocess by looking at it at the molecular and atomic level. In the first part methods of statistical physics, physical kinetics andnumerical modeling are outlined including the Maxwell's distributionfunction, the Boltzmann kinetic equation, the Vlasov approach, and theCUDA technique. The distribution functions of evaporating particles are then defined.Experimental results on the evaporation coefficient and the temperaturejump on the evaporation surface are critically reviewed and compared tothe theory and numerical results presented in previous chapters. The book ends with a chapter devoted to evaporation in differentprocesses, such as boiling and cavitation.This monograph addressesgraduate students and researchers working on phase transitions andrelated fields.
This book explores some of the connections between dissipative and quantum effects from a theoretical point of view. It focuses on three main topics: the relation between synchronization and quantum correlations, the thermodynamical properties of fluctuations, and the performance of quantum thermal machines. Dissipation effects have a profound impact on the behavior and properties of quantum systems, and the unavoidable interaction with the surrounding environment, with which systems continuously exchange information, energy, angular momentum and matter, is ultimately responsible for decoherence phenomena and the emergence of classical behavior. However, there is a wide intermediate regime in which the interplay between dissipative and quantum effects gives rise to a plethora of rich and striking phenomena that has just started to be understood. In addition, the recent breakthrough techniques in controlling and manipulating quantum systems in the laboratory have made this phenomenology accessible in experiments and potentially applicable.
This book discusses the elementary ideas and tools needed for open quantum systems in a comprehensive manner. The emphasis is given to both the traditional master equation as well as the functional (path) integral approaches. It discusses the basic paradigm of open systems, the harmonic oscillator and the two-level system in detail. The traditional topics of dissipation and tunneling, as well as the modern field of quantum information, find a prominent place in the book. Assuming a basic background of quantum and statistical mechanics, this book will help readers familiarize with the basic tools of open quantum systems. Open quantum systems is the study of quantum dynamics of the system of interest, taking into account the effects of the ambient environment. It is ubiquitous in the sense that any system could be envisaged to be surrounded by its environment which could naturally exert its influence on it. Open quantum systems allows for a systematic understanding of irreversible processes such as decoherence and dissipation, of the essence in order to have a correct understanding of realistic quantum dynamics and also for possible implementations. This would be essential for a possible development of quantum technologies.
At the heart of many fields - physics, chemistry, engineering - lies thermodynamics. While this science plays a critical role in determining the boundary between what is and is not possible in the natural world, it occurs to many as an indecipherable black box, thus making the subject a challenge to learn. Two obstacles contribute to this situation, the first being the disconnect between the fundamental theories and the underlying physics and the second being the confusing concepts and terminologies involved with the theories. While one needn't confront either of these two obstacles to successfully use thermodynamics to solve real problems, overcoming both provides access to a greater intuitive sense of the problems and more confidence, more strength, and more creativity in solving them. This book offers an original perspective on thermodynamic science and history based on the three approaches of a practicing engineer, academician, and historian. The book synthesises and gathers into one accessible volume a strategic range of foundational topics involving the atomic theory, energy, entropy, and the laws of thermodynamics.
Features twenty-five chapter contributions from an international array of distinguished academics based in Asia, Eastern and Western Europe, Russia, and the USA. This multi-author contributed volume provides an up-to-date and authoritative overview of cutting-edge themes involving the thermal analysis, applied solid-state physics, micro- and nano-crystallinity of selected solids and their macro- and microscopic thermal properties. Distinctive chapters featured in the book include, among others, calorimetry time scales from days to microseconds, glass transition phenomena, kinetics of non-isothermal processes, thermal inertia and temperature gradients, thermodynamics of nanomaterials, self-organization, significance of temperature and entropy. Advanced undergraduates, postgraduates and researchers working in the field of thermal analysis, thermophysical measurements and calorimetry will find this contributed volume invaluable. This is the third volume of the triptych volumes on thermal behaviour of materials; the previous two receiving thousand of downloads guaranteeing their worldwide impact.
The subject of this book stands at the crossroads of ergodic theory and measurable dynamics. With an emphasis on irreversible systems, the text presents a framework of multi-resolutions tailored for the study of endomorphisms, beginning with a systematic look at the latter. This entails a whole new set of tools, often quite different from those used for the "easier" and well-documented case of automorphisms. Among them is the construction of a family of positive operators (transfer operators), arising naturally as a dual picture to that of endomorphisms. The setting (close to one initiated by S. Karlin in the context of stochastic processes) is motivated by a number of recent applications, including wavelets, multi-resolution analyses, dissipative dynamical systems, and quantum theory. The automorphism-endomorphism relationship has parallels in operator theory, where the distinction is between unitary operators in Hilbert space and more general classes of operators such as contractions. There is also a non-commutative version: While the study of automorphisms of von Neumann algebras dates back to von Neumann, the systematic study of their endomorphisms is more recent; together with the results in the main text, the book includes a review of recent related research papers, some by the co-authors and their collaborators.
This book presents a history of shock compression science, including development of experimental, material modeling, and hydrodynamics code technologies over the past six decades at Sandia National Laboratories. The book is organized into a discussion of major accomplishments by decade with over 900 references, followed by a unique collection of 45 personal recollections detailing the trials, tribulations, and successes of building a world-class organization in the field. It explains some of the challenges researchers faced and the gratification they experienced when a discovery was made. Several visionary researchers made pioneering advances that integrated these three technologies into a cohesive capability to solve complex scientific and engineering problems. What approaches worked, which ones did not, and the applications of the research are described. Notable applications include the turret explosion aboard the USS Iowa and the Shoemaker-Levy comet impact on Jupiter. The personal anecdotes and recollections make for a fascinating account of building a world-renowned capability from meager beginnings. This book will be inspiring to the expert, the non expert, and the early-career scientist. Undergraduate and graduate students in science and engineering who are contemplating different fields of study should find it especially compelling. |
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