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Books > Science & Mathematics > Physics > Thermodynamics & statistical physics > Thermodynamics
Continuing the tradition of the IUTAM Symposia TRANSSONICA, this review of the numerical simulation and physical modelling of transonic flows presents new developments in the fields of computational and experimental aerodynamics. A major topic of the symposium proceedings is the evaluation of present numerical analysis techniques with respect to transonic aerodynamics. In the field of experimental aerodynamics, the high Reynolds number effect and the interference-free testing in transonic wind tunnels are of special interest.
ill the past three decades there has been enonnous progress in identifying the es sential role that "nonlinearity" plays in physical systems. Classical nonlinear wave equations can support localized, stable "soliton" solutions, and nonlinearities in quantum systems can lead to self-trapped excitations, such as polarons. Since these nonlinear excitations often dominate the transport and response properties of the systems in which they exist, accurate modeling of their effects is essential to interpreting a wide range of physical phenomena. Further, the dramatic de velopments in "deterministic chaos", including the recognition that even simple nonlinear dynamical systems can produce seemingly random temporal evolution, have similarly demonstrated that an understanding of chaotic dynamics is vital to an accurate interpretation of the behavior of many physical systems. As a conse quence of these two developments, the study of nonlinear phenomena has emerged as a subject in its own right. During these same three decades, similar progress has occurred in understand ing the effects of "disorder". Stimulated by Anderson's pioneering work on "dis ordered" quantum solid state materials, this effort has also grown into a field that now includes a variety of classical and quantum systems and treats "disorder" arising from many sources, including impurities, random spatial structures, and stochastic applied fields. Significantly, these two developments have occurred rather independently, with relatively little overlapping research.
Fundamentals of Continuum Mechanics of Soils provides a long-needed general scheme for the study of the important yet problematic material of soil. It closes the gap between two disciplines, soil mechanics and con- tinuum mechanics, showing that the familiar concepts of soil mechanics evolve directly from continuum mechanics. It confirms concepts such as pore pressures, cohesion and dependence of the shear stress on consolidation, and rejects the view that continuum mechanics cannot be applied to a material such as soil. The general concepts of continuum mechanics, field equations and constitutive equations are discussed. It is shown how the theory of mixtures evolves from these equations and how, along with energetics and irrevers- ible thermodynamics, it can be applied to soils. The discussion also sheds light on some aspects of mechanics of materials, especially compressible materials. Examples are the introduction of the Hencky measure of strain, the requirement of dual constitutive equations, and the dependence of the spent internal energy on the stored internal energy. Researchers in engineering mechanics and material sciences may find that the results of experiments on soils can be generalized and extended to other materials. The book is a reference text for students familiar with the fundamentals of mechanics, for scholars of soil engineering, and for soil scientists. It is also suitable as an advanced undergraduate course in soil mechanics.
Since the petroleum crisis in the 1970s, a lot of effort to save energy was made in industry, and remarkable achievements have been made. In the research and development concerning thermal energy, however, it was clar ified that one of the most important problems was manufacturing con densing systems with smaller size and higher performance. To solve this problem we need a method which synthesizes selections_ of the type of con denser, cooling tube and its arrangement, assessment of fouling on the cooling surfaces, consideration of transient characteristics of a condenser, etc. The majority of effort, however, has been to devise a surface element which enhances the heat transfer coefficient in condensation of a single or multicomponent vapor. Condensation phenomena are complexly affected by a lot of physical property values, and accordingly the results of theo retical research are expressed with several dimensionless parameters. On the other hand, the experimental research is limited to those with some specified cooling surfaces and some specified working fluids. Hence, the basic research of condensation is necessary for criticizing the enhancement effect as well as for an academic interest."
This book brings together data from Czechoslovakia on vapor pressures, data from England on critical properties, and data from America on physical properties of organic and organometallic compounds to provide a basic reference book for engineers and scientists involved with research and design in the chemical and petroleum industries. We would like to acknowledge Jaroslav Dykyj, Milan Repas, and Josef Svo boda of Czechoslovakia for providing the material on Antoine constants and Douglas Ambrose of the University of London for providing the material on critical properties. Stanislaw Malanowski pointed out and made available the sources of data from Eastern Europe. Richard Stephenson translated and correlated the data in tabular form. We would like to thank Dr. Matej Andras of the Slovenska Literarna Agentura for granting permission to use the data from Czechoslovakia and Dr. Marjan Bace of Elsevier Science Publishing Co., Inc., who encouraged preparation of this manuscript and handled the publishing arrangements. Particular thanks go to Mary Stephenson for typing the entire camera-ready copy. Richard M. Stephenson University of Connecticut Storrs, Connecticut Stanislaw Malanowski Institute of Physical Chemistry Warsaw, Poland vii Introduction All scientific and engineering calculations are dependent on the availability of thennodynamic and physical property data for the materials or systems in question. This dependency is particularly true in engineering design, which relies almost exclusively on computers for accurate data to produce meaningful final designs."
This volume comprises a selection of the best papers presented at
the Eighth International Symposium on Applications of Laser
Techniques to Fluid Mechanics, held in Lisbon in July 1996.
At first glance it may seem presumptuous to want to add yet another to the numerous books on Differential Thermal Analysis (DT A). Thermoanalytical methods have been in use for some time, as shown by the more than five thousand publications containing DT A or TG curves listed by SMOTHERS and CHIANG in the bibliography to their handbook and abstracted in the several volumes of Thermal Analysis Abstracts (TAA), edited by J. P. REDFERN for the International Con federation for Thermal Analysis (ICT A). Every three years the proceed ings of ICT A meetings are published, bringing the latest results of thermoanalytic research. There is also the Scifax DT A Data Index, edited by R. C. MACKENZIE (1962) and modeled on the ASTM pattern card index (used for X-ray investigations), a compilation of the DT A data for several hundred minerals, and inorganic and organic materials. The theoretical foundations of thermogravimetry and DT A have been described in detail by LEHMANN, DAS and PAETSCH (1953), R. C. MACKENZIE (1957, 1970), DUVAL (1963), WENDLANDT (1964), GARN (1965), F. PAULIK et al. (1966), SMOTHERS and CHIANG (1966), and KEATTCH (1969). Thermoanalytical results are strongly influenced by various factors relative to preparation and equipment (see 1-2. 4 of this study). This is the reason why we frequently find, in these books as well as in the Scifax-Card catalog, contradictory data on the same substance."
The result of two decades spent developing and refining the phase-integral method to a high level of precision, the authors have applied this method to problems in various fields of theoretical physics. The problems treated are of a mathematical nature, but have important physical applications. This book will thus be of great use to research workers in various branches of theoretical physics, where the problems can be reduced to one-dimensional second-order differential equations of the Schrodinger type for which phase-integral solutions are required. Includes contributions from notable scientists who have already made use of the authors'technique."
It seemed appropriate to arrange a meeting of teachers of thermodynamics in the United Kingdom, a meeting held in the pleasant surroundings of Emmanuel College, Cambridge, in Sept mber, 1984. This volume records the ideas put forward by authors, the discussion generated and an account of the action that discussion has initiated. Emphasis was placed on the Teaching of Thermodynamics to degree-level students in their first and second years. The meeting, a workshop for practitioners in which all were expected to take part, was remarkably well supported. This was notable in the representation of essentially every UK university and polytechnic engaged in teaching engineering thermodynamics and has led to a stimulating spread of ideas. By intention, the emphasis for attendance was put on teachers of engineering concerned with thermodynamics, both mechanical and chemical engineering disciplines. Attendance from others was encouraged but limited as follows: non-engineering acad emics, 10%, industrialists, 10%. The record of attendance, which will also provide addresses for direct correspondance, will show the broad cover achieved. I am indeed grateful for the attendance of those outside the engineering departments who in many cases brought a refreshing approach to discussions of the 'how' and 'why' of teaching thermodynamics. It was also notable that many of those speaking from the polytechnics had a more original approach to the teaching of thermodynamics than those from conventional universities. The Open University however brought their own special experience to bear."
One of the major achievements in computational fluid dynamics has been the development of numerical methods for simulating compressible flows, combining higher-order accuracy in smooth regions with a sharp, oscillation-free representation of embedded shocks methods and now known as "high-resolution schemes." Together with introductions from the editors written from the modern vantage point this volume collects in one place many of the most significant papers in the development of high-resolution schemes as occured at ICASE.
In the decades the of the formation of structures past subject spontaneous in far from has into a branch of - systems equilibrium major physics grown search with ties to It has become evident that strong neighboring disciplines. a diverse of can be understood within a common mat- phenomena range matical framework which has been called nonlinear of continuous dynamics This name the close to the field of nonlinear systems. emphasizes relationship of with few of freedom which has evolved into a dynamics systems degrees mature in the recent features mathematically subject past. Many dynamical of continuous be described reduction few can a to a systems actually through of freedom and of the latter of continue to degrees properties type systems of continuous the inspire study systems. The of this book is to demonstrate the numerous goal through examples that exist for the of nonlinear the opportunities study phenomena through tools of mathematical and use of common analyses dynamical interpretations. Instead of overview of the a providing comprehensive rapidly evolving field, the contributors to this book are to communicate to a wide scientific trying audience the of what have learnt about the formation of essence they spon- neous structures in continuous and about the dissipative systems competition between order and chaos that characterizes these It is that systems. hoped the book will be even to those scientists whose not helpful are disciplines the authors.
This book addresses several of the foundational problems in thermophysics, i. e. thermodynamics and statistical mechanics. It is an interdisciplinary work in that it examines the philosophical underpinning of scientific models and theories; it also refines the analysis of the problems at hand and delineates the place occupied by various scientific models in a generalized philosophical landscape. Hence, our philosophical - or theoretical - inquiry focuses sharply on the concept of models; and our empirical - or laboratory - evidence is sought in the model-building activities of scientists who have tried to confront the epistemological problems arising in the thermophysical sciences. Primarily for researchers and students in physics, philosophy of science, and mathematics, our book aims at informing the readers - with all the in dispensable technical details made readily available - about the nature of the foundational problems, how these problems are approached with the help of various mathematical models, and what the philosophical implications of such models and approaches involve. Some familiarity with elementary ther mophysics and/or with introductory-level philosophy of science may help, but neither is a prerequisite. The logical and mathematical background re quired for the book are introduced in the Appendices. Upon using the Subject Index, the readers may easily locate the concepts and theorems needed for understanding various parts of the book. The Citation Index lists the authors of the contributions we discuss in detail."
Fluid flows that transfer heat and mass often involve drops and bubbles, particularly if there are changes of phase in the fluid in the formation or condensation of steam, for example. Such flows pose problems for the chemical and mechanical engineer significantly different from those posed by single-phase flows. This book reviews the current state of the field and will serve as a reference for researchers, engineers, teachers, and students concerned with transport phenomena. It begins with a review of the basics of fluid flow and a discussion of the shapes and sizes of fluid particles and the factors that determine these. The discussion then turns to flows at low Reynolds numbers, including effects due to phase changes or to large radial inertia. Flows at intermediate and high Reynolds numbers are treated from a numerical perspective, with reference to experimental results. The next chapter considers the effects of solid walls on fluid particles, treating both the statics and dynamics of the particle-wall interaction and the effects of phase changes at a solid wall. This is followed by a discussion of the formation and breakup of drops and bubbles, both with and without phase changes. The last two chapters discuss compound drops and bubbles, primarily in three-phase systems, and special topics, such as transport in an electric field.
This work marks a stage in the evolution of a scientific and technical field which has been developed by the Commissariat a l'Energie Atomique (CEA) over several decades. Many members of the staff of the CEA have won re nown in this field, and their work has brought it to the high degree of excel lence for which it is internationally recognized today. These scientists had to consider every aspect of the field, as it concerned: modeling, which has recourse to fluid thermodynamics, molecular phys ics, and chemistry; numerical evaluation, which relies on mathematical analysis and data processing; and experiments in the firing area, which require specific stress generators and instrumentation. Whilst this book is a testament to the activity and success of staff of the CEA, it also reviews a number ofthe advances made in the discipline. How ever, it is not intended to be an exhaustive account of those advances; it is assumed that the reader can, if desired, consult the standard monographs, and more recent, more specialized works (notably W.C. Davis and W. Fickett, and C.L. Mader). The history of the discipline is interesting in itself, and also as an illustra tion of the causes which lead to progress in a coherent body of scientific work. I should like to make some comments on this progress, of which there is a fascinating summary in the introduction, and which will figure largely throughout the work."
This book is devoted to the problems of oxidation chemical reactions and addresses bimodal reaction sequences. Chemical reactions of oxidation, occurring under certain conditions and in multicomponent systems are complex processes. The process of the oxidation essentially changes in the presence and contact of the solid substances with reactants. The role of solid substances and the appearance of this phenomenon in oxidation reaction are discussed. The reader will understand the "driving forces" of this phenomenon and apply it in practice. Written for chemists, physicists, biologists and engineers working in the domain of oxidation reactions. Key Selling Features: Covers the historical background, modern state of the art, and perspectives in investigations of the coupling between heterogeneous and homogeneous reactions Discusses the feasible pathways of the coupling of heterogeneous and homogeneous reactions in oxidation in man-made and natural chemical systems Addresses the abundance, peculiarities and mechanisms of the bimodal reaction sequences in oxidation with dioxygen in recent decades Discusses the existence of the bimodal reaction sequences in chemical systems investigations in atmospheric chemistry and heterogeneous photocatalysis Presented in a simple concise style, accessible for both specialists and non-specialists
Convective heat tranfer is the result of fluid flowing between objects of different temperatures. Thus it may be the objective of a process (as in refrigeration) or it may be an incidental aspect of other processes. This monograph reviews in a concise and unified manner recent contributions to the principles of convective heat transfer for single- and multi-phase systems: It summarizes the role of the fundamental mechanism, discusses the governing differential equations, describes approximation schemes and phenomenological models, and examines their solutions and applications. After a review of the basic physics and thermodynamics, the book divides the subject into three parts. Part 1 deals with single-medium transfer, specifically with intraphase transfers in single-phase flows and with intramedium transfers in two-phase flows. Part 2 deals with fluid-solid transfer processes, both in cases where the interface is small and in cases where it is large, as well as liquid-liquid transfer processes. Part 3 considers three media, addressing both liquid-solid-solid and gas-liquid-solid systems.
This concise and unified text reviews recent contributions to the principles of convective heat transfer for single and multi-phase systems. This valuable new edition has been updated throughout and contains new examples and problems.
B. Coleman, M.E. Gurtin: Thermodynamics and wave propagation in Elastic and Viscoelastic media.- L. De Vito: Sui fondamenti della meccanica di sistemi continui (II).- G. Fichera: Problemi elastostatici con ambigue condizioni al contorno.- G. Grioli: Sistemi a trasformazioni reversibili.- W. Noll: the foundations of mechanics.- R.A. Toupin: Elasticity and electromagnetic.- C.C. Wang: Subfluids.
Written for an advanced undergraduate or first-year graduate course, Intermediate Heat Transfer starts with the basics, and puts emphasis on formulating problems, obtaining solutions, and analyzing results using analytical, and numerical methods with the aid of spreadsheets and CFD software. The text employs nondimensionalization as a tool for simplifying the governing equations, developing additional insights into the physics of the problems, identifying the relevant parameters, and arriving at general solutions. It provides comprehensive coverage of the topics and develops the skills for solving heat transfer problems using numerical methods with the aid of spreadsheets and computational fluid mechanics software. Presents coverage of convective, conductive, and radiative heat transfer at the graduate level Provides a balance of analytical and numerical approaches to advanced heat transfer Stresses nondimensionalization throughout the book as a tool for simplifying the governing equations The author presents detailed numerical solutions to many advanced problems using spreadsheets, although the methods presented for obtaining solutions can be can also be implemented using equation solvers and computing environments, or direct programming using languages such as Fortran or C. The text contains a chapter on CFD to provide the necessary background for obtaining and analyzing CFD solutions. It includes a number of step-by-step tutorials for solving more complicated problems using Fluent, both to show how CFD codes are used as well as a further check of some of the more commonly used assumptions. The text also has extensive coverage of heat exchangers, including being the first text to cover the heat exchanger efficiency for the design and analysis of heat exchangers. This approach eliminates the need for complicated charts or equations. The chapter on mass tr
Enrico Fermi s scientific work, noted for its originality and breadth, has had lasting consequences throughout modern science. Written by close colleagues as well as scientists whose fields were profoundly influenced by Fermi, the papers collected here constitute a tribute to him and his scientific legacy. They were commissioned on the occasion of his 100th birthday by the Italian Physical Society and confirm that Fermi was a rare combination of theorist, experimentalist, teacher, and inspiring colleague. The book is organized into three parts: three biographical overviews by close colleagues, replete with personal insights; fourteen analyses of Fermi's impact by specialists in their fields, spanning physics, chemistry, mathematics, and engineering; and a year-by-year chronology of Fermi s scientific endeavors. Written for a general scientific audience, Enrico Fermi: His Work and Legacy offers a highly readable source on the life of one of the 20th century's most distinguished scientists and a must for everybody interested in the history of modern science."
As a basis for printed property charts and tables, empirical multiparameter equa tions of state have been the most important source of accurate thermodynamic property data for more than 30 years now. However, due to increasing demands on the accuracy of thermodynamic property data in computerised calculations as well as the availability of appropriate software tools, and the ever increasing computer power, such formulations are nowadays becoming a valuable tool for everyday work. This development has substantially increased the number of scientists, engi neers, and students who are working with empirical multiparameter equations of state, and it continues to do so. Nevertheless, common knowledge on this kind of thermodynamic property models and on the ongoing progress in this scientific discipline is still very limited. Multiparameter equations of state do not belong to the topics which are taught intensively in thermodynamic courses in engineering and natural sciences and the books and articles where they are published mainly deal with the thermodynamic properties of certain substances rather than with the theoretical background of the used equations of state. In contrast to this, my concern mainly was to give a survey of the theoretical background of multiparameter equations of state both with regard to their application and their development."
This booklet is designed to bridge the gap between handbooks and technical literature and aims at graduate students or experienced readers. Commercial flow sheeting simulation software is increasingly available and is used in the early steps of process design in industry. As to this, more sophisticated and precise models based on activities instead of concentrations should be used. After an introductory chapter there is in Chapter 2 an intensive discussion of reactive phase equilibria of ionic and non-ionic solutes based on chemical potentials. Chapter 3 introduces to multicomponent diffusion and mass transfer. However, the main focus is on the reactive mass transfer on rigid and mobile surfaces where the interfacial reaction, molecular diffusion and adsorption layers are decisive. The respective extraction of zinc with a cation exchanger and of acetic acid with an anion exchanger is discussed as case studies. Since adsorption layers and surfactants have a major impact on liquid-liquid extraction efficiency, the final chapter reviews several tech niques which make use of polymeric species in an extractive process. A short review is also given on extraction apparatus and the hydrodynamics (hydraulic design, droplet populance balances) of columns. Much of the booklet is based on the PhD works of C. Czapla (2000), G. Modes (2000), H. Klocker (1996), T. Kronberger (1995), M. Marters (2000), M. Roos (2000), M. Traving (2000) and B. Wachter (1996) who I wish to thank for their fruitful contributions."
Properties of systems with long range interactions are still poorly understood despite being of importance in most areas of physics. The present volume introduces and reviews the effort of constructing a coherent thermodynamic treatment of such systems by combining tools from statistical mechanics with concepts and methods from dynamical systems. Analogies and differences between various systems are examined by considering a large range of applications, with emphasis on Bose--Einstein condensates. Written as a set of tutorial reviews, the book will be useful for both the experienced researcher as well as the nonexpert scientist or postgraduate student.
Combustion of Two-Phase Reactive Media addresses the complex phenomena involved in the burning of solid and liquid fuels. In fact, the multiplicity of phenomena characteristic of combustion of two-phase media determine the contents. The three parts deal with: the dynamics of a single particle; combustion wave propagation in two-phase reactive media; and thermal regimes of combustion reactors. The book generalizes the results of numerous investigations into the ignition and combustion of solid particles, droplets and bubbles, combustion wave propagation in heterogeneous reactive media, the stability of combustion of two-phase media, as well as the thermal regimes of high-temperature combustion reactors. It merges findings from the authors investigations into problems of two-phase flows and material from graduate-level courses they teach at Technion-Israel Institute of Technology.
Providing the first comprehensive treatment, this book covers all aspects of the laser Doppler and phase Doppler measurement techniques, including light scattering from small particles, fundamental optics, system design, signal and data processing, tracer particle generation, and applications in single and two-phase flows. The book is intended as both a reference book for more experienced users as well as an instructional book for students. It provides ample material as a basis for a lecture course on the subject and represents one of the most comprehensive treatments of the phase Doppler technique to date. The book will serve as a valuable reference book in any fluid mechanics laboratory where the laser Doppler or phase Doppler techniques are used. This work reflects the authors' long practical experience in the development of the techniques and equipment, as the many examples confirm. |
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