J.-P. CALISTE, A. TRUYOL AND J. WESTBROOK The Series, "Data and Knowledge in a Changing World", exemplifies CODATA's primary purpose of collecting, from widely different fields, a wealth of information on efficient exploitation of data for progress in science and technology and making that information available to scientists and engineers. A separate and complementary CODATA Reference Series will present Directories of compiled and evaluated data and Glossaries of data-related terms. The present book "Thermodynamic Modeling and Materials Data Engineering" discusses thermodynamic, structural, systemic and heuristic approaches to the modeling of complex materials behavior in condensed phases, both fluids and solids, in order to evaluate their potential applications. Itwas inspired by the Symposium on "Materials and Structural Properties" held during the 14th International CODATA Conference in Chambery, France. The quality of the contributions to this Symposium motivated us to present" a coherent book of interest to the field. Updated contributions inspired by Symposium discussions and selections from other CODATA workshops concerning material properties data and Computer Aided Design combine to highlight the complexity of material data issues on experimental, theoretical and simulation levels Articles were selected for their pertinence in three areas. Complex data leading to interesting developments and tools such as: * new developments in state equations and their applications, * prediction and validation of physical and energy data by group correlations for pure compounds, * modeling and prediction of mixture properties.

The aim of this book is to give a unified and critical account of the fundamental aspects of liquid crystals. Preference is given to discussing the assumptions made in developing theories and analyzing experimental data rather than to attempting to compile all the latest results. The book has four parts. Part I is quite descriptive in character and gives a general overview of the various liquid crystalline phases. Part II deals with the macroscopic continuum theory of liquid crystals and gives a systematic development of the theory from a tensorial point of view thus emphasizing the relevant symmetries. Part III concentrates on experiments that provide microscopic information on the orientational behaviour of the molecules. Finally Part IV discusses the theory of the various phases and their attendant phase transitions from both a Landau and a molecular-statistical point of view. Simplifying the various models as far as possible, it critically examines the merits of a molecular-statistical approach.

Shock wave research covers important inderdisciplinary areas which range from basic topics on gasdynamics, combustion and detonation, physico-chemistry of high temperature gases, plasma physics, astro and geophysics, materials science, astronautics and space technology to medical and industrial applications. This book includes 202 papers presented at the 18th the International Symposium on Shock Waves which describe the research frontier of shock wave phenopmena and 14 plenary lectures which show the state of the art of various fields of shock wave research. This proceedings is a unique collection of most important and updated shock wave research.

Macroscopic physics provides us with a great variety of pattern-forming systems displaying propagation phenomena, from reactive fronts in combustion, to wavy structures in convection and to shear flow instabilities in hydrodynamics. These proceedings record progress in this rapidly expanding field. The contributions have the following major themes: - The problems of velocity selection and front morphology of propagating interfaces in multiphase media, with emphasis on recent theoretical and experimental results on dendritic crystal growth, Saffman-Taylor fingering, directional solidification and chemical waves. - The "unfolding" of large-scale, low-frequency behavior in weakly confined homogeneous systems driven far from equilibrium, and more specifically, the envelope approach to the mathematical description of textures in different cases: steady cells, propagating waves, structural defects, and phase instabilities. - The implications of the presence of global downstream transport in open flows for the nature, convective or absolute, of shear flow instabilities, with applications to real boundary layer flows or shear layers, as reported in contributions covering experimental situations of fundamental and/or engineering interest.

This book summarizes the most recent theoretical, computational and experimental results dealing with homogeneous turbulence dynamics. A large class of flows is covered: flows governed by anisotropic production mechanisms (e.g. shear flows) and flows without production but dominated by waves (e.g. homogeneous rotating or stratified turbulence). Compressible turbulent flows are also considered. In each case, main trends are illustrated using computational and experimental results, while both linear and nonlinear theories and closures are discussed. Details about linear theories (e.g. Rapid Distortion Theory and variants) and nonlinear closures (e.g. EDQNM) are provided in dedicated chapters, following a fully unified approach. The emphasis is on homogeneous flows, including several interactions (rotation, stratification, shear, shock waves, acoustic waves, and more) which are pertinent to many applications fields - from aerospace engineering to astrophysics and Earth sciences.

The renormalization-group approach is largely responsible for the considerable success which has been achieved in the last ten years in developing a complete quantitative theory of phase transitions. Before, there was a useful physical picture of phase transitions, but a general method for making accurate quantitative predictions was lacking. Existent theories, such as the mean-field theory of Landau, sometimes reproduce phase diagrams reliably but were known to fail qualitatively near critical points, where the critical behavior is particularly interesting be cause of its universal character. In the mid 1960's Widom found that the singularities in thermodynamic quanti ties were well described by homogeneous functions. Kadanoff extended the homogeneity hypothesis to correlation functions and linked it to the idea of scale invariance. In the early 1970's Wilson showed how Kadanoff's rescaling could be explicitly carried out near the fixed point of a flow in Hamiltonian space. He made the first practical renormalization-group calculation of the flow induced by the elimination of short-wave-length Fourier components of the order-parameter field. The univer sality of the critical behavior emerges in a natural way in this approach, with a different fixed point for each universality class. The discovery by Wilson and Fisher of a systematic expansion procedure in E for a system in d = 4 - E dimen sions was followed by a cascade of calculations of critical quantities as a function of d and of the order-parameter dimensionality n."

This volume contains the proceedings of the Fourth International Conference on Phonon Scattering in Condensed Matter held from August 22-26, 1983 at the University of Stuttgart. The preceding conferences were organized at Saint Maxime and Paris in 1972, at the University of Nottingham in 1975, and at the Brown University Providence/Rhode Island in 1979. The Stuttgart conference, like the preceding conferences, was mainly con cerned with "propagating" high-frequency acoustic phonons, mechanical waves and heat up to the lattice limiting frequency. Lattice dynamics, optical pho nons, phase transitions, etc., were included as far as they are involved in acoustical phonon scattering, propagation and generation. In this context the conference covered all aspects of acoustical phonon physics, especially generation of phonons, propagation, scattering and detection. Since acoustic phonons participate in most energy-transfer processes in solids and liquids, the field of interest is growing rapidly. Therefore exciting new developments of acoustic phonon physics could be presented at the Stuttgart conference as well as important progress with respect to well-known problems, as, for example, the Kapitza resistance. Two hundred and six scientists from 21 countries attended the conference. Thirteen invited papers and 105 contributed papers, with 34 as posters, were presented. The discussions are included in this volume. A discussion session on large wave vector phonons was organized and chaired by V. Narayanamurti. A discussion session on phonon scattering at interfaces was organized and chaired by R.O. Pohl."

Covers a wide spectrum of applications and contains a wide discussion of the foundations and the scope of the most current theories of non-equilibrium thermodynamics. The new edition reflects new developments and contains a new chapter on the interplay between hydrodynamics and thermodynamics.

This unique book provides a fundamental introduction to all aspects of modern plasma chemistry. The book describes mechanisms and kinetics of chemical processes in plasma, plasma statistics, thermodynamics, fluid mechanics, and electrodynamics, as well as all major electric discharges applied in plasma chemistry. The book considers most of the major applications of plasma chemistry from electronics to thermal coatings, from treatment of polymers to fuel conversion and hydrogen production, and from plasma metallurgy to plasma medicine. The book can be helpful to engineers, scientists, and students interested in plasma physics, plasma chemistry, plasma engineering, and combustion, as well as in chemical physics, lasers, energy systems, and environmental control. The book contains an extensive database on plasma kinetics and thermodynamics as well as a lot of convenient numerical formulas for practical calculations related to specific plasma-chemical processes and applications. The book contains a large number of problems and concept questions that are helpful in university courses related to plasma, lasers, combustion, chemical kinetics, statistics and thermodynamics, and high-temperature and high-energy fluid mechanics.

ill the past three decades there has been enonnous progress in identifying the es sential role that "nonlinearity" plays in physical systems. Classical nonlinear wave equations can support localized, stable "soliton" solutions, and nonlinearities in quantum systems can lead to self-trapped excitations, such as polarons. Since these nonlinear excitations often dominate the transport and response properties of the systems in which they exist, accurate modeling of their effects is essential to interpreting a wide range of physical phenomena. Further, the dramatic de velopments in "deterministic chaos", including the recognition that even simple nonlinear dynamical systems can produce seemingly random temporal evolution, have similarly demonstrated that an understanding of chaotic dynamics is vital to an accurate interpretation of the behavior of many physical systems. As a conse quence of these two developments, the study of nonlinear phenomena has emerged as a subject in its own right. During these same three decades, similar progress has occurred in understand ing the effects of "disorder". Stimulated by Anderson's pioneering work on "dis ordered" quantum solid state materials, this effort has also grown into a field that now includes a variety of classical and quantum systems and treats "disorder" arising from many sources, including impurities, random spatial structures, and stochastic applied fields. Significantly, these two developments have occurred rather independently, with relatively little overlapping research.

Advances through carefully conducted quantitative work on well designed, high quality materials characterize the present state of high-temperature superconductivity research. The contributions to this volume present a theoretical and experimental overview of electronic structure and physical properties, including anisotropic features, of high-temperative materials, with a focus on cuprates. In order to enhance the understanding of the mechanisms of superconductivity at high temperatures, this volume is divided into theoretical and experimental parts. The contributions to the two parts correspond to each other, giving readers involved in either area of research activity a reference to findingsof the other. On the other hand, this book gives young physicists high-level information on the present state of research, enhanced by tutorial contributions of leading physicists in the field.

The development of the modern theory of metals and alloys has coincided with great advances in quantum-mechanical many-body theory, in electronic structure calculations, in theories of lattice dynamics and of the configura tional thermodynamics of crystals, in liquid-state theory, and in the theory of phase transformations. For a long time all these different fields expanded quite independently, but now their overlap has become sufficiently large that they are beginning to form the basis of a comprehensive first-principles the ory of the cohesive, structural, and thermodynamical properties of metals and alloys in the crystalline as well as in the liquid state. Today, we can set out from the quantum-mechanical many-body Hamiltonian of the system of electrons and ions, and, following the path laid out by generations of the oreticians, we can progress far enough to calculate a pressure-temperature phase diagram of a metal or a composition-temperature phase diagram of a binary alloy by methods which are essentially rigorous and from first prin ciples. This book was written with the intention of confronting the materials scientist, the metallurgist, the physical chemist, but also the experimen tal and theoretical condensed-matter physicist, with this new and exciting possibility. Of course there are limitations to such a vast undertaking as this. The selection of the theories and techniques to be discussed, as well as the way in which they are presented, are necessarily biased by personal inclination and personal expertise."

The 2002 Pan-American Advanced Studies Institute School on Quantum Gravity was held at the Centro de Estudios Cientificos (CECS), Valdivia, Chile, January 4-14, 2002. The school featured lectures by ten speakers, and was attended by nearly 70 students from over 14 countries. A primary goal was to foster interaction and communication between participants from different cultures, both in the layman 's sense of the term and in terms of approaches to quantum gravity. We hope that the links formed by students and the school will persist throughout their professional lives, continuing to promote interaction and the essential exchange of ideas that drives research forward.

This volume contains improved and updated versions of the lectures given at the School. It has been prepared both as a reminder for the participants, and so that these pedagogical introductions can be made available to others who were unable to attend. We expect them to serve students of all ages well.

This text on the statistical theory of nonequilibrium phenomena grew out of lecture notes for courses on advanced statistical mechanics that were held more or less regularly at the Physics Department of the Technical University in Munich. My aim in these lectures was to incorporate various developments of many-body theory made during the last 20-30 years, in particular the correlation function approach, not just as an "extra" alongside the more "classical" results; I tried to use this approach as a unifying concept for the presentation of older as well as more recent results. I think that after so many excellent review articles and advanced treatments, correlation functions and memory kernels are as much a matter of course in nonequilibrium statistical physics as partition functions are in equilibrium theory, and should be used as such in regular courses and textbooks. The relations between correlation functions and earlier vehicles for the formulation of nonequilibrium theory such as kinetic equations, master equations, Onsager's theory, etc. , are discussed in detail in this volume. Since today there is growing interest in nonlinear phenomena I have included several chapters on related problems. There is some nonlinear response theory, some results on phenomenological nonlinear equations and some microscopic applications of the nonlinear response formalism. The main focus, however, is on the linear regime.

Efficiency is one of the most frequently used terms in thermodynamics, and it indicates how well an energy conversion or process is accomplished. Efficiency is also one of the most frequently misused terms in thermodynamics and is often a source of misunderstanding. This is because efficiency is often used without being properly defined first. This book intends to provide a comprehensive evaluation of various efficiencies used for energy transfer and conversion systems including steady-flow energy devices (turbines, compressors, pumps, nozzles, heat exchangers, etc.), various power plants, cogeneration plants, and refrigeration systems. The book will cover first-law (energy based) and second-law (exergy based) efficiencies and provide a comprehensive understanding of their implications. It will help minimize the widespread misuse of efficiencies among students and researchers in energy field by using an intuitive and unified approach for defining efficiencies. The book will be particularly useful for a clear understanding of second law (exergy) efficiencies for various systems. It may serve as a reference book to the researchers in energy field. The definitions and concepts developed in the book will be explained through illustrative examples.

Review articles by leading scientists in their fields are brought together in this volume to provide a comprehensive treatment of photoacoustic, photothermal and photochemical processes at surfaces and in thin films. The articles introduce the fields, review present knowledge and conclude with latest developments and future prospects. Topics covered include laser-induced desorption, ablation and surface damage; surface acoustic waves; photothermal and photoacoustic characterization of thin films and interfaces; depth profiling in the frequency and time domains; remote testing and nondestructive evaluation; materials characterization; and new theoretical approaches using fractals. The book will interest newcomers to photoacoustics, since it gives an overview of current research and details of experimental methods. It will also be a source of information for those already in the field due to its clear presentation of theory and experimental results. All relevant literature references in this rapidly expanding field are included.

The idea of a workshop devoted to the static and dynamic properties of liquids arose from two smaller meetings on the same topic held at the Interfaculty Reactor Institute, Delft, The Netherlands in 1985 and 1987, and from the LAM conference (International Conference on Liquid and Amorphous Metals) held at Garmisch Partenkirchen, FRG, in 1986. The object of the Workshop was to bring together experimentalists, theoreticians and people working on computer simulations in or der to learn about developments in the microscopic behaviour of liquids. Approx imately 35 scientists from Austria, France, Israel, Italy, Sweden, The Netherlands, the United Kingdom, the Federal Republic of Germany and Yugoslavia gathered at the Hotel "Libertas", Dubrovnik, in Yugoslavia, June 27-30, 1988 to hear ten in vited talks and nineteen contributed papers on a wide range of subjects, including generalized hydrodynamics, mode coupling theory, liquids at surfaces, extraction of effective potentials, and the glass transition. The most numerous were the papers dealing with computer simulation, and then those on supercooled liquids and the glass transition. The number of experimental results was relatively small, which points to difficulties in this kind of research (evaluation of experimental data). The workshop closed with an expanded round-table discussion of the main themes of the meeting, with an emphasis on the likely trend of investigations in the future. This discussion is summarized at the end of this volume.

Radio telescopes as well as communication antennas operate under the influence of gravity, temperature and wind. Among those, temperature influences may degrade the performance of a radio telescope through transient changes of the focus, pointing, path length and sensitivity, often in an unpredictable way. Thermal Design and Thermal Behaviour of Radio Telescopes and their Enclosures reviews the design and construction principles of radio telescopes in view of thermal aspects and heat transfer with the variable thermal environment; it explains supporting thermal model calculations and the application and efficiency of thermal protection and temperature control; it presents many measurements illustrating the thermal behaviour of telescopes in the environment of their observatory sites.

The book benefits scientists and radio/communication engineers, telescope designers and construction firms as well as telescope operators, observatory staff, but also the observing astronomer who is directly confronted with the thermal behaviour of a telescope.

Introduction to Thermoelectricity is the latest work by Professor Julian Goldsmid drawing on his 55 years experience in the field. The theory of the thermoelectric and related phenomena is presented in sufficient detail to enable researchers to understand their observations and develop improved thermoelectric materials. The methods for the selection of materials and their improvement are discussed. Thermoelectric materials for use in refrigeration and electrical generation are reviewed. Experimental techniques for the measurement of properties and for the production of thermoelements are described. Special emphasis is placed on nanotechnology which promises to yield great improvements in the efficiency of thermoelectric devices. Chapters are also devoted to transverse thermoelectric effects and thermionic energy conversion, both techniques offering the promise of important applications in the future.

Enrico Fermi s scientific work, noted for its originality and breadth, has had lasting consequences throughout modern science. Written by close colleagues as well as scientists whose fields were profoundly influenced by Fermi, the papers collected here constitute a tribute to him and his scientific legacy. They were commissioned on the occasion of his 100th birthday by the Italian Physical Society and confirm that Fermi was a rare combination of theorist, experimentalist, teacher, and inspiring colleague. The book is organized into three parts: three biographical overviews by close colleagues, replete with personal insights; fourteen analyses of Fermi's impact by specialists in their fields, spanning physics, chemistry, mathematics, and engineering; and a year-by-year chronology of Fermi s scientific endeavors. Written for a general scientific audience, Enrico Fermi: His Work and Legacy offers a highly readable source on the life of one of the 20th century's most distinguished scientists and a must for everybody interested in the history of modern science."

During the last decade there has been a renewed interest in research on supramolecular assemblies in solutions, such as micelles and microemulsions, not only because of their extensive applications in industries dealing with catalysts, detergency, biotechnology, and enhanced oil recovery, but also due to the development of new and more powerful experimental and theoretical tools for probing the microscopic behavior of these systems. Prominent among the array of the newly available experimental techniques are photon correlation spectroscopy, small-angle neutron and X-ray scattering, and neutron spin-echo and nuclear magnetic resonance spectroscopies. On the theoretical side, the traditionally emphasized thermodynamic approach to the study of the phase behavior of self-assembled systems in solutions is gradually being replaced by statistical mechanical studies of semi-micro scopic and microscopic models of the assemblies. Since the statistical mechanical approach demands as its starting point the microscopic struc tural information of the self-assembled system, the experimental determina tion of the structures of micelles and microemulsions becomes of paramount interest. In this regard the scattering techniques mentioned above have played an important role in recent years and will continue to do so in the future. In applying the scattering techniques to the supramolecular species in solution, one cannot often regard the solution to be ideal. This is because the inter-aggregate interaction is often long-ranged since it is coulombic in nature and the interparticle correlations are thus appreciable."

As a basis for printed property charts and tables, empirical multiparameter equa tions of state have been the most important source of accurate thermodynamic property data for more than 30 years now. However, due to increasing demands on the accuracy of thermodynamic property data in computerised calculations as well as the availability of appropriate software tools, and the ever increasing computer power, such formulations are nowadays becoming a valuable tool for everyday work. This development has substantially increased the number of scientists, engi neers, and students who are working with empirical multiparameter equations of state, and it continues to do so. Nevertheless, common knowledge on this kind of thermodynamic property models and on the ongoing progress in this scientific discipline is still very limited. Multiparameter equations of state do not belong to the topics which are taught intensively in thermodynamic courses in engineering and natural sciences and the books and articles where they are published mainly deal with the thermodynamic properties of certain substances rather than with the theoretical background of the used equations of state. In contrast to this, my concern mainly was to give a survey of the theoretical background of multiparameter equations of state both with regard to their application and their development."

This booklet is designed to bridge the gap between handbooks and technical literature and aims at graduate students or experienced readers. Commercial flow sheeting simulation software is increasingly available and is used in the early steps of process design in industry. As to this, more sophisticated and precise models based on activities instead of concentrations should be used. After an introductory chapter there is in Chapter 2 an intensive discussion of reactive phase equilibria of ionic and non-ionic solutes based on chemical potentials. Chapter 3 introduces to multicomponent diffusion and mass transfer. However, the main focus is on the reactive mass transfer on rigid and mobile surfaces where the interfacial reaction, molecular diffusion and adsorption layers are decisive. The respective extraction of zinc with a cation exchanger and of acetic acid with an anion exchanger is discussed as case studies. Since adsorption layers and surfactants have a major impact on liquid-liquid extraction efficiency, the final chapter reviews several tech niques which make use of polymeric species in an extractive process. A short review is also given on extraction apparatus and the hydrodynamics (hydraulic design, droplet populance balances) of columns. Much of the booklet is based on the PhD works of C. Czapla (2000), G. Modes (2000), H. Klocker (1996), T. Kronberger (1995), M. Marters (2000), M. Roos (2000), M. Traving (2000) and B. Wachter (1996) who I wish to thank for their fruitful contributions."

Properties of systems with long range interactions are still poorly understood despite being of importance in most areas of physics. The present volume introduces and reviews the effort of constructing a coherent thermodynamic treatment of such systems by combining tools from statistical mechanics with concepts and methods from dynamical systems. Analogies and differences between various systems are examined by considering a large range of applications, with emphasis on Bose--Einstein condensates. Written as a set of tutorial reviews, the book will be useful for both the experienced researcher as well as the nonexpert scientist or postgraduate student.

Speech by Toyosaburo Taniguchi Dr. Kubo, Chairman, Distinguished Guests, and Friends, I am very happy, pleased and honored to be here this evening with so many distinguished guests, friends, and scholars from within this country and from different parts of the world. The Taniguchi Foundation wishes to extend a warm and sincere welcome to the many participants of the Ninth International Symposium on the Theory of Condensed Matter, which se ries was inaugurated eight years ago through the strenuous efforts of Dr. Ryogo Kubo, who is gracing us today with his presence. We are deeply indebted to Dr. Kubo, Dr. Suzuki, and their associates, who havE' spent an enormous amount of time and effort to make this particular symposium possible. We are convinced that the foundation should not be considered as what makes our symposium a success. The success is entirely due, I feel, to the continuous efforts of the Organizing Committee and of all those who have lent their support to this program. In this sense, your words of praise about the symposium, if any, should be directed to all of them. So far, I have met in person a total of 62 participants in this Division from 12 countries: Argentina, Belgium, Canada, Denmark, the Federal Republic of Germany, France, Ireland, Israel, Rumania, Switzerland, the United Kingdom, and the United States of America, with 133 participants from Japan. Those friends I have been privileged to make, I shall always treasure."