Owing to efforts and legislative action - initiated above all by the government of the United States - to use cleaner fuels and thus make a contribution towards a better environment, public attention is back again on using methanol in carbu rettor and diesel engines. Most prominent among the raw materials from which methanol can be produced is coal, whose deposits and resources are many times larger than those of liquid and gaseous hydrocarbons. This book deals with the production of methanol from coal. It describes both the individual steps that are required for this process and the essential ancillary units and offsites associated with the process itself . . It is not meant to inform the reader about the intricate details of the processes, which can much better be taken from the specialized literature that deals exclusively and in detail with them or from the well-known standard engineering books. Rather, this book is to give the reader an impression how manifold a field this is, how many process variations and combinations the designer of such plants has to consider in order to arrive at an optimum design in each particular case. Apart from the production of chemical-grade methanol, the book deals briefly also with fuel methanol production, i. e. with the production of alcohol mixes. One of the many possible routes from coal to methanol is illustrated by a process flow diagram, and a material and energy balance is compiled for this typical example."

The potential of supercritical fluid methods is presented in a comprehensive way. On the basis of a careful discussion of physical and chemical principles, the application of this method in process technology is demonstrated.

The aim of this book is to comment on, and clarify, the mathematical aspects of the theory of thermodynamics. The standard presentations of the subject are often beset by a number of obscurities associated with the words "state", "reversible", "irreversible", and "quasi-static". This book is written in the belief that such obscurities are best removed not by the formal axiomatization of thermodynamics, but by setting the theory in the wider context of a genuine field theory which incorporates the effects of heat conduction and intertia, and proving appropriate results about the governing differential equations of this field theory. Even in the simplest one-dimensional case it is a nontrivial task to carry through the details of this program, and many challenging problems remain open.

During the last half century, the development and testing of prediction models of combustion chamber performance have been an ongoing task at the International Flame Research Foundation (IFRF) in IJmuiden in the Netherlands and at many other research organizations. This task has brought forth a hierarchy of more or less standard numerical models for heat transfer predictions, in particular for the prediction of radiative heat transfer. Unfortunately all the methods developed, which certainly have a good physical foundation, are based on a large number of extreme sim plifications or uncontrolled assumptions. To date, the ever more stringent requirements for efficient production and use of energy and heat from com bustion chambers call for prediction algorithms of higher accuracy and more detailed radiative heat transfer calculations. The driving forces behind this are advanced technology requirements, the costs of large-scale experimen tal work, and the limitation of physical modeling. This interest is growing more acute and has increased the need for the publication of a textbook for more accurate treatment of radiative transfer in enclosures. The writing of a textbook on radiative heat transfer, however, in ad dition to working regularly on other subjects is a rather difficult task for which some years of meditation are necessary. The book must satisfy two requirements which are not easily reconciled. From the mathematical point of view, it must be written in accordance with standards of mathemati cal rigor and precision."

In the tradition of its predecessors, this volume comprises a selection of the best papers presented at the Ninth International Symposium on Applications of Laser Techniques to Fluid Mechanics, held in Lisbon in July 2000.
The papers reflect the state-of-the-art in laser applications of laser techniques in fluid mechanics describing novel ideas for instrumentation, instrumentation developments, results of measurements of wall-bounded flows, free flows and flames and flow and combustion in engines. The papers demonstrate the continuing interest in the development of an understanding of new methodologies and implementation in terms of new instrumentation.

This volume contains twenty contributions of work, conducted since 1996 in the French- German Research Programme "Numerical Flow Simulation" of the Centre National de la Recherche Scientifique (CNRS) and the Deutsche Forschungsgemeinschaft (DFG). The main purpose of this publication is to give an overview over the work conducted in this programme, and to make the results obtained available to the pUblic. The reports are grouped under the four headings "Development of Solution Techniques", "Crystal Growth and Melts", "Flows of Reacting Gases" and "Turbulent Flows". AIl contributions to this publica- tion were reviewed by a board consisting of T. Alziary de Roquefort (Poitiers, France), P. Bontoux (Marseille, France), JA Desideri (Sophia-Antipolis, France), W. Kordulla (G6t- tingen, Germany), R. Peyret (Nice, France), R. Rannacher (Heidelberg, Germany), G. War- necke (Magdeburg, ,Germany), and the editor. The responsibility for the contents of the reports nevertheless lies with the authors. E. H. Hirschel Editor Preface The Colloquium on "Numerical Simulation of Flows", Marseille, November 21 and 22, th 1997, was the 6 Joint CNRS-DFG Colloquium organized in the frame of the French- German Research Collaboration on Computational Fluid Dynamics. This Collaborative Program was elaborated progressively since 1991, when the two major research groups were brought together: the Priority Program "Flow Simulation with Super Computers" from the DFG in Germany and the Groupement de Recherche de "Mecanique des Fluides NumCrique" (GDR MFN) from the CNRS in France.

This book takes the topic of H-infinity control as a point of departure, and pursues an improved controller design suggested in the mainstream of robust control. Using stochastic methods, the book is important to the circuits and systems community, alongside researchers in networking systems, operator theory and linear multivariable control.

Simple random walks - or equivalently, sums of independent random vari ables - have long been a standard topic of probability theory and mathemat ical physics. In the 1950s, non-Markovian random-walk models, such as the self-avoiding walk, were introduced into theoretical polymer physics, and gradu ally came to serve as a paradigm for the general theory of critical phenomena. In the past decade, random-walk expansions have evolved into an important tool for the rigorous analysis of critical phenomena in classical spin systems and of the continuum limit in quantum field theory. Among the results obtained by random-walk methods are the proof of triviality of the cp4 quantum field theo ryin space-time dimension d (:::: ) 4, and the proof of mean-field critical behavior for cp4 and Ising models in space dimension d (:::: ) 4. The principal goal of the present monograph is to present a detailed review of these developments. It is supplemented by a brief excursion to the theory of random surfaces and various applications thereof. This book has grown out of research carried out by the authors mainly from 1982 until the middle of 1985. Our original intention was to write a research paper. However, the writing of such a paper turned out to be a very slow process, partly because of our geographical separation, partly because each of us was involved in other projects that may have appeared more urgent.

Building on Wilson's renormalization group, the authors have developed a unified approach that not only reproduces known results but also yields new results. A systematic exposition of the contemporary theory of phase transitions, the book includes detailed discussions of phenomena in Heisenberg magnets, granular super-conducting alloys, anisotropic systems of dipoles, and liquid-vapor transitions. Suitable for advanced undergraduates as well as graduate students in physics, the text assumes some knowledge of statistical mechanics, but is otherwise self-contained.

Covers a wide spectrum of applications and contains a wide discussion of the foundations and the scope of the most current theories of non-equilibrium thermodynamics. The new edition reflects new developments and contains a new chapter on the interplay between hydrodynamics and thermodynamics.

Among various branches of polymer physics an important position is occupied by that vast area, which deals with the thermal behav ior and thermal properties of polymers and which is normally called the thermal physics of polymers. Historically it began when the un usual thermo-mechanical behavior of natural rubber under stretch ing, which had been discovered by Gough at the very beginning of the last century, was studied 50 years later experimentally by Joule and theoretically by Lord Kelvin. This made it possible even at that time to distinguish polymers from other subjects of physical investigations. These investigation laid down the basic principles of solving the key problem of polymer physics - rubberlike elasticity - which was solved in the middle of our century by means of the statistical thermodynamics applied to chain molecules. At approx imately the same time it was demonstrated, by using the methods of solid state physics, that the low temperature dependence of heat capacity and thermal expansivity of linear polymers should fol low dependencies different from that characteristic of nonpolymeric solids. Finally, new ideas about the structure and morphology of polymers arised at the end of the 1950s stimulated the development of new thermal methods (differential scanning calorimetry, defor mation calorimetry), which have become very powerful instruments for studying the nature of various states of polymers and the struc tural heterogeneity."

This work was begun quite some time ago at the University of Oxford during the tenure of an Overseas Scholarship of the Royal Commission for the Exhibition of 1851 and was completed at Banga lore when the author was being supported by a maintenance allowance from the CSIR Pool for unemployed scientists. It is hoped that significant developments taking place as late as the beginning of 1965 have been incorporated. The initial impetus and inspiration for the work came from Dr. K. Mendelssohn. To him and to Drs. R. W. Hill and N. E. Phillips, who went through the whole of the text, the author is obliged in more ways than one. For permission to use figures and other materials, grateful thanks are tendered to the concerned workers and institutions. The author is not so sanguine as to imagine that all technical and literary flaws have been weeded out. If others come across them, they may be charitably brought to the author's notice as proof that physics has become too vast to be comprehended by a single onlooker. E. S. RAJA GoPAL Department of Physics Indian Institute of Science Bangalore 12, India November 1965 v Contents Introduction ................................................................. .

Modern astronomy has been characterized by an enormous growth in data acquisition - from new technologies in telescopes, detectors, and computation. One can now compile catalogs of tens or hundreds of millions of stars or galaxies and databases from satellite-based observations are reaching terabit proportions. This wealth of data gives rise to statistical challenges not previously encountered in astronomy. This book is the result of a workshop held at Pennsylvania State University in August 1991 that brought together leading astronomers and statisticians to consider statistical challenges encountered in modern astronomical research. The chapters have all been thoroughly revised in the light of the discussions at the conference, and some of the lively discussion is recorded here as well.

This monograph treats, for the first time, major aspects of gas dynamics of nozzles from a general point of view. Its outstanding feature is the pre- sentation of the modern theory of gas flows and modern analytical and nu- merical methods, together with numerous examples of practical applications. At the same time, quite diverse physico-chemical processes, such as disso- ciation and recombination, relaxation of vibrational degrees of freedom, two-phase flows wi th phase trans formati ons and e 1 ectromagneti c i nf1 uences, are considered. The material is presented in such a way as to help the reader to use numer- ous methods and approaches, not only for the study of gas flows in nozzles, but also for the investigation of a wide variety of problems of physical gas dynamics in different areas of application. The number of applications which may benefit from the use of the methods and results presented in this book is constantly growing. Theoretical, numerical and analytical methods of physical gas dynamics of internal flows may be, and are nowadays, ap- plied to solving the problem of preventing pollution of the air basin with toxic substances. These methods make it possible to describe the formation and transformation of toxic components in the vapour generators of thermal power plants, internal combustion engines and various metallurgical instal- lations. The methods of physical gas dynamics may be used in meteorology and powder metallurgy to create ultradispersed media and predict their proper- ties.

Stochastic Energetics by now commonly designates the emerging field that bridges the gap between stochastic dynamical processes and thermodynamics. Triggered by the vast improvements in spatio-temporal resolution in nanotechnology, stochastic energetics develops a framework for quantifying individual realizations of a stochastic process on the mesoscopic scale of thermal fluctuations. This is needed to answer such novel questions as: Can one cool a drop of water by agitating an immersed nano-particle? How does heat flow if a Brownian particle pulls a polymer chain? Can one measure the free-energy of a system through a single realization of the associated stochastic process? This book will take the reader gradually from the basics to the applications: Part I provides the necessary background from stochastic dynamics (Langevin, master equation), Part II introduces how stochastic energetics describes such basic notions as heat and work on the mesoscopic scale, Part III details several applications, such as control and detection processes, as well as free-energy transducers. It aims in particular at researchers and graduate students working in the fields of nanoscience and technology.

This volume contains the proceedings of the symposium held on Friday 6 July 1990 at the University Pierre et Marie Curie (Paris VI), France, in honor of Professor Henri Cabannes on the occasion of his retirement. There were about one hundred participants from nine countries: Canada, France, Germany, Italy, Japan, Norway, Portugal, the Netherlands, and the USA. Many of his past students or his colleagues were among the participants. The twenty-six papers in this volume are written versions submitted by the authors and cover almost all the fields in which Professor Cabannes has actively worked for more than forty-five years. The papers are presented in four chapters: classical kinetic theory and fluid dynamics, discrete kinetic theory, applied fluid mechanics, and continuum mechanics. The editors would like to take this opportunity to thank the generous spon sors of the symposium: the University Pierre et Marie Curie, Commissariat a l'Energie Atomique (especially Academician R. Dautray and Dr. N. Camarcat) and Direction des Recherches et Etudes Techniques (especially Professor P. Lallemand). Many thanks are also due to all the participants for making the symposium a success. Finally, we thank Professor W. Beiglbock and his team at Springer-Verlag for producing this volume.

Many laboratory and astrophysical plasmas show deviations from local ther modynamic equilibrium (LTE). This monograph develops non-LTE plasma spectroscopy as a kinetic theory of particles and photons, considering the radiation field as a photon gas whose distribution function (the radiation in tensity) obeys a kinetic equation (the radiative transfer equation), just as the distribution functions of particles obey kinetic equations. Such a unified ap proach provides clear insight into the physics of non-LTE plasmas. Chapter 1 treats the principle of detailed balance, of central importance for understanding the non-LTE effects in plasmas. Chapters 2, 3 deal with kinetic equations of particles and photons, respectively, followed by a chapter on the fluid description of gases with radiative interactions. Chapter 5 is devoted to the H theorem, and closes the more general first part of the book. The last two chapters deal with more specific topics. After briefly discuss ing optically thin plasmas, Chap. 6 treats non-LTE line transfer by two-level atoms, the line profile coefficients of three-level atoms, and non-Maxwellian electron distribution functions. Chapter 7 discusses topics where momentum exchange between matter and radiation is crucial: the approach to thermal equilibrium through interaction with blackbody radiation, radiative forces, and Compton scattering. A number of appendices have been added to make the book self-contained and to treat more special questions. In particular, Appendix B contains an in troductory discussion of atomic line profile coefficients."

Thermodynamicsandstatisticalphysicsstudythephysicalproperties(mec- nical, thermal, magnetic, optical, electrical, etc.) of the macroscopic system. The tasks and objects of study in thermodynamics and statistical physics are identical. However, the methods of investigationinto macroscopicsystems are di?erent. Thermodynamics is a phenomenological theory. It studies the properties of bodies, without going into the mechanism of phenomena, i.e., not taking into consideration the relation between the internal structure of substance and phenomena, it generalizes experimental results. As a result of such a g- eralization, postulates and laws of thermodynamics made their appearance. These laws make it possible to ?nd general relations between the di?erent properties of macroscopic systems and the physical events occurring in them. Statisticalphysicsisa microscopic theory.Onthebasisoftheknowledgeof the type of particles a system consists of, the nature of their interaction, and thelawsofmotionoftheseparticlesissuingfromtheconstructionofsubstance, it explains the properties being observedon experiment, and predicts the new properties of systems. Using the laws of classical or quantum mechanics, and alsothe theoryofprobability, itestablishesqualitativelynewstatistical app- priatenesses of the physical properties of macroscopic systems, substantiates the laws of thermodynamics, determines the limits of their applicability, gives the statistical interpretation of thermodynamic parameters, and also works out methods of calculations of their means. The Gibbs method is based on statisticalphysics.Thismethodis themostcanonical.Therefore, inthis book, the exposition of the Gibbs method takes an important pla

Efficiency is one of the most frequently used terms in thermodynamics, and it indicates how well an energy conversion or process is accomplished. Efficiency is also one of the most frequently misused terms in thermodynamics and is often a source of misunderstanding. This is because efficiency is often used without being properly defined first. This book intends to provide a comprehensive evaluation of various efficiencies used for energy transfer and conversion systems including steady-flow energy devices (turbines, compressors, pumps, nozzles, heat exchangers, etc.), various power plants, cogeneration plants, and refrigeration systems. The book will cover first-law (energy based) and second-law (exergy based) efficiencies and provide a comprehensive understanding of their implications. It will help minimize the widespread misuse of efficiencies among students and researchers in energy field by using an intuitive and unified approach for defining efficiencies. The book will be particularly useful for a clear understanding of second law (exergy) efficiencies for various systems. It may serve as a reference book to the researchers in energy field. The definitions and concepts developed in the book will be explained through illustrative examples.

Introduction to Thermoelectricity is the latest work by Professor Julian Goldsmid drawing on his 55 years experience in the field. The theory of the thermoelectric and related phenomena is presented in sufficient detail to enable researchers to understand their observations and develop improved thermoelectric materials. The methods for the selection of materials and their improvement are discussed. Thermoelectric materials for use in refrigeration and electrical generation are reviewed. Experimental techniques for the measurement of properties and for the production of thermoelements are described. Special emphasis is placed on nanotechnology which promises to yield great improvements in the efficiency of thermoelectric devices. Chapters are also devoted to transverse thermoelectric effects and thermionic energy conversion, both techniques offering the promise of important applications in the future.

Con?gurational mechanics has attracted quite a bit of attention from various - search ?elds over the recent years/decades. Having been regarded in its infancy of the early years as a somewhat obscureand almost mystic ?eld of researchthat could only be understood by a happy few of insiders with a pronounced theoretical inc- nation, con?gurational mechanics has developed by now into a versatile tool that can be applied to a variety of problems. Since the seminal works of Eshelby a general notion of con?gurational - chanics has been developed and has successfully been applied to many pr- lems involving various types of defects in continuous media. The most pro- nent application is certainly the use of con?gurational forces in fracture - chanics. However, as con?gurational mechanics is related to arbitrary mat- ial inhomogeneities it has also very successfully been applied to many ma- rials science and engineering problems such as phase transitions and inelastic deformations. Also the modeling of materials with micro-structure evolution is an important ?eld, in which con?gurational mechanics can provide a better understanding of processes going on within the material. Besides these mechanically, physically, and chemically motivated applications, ideas from con?gurational mechanics are now increasingly applied within computational mechanics.

The term transport phenomena is used to describe processes in which mass, momentum, energy and entropy move about in matter. Advances in Transport Phenomena provide state-of-the-art expositions of major advances by theoretical, numerical and experimental studies from a molecular, microscopic, mesoscopic, macroscopic or megascopic point of view across the spectrum of transport p- nomena, from scientific enquiries to practical applications. The annual review series intends to fill the information gap between regularly published journals and university-level textbooks by providing in-depth review articles over a broader scope than in journals. The authoritative articles, contributed by international- leading scientists and practitioners, establish the state of the art, disseminate the latest research discoveries, serve as a central source of reference for fundamentals and applications of transport phenomena, and provide potential textbooks to senior undergraduate and graduate students. The series covers mass transfer, fluid mechanics, heat transfer and thermo- namics. The 2009 volume contains the four articles on biomedical, environmental and nanoscale transports. The editorial board expresses its appreciation to the c- tributing authors and reviewers who have maintained the standard associated with Advances in Transport Phenomena. We also would like to acknowledge the efforts of the staff at Springer who have made the professional and attractive pr- entation of the volume. Serial Editorial Board Editor-in-Chief Professor L. Q. Wang The University of Hong Kong, Hong Kong; lqwang@hku. hk Editors Professor A. R. Balakrishnan Indian Institute of Technology Madras, India Professor A.

Elements of Rapid Solidification: Fundamentals and Applications is the product of many years of concentrated work in the field of rapid solidification and processing. This quasi-monograph is unique in two ways. It brings together the talent of many international scientists in an effort to focus attention on all aspects of a new scientific field and it concentrates on fundamentals and practical applications. Simply stated, this book has been written by the senior students in the field of rapid solidification technology for the new generation of solid-state physicists, materials scientists, materials engineers, metallurgists and ceramicists.

The present book treats the science of heat conduction to an extent to which it can be taught in the specialized departments of Mechanical, Chemical or Electrical Engineering at a German Engineering University. No special prerequisites are assumed, and the mathematical methods employed draw, essentially, on the content of a normal curriculum in the depart ments mentioned above. The book is intended for adoption in conjunction with a standard lecture course or as an aid to review before examinations. It should also be found helpful to a practicing engineer in solving problems in heat conduction. As far as the readers are concerned, the book should, above all, show that exact and approximate solutions to answer questions which arise in a very large number of important, practical applications are at their disposal. Further, the book will show that in many cases it is possible to perform first estimates in a very elementary manner before engaging in the derivation of complicated analytic solutions. It is in this way that we utilize the past results of the great mathematicians of earlier generations who have bequeathed to us a considerable stock of methods and solutions. The application of such methods is illustrated in this book with the aid of examples drawn from various branches of science and technology. In this manner, the wide field of applicability of heat transfer will be made clear."