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Books > Science & Mathematics > Physics > Thermodynamics & statistical physics > Thermodynamics
The five contributions describe some key mathematical concepts involved in the study of complex systems and non-perturbative problems. The selection of topics is intended to cross-fertilize the various fields where complex systems theory has made an impact. The book presents specific and detailed results meant for a wide audience of researchers and students. It begins with those contributions which help to set up a general theoretical framework and ends with selected applications to the particular areas of biophysics, statistical physics, astrophysics and cosmology. It also includes an extensive bibliography. This pedagogically written text can be used as an introduction to the fundamental ideas behind complex systems theory.
This critical overview describes fluid flow driven by the thermocapillary effect in models of crystal growth. Simple models are the floating-zone technique and the open-boat technique. Basic equations, boundary layer scaling, stability analysis, pattern formation and additional buoyancy are discussed. Particular emphasis is given to the understanding of the physics of flow. This reference book gives a state-of-the-art report and reviews the literature available.
Nothing happens in the world without energy conversion and entropy production. These fundamental natural laws are familiar to most of us when applied to the evolution of stars, biological processes, or the working of an internal combustion engine, but what about industrial economies and wealth production, or their constant companion, pollution? Does economics conform to the First and the Second Law of Thermodynamics? In this important book, Reiner Kummel takes us on a fascinating tour of these laws and their influence on natural, technological, and social evolution. Analyzing economic growth in Germany, Japan, and the United States in light of technological constraints on capital, labor, and energy, Professor Kummel upends conventional economic wisdom by showing that the productive power of energy far outweighs its small share of costs, while for labor just the opposite is true. Wealth creation by energy conversion is accompanied and limited by polluting emissions that are coupled to entropy production. These facts constitute the Second Law of Economics. They take on unprecedented importance in a world that is facing peak oil, debt-driven economic turmoil, and threats from pollution and climate change. They complement the First Law of Economics: Wealth is allocated on markets, and the legal framework determines the outcome. By applying the First and Second Law we understand the true origins of wealth production, the issues that imperil the goal of sustainable development, and the technological options that are compatible both with this goal and with natural laws. The critical role of energy and entropy in the productive sectors of the economy must be realized if we are to create a road map that avoids a Dark Age of shrinking natural resources, environmental degradation, and increasing social tensions.
Composed of papers written by leading engineers and scientists in the field, this valuable collection reports the most recent advances in cryocooler development, contains extensive performance test results and comparisons, and relates the latest experience in integrating cryocoolers into advanced applications.
The articles in this book reflect the omnipresence of diffusion processes in the natural sciences. They describe experimental results as well as theoretical models and computer simulations, and address a wide readership including graduate students. The problems treated stem from physics, astronomy, physical chemistry, biology, and medicine. The papers are presented in a tutorial style and reflect the present-day trends in the field.
This is a collection of reasonably self-contained review articles on various features of wetting phenomena from both experimental and theoretical points of view. The experimental papers are concerned with wetting at nanoscopic scales, magnetic wetting transitions, convection at interfaces, and adsorption on a surface. The theoretical part is constituted by recent exact results at d=3, some reviews on wetting and disorder, a mathematical description of wetting, front propagation, random surfaces, and wetting within Potts models. The book addresses researchers, engineers, and graduate students in chemistry, physics, and applied mathematics.
The last two years have witnessed a continuation in the breakthrough shift toward pulse tube cryocoolers for long-life, high-reliability cryocooler applications. One class of pulse tubes that has reached maturity is referred to as "Stirling type" because they are based on the linear Oxford Stirling-cooler type compressor; these generally provide cooling in the 30 to 100 K temperature range and operate at frequencies from 30 to 60 Hz. The other type of pulse tube cooler making great advances is the so-called "Gifford-McMahon type. " Pulse tube coolers of this type use a G-M type compressor and lower frequency operation to achieve temperatures in the 2 to 10 K temperature range. Nearly a third of this proceedings covers these new developments in the pulse tube arena. Complementing the work on low-temperature pulse tubes is substantial continued progress on rare earth regenerator materials and Gifford-McMahon coolers. These technologies continue to make great progress in opening up the 2 - 4 K market. Also in the commercial sector, continued interest is being shown in the development of long-life, low-cost cryocoolers for the emerging high temperature superconductor electronics market, particularly the cellular telephone base-station market. At higher temperature levels, closed-cycle J-T or throttle-cycle refrigerators are taking advantage of mixed refrigerant gases to achieve low-cost cryocooler systems in the 65 to 80 K temperature range.
If a Writer would know how to behave himself with relation to Posterity; let him consider in old Books, what he finds, that he is glad to know; and what Omissions he most laments. Jonathan Swift This book emerges from a long story of teaching. I taught chemical engineering thermodynamics for about ten years at the University of Naples in the 1960s, and I still remember the awkwardness that I felt about any textbook I chose to consider-all of them seemed to be vague at best, and the standard of logical rigor seemed immensely inferior to what I could find in books on such other of the students in my first class subjects as calculus and fluid mechanics. One (who is now Prof. F. Gioia of the University of Naples) once asked me a question which I have used here as Example 4. 2-more than 20 years have gone by, and I am still waiting for a more intelligent question from one of my students. At the time, that question compelled me to answer in a way I didn't like, namely "I'll think about it, and I hope I'll have the answer by the next time we meet. " I didn't have it that soon, though I did manage to have it before the end of the course.
Fundamentals of Combustion Processes is designed as a textbook for an upper-division undergraduate and graduate level combustion course in mechanical engineering. The authors focus on the fundamental theory of combustion and provide a simplified discussion of basic combustion parameters and processes such as thermodynamics, chemical kinetics, ignition, diffusion and pre-mixed flames. The text includes exploration of applications, example exercises, suggested homework problems and videos of laboratory demonstrations
The term transport phenomena is used to describe processes in which mass, momentum, energy and entropy move about in matter. Advances in Transport Phenomena provide state-of-the-art expositions of major advances by theoretical, numerical and experimental studies from a molecular, microscopic, mesoscopic, macroscopic or megascopic point of view across the spectrum of transport phenomena, from scientific enquiries to practical applications. The annual review series intends to fill the information gap between regularly published journals and university-level textbooks by providing in-depth review articles over a broader scope than in journals. The authoritative articles, contributed by internationally-leading scientists and practitioners, establish the state of the art, disseminate the latest research discoveries, serve as a central source of reference for fundamentals and applications of transport phenomena, and provide potential textbooks to senior undergraduate and graduate students. This review book provides state-of-the-art expositions of major advances by theoretical, numerical and experimental studies from a molecular, microscopic, mesoscopic, macroscopic or megascopic point of view across the spectrum of transport phenomena, from scientific enquiries to practical applications. This new volume of the annual review "Advances in Transport Phenomena" series provides in-depth review articles covering the fields of mass transfer, fluid mechanics, heat transfer and thermodynamics. This review book provides state-of-the-art expositions of major advances by theoretical, numerical and experimental studies from a molecular, microscopic, mesoscopic, macroscopic or megascopic point of view across the spectrum of transport phenomena, from scientific enquiries to practical applications. This new volume of the annual review "Advances in Transport Phenomena" series provides in-depth review articles covering the fields of mass transfer, fluid mechanics, heat transfer and thermodynamics.
Addressing graduate students and researchers in physics and mathematics, this book fills a gap in the literature. It is an introduction into modern constructive physics, field theory and statistical mechanics and a survey on the most recent research in this field. It presents the main technical tools such as cluster expansion and their implementation in the rigorous renormalization group, and studies physical models in some detail. The reader will find a study of the ultraviolet limit of the Gross-Neveu model, of continuous symmetry breaking and of self-avoiding random walks in statistical mechanics, as well as applications to solid-state physics. Mathematicians will find constructive methods useful for studies in partial differential equations.
The study of chaotic behaviour of dynamical systems has triggered new efforts to reconcile deterministic and stochastic processes as well as classical and quantum physics. New efforts are made to understand complex and unpredictable behaviour. The papers collected in this volume give a broad overview of these activities. Readers will get a glimpse of the growing importance of Levy processes for physics. They will find new views on fundamental concepts of quantum physics and will see many applications of chaotic and essentially random phenomena to a number of physical problems."
Quantum effects may be modelled by means of stochastic perturbation of non-linear partial differential (field) equations. Contributions to this field of research are collected in this volume. Finite dimensional stochastically perturbed Hamiltonian systems and infinite dimensional white noise analysis are treated. The main part concerns problems encountered in deterministic equations. Papers treat the existence of solutions for given initial data, the existence of non-linear bound states or solitary waves including a thorough discussion of various approaches to stability, and global properties (e.g. time decay properties) for non-linear wave equations. This volume provides a good survey of present-day research in non-linear problems of quantum theory for researchers and graduate students.
This is a collection of papers on a variety of topics of current interest in mathematical physics: integrable systems, quantum groups, topological quantum theory, string theory. Some of the contributions are lengthy reviews of lasting value on subjects like symplectic geometry of the Chern-Simons theory or on mirror symmetry. The book addresses graduate students as well as researchers in mathematical physics.
Written for researchers and advanced students the book exhibits a combination of various methods and tools required to describe the complexity of the chemical and physical behaviour of fluid surfaces. The common denominator for all the contributions presented here is the simultaneous use of concepts from surface chemistry and physics and from hydrodynamics where external force fields can be introduced. Theoretical and experimental work is equally represented. Most of the basic problems in the area of nonequilibrium multiphase systems have not yet received extensive treatment. This volume should be a reference for physicists, physico-chemists, and chemical engineers and will serve as a jumping-off point for new directions and new points of view.
The book covers the basics and some generalizations of Monte Carlo methods and its applications to discrete and field theoretic models. It covers the study of nonequilibrium models of granular media by computer simulation and pattern formation. Furthermore, the lectures deal with details of phenomena such as chaos, segregation, pattern formation and phase transitions, convection, fluidification, density waves, surface reaction and growth, spread of epidemics, acoustics, deformation, etc. The book addresses students in physics and scientific computation. It should be a valuable reference work for researchers as well.
Existing standard textbooks on radiative transfer (RT) are usually confined to theoretical models with little reference to experimental methods. This book has been written to illustrate how calorimetric and spectroscopic measurements can be used to check theoretical predictions on extinction properties of infrared radiation in optically thick, absorbing and scattering particulate media. A determination of infrared extinction coefficients is now possible from three completely independent methods. An interpretation of the results of thermal conductivity measurements is made in terms of the diffusion model of RT. One of the most important topics of the book is the experimental separation of heat transfer modes. Since all modes other than scattered radiation are coupled by temperature profiles, conservation of energy also requires an understanding of the non-radiative heat flow components. Unlike other volumes on RT, this book also contains a review of non-radiative heat flow mechanisms. Thus the book does not treat RT as an isolated phenomenon but stresses the key role of RT among the other transport processes. A considerable part of the book is devoted to the calculation of extinction cross sections by application of Mie theory, anisotropic and dependent scattering, optimization of radiation extinction by experimental means, existence or non-existence of thermal conductivity, and other general questions within the field of thermophysics.
This book contains papers presented at the Engineering Foundation Conference on mineral matter in fuels held on November 2-7, 1997 in Kona, Hawaii. The conference is one of a continuing series that was initiated by the CEGB Mar- wood Engineering Laboratories in 1963. The conference was to be eventually organised by the Engineering Foundation as the need for multi-disciplinary work related to c- trolling ash effects in combustors became apparent. The conference covers both the science and the applications. The papers also present case histories, particularly for current fuel technologies, developments in advanced technologies for power generation and mathematical modelling of these processes. Developments since 1963 have been slow, but steady, due to the complexity of the chemical and physical processes involved. However, the research presented here displays great improvement in our understanding of the mechanisms by which mineral matter will influence fuel use. Steve Benson from EERC presented a review and current status of issues related to ash deposition in coal combustion and gasification. The application of new analytical tools, which have been detailed in the previous conferences, is presented. These include CCSEM, as well as new techniques for char- terising sintering of ash, such as TMA, image analysis, X-ray diffraction crystallography and thermal analysis. The new analytical techniques were extended to encompass widely differing fuels such as biomass. Ole H Larsen from ELSAM Denmark presented a review of these advanced techniques.
Predicting thermodynamic quantities for chemically realistic systems on the basis of atomistic calculations is still, even today, a nontrivial task. Nonetheless, accurate treatment of inter-particle interactions, in terms of quantum chemical first principles methods, is a prerequisite for many applications, because of the complexity of both reactants and solvents in modern molecular sciences. Currently, a straightforward calculation of thermodynamic properties from these methods is only possible for high-temperature and low- density systems. Although the enthalpy of a system can often be predicted to a good level of precision with this ideal gas approach, calculating the entropy contribution to the free energy is problematic, especially as the density of the system increases. This thesis contains a compact and coherent introduction of basic theoretical features. The foundations are then laid for the development of approaches suitable for calculation of condensed phase entropies on the basis of well-established quantum chemical methods. The main emphasis of this work is on realistic systems in solution, which is the most important environment for chemical synthesis. The presented results demonstrate how isolated molecular concepts typically employed in modern quantum chemistry can be extended for the accurate determination of thermodynamic properties by means of scale- transferring approaches.
This book surveys significant modern contributions to the mathematical theories of generalized heat wave equations. The first three chapters form a comprehensive survey of most modern contributions also describing in detail the mathematical properties of each model. Acceleration waves and shock waves are the focus in the next two chapters. Numerical techniques, continuous data dependence, and spatial stability of the solution in a cylinder, feature prominently among other topics treated in the following two chapters. The final two chapters are devoted to a description of selected applications and the corresponding formation of mathematical models. Illustrations are taken from a broad range that includes nanofluids, porous media, thin films, nuclear reactors, traffic flow, biology, and medicine, all of contemporary active technological importance and interest. This book will be of value to applied mathematicians, theoretical engineers and other practitioners who wish to know both the theory and its relevance to diverse applications. "
Once again, it gives me a great pleasure to pen the Foreword to the Proceedings of the 15th International Conference on Thermal Conductivity. As in the past, these now biannual conferences pro vide a broadly based forum for those researchers actively working on this important property of matter to convene on a regular basis to exchange their experiences and report their findings. As it is apparent from the Table of Contents, the 15th Conference represents perhaps the broadest coverage of subject areas to date. This is indicative of the times as the boundaries between disciplines be come increasingly diffused. I am sure the time has come when Con ference Chairmen in coming years will be soliciting contributions not only in the physical sciences and engineering', but will actively seek contributions from the earth sciences and life sciences as well. Indeed, the thermal conductivity and related properties of geological and biological materials are becoming of increasing im portance to our way of life. As it can be seen from the summary table, unfortunately, proceedings have been published only for six of the fifteen con ferences. It is hoped that hereafter this Series will become increasingly well known and be recognized as a major vehicle for the reporting of research on thermal conductivity."
This book deals with a subject that has been studied since the beginning of physical chemistry. Despite the thousands of articles and scores of books devoted to solvation thermodynamics, I feel that some fundamen tal and well-established concepts underlying the traditional approach to this subject are not satisfactory and need revision. The main reason for this need is that solvation thermodynamics has traditionally been treated in the context of classical (macroscopic) ther modynamics alone. However, solvation is inherently a molecular pro cess, dependent upon local rather than macroscopic properties of the system. Therefore, the starting point should be based on statistical mechanical methods. For many years it has been believed that certain thermodynamic quantities, such as the standard free energy (or enthalpy or entropy) of solution, may be used as measures of the corresponding functions of solvation of a given solute in a given solvent. I first challenged this notion in a paper published in 1978 based on analysis at the molecular level. During the past ten years, I have introduced several new quantities which, in my opinion, should replace the conventional measures of solvation thermodynamics. To avoid confusing the new quantities with those referred to conventionally in the literature as standard quantities of solvation, I called these "nonconventional," "generalized," and "local" standard quantities and attempted to point out the advantages of these new quantities over the conventional ones." |
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