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Books > Science & Mathematics > Physics > Thermodynamics & statistical physics > Thermodynamics
There are many thermodynamics introductory texts on the market, yet most provide a presentation that is at a level to high for those new to the field This second edition of Thermodynamics continues to provide an accessible introduction to thermodynamics, which maintains an appropriate rigor to prepare newcomers for subsequent, more advanced topics. The book presents a logical methodology for solving problems in the context of conservation laws and property labels. The author elucidates the terms around which thermodynamics has historically developed such as work, temperature, entropy, and energy. Using a pedagogical approach that builds from basic principles to laws and eventually corollaries of the law, the text will enable students to think in clear and correct thermodynamic terms as well as solve real engineering problems. For those just beginning their studies in the field, Thermodynamics, Second Edition provides the core fundamentals in a rigorous, accurate, and accessible presentation.
Discover the many facets of non-equilibrium thermodynamics. The first part of this book describes the current thermodynamic formalism recognized as the classical theory. The second part focuses on different approaches. Throughout the presentation, the emphasis is on problem-solving applications. To help build your understanding, some problems have been analyzed using several formalisms to underscore their differences and their similarities.
This thoroughly revised 5th edition of Zeh's classic text investigates irreversible phenomena and their foundation in classical, quantum and cosmological settings. It includes new sections on the meaning of probabilities in a cosmological context, irreversible aspects of quantum computers, and various consequences of the expansion of the Universe. In particular, the book offers an analysis of the physical concept of time.
Reinvigorated by advances and insights the quantum theory of irreversible processes has recently attracted growing attention. This volume introduces the very basic concepts of semigroup dynamics of open quantum systems and reviews a variety of modern applications. Originally published as Volume 286 (1987) in Lecture in Physics, this volume has been newly typeset, revised and corrected and also expanded to include a review on recent developments.
In this compelling, and important book, John Schmitz brings order
to the world of chaos that surrounds us. The Second Law of Life
refers to the second law of thermodynamics, entropy, which is an
omnipresent force that quietly and crucially determines every
aspect of our society, culture and daily lives. Unless we come to
understand entropy, future generations will face consequences of
the unstoppable laws of physics.
Low-Grade Thermal Energy Harvesting: Advances in Thermoelectrics, Materials, and Emerging Applications provides readers with fundamental and key concepts surrounding low-grade thermal energy conversion while also reviewing the latest research directions. The book covers the most promising and emerging technologies for low-grade heat recovery, harvesting and conversion, including wearable thermoelectrics and organic thermoelectrics. Each chapter includes key materials, principles, design and fabrication strategies for low-grade heat recovery. Special attention on emerging materials such as organic composites, 2D materials and nanomaterials are also included. The book emphasizes materials and device structures that enable the powering of wearable electronics and consumer electronics. The book is suitable for materials scientists and engineers in academia and R&D in manufacturing, industry, energy and electronics.
This book treats atmospheric convection from different angles including the theoretical aspects of atmospheric deep convection and the weather phenomena related to convection. The problem of boundary conditions that result in severe convective weather patterns is explored within the framework of worldwide climatology. The book bridges the gap between theory and its operational application both within the fields of weather forecasting and that of risk management.
This book presents a solution for direct and inverse heat conduction problems, discussing the theoretical basis for the heat transfer process and presenting selected theoretical and numerical problems in the form of exercises with solutions. The book covers one-, two- and three dimensional problems which are solved by using exact and approximate analytical methods and numerical methods. An accompanying CD-Rom includes computational solutions of the examples and extensive FORTRAN code.
The authors are very glad to see the publication ofThermodynamicEquilibriaand Extrema in English and would like to express their gratitude to everybody who contributed to this end. The book is devoted to the analysis of attainability regions and partial equilibria in physicochemical and other systems. This analysis employs the extreme models ofclassicalequilibriumthermodynamics. Considerationisgiventotheproblemof choosing, from the set of equilibrium states belonging to the attainability regions, that equilibrium corresponding to the extreme values of a property of interest to a researcher. For example, one might desire to maximize the concentration of target products of a chemical reaction. The problem of coordinating thermodynamics and kinetics is very important in the analysis presented. Ataglance, itmayseemthattheobjectsofstudyinthermodynamics(thescience ofequilibria)andkinetics(thescienceofmotiontowardequilibrium)coincideonly in the case of complete and ?nal equilibrium. In reality, joint application of th- modynamics and kinetic models gives a clearer understanding of the regularities of the kinetics involved. Relativity of the notions of rest and motion was already ?rmly established in mechanics when the principles of equilibrium were formulated by Galilei, D'Alembert, and Lagrange. Historically, the theories of motion and equilibrium states are related. It is precisely the study of gas kinetics that led Clausius and Boltzmann to the main principles of thermodynamics. The systematic analysis of theseprinciplesintheclassicbookbyGibbs, OntheEquilibriumofHeterogeneous Substances 54], demonstrated the feasibility of substituting the models of rest for themodelsofmotionwhenstudyingvariousphysicochemicalprocesses.
This book is based on the results of our interest in the ?eld of ultrashort laser pulses interaction with matter. The aim of our monograph was to build the balanced description of the thermal transport phenomena generated by laser pulses shorter than the characteristic relaxation time. In the book we explore the matter on the quark, nuclear as well atomic scales. Also on the cosmic scale (Planck Era) the thermal disturbance shorter than the Planck time creates the new picture of the Universe. The mathematics, especially PDE, are the main tool in the description of the ultrashort thermal phenomena. Two types of the PDE: parabolic and hyperbolic partial di?erential equations are of special interest in the study of the thermal processes. We assume a moderate knowledge of basic Fourier and d'Alembert eq- tions. The scope of the book is deliberately limited to the background of the quantum mechanics equations: Schr] odinger and Klein-Gordon. In this book the attosecond laser pulses are the main source of the dist- bance of the thermal state of the matter. Recently, the attosecond laser pulses constitute a novel tool for probing processes taking place on the time scale of electron motion inside atoms. The research presented in this book appears to provide the basic tools and concepts for attosecond thermal dynamics. Nevertheless much research is still needed to make this emerging ?eld routinely applicable for a broad range of processes on atomic and subatomic scales."
- It provides a rigorous mathematical and physical basis to techniques that are often introduced on empirical basis - While the book covers a broad range of techniques, it starts at a basic theoretical level. This gives the book a strong foundation and makes it accessible to students from various backgrounds. - Has a computational focus unlike many competing titles
Nucleation is the initial step of every first-order phase transition, and most phase transitions encountered both in everyday life and industrial processes are of the first-order. Using an elegant classical theory based on thermodynamics and kinetics, this book provides a fully detailed picture of multi-component nucleation. As many of the issues concerning multi-component nucleation theory have been solved during the last 10-15 years, it also thoroughly integrates both fundamental theory with recent advances presented in the literature. Classical Nucleation Theory in Multicomponent Systems serves as a textbook for advanced thermodynamics courses, as well as an important reference for researchers in the field. The main topics covered are: the basic relevant thermodynamics and statistical physics; modelling a molecular cluster as a spherical liquid droplet; predicting the size and composition of the nucleating critical clusters; kinetic models for cluster growth and decay; calculating nucleation rates; and a full derivation and application of nucleation theorems that can be used to extract microscopic cluster properties from nucleation rate measurements. The assumptions and approximations needed to build the classical theory are described in detail, and the reasons why the theory fails in certain cases are explained. Relevant problems are presented at the end of each chapter.
Exactly solvable models are very important in physics. They are important not just from a theoretical point of view but also from the experimentalist's perspective because in such cases theoretical results and experimental results can be compared without ambiguity. This 1999 book is about an important class of exactly solvable models in physics. The subject area is the Bethe-ansatz approach for a number of one-dimensional models, and the setting up of equations within this approach to determine the thermodynamics of these systems. It is a topic that crosses the boundaries between condensed matter physics, mathematics and field theory. The derivation and application of thermodynamic Bethe-ansatz equations for one-dimensional models are explained in detail. This technique is indispensable for physicists studying the low-temperature properties of one-dimensional substances. This book, written by one of the top physicists in this field, and the originator of much of the work in the subject, will be of great interest to theoretical condensed matter physicists.
The well known transport laws of Navier-Stokes and Fourier fail for the simulation of processes on lengthscales in the order of the mean free path of a particle that is when the Knudsen number is not small enough. Thus, the proper simulation of flows in rarefied gases requires a more detailed description. This book discusses classical and modern methods to derive macroscopic transport equations for rarefied gases from the Boltzmann equation, for small and moderate Knudsen numbers, i.e. at and above the Navier-Stokes-Fourier level. The main methods discussed are the classical Chapman-Enskog and Grad approaches, as well as the new order of magnitude method, which avoids the short-comings of the classical methods, but retains their benefits. The relations between the various methods are carefully examined, and the resulting equations are compared and tested for a variety of standard problems. The book develops the topic starting from the basic description of an ideal gas, over the derivation of the Boltzmann equation, towards the various methods for deriving macroscopic transport equations, and the test problems which include stability of the equations, shock waves, and Couette flow.
This book describes advances in the application of chaos theory to classical scattering and nonequilibrium statistical mechanics generally, and to transport by deterministic diffusion in particular. The author presents the basic tools of dynamical systems theory, such as dynamical instability, topological analysis, periodic-orbit methods, Liouvillian dynamics, dynamical randomness and large-deviation formalism. These tools are applied to chaotic scattering and to transport in systems near equilibrium and maintained out of equilibrium. Chaotic Scattering is illustrated with disk scatterers and with examples of unimolecular chemical reactions and then generalized to transport in spatially extended systems. This book will be bought by researchers interested in chaos, dynamical systems, chaotic scattering, and statistical mechanics in theoretical, computational and mathematical physics and also in theoretical chemistry.
Thermal Management of Gallium Nitride Electronics outlines the technical approaches undertaken by leaders in the community, the challenges they have faced, and the resulting advances in the field. This book serves as a one-stop reference for compound semiconductor device researchers tasked with solving this engineering challenge for future material systems based on ultra-wide bandgap semiconductors. A number of perspectives are included, such as the growth methods of nanocrystalline diamond, the materials integration of polycrystalline diamond through wafer bonding, and the new physics of thermal transport across heterogeneous interfaces. Over the past 10 years, the book's authors have performed pioneering experiments in the integration of nanocrystalline diamond capping layers into the fabrication process of compound semiconductor devices. Significant research efforts of integrating diamond and GaN have been reported by a number of groups since then, thus resulting in active thermal management options that do not necessarily lead to performance derating to avoid self-heating during radio frequency or power switching operation of these devices. Self-heating refers to the increased channel temperature caused by increased energy transfer from electrons to the lattice at high power. This book chronicles those breakthroughs.
The present volume studies the application of concepts from non-equilibrium thermodynamics to a variety of research topics. Emphasis is on the Maximum Entropy Production (MEP) principle and applications to Geosphere-Biosphere couplings. Written by leading researchers from a wide range of backgrounds, the book presents a first coherent account of an emerging field at the interface of thermodynamics, geophysics and life sciences.
The Nature of Biological Systems as Revealed by Thermal Methods is a guide for experiments using thermal methods. The Editor has used his many years of experience to create a unique resource that will enable others with a less mathematical background, to realize the beauty and power of this tool and to gain a better understanding of biological problems. Biological calorimetry (and of course thermal analysis) is of increasing interest and is not covered thoroughly in other resources. The methods presented are macroscopic, for the rather inhomogeneous material (micromethods are often not possible or not pertinent). This book will help beginners in the field of thermal analysis or calorimetry understand the principles of thermodynamics being applied to biological systems. Biological systems are highly organized and very complex. The water and the different types of weak interactions among the macromolecules make the interpretation of thermal events very difficult. This book includes examples how to handle such problems. The Nature of Biological Systems as Revealed by Thermal Methods
is unique in that it: The book is an invaluable resource for anyone interested in thermodynamics, including practising professionals applying thermal methods to biological problems; researchers and graduate students beginning work using thermal methods; and specialists of thermal analysis starting work on biological problems. In addition, this book will be a useful resource for libraries and institutes as the only book covering quantitative thermal analysis of biological systems.
Modulation Calorimetry reviews modulation techniques for measuring specific heat, thermal expansivity, temperature derivative of resistance, thermopower, and spectral absorptance. Owing to the periodic nature of the temperature oscillations, high sensitivity and excellent temperature resolution are peculiar to all these methods. The monograph presents the various methods of the modulation and of measuring the temperature oscillations. Important applications of the modulation techniques for studying physical phenomena in solids and liquids are considered in depth (equilibrium point defects, phase transitions, superconductors, liquid crystals, biological materials, relaxation phenomena in specific heat, and more).
The contents of this book correspond to Sessions VII and VIII of the International Workshop on Instabilities and Nonequilibrium Structures which took place in Vifia del Mar, Chile, in December 1997 and December 1999, respectively. We were not able to publish this book before and we apologize for this fact to the authors and participants of the meeting. We have made an effort to actualize the courses and articles which have been reviewed by the authors. Both Workshops were organized by Facultad de Ciencias Fisicas y Matematicas, Universidad de Chile, Instituto de Fisica of Universidad Cat61ica de Valparaiso and Centro de Fisica No Lineal y Sistemas Complejos de Santiago. We are glad to acknowledge here the support of the Facultad de Ingenieria of Universidad de los Andes of Santiago which also be from now on one of the organizing Institutions of future Workshops. Enrique Tirapegui PREFACE This book is divided in two parts. In Part I we have collected the courses given in Sessions VII and VIII of the Workshop and in Part II we include a selection of the invited Conferences and Seminars presented at both meetings.
Experiments with rubber balloons and rubber sheets have led to surprising observations, some of them hitherto unknown or not previously described in the literature. In balloons, these phenomena are due to the non-monotonic pressure-radius characteristic which makes balloons a subject of interest to physicists engaged in stability studies. Here is a situation in which symmetry breaking and hysteresis may be studied analytically, because the stress-stretch relations of rubber - and its non-convex free energy - can be determined explicitly from the kinetic theory of rubber and from non-linear elasticity. Since rubber elasticity and the elasticity of gases are both entropy-induced, a rubber balloon represents a compromise between the entropic tendency of a gas to expand and the entropic tendency of rubber to contract. Thus rubber and rubber balloons furnish instructive paradigms of thermodynamics. This monograph treats the subject at a level appropriate for post-graduate studies.
Numerous fundamental properties of quantum information measurement are developed, including the von Neumann entropy of a statistical operator and its limiting normalized version, the entropy rate. Use of quantum-entropy quantities is made in perturbation theory, central limit theorems, thermodynamics of spin systems, entropic uncertainty relations, and optical communication. This new softcover corrected reprint contains summaries of recent developments added to the ends of the chapters.
Combustion of Two-Phase Reactive Media addresses the complex phenomena involved in the burning of solid and liquid fuels. In fact, the multiplicity of phenomena characteristic of combustion of two-phase media determine the contents. The three parts deal with: the dynamics of a single particle; combustion wave propagation in two-phase reactive media; and thermal regimes of combustion reactors. The book generalizes the results of numerous investigations into the ignition and combustion of solid particles, droplets and bubbles, combustion wave propagation in heterogeneous reactive media, the stability of combustion of two-phase media, as well as the thermal regimes of high-temperature combustion reactors. It merges findings from the authors’ investigations into problems of two-phase flows and material from graduate-level courses they teach at Technion-Israel Institute of Technology.
Studies of surfaces and interactions between dissimilar materials or phases are vital for modern technological applications. Computer simulation methods are indispensable in such studies and this book contains a substantial body of knowledge about simulation methods as well as the theoretical background for performing computer experiments and analyzing the data. The book is self-contained, covering a range of topics from classical statistical mechanics to a variety of simulation techniques, including molecular dynamics, Langevin dynamics and Monte Carlo methods. A number of physical systems are considered, including fluids, magnets, polymers, granular media, and driven diffusive systems. The computer simulation methods considered include both standard and accelerated versions. The simulation methods are clearly related to the fundamental principles of thermodynamics and statistical mechanics.
Studies of surfaces and interactions between dissimilar materials or phases are vital for modern technological applications. Computer simulation methods are indispensable in such studies and this book contains a substantial body of knowledge about simulation methods as well as the theoretical background for performing computer experiments and analyzing the data. The book is self-contained, covering a range of topics from classical statistical mechanics to a variety of simulation techniques, including molecular dynamics, Langevin dynamics and Monte Carlo methods. A number of physical systems are considered, including fluids, magnets, polymers, granular media, and driven diffusive systems. The computer simulation methods considered include both standard and accelerated versions. The simulation methods are clearly related to the fundamental principles of thermodynamics and statistical mechanics. |
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