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Books > Science & Mathematics > Physics > Thermodynamics & statistical physics > Thermodynamics
The equations which we are going to study in these notes were first presented in 1963 by E. N. Lorenz. They define a three-dimensional system of ordinary differential equations that depends on three real positive parameters. As we vary the parameters, we change the behaviour of the flow determined by the equations. For some parameter values, numerically computed solutions of the equations oscillate, apparently forever, in the pseudo-random way we now call "chaotic"; this is the main reason for the immense amount of interest generated by the equations in the eighteen years since Lorenz first presented them. In addition, there are some parameter values for which we see "preturbulence," a phenomenon in which trajectories oscillate chaotically for long periods of time before finally settling down to stable stationary or stable periodic behaviour, others in which we see "intermittent chaos," where trajectories alternate be tween chaotic and apparently stable periodic behaviours, and yet others in which we see "noisy periodicity," where trajectories appear chaotic though they stay very close to a non-stable periodic orbit. Though the Lorenz equations were not much studied in the years be tween 1963 and 1975, the number of man, woman, and computer hours spent on them in recent years - since they came to the general attention of mathematicians and other researchers - must be truly immense."
Molecular Driving Forces, Second Edition is an introductory statistical thermodynamics text that describes the principles and forces that drive chemical and biological processes. It demonstrates how the complex behaviors of molecules can result from a few simple physical processes, and how simple models provide surprisingly accurate insights into the workings of the molecular world. Widely adopted in its First Edition, Molecular Driving Forces is regarded by teachers and students as an accessible textbook that illuminates underlying principles and concepts. The Second Edition includes two brand new chapters: (1) "Microscopic Dynamics" introduces single molecule experiments; and (2) "Molecular Machines" considers how nanoscale machines and engines work. "The Logic of Thermodynamics" has been expanded to its own chapter and now covers heat, work, processes, pathways, and cycles. New practical applications, examples, and end-of-chapter questions are integrated throughout the revised and updated text, exploring topics in biology, environmental and energy science, and nanotechnology. Written in a clear and reader-friendly style, the book provides an excellent introduction to the subject for novices while remaining a valuable resource for experts.
This textbook facilitates students' ability to apply fundamental principles and concepts in classical thermodynamics to solve challenging problems relevant to industry and everyday life. It also introduces the reader to the fundamentals of statistical mechanics, including understanding how the microscopic properties of atoms and molecules, and their associated intermolecular interactions, can be accounted for to calculate various average properties of macroscopic systems. The author emphasizes application of the fundamental principles outlined above to the calculation of a variety of thermodynamic properties, to the estimation of conversion efficiencies for work production by heat interactions, and to the solution of practical thermodynamic problems related to the behavior of non-ideal pure fluids and fluid mixtures, including phase equilibria and chemical reaction equilibria. The book contains detailed solutions to many challenging sample problems in classical thermodynamics and statistical mechanics that will help the reader crystallize the material taught. Class-tested and perfected over 30 years of use by nine-time Best Teaching Award recipient Professor Daniel Blankschtein of the Department of Chemical Engineering at MIT, the book is ideal for students of Chemical and Mechanical Engineering, Chemistry, and Materials Science, who will benefit greatly from in-depth discussions and pedagogical explanations of key concepts. Distills critical concepts, methods, and applications from leading full-length textbooks, along with the author's own deep understanding of the material taught, into a concise yet rigorous graduate and advanced undergraduate text; Enriches the standard curriculum with succinct, problem-based learning strategies derived from the content of 50 lectures given over the years in the Department of Chemical Engineering at MIT; Reinforces concepts covered with detailed solutions to illuminating and challenging homework problems.
The first edition of this book was greeted with broad interest from readers en gaged in various disciplines of biophysics. I received many stimulating and en couraging responses, however, some of the book's reviewers wanted to stress the fact that an extensive literature of network theory was not included or reported in the book. But the main aspect of the book is intended to be substantive rather than methodical: networks simply serve as a remedy for doing some first steps in analysing and modelling complex biological systems. For an advanced stage in the investigation of a particular system it may be appropriate to replace the pheno menological network method by more detailed techniques like statistical equations or computer simulations. According to this intention, the second edition of the book has been enlarged by further biological examples for network analysis, not by more network theory. There is a completely new section on a network model for photoreception. For this section I am obliged to J. Tiedge who did most of the detailed calculation and to my colleague Professor Stieve with whom we have had a very fruitful cooperation. Also I would like to mention that this work has been sponsored by the "Deutsche Forschungsgemei nschaft" i n the "Sonderforschungsberei ch 160." Recent results for excitable systems represented by feedback networks have also been included in the second edition, especially for limit cycle networks."
Written for an advanced undergraduate or first-year graduate course, Intermediate Heat Transfer starts with the basics, and puts emphasis on formulating problems, obtaining solutions, and analyzing results using analytical, and numerical methods with the aid of spreadsheets and CFD software. The text employs nondimensionalization as a tool for simplifying the governing equations, developing additional insights into the physics of the problems, identifying the relevant parameters, and arriving at general solutions. It provides comprehensive coverage of the topics and develops the skills for solving heat transfer problems using numerical methods with the aid of spreadsheets and computational fluid mechanics software.
The author presents detailed numerical solutions to many advanced problems using spreadsheets, although the methods presented for obtaining solutions can be can also be implemented using equation solvers and computing environments, or direct programming using languages such as Fortran or C. The text contains a chapter on CFD to provide the necessary background for obtaining and analyzing CFD solutions. It includes a number of step-by-step tutorials for solving more complicated problems using Fluent, both to show how CFD codes are used as well as a further check of some of the more commonly used assumptions. The text also has extensive coverage of heat exchangers, including being the first text to cover the heat exchanger efficiency for the design and analysis of heat exchangers. This approach eliminates the need for complicated charts or equations. The chapter on mass transfer and chemically reactive flows provides the background needed for modeling of combustion problems. This book fills the gap between the undergraduate heat transfer course and specialized advanced courses like conduction, convection, radiation, and mass transfer. Much has changed in the field of heat transfer, in what is taught, and how it is presented. An important change has been a shift away from advanced analytical techniques, to more reliance on numerical solutions, which also broadens the topics that are covered in these courses.
Because classical thermodynamics evolved into many branches of science and engineering, most undergraduate courses on the subject are taught from the perspective of each area of specialization. General Thermodynamics combines elements from mechanical and chemical engineering, chemistry (including electrochemistry), materials science, and biology to present a unique and thorough treatment of thermodynamics that is broader in scope than other fundamental texts. This book contains classroom-tested materials designed to meet the academic requirements for students from a variety of scientific and engineering backgrounds in a single course. The first half focuses on classical concepts of thermodynamics, whereas the latter half explores field-specific applications, including a unique chapter on biothermodynamics. The book's methodology is unified, concise, and multidisciplinary, allowing students to understand how the principles of thermodynamics apply to all technical fields that touch upon this most fundamental of scientific theories. It also offers a rigorous approach to the quantitative aspects of thermodynamics, accompanied by clear explanations to help students transition smoothly from the physical concepts to their mathematical representations. Each chapter contains numerous worked examples taken from different engineering applications, illustrations, and an extensive set of exercises to support the material. A complete solutions manual is available to professors with qualifying course adoptions.
Advanced Analytic Control Techniques for Thermal Systems with Heat Exchangers presents the latest research on sophisticated analytic and control techniques specific for Heat Exchangers (HXs) and heat Exchanger Networks (HXNs), such as Stability Analysis, Efficiency of HXs, Fouling Effect, Delay Phenomenon, Robust Control, Algebraic Control, Geometric Control, Optimal Control, Fuzzy Control and Artificial Intelligence techniques. Editor Libor Pekar and his team of global expert contributors combine their knowledge and experience of investigated and applied systems and processes in this thorough review of the most advanced networks, analyzing their dynamics, efficiency, transient features, physical properties, performance, feasibility, flexibility and controllability. The structural and dynamic analyses and control approaches of HXNs, as well as energy efficient manipulation techniques are discussed, in addition to the design of the control systems through the full life cycle. This equips the reader with an understanding of the relevant theory in a variety of settings and scenarios and the confidence to apply that knowledge to solve problems in an academic or professional setting. Graduate students and early-mid career professionals require a robust understanding of how to suitably design thermal systems with HXs and HXNs to achieve required performance levels, which this book offers in one consolidated reference. All examples and solved problems included have been tried and tested, and these combined with the research driven theory provides professionals, researchers and students with the most recent techniques to maximize the energy efficiency and sustainability of existing and new thermal power systems.
Airbreathing Propulsion covers the physics of combustion, fluid and thermo-dynamics, and structural mechanics of airbreathing engines, including piston, turboprop, turbojet, turbofan, and ramjet engines. End-of-chapter exercises allow the reader to practice the fundamental concepts behind airbreathing propulsion, and the included PAGIC computer code will help the reader to examine the relationships between the performance parameters of different engines. Large amounts of data have on many different piston, turbojet, and turboprop engines have been compiled for this book and are included as an appendix. This textbook is ideal for senior undergraduate and graduate students studying aeronautical engineering, aerospace engineering, and mechanical engineering.
This book is the second edition of Numerical methods for diffusion phenomena in building physics: a practical introduction originally published by PUCPRESS (2016). It intends to stimulate research in simulation of diffusion problems in building physics, by providing an overview of mathematical models and numerical techniques such as the finite difference and finite-element methods traditionally used in building simulation tools. Nonconventional methods such as reduced order models, boundary integral approaches and spectral methods are presented, which might be considered in the next generation of building-energy-simulation tools. In this reviewed edition, an innovative way to simulate energy and hydrothermal performance are presented, bringing some light on innovative approaches in the field.
This textbook brings together the fundamentals of the macroscopic and microscopic aspects of thermal physics by presenting thermodynamics and statistical mechanics as complementary theories based on small numbers of postulates. The book is designed to give the instructor flexibility in structuring courses for advanced undergraduates and/or beginning graduate students and is written on the principle that a good text should also be a good reference. The presentation of thermodynamics follows the logic of Clausius and Kelvin while relating the concepts involved to familiar phenomena and the modern student's knowledge of the atomic nature of matter. Another unique aspect of the book is the treatment of the mathematics involved. The essential mathematical concepts are briefly reviewed before using them, and the similarity of the mathematics to that employed in other fields of physics is emphasized. The text gives in depth treatments of low density gases, harmonic solids, magnetic and dielectric materials, phase transitions, and the concept of entropy. The microcanonical, canonical, and grand canonical ensembles of statistical mechanics are derived and used as the starting point for the analysis of fluctuations, blackbody radiation, the Maxwell distribution, Fermi-Dirac statistics, Bose-Einstein condensation, and the statistical basis of computer simulations. Supplementary material including PowerPoint slides and detailed worked solutions can be downloaded online at http://booksupport.wiley.com
This book presents a variety of techniques for tackling phenomena that are not amenable to the conventional approach based on the concept of probabilities. The methods described rely on the use of path integration, thermal Green functions, time-temperature propagators, Liouville operators, second quantization, and field correlators at finite density and temperature. Also exploring the statistical mechanics of unstable quantum systems, the book is intended as a supplementary or reference text for use in one-semester graduate courses on Quantum Mechanics, Thermodynamics, Electromagnetism, and Mathematical Methods in Physics.
Many people, including physicists, are confused about what the Second Law of thermodynamics really means, about how it relates to the arrow of time, and about whether it can be derived from classical mechanics. They also wonder what entropy really is: Is it all about information? But, if so, then, what is its relation to fluxes of heat? One might ask similar questions about probabilities: Do they express subjective judgments by us, humans, or do they reflect facts about the world, i.e. frequencies. And what notion of probability is used in the natural sciences, in particular statistical mechanics? This book addresses all of these questions in the clear and pedagogical style for which the author is known. Although valuable as accompaniment to an undergraduate course on statistical mechanics or thermodynamics, it is not a standard course book. Instead it addresses both the essentials and the many subtle questions that are usually brushed under the carpet in such courses. As one of the most lucid accounts of the above questions, it provides enlightening reading for all those seeking answers, including students, lecturers, researchers and philosophers of science.
The concept of traceability has evolved to ensure measurements can be communicated consistently and unambiguously. This new edition of a classic reference offers a systematic treatment of traceable temperature measurement and presents a practical guide to the principles and purpose of measurements. With an emphasis on recognizing sources of uncertainty, Nicholas and White examine the most commonly used thermometers: liquid-in-glass thermometers, platinum resistance thermometers, thermocouples and radiation thermometers. The new edition features:
Fundamentals of Classical and Statistical Thermodynamics provides a comprehensive introduction to this pivotal subject. Starting from basics, the book begins with a thorough introduction to the field, providing concise definitions and an overview of thermodynamics and its applications. The book discusses the fundamentals of classical equilibrium thermodynamics, thermal physics, kinetic theory and statistical mechanics. This comprehensive coverage enables the reader to understand not only the interrelationships between these subjects but also encourages an ability to interpret the thermodynamic quantities and laws in terms of statistical mechanics. Beginning with a detailed discussion of the four laws of thermodynamics the text introduces more advanced topics in later chapters, such as applications of the first and second laws, free energy and chemical equilibria, and equilibrium statististical mechanics and applications. Uniquely, this text includes a large number of worked examples throughout, with a range of problems at the end of each chapter and their solutions all at the end of the book. The most fundamental concepts of the subject are emphasised throughout and new derivations of many of the standard formulae have been developed to avoid excessive mathematical rigour. Fundamentals of Classical and Statistical Thermodynamics:
Waste Biorefineries: Advanced Design Concepts for Integrated Waste to Energy Processes presents a detailed guide to the design of energy-efficient and cost-effective waste-integrated biorefineries. Integrating thermochemical processing of waste with existing waste-to-energy technologies, the book includes the latest developments and technologies. It introduces current waste valorization techniques and examines reasons to modify existing waste-to-energy systems through the integration of new processes. In addition, the book explains the design of novel biorefineries and methods to assess these processes alongside detailed results, including the integration of waste-based CHP plants with waste gasification and the integration of pyrolysis technologies and biogas plants with waste thermochemical processing. Other sections discuss the issues and challenges of commercializing waste-to-energy technologies, including uncertainty in waste thermochemical process designs, the environmental impact of waste-integrated biorefineries, and the role of integrated waste-to-energy management in smart cities and urban energy systems. This book will be an invaluable reference for students, researchers and those in industry who are interested in the design and implementation of waste-to-energy systems, waste biomass-based combined heat and power plants, biogas plants and forest-based industries.
Develop a fundamental understanding of heat transfer analysis techniques as applied to earth based spacecraft with this practical guide. Written in a tutorial style, this essential text provides a how-to manual tailored for those who wish to understand and develop spacecraft thermal analyses. Providing an overview of basic heat transfer analysis fundamentals such as thermal circuits, limiting resistance, MLI, environmental thermal sources and sinks, as well as contemporary space based thermal technologies, and the distinctions between design considerations inherent to room temperature and cryogenic temperature applications, this is the perfect tool for graduate students, professionals and academic researchers.
The Mechanics of Threaded Fasteners and Bolted Joints outlines how threaded fasteners and bolted joints fail, how these failures can be remedied, and ultimately how to avoid them altogether through tightening methods, material strength, and avoiding loosening. The book demonstrates how to select the appropriate tightening method and determine the optimal tightening procedure for varying nominal diameters. Using the finite element method, it discusses characteristics of stress concentration and fatigue strength and covers bolt force variation due to elastic interaction. The separation of the plate interface via increased external force as the primary cause of fatigue failure in threaded fasteners is discussed, with effective countermeasures provided. Empirical equations of thermal contact coefficient and apparent thermal contact coefficient in simple form are included as well.
This superb text describes a novel and powerful method for allowing
design engineers to firstly model a linear problem in heat
conduction, then build a solution in an explicit form and finally
obtain a numerical solution. It constitutes a modelling and
calculation tool based on a very efficient and systemic
methodological approach. |
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