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Books > Science & Mathematics > Physics > Thermodynamics & statistical physics > Thermodynamics
From the reviews: "The book is excellent, and covers a very broad area (usually treated as separate topics) from a unified perspective. [ ] It will be very useful for both mathematicians and physicists." EMS Newsletter
Most of the specialists working in this interdisciplinary field of physics, biology, biophysics and medicine are associated with "The International Institute of Biophysics" (IIB), in Neuss, Germany, where basic research and possibilities for applications are coordinated. The growth in this field is indicated by the increase in financial support, interest from the scientific community and frequency of publications. Audience: The scientists of IIB have presented the most essential background and applications of biophotonics in these lecture notes in biophysics, based on the summer school lectures by this group. This book is devoted to questions of elementary biophysics, as well as current developments and applications. It will be of interest to graduate and postgraduate students, life scientists, and the responsible officials of industries and governments looking for non-invasive methods of investigating biological tissues.
This unique book provides a fundamental introduction to all aspects of modern plasma chemistry. The book describes mechanisms and kinetics of chemical processes in plasma, plasma statistics, thermodynamics, fluid mechanics, and electrodynamics, as well as all major electric discharges applied in plasma chemistry. The book considers most of the major applications of plasma chemistry from electronics to thermal coatings, from treatment of polymers to fuel conversion and hydrogen production, and from plasma metallurgy to plasma medicine. The book can be helpful to engineers, scientists, and students interested in plasma physics, plasma chemistry, plasma engineering, and combustion, as well as in chemical physics, lasers, energy systems, and environmental control. The book contains an extensive database on plasma kinetics and thermodynamics as well as a lot of convenient numerical formulas for practical calculations related to specific plasma-chemical processes and applications. The book contains a large number of problems and concept questions that are helpful in university courses related to plasma, lasers, combustion, chemical kinetics, statistics and thermodynamics, and high-temperature and high-energy fluid mechanics.
With the development of science and technology, more and more complex materials such as porous materials, ion liquid, liquid crystals, thin ?lms and colloids etc. are being developed in laboratories. However, it is dif?cult to prepare these advanced materials and use them on a large scale without some experience. Therefore, mo- cular thermodynamics, a method that laid emphasis on correlating and interpreting the thermodynamic properties of a variety of ?uids in the past, has been recently employed to study the equilibrium properties of complex materials and establish thermodynamic models to analyse the evolution process of their components, - crostructures and functions during the preparation process. In this volume, some important progress in this ?eld, from fundamental aspects to practical applications, is reviewed. In the ?rst chapter of this volume, Prof. Jianzhong Wu presents the application of Density Functional theory (DFT) for the study of the structure and thermodynamic properties of both bulk and inhomogeneous ?uids. This chapter presents a tut- ial overview of the basic concepts of DFT for classical systems, the mathematical relations linking the microstructure and correlation functions to measurable th- modynamic quantities, and the connections of DFT with conventional liquid-state theories. While for pedagogythe discussion is limited to one-componentsimple - ids, similar ideas and concepts are directly applicable to mixtures and polymeric systems of practical concern. This chapter also covers a few theoretical approaches to formulate the thermodynamic functional
The present volume contains expanded and substantially reworked records of invitedlecturesdeliveredduringthe38thKarpaczWinterSchoolofTheoretical Physics on "Dynamical Semigroups: Dissipation, Chaos, Quanta", which took placeinLadek , Zdr' oj,(Poland)intheperiod6-15February2002. Themainpurposeoftheschoolwastocreateaplatformfortheconfrontation ofviewpointsandresearchmethodologiesrepresentedbytwogroupsofexperts actually working in the very same area of theoretical physics. This situation is quite distinct in non-equilibrium statistical physics of open systems, where classicalandquantumaspectsareaddressedseparatelybymeansofverydi?erent andevenincompatibleformaltools. TheschooltopicsselectionbytheLecturersreads:dissipativedynamicsand chaoticbehaviour,modelsofenvironment-systemcouplingandmodelsofth- mostats;non-equilibriumstatisticalmechanicsandfarfromequilibriumphen- ena;quantumopensystems,decoherenceandlinkstoquantumchaos;quantum andclassicalapplicationsofMarkovsemigroupsandthevalidityofMarkovian approximations. Theorganizingprincipleforthewholeendeavourwastheissueofthedyn- ics of open systems and more speci?cally -15February2002. Themainpurposeoftheschoolwastocreateaplatformfortheconfrontation ofviewpointsandresearchmethodologiesrepresentedbytwogroupsofexperts actually working in the very same area of theoretical physics. This situation is quite distinct in non-equilibrium statistical physics of open systems, where classicalandquantumaspectsareaddressedseparatelybymeansofverydi?erent andevenincompatibleformaltools. TheschooltopicsselectionbytheLecturersreads:dissipativedynamicsand chaoticbehaviour,modelsofenvironment-systemcouplingandmodelsofth- mostats;non-equilibriumstatisticalmechanicsandfarfromequilibriumphen- ena;quantumopensystems,decoherenceandlinkstoquantumchaos;quantum andclassicalapplicationsofMarkovsemigroupsandthevalidityofMarkovian approximations. Theorganizingprincipleforthewholeendeavourwastheissueofthedyn- ics of open systems and more speci?cally - thedynamics of dissipation. Since this research area is extremely broad and varied, no single book can cover all importantdevelopments. Therefore,linkswithdynamicalchaoswerechosento representasupplementaryconstraint. Theprogrammeoftheschoolandits?naloutcomeintheformofthepresent volumehasbeenshapedwiththehelpofthescienti?ccommitteecomprising:R. Alicki,Ph. Blanchard,J. R. Dorfman,G. Gallavotti,P. Gaspard,I. Guarneri, ? F. Haake, M. Ku's, A. Lasota, B. Zegarlinski ' and K. Zyczkowski. Some of the committeememberstookchargeoflecturingtoo. Weconveyourthankstoall ofthem. Wewouldliketoexpresswordsofgratitudetomembersofthelocalorgan- ingcommittee,W. Ceg laandP. Lugiewicz, fortheirhelp. Specialthanksmust beextendedtoMrsAnnaJadczykforherhelpatvariousstagesoftheschool organizationandthecompetenteditorialassistance. Theschoolwas?nanciallysupportedbytheUniversityofWroc law,Univ- sityofZielonaG' ora,PolishMinistryofEducation,PolishAcademyofSciences, FoundationfortheKarpaczWinterSchoolofTheoreticalPhysicsandthe- nationfromtheDrWilhelmHeinrichHeraeusundElseHeraeusStiftung. Wrocla wandZielonaG' ora,Poland PiotrGarbaczewski June2002 RobertOlkiewicz TableofContents Introduction...1 ChapterI NonequilibriumDynamics SomeRecentAdvancesinClassicalStatisticalMechanics E. G. D. Cohen...7 DeterministicThermostatsandFluctuationRelations L. Rondoni...35 WhatIstheMicroscopicResponseofaSystem DrivenFarFromEquilibrium? C. Jarzynski...63 Non-equilibriumStatisticalMechanics ofClassicalandQuantumSystems D. Kusnezov,E. Lutz,K. Aoki...8 3 ChapterII DynamicsofRelaxationandChaoticBehaviour DynamicalTheoryofRelaxation inClassicalandQuantumSystems P. Gaspard...111 RelaxationandNoiseinChaoticSystems S. Fishman,S. Rahav...165 FractalStructuresinthePhaseSpace ofSimpleChaoticSystemswithTransport J. R. Dorfman...193 ChapterIII DynamicalSemigroups MarkovSemigroupsandTheirApplications R. Rudnicki,K. Pich'or,M. Tyran-Kaminska ' ...215 VIII TableofContents InvitationtoQuantumDynamicalSemigroups R. Alicki...239 FiniteDissipativeQuantumSystems M. Fannes...265 CompletePositivityinDissipativeQuantumDynamics F. Benatti,R. Floreanini,R. Romano...283 QuantumStochasticDynamicalSemigroup W. A. Majewski ...305 ChapterIV Driving,DissipationandControlinQuantumSystems DrivenChaoticMesoscopicSystems, DissipationandDecoherence D. Cohen...317 QuantumStateControlinCavityQED T. WellensandA. Buchleitner...351 SolvingSchrodinger'sEquationforanOpenSystem andItsEnvironment W. T. Strunz...377 ChapterV DynamicsofLargeSystems ThermodynamicBehaviorofLargeDynamicalSystems -Quantum1dConductorandClassicalMultibakerMap- S. Tasaki...395 CoherentandDissipativeTransport inAperiodicSolids:AnOverview J. Bellissard...
The nuclear thermal hydraulic is the science providing knowledge about the physical processes occurring during the transferring the fission heat released in structural materials due to nuclear reactions into its environment. Along its way to the environment the thermal energy is organized to provide useful mechanical work or useful heat or both. Chapter 1 contains introductory information about the heat release in the re- tor core, the thermal power and thermal power density in the fuel, structures and moderator, the influence of the thermal power density on the coolant temperature, the spatial distribution of the thermal power density. Finally some measures are introduced for equalizing of the spatial distribution of the thermal power density. Chapter 2 gives the methods for describing of the steady and of the transient temperature fields in the fuel elements. Some information is provided regarding influence of the cladding oxidation, hydrogen diffusion and of the corrosion pr- uct deposition on the temperature fields. Didactically the nuclear thermal hydraulic needs introductions at different level of complexity by introducing step by step the new features after the previous are clearly presented. The followed two Chapters serve this purpose. Chapter 3 describes mathematically the "simple" steady boiling flow in a pipe. The steady mass-, momentum- and energy conservation equations are solved at different level of complexity by removing one after the other simplifying assu- tions. First the idea of mechanical and thermodynamic equilibrium is introduced.
This book addresses several of the foundational problems in thermophysics, i. e. thermodynamics and statistical mechanics. It is an interdisciplinary work in that it examines the philosophical underpinning of scientific models and theories; it also refines the analysis of the problems at hand and delineates the place occupied by various scientific models in a generalized philosophical landscape. Hence, our philosophical - or theoretical - inquiry focuses sharply on the concept of models; and our empirical - or laboratory - evidence is sought in the model-building activities of scientists who have tried to confront the epistemological problems arising in the thermophysical sciences. Primarily for researchers and students in physics, philosophy of science, and mathematics, our book aims at informing the readers - with all the in dispensable technical details made readily available - about the nature of the foundational problems, how these problems are approached with the help of various mathematical models, and what the philosophical implications of such models and approaches involve. Some familiarity with elementary ther mophysics and/or with introductory-level philosophy of science may help, but neither is a prerequisite. The logical and mathematical background re quired for the book are introduced in the Appendices. Upon using the Subject Index, the readers may easily locate the concepts and theorems needed for understanding various parts of the book. The Citation Index lists the authors of the contributions we discuss in detail."
The core of ths book presents a theory developed by the author to combine the recent insight into empirical data with mathematical models in freeway traffic research based on dynamical non-linear processes.
Based on practical problems in mechanical engineering, here the author develops the fundamental concepts of non-smooth mechanics and introduces the necessary background material needed to deal with mechanics involving discontinuities and non-smooth constraints.
As the field of Microsystems expands into more disciplines and new
applications such as RF-MEMS, Optical MEMS and Bio-MEMS, thermal
management is becoming a critical issue in the operation of many
microdevices, including microelectronic chips.
Speckle photography is an advanced experimental technique used for quantitatve determination of density, velocity and temperature fields in gas, liquid, and plasma flows. This book presents the most important equations for the diffraction theory of speckle formation and the statistical properties of speckle fields. It also describes experimental set-ups and the equipment needed to implement these methods. Speckle photography methods for automatic data acquisition and processing are considered and examples for their use are given.
By bringing together various ideas and methods for extracting the slow manifolds, the authors show that it is possible to establish a more macroscopic description in nonequilibrium systems. The book treats slowness as stability. A unifying geometrical viewpoint of the thermodynamics of slow and fast motion enables the development of reduction techniques, both analytical and numerical. Examples considered in the book range from the Boltzmann kinetic equation and hydrodynamics to the Fokker-Planck equations of polymer dynamics and models of chemical kinetics describing oxidation reactions. Special chapters are devoted to model reduction in classical statistical dynamics, natural selection, and exact solutions for slow hydrodynamic manifolds. The book will be a major reference source for both theoretical and applied model reduction. Intended primarily as a postgraduate-level text in nonequilibrium kinetics and model reduction, it will also be valuable to PhD students and researchers in applied mathematics, physics and various fields of engineering.
The utilisation of renewable energies is not at all new; in the history of mankind renewable energies have for a long time been the primary possibility of generating energy. This only changed with industrial revolution when lignite and hard coal became increasingly more important. Later on, also crude oil gained importance. Offering the advantages of easy transportation and processing also as a raw material, crude oil has become one of the prime energy carriers applied today. Moreover, natural gas used for space heating and power provision as well as a transportation fuel has become increasingly important, as it is abundantly available and only requires low investments in terms of energy conversion facilities. As fossil energy carriers were increasingly used for energy generation, at least by the industrialised countries, the application of renewable energies decreased in absolute and relative terms; besides a few exceptions, renewable energies are of secondary importance with regard to overall energy generation.
Thermodynamics is not the oldest of sciences. Mechanics can make that claim. Thermodynamicsisaproductofsomeofthegreatestscienti?cmindsofthe19thand 20th centuries. But it is suf?ciently established that most authors of new textbooks in thermodynamics ?nd it necessary to justify their writing of yet another textbook. I ?nd this an unnecessary exercise because of the centrality of thermodynamics as a science in physics, chemistry, biology, and medicine. I do acknowledge, however, that instruction in thermodynamics often leaves the student in a confused state. My attempt in this book is to present thermodynamics in as simple and as uni?ed a form as possible. As teachers we identify the failures of our own teachers and attempt to correct them. Although I personally acknowledge with a deep gratitude the appreciation for thermodynamics that I found as an undergraduate, I also realize that my teachers did not convey to me the sweeping grandeur of thermodynamics. Speci?cally the s- plicity and the power that James Clerk Maxwell found in the methods of Gibbs were not part of my undergraduate experience. Unfortunately some modern authors also seem to miss this central theme, choosing instead to introduce the thermodynamic potentials as only useful functions at various points in the development.
Modern energetic materials include explosives, blasting powders, pyrotechnic m- tures and rocket propellants [1, 2]. The study of high-temperature decomposition of condensed phases of propellants and their components (liquid, solid and hybrid) is currently of special importance for the development of space-system engineering [3, 4]. To better understand the burning mechanisms (stationary, nonstationary, - steady) of composite solid propellants and their components, information about the macrokinetics of their high-temperature decomposition is required [5]. To be able to evaluate the ignition parameters and conditions of safe handling of heat-affected explosives, one needs to know the kinetic constants of their high-temperature - composition. The development of new composite solid propellants characterized by high performance characteristics (high burning rates, high thermal stability, stability to intrachamber perturbations, and other aspects) is not possible without quanti- tive data on the high-temperature decomposition of composite solid propellants and their components [6]. The same reasons have resulted in signi?cant theoretical and practical interest in the high-temperature decomposition of components of hybrid propellants. It is known that hybrid propellants have not been used very widely due to the low bu- ing (pyrolysis) rates of the polymer blocks in the combustion chambers of hybrid rocket engines. To increase the burning rates it is necessary to obtain information about their relationships to the corresponding kinetic and thermophysical prop- ties of the fuels.
This monograph develops a unified microscopic basis for phases and phase changes of bulk matter and small systems, based on classical physics. It describes the thermodynamics of ensembles of particles and explains phase transition in gaseous and liquid systems. The origins are derived from simple but physically relevant models of how transitions occur between rigid and fluid states, of how phase equilibria arise, and how they differ for small and large systems.
Here is a new method for calculating heat transfer in coupled convective-conductive fluid-wall systems under periodical intensity oscillations in fluid flow. The true steady state mean value of the heat transfer coefficient must be multiplied by a newly defined coupling factor, which is always smaller than one and depends on the coupling parameters Biot number, Fourier number as well as dimensionless geometry and oscillation parameters. Includes characteristic solved problems, with tables and diagrams.
The first volume of this work is organized in three levels, so that the portion and importance of thermodynamics and mathematics increase from level to level. The ground level shows that basics of phase equilibria can be understood without thermodynamics provided the concept of chemical potential is introduced early. The intermediate level introduces thermodynamics, culminating in the Gibbs energy as the arbiter for equilibrium. At the third level the accent is on binary systems, where one or more phases are solutions of the components. Priority is given throughout to the thermodynamic assessment of experimental data. 200 exercises are included with solutions.
The contents of this book are the result of work performed in the past three years to provide some answers to questions raised by several colleagues wo- inginastrophysics. Examiningseveraltransportprocessesinplasmasrelated to dissipative e?ects in phenomena such as cooling ?ows, propagation of sound waves, thermal conduction in the presence of magnetic ?elds, an- lar momentum transfer in accretion disks, among many, one ?nds a rather common pattern. Indeed when values for transport coe?cients are required the overwhelming majority of authors refer to the classical results obtained by L. Spitzer and S. Braginski over forty years ago. Further, it is also often mentioned that under the prescribed working conditions the values of such coe?cients are usually insu?cient to provide agreement with observations. The methodology followed by these authors is based upon Landau's - oneering idea that collisions in plasmas may be substantially accounted for when viewed as a di?usive process. Consequently the ensuing basic kinetic equation is the Fokker-Planck version of Boltzmann's equation as essentially proposed by Landau himself nearly 70 years ago. Curiously enough the magni?cent work of the late R. Balescu in both Classical and Non-Classical transport in plasmas published in 1988 and also based on the Fokker-Planck equation is hardly known in the astrophysical audience. The previous work of Spitzer and Braginski is analyzed with much more rigorous vision in his two books on the subject.
The book unifies classical continuum mechanics and turbulence modeling, i.e. the same fundamental concepts are used to derive model equations for material behaviour and turbulence closure and complements these with methods of dimensional analysis. The intention is to equip the reader with the ability to understand the complex nonlinear modeling in material behaviour and turbulence closure as well as to derive or invent his own models. Examples are mostly taken from environmental physics and geophysics.
The book constitutes a particularly complete and original collection of ideas, models, numerical methods and experimental tools which will prove invaluable in the study of microscale and nanoscale heat transfer. It should be of interest to research scientists and thermal engineers who wish to carry out theoretical research or metrology in this field, but also to physicists concerned with the problems of heat transfer, or teachers requiring a solid foundation for an undergraduate university course in this area.
Centered around the natural phenomena of relaxations and fluctuations, this monograph provides readers with a solid foundation in the linear and nonlinear Fokker-Planck equations that describe the evolution of distribution functions. It emphasizes principles and notions of the theory (e.g. self-organization, stochastic feedback, free energy, and Markov processes), while also illustrating the wide applicability (e.g. collective behavior, multistability, front dynamics, and quantum particle distribution). The focus is on relaxation processes in homogeneous many-body systems describable by nonlinear Fokker-Planck equations. Also treated are Langevin equations and correlation functions. Since these phenomena are exhibited by a diverse spectrum of systems, examples and applications span the fields of physics, biology and neurophysics, mathematics, psychology, and biomechanics.
This book is based on the results of our interest in the ?eld of ultrashort laser pulses interaction with matter. The aim of our monograph was to build the balanced description of the thermal transport phenomena generated by laser pulses shorter than the characteristic relaxation time. In the book we explore the matter on the quark, nuclear as well atomic scales. Also on the cosmic scale (Planck Era) the thermal disturbance shorter than the Planck time creates the new picture of the Universe. The mathematics, especially PDE, are the main tool in the description of the ultrashort thermal phenomena. Two types of the PDE: parabolic and hyperbolic partial di?erential equations are of special interest in the study of the thermal processes. We assume a moderate knowledge of basic Fourier and d'Alembert eq- tions. The scope of the book is deliberately limited to the background of the quantum mechanics equations: Schr] odinger and Klein-Gordon. In this book the attosecond laser pulses are the main source of the dist- bance of the thermal state of the matter. Recently, the attosecond laser pulses constitute a novel tool for probing processes taking place on the time scale of electron motion inside atoms. The research presented in this book appears to provide the basic tools and concepts for attosecond thermal dynamics. Nevertheless much research is still needed to make this emerging ?eld routinely applicable for a broad range of processes on atomic and subatomic scales."
The Second European Turbulence Conference was held at the Technische Univer sitat Berlin, Federal Republic of Germany, from August 30th to September 2nd 1988 under the auspices of the European Mechanics Committee. It was primar ily devoted to fundamental aspects of turbulence, and aimed at bringing together engineers, physicists, and mathematicians. The scientific committee - serving also as Sub-committee of the European Turbulence Conference - consisted of the following members: G. Comte-Bellot (Lyon), H.-H. Fernholz and H.E. Fiedler (both from Berlin) as co-chairmen of the conference, U. Frisch (Nice), J.C.R. Hunt (Cambridge), E. Krause (Aachen), M. Landahl (Stockholm), A.M. Obukhov (Moscow), and G. Ooms (Amsterdam). The conference programme comprised 6 invited lectures and 94 contributions, presented either orally or at poster sessions. There were 165 participants from 18 countries. All papers published in these conference proceedings were, with the exception of the invited ones, again refereed by the members of the scientific committee. The main research topics discussed at this meeting were stability and gener ation of turbulence, effects of rotation, stratification and buoyancy forces, novel instrumentation, manipulation and control, boundary layers with separation and reattachment, computer simulation, turbulent diffusion, image analysis and flow visualization, vorticity dynamics and turbulence, and large-scale structures. We have taken the liberty of regrouping some papers following the submitted final versions for this volume. Authors may therefore find their paper under a different heading from that in the conference programme."
This concise and unified text reviews recent contributions to the principles of convective heat transfer for single and multi-phase systems. This valuable new edition has been updated throughout and contains new examples and problems. |
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