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Books > Science & Mathematics > Physics > Thermodynamics & statistical physics > Thermodynamics

Problems And Solutions On Thermodynamics And Statistical Mechanics (Hardcover): Yung-Kuo Lim Problems And Solutions On Thermodynamics And Statistical Mechanics (Hardcover)
Yung-Kuo Lim; Series edited by Kelin Wang
R2,867 Discovery Miles 28 670 Ships in 12 - 17 working days

The material for these volumes has been selected from the past twenty years' examination questions for graduate students at University of California at Berkeley, Columbia University, the University of Chicago, MIT, State University of New York at Buffalo, Princeton University and University of Wisconsin.

Problems And Solutions On Thermodynamics And Statistical Mechanics (Paperback): Yung-Kuo Lim Problems And Solutions On Thermodynamics And Statistical Mechanics (Paperback)
Yung-Kuo Lim; Series edited by Kelin Wang
R1,427 Discovery Miles 14 270 Ships in 12 - 17 working days

The material for these volumes has been selected from the past twenty years' examination questions for graduate students at University of California at Berkeley, Columbia University, the University of Chicago, MIT, State University of New York at Buffalo, Princeton University and University of Wisconsin.

Applications of Electrodynamics in Theoretical Physics and Astrophysics (Paperback, Revised): David Ginsburg Applications of Electrodynamics in Theoretical Physics and Astrophysics (Paperback, Revised)
David Ginsburg
R10,427 Discovery Miles 104 270 Ships in 12 - 17 working days

This book is intended as a supplementary text to the standard course books on theoretical physics and astrophysics, addressing applications and selected problems in theoretical physics and astrophysics, most of which are to a greater or lesser extent associated with electrodynamics.

An Introduction to Sustainable Resource Use (Hardcover): Callum Hill An Introduction to Sustainable Resource Use (Hardcover)
Callum Hill
R6,236 Discovery Miles 62 360 Ships in 10 - 15 working days

This book explores the challenges our society faces in making the transition to renewable resource use in a way that is truly sustainable - environmentally, economically and socially. After exploring the physical limits the laws of thermodynamics impose on resource exploitation, the book outlines options for managing resources within these limits. It then moves on to look at the resources themselves (from fossil fuels, through minerals to renewable resources such as timber) and the salient question of how the relentless increase in consumption is putting untenable strain on resource use. Case studies investigate what is being done across a range of sectors - and what is and isn't working. The second half of the book turns to solutions, from the promise of industrial ecology to a new economy based on renewable resources such as biobased materials from agricultural crops and forests. Suitable for under- and postgraduate courses on environmental limits and resource use, and continuing professional development - particularly resource management, materials, industrial ecology, energy, resource economics and engineering.

Chemical Thermodynamics in Materials Science - From Basics to Practical Applications (Hardcover, 1st ed. 2018): Taishi... Chemical Thermodynamics in Materials Science - From Basics to Practical Applications (Hardcover, 1st ed. 2018)
Taishi Matsushita, Kusuhiro Mukai
R2,448 Discovery Miles 24 480 Ships in 10 - 15 working days

This textbook covers chemical thermodynamics in materials science from basic to advanced level, especially for iron and steel making processes. To improve a process by applying knowledge of thermodynamics or to assess the calculation results of thermodynamic software, an accurate and systematic understanding of thermodynamics is required. For that purpose, books from which one can learn thermodynamics from the basic to the advanced level are needed, but such books are rarely published. This book bridges the gap between the basics, which are treated in general thermodynamic books, and their application, which are only partially dealt with in most specialized books on a specific field. This textbook can be used to teach the basics of chemical thermodynamics and its applications to beginners. The basic part of the book is written to help learners acquire robust applied skills in an easy-to-understand manner, with in-depth explanations and schematic diagrams included. The same book can be used by advanced learners as well. Those higher-level readers such as post-graduate students and researchers may refer to the basic part of the book to get down to the basic concepts of chemical thermodynamics or to confirm the basic concepts. Abundant pages are also devoted to applications designed to present more advanced applied skills grounded in a deep understanding of the basics. The book contains some 50 examples and their solutions so that readers can learn through self-study.

Numerical Heat Transfer and Fluid Flow (Hardcover): Suhas Patankar Numerical Heat Transfer and Fluid Flow (Hardcover)
Suhas Patankar
R7,459 Discovery Miles 74 590 Ships in 12 - 17 working days

This book focuses on heat and mass transfer, fluid flow, chemical reaction, and other related processes that occur in engineering equipment, the natural environment, and living organisms. Using simple algebra and elementary calculus, the author develops numerical methods for predicting these processes mainly based on physical considerations. Through this approach, readers will develop a deeper understanding of the underlying physical aspects of heat transfer and fluid flow as well as improve their ability to analyze and interpret computed results.

Stochastic Energetics (Hardcover, 2010 ed.): Ken Sekimoto Stochastic Energetics (Hardcover, 2010 ed.)
Ken Sekimoto
R2,465 Discovery Miles 24 650 Ships in 12 - 17 working days

Stochastic Energetics by now commonly designates the emerging field that bridges the gap between stochastic dynamical processes and thermodynamics.

Triggered by the vast improvements in spatio-temporal resolution in nanotechnology, stochastic energetics develops a framework for quantifying individual realizations of a stochastic process on the mesoscopic scale of thermal fluctuations.

This is needed to answer such novel questions as:

Can one cool a drop of water by agitating an immersed nano-particle?

How does heat flow if a Brownian particle pulls a polymer chain?

Can one measure the free-energy of a system through a single realization of the associated stochastic process?

This book will take the reader gradually from the basics to the applications: Part I provides the necessary background from stochastic dynamics (Langevin, master equation), Part II introduces how stochastic energetics describes such basic notions as heat and work on the mesoscopic scale, Part III details several applications, such as control and detection processes, as well as free-energy transducers.

It aims in particular at researchers and graduate students working in the fields of nanoscience and technology.

The Quantum Theory of Radiation (Hardcover): E.R. Pike, Sarben Sarkar The Quantum Theory of Radiation (Hardcover)
E.R. Pike, Sarben Sarkar
R6,589 R5,885 Discovery Miles 58 850 Save R704 (11%) Ships in 12 - 17 working days

This book is unique in covering phenomena in photon- matter interactions in a unified way over a range of many orders in energy. The quantum field theoretic approach to the fully relativistic theory of quantum electrodynamics (QED) is presented together with the non- relativistic theory in both confined and unconfined geometries. The predictions of QED have been verified to a greater accuracy than any other physical theory. Moreover QED is a paradigm for other gauge theories and is presented in such a way that the generalisation to other gauge theories is natural. Gauge and Poincare symmetry properties and the non-existence of a photon wave function are thoroughly discussed. Starting from the Dirac equation the non-relativistic interaction of the electron with the electromagnetic field is derived as an effective Hamiltonian of multipole expansions. Much of quantum optics is based on the lowest order dipole approximation. From this point on the treatment of fully relativistic QED and quantum optics is done in parallel. Applications of perturbation theory such as Compton and Moller scattering and the theory photdetection are given. After the impressive successes of QED, the limitation of the theory and the necessity of electroweak theory and quantumchromodynamics are discussed. The remaining chapters are devoted to quantum optics inside cavaties. Various approaches to open systems such as master equations are discussed within the context of active systems (e.g. the laser) and passive systems. Semi- classical approximarions are shown to imply a rich non- linear dynamics including chaos for certain parameter regimes. The effect of fluctuations on such non-linear dynamics is also studied. The final chapter is devoted to highly non- classical states of the light field such as photon number, squeezed and two photon entangled states. The latter are studied for the important system of parametric down conversion and the localisation properties of photons are characterised in terms of asympotic tails in photodetection probabilities as a function of time delay. The range of the book has wider benefits. Workers in quantum optics will gain a deeper understanding of the foundations of their subject and field theorists will see concrete examples of open systems, which are beginning to impinge on fundamental theories.

Perturbation Theories for the Thermodynamic Properties of Fluids and Solids (Hardcover): J. R. Solana Perturbation Theories for the Thermodynamic Properties of Fluids and Solids (Hardcover)
J. R. Solana
R5,265 Discovery Miles 52 650 Ships in 12 - 17 working days

This book, Perturbation Theories for the Thermodynamic Properties of Fluids and Solids, provides a comprehensive review of current perturbation theories-as well as integral equation theories and density functional theories-for the equilibrium thermodynamic and structural properties of classical systems. Emphasizing practical applications, the text avoids complex theoretical derivations as much as possible. It begins with discussions of the nature of intermolecular forces and simple potential models. The book also presents a summary of statistical mechanics concepts and formulae. In addition, it reviews simulation techniques, providing background for the performance analyses of theories executed throughout the text using simulation data. Chapters describe integral equation theories, theoretical approaches for hard-sphere fluid or solid systems, and perturbation theories for simple fluids and solids for monocomponent and multicomponent systems. They also cover density functional theories for inhomogeneous systems and perturbative and nonperturbative approaches to describe the structure and thermodynamics of hard-body molecular fluids. The final chapter examines several more challenging systems, such as fluids near the critical point, liquid metals, molten salts, colloids, and aqueous protein solutions. This book offers a thorough account of the available equilibrium theories for the thermodynamic and structural properties of fluids and solids, with special focus on perturbation theories, emphasizing their applications, strengths, and weaknesses. Appropriate for experienced researchers as well as postgraduate students, the text presents a wide-ranging yet detailed view and provides a useful guide to the application of the theories described.

Heat Transfer Due to Laminar Natural Convection of Nanofluids - Theory and Calculation (Hardcover, 1st ed. 2019): Deyi Shang,... Heat Transfer Due to Laminar Natural Convection of Nanofluids - Theory and Calculation (Hardcover, 1st ed. 2019)
Deyi Shang, Liang-Cai Zhong
R2,935 Discovery Miles 29 350 Ships in 10 - 15 working days

This book presents a theoretical study of heat transfer due to laminar natural convection of nanofluids, using Al2O3-water nanofluid as an example. An innovative method of similarity transformation of velocity fields on laminar boundary layers is applied for the development of a mathematical governing model of natural convection with actual nanofluids, and a novel model of the nanofluid's variable thermophysical properties is derived by a mathematical analysis based on the developed model of variable physical properties of fluids combined with the model of the nanofluid's thermal conductivity and viscosity. Based on these, the physical property factors of nanofluids are produced, which leads to a simultaneous solution for deep investigations of hydrodynamics and heat transfer of nanofluid's natural convection. The book also proposes novel predictive formulae for the evaluation of heat transfer of Al2O3-water nanofluid's natural convection. The formulae have reliable theoretical and practical value because they are developed by rigorous theoretical analysis of heat transfer combined with full consideration of the effects of the temperature-dependent physical properties of nanofluids and the nanoparticle shape factor and concentration, as well as variations of fluid boundary temperatures. The conversion factors proposed help to turn the heat transfer coefficient and rate of fluid natural convection into those of nanofluid natural convection. Furthermore, several calculation examples are provided to demonstrate the heat transfer application of the proposed predictive formulae.

Physics of Thermal Therapy - Fundamentals and Clinical Applications (Hardcover, New): Eduardo Moros Physics of Thermal Therapy - Fundamentals and Clinical Applications (Hardcover, New)
Eduardo Moros
R5,569 Discovery Miles 55 690 Ships in 12 - 17 working days

The field of thermal therapy has been growing tenaciously in the last few decades. The application of heat to living tissues, from mild hyperthermia to high-temperature thermal ablation, has produced a host of well-documented genetic, cellular, and physiological responses that are being researched intensely for medical applications, particularly for treatment of solid cancerous tumors using image guidance. The controlled application of thermal energy to living tissues has proven a great challenge, requiring expertise from multiple disciplines, thereby leading to the development of many sophisticated pre-clinical and clinical devices and treatment techniques. Physics of Thermal Therapy: Fundamentals and Clinical Applications captures the breadth and depth of this highly multidisciplinary field.

Focusing on applications in cancer treatment, this book covers basic principles, practical aspects, and clinical applications of thermal therapy. An overview of the fundamentals shows how use of controlled heat in medicine and biology involves electromagnetics, acoustics, thermodynamics, heat transfer, and imaging sciences. The book discusses challenges in the use of thermal energy on living tissues and explores the genetic, cellular, and physiological responses that can be employed in the fight against cancer from the physics and engineering perspectives. It also highlights recent advances, including the treatment of solid tumors using image-guided thermal therapy, microbubbles, nanoparticles, and other cutting-edge techniques.

Physical Chemistry of Polymers - A Conceptual Introduction (Paperback, 2nd Revised edition): Sebastian Seiffert Physical Chemistry of Polymers - A Conceptual Introduction (Paperback, 2nd Revised edition)
Sebastian Seiffert
R1,966 R1,566 Discovery Miles 15 660 Save R400 (20%) Ships in 10 - 15 working days

This book introduces the concepts of physical chemistry of polymers in a format targeted for a blended-learning approach. It provides a basis to bridge polymer chemistry, which targets microscopic chain structures, and polymer engineering, which targets macroscopic material properties and functions. Topics covered are single chain statistics, multi-chain interactions, and chain dynamics, both from a viewpoint of structure, properties (mostly mechanical ones), and their interrelation. In all that, the author encourages the reader to think conceptually. Explains complex facts through simplifying models, diagrams, and illustrations Accessible to chemists, chemical engineers, materials scientists, and physicists Tailored content for an interactive blended-learning format

Nitrate Esters Chemistry and Technology (Hardcover, 1st ed. 2019): Jiping Liu Nitrate Esters Chemistry and Technology (Hardcover, 1st ed. 2019)
Jiping Liu
R4,188 Discovery Miles 41 880 Ships in 12 - 17 working days

The idea of this book is to present the up-to-date research results on Nitrate Esters as explosive materials. It covers many aspects including the material structures, nitrating agent, chemical synthesis devices, preparation technology, and applications etc. In particular, this work sheds light on the comprehensive utilization and thorough destruction of the used Nitrate Easters which is crucial for preventing repeated pollution. This is a highly informative and instructive book providing insight for the researchers working on nitrating theory, energetic materials and chemical equipments.

Statistical Mechanics for Chemists (Hardcover, New): J. Goodisman Statistical Mechanics for Chemists (Hardcover, New)
J. Goodisman
R5,319 Discovery Miles 53 190 Ships in 12 - 17 working days

From the basics of thermodynamics to solutions for modern dynamical problems —the complete beginner's guide to statistical mechanics.

Unlike most books on statistical mechanics, this one is written for advanced students in chemistry, chemical engineering, biophysics, and related fields. It targets readers with no prior exposure to statistical mechanics and provides a complete introduction to all the important principles, concepts, and equations, while maintaining a level of mathematical sophistication that most advanced chemistry students will find manageable. The emphasis is on finding solutions to common problems in chemistry. Topics covered include:

  • The Maxwell-Boltzmann velocity distribution for molecules in a gas, partition functions, and calculation of thermodynamic properties
  • Ensembles (including the grand canonical ensemble), independent particles, and thermodynamic properties of atoms and molecules
  • Practical introductions to quantum statistical mechanics and classical statistical mechanics
  • Applications to electrons in metals and semiconductors; bosons and fermions; imperfect gases; transport properties; dipole moments in electric and magnetic fields; and distribution functions and correlation functions in fluids
  • Time-dependent techniques for handling both simple and modern dynamical problems —the Liouville equation, time-correlation functions, and the Langevin equation.

Clearly written, and with a minimum of theory, Statistical Mechanics for Chemists takes you step by step through mathematical manipulations and explains the physical and chemical bases for each procedure. It is a valuable resource for advanced students in chemistry, chemical engineering, biophysics, and related fields.

Linear Isentropic Oscillations of Stars - Theoretical Foundations (Hardcover, Edition.): Paul Smeyers, Tim Van Hoolst Linear Isentropic Oscillations of Stars - Theoretical Foundations (Hardcover, Edition.)
Paul Smeyers, Tim Van Hoolst
R5,791 Discovery Miles 57 910 Ships in 10 - 15 working days

This monograph attempts to provide a systematic and consistent survey of the fundamentals of the theory of free, linear, isentropic oscillations in spherically symmetric, gaseous equilibrium stars, whose structure is affected neither by axial rotation, nor by the tidal action of a companion, nor by a magnetic eld. Three parts can be distinguished. The rst part, consisting of Chaps.1-8, covers the basic concepts and equations, the distinction between spheroidal and toroidal normal modes, the solution of Poisson's differential equation for the perturbation of the gravitational potential, and Hamilton's variational principle. The second part, consisting of Chaps.9-13, is devotedto the possible existenceof waves propagating in the radial direction, the origin and classi cation of normal modes, the comple- ness of the normal modes, and the relation between the local stability with respect to convection and the global stability of a star. In the third part, Chaps.14-18 c- tain asymptoticrepresentationsof normalmodes. Chapter 19 deals with slow period changes in rapidly evolving pulsating stars. The theory is developed within the framework of the Newtonian theory of gr- itation and the hydrodynamics of compressible uids. It is described in its present status, with inclusion of open questions. We give preference to the use of the adjective "isentropic" above that of the adjective "adiabatic," since, from a thermodynamic point of view, these stellar - cillations are described as reversible adiabatic processes and thus as processes that take place at constant entropy.

Physical Science Under Microgravity: Experiments on Board the SJ-10 Recoverable Satellite (Hardcover, 1st ed. 2019): Wen-Rui... Physical Science Under Microgravity: Experiments on Board the SJ-10 Recoverable Satellite (Hardcover, 1st ed. 2019)
Wen-Rui Hu, Qi Kang
R2,989 Discovery Miles 29 890 Ships in 10 - 15 working days

This book presents the physical science experiments in a space microgravity environment conducted on board the SJ-10 recoverable satellite, which was launched on April 6th, 2016 and recovered on April 18th, 2016. The experiments described were selected from ~100 proposals from various institutions in China and around the world, and have never previously been conducted in the respective fields. They involve fluid physics and materials science, and primarily investigate the kinetic properties of matter in a space microgravity environment. The book provides a comprehensive review of these experiments, as well as the mission's execution, data collection, and scientific outcomes.

Optimal Auxiliary Functions Method for Nonlinear Dynamical Systems (Paperback, 1st ed. 2021): Vasile Marinca, Nicolae Herisanu,... Optimal Auxiliary Functions Method for Nonlinear Dynamical Systems (Paperback, 1st ed. 2021)
Vasile Marinca, Nicolae Herisanu, Bogdan Marinca
R4,753 Discovery Miles 47 530 Ships in 10 - 15 working days

This book presents the optimal auxiliary functions method and applies it to various engineering problems and in particular in boundary layer problems. The cornerstone of the presented procedure is the concept of "optimal auxiliary functions" which are needed to obtain accurate results in an efficient way. Unlike other known analytic approaches, this procedure provides us with a simple but rigorous way to control and adjust the convergence of the solutions of nonlinear dynamical systems. The optimal auxiliary functions are depending on some convergence-control parameters whose optimal values are rigorously determined from mathematical point of view. The capital strength of our procedure is its fast convergence, since after only one iteration, we obtain very accurate analytical solutions which are very easy to be verified. Moreover, no simplifying hypothesis or assumptions are made. The book contains a large amount of practical models from various fields of engineering such as classical and fluid mechanics, thermodynamics, nonlinear oscillations, electrical machines, and many more. The book is a continuation of our previous books "Nonlinear Dynamical Systems in Engineering. Some Approximate Approaches", Springer-2011 and "The Optimal Homotopy Asymptotic Method. Engineering Applications", Springer-2015.

Thermodynamics and Statistical Mechanics - An Integrated Approach (Hardcover): Robert J. Hardy, Christian Binek Thermodynamics and Statistical Mechanics - An Integrated Approach (Hardcover)
Robert J. Hardy, Christian Binek
R3,528 Discovery Miles 35 280 Ships in 12 - 17 working days

This textbook brings together the fundamentals of the macroscopic and microscopic aspects of thermal physics by presenting thermodynamics and statistical mechanics as complementary theories based on small numbers of postulates. The book is designed to give the instructor flexibility in structuring courses for advanced undergraduates and/or beginning graduate students and is written on the principle that a good text should also be a good reference. The presentation of thermodynamics follows the logic of Clausius and Kelvin while relating the concepts involved to familiar phenomena and the modern student's knowledge of the atomic nature of matter. Another unique aspect of the book is the treatment of the mathematics involved. The essential mathematical concepts are briefly reviewed before using them, and the similarity of the mathematics to that employed in other fields of physics is emphasized. The text gives in depth treatments of low density gases, harmonic solids, magnetic and dielectric materials, phase transitions, and the concept of entropy. The microcanonical, canonical, and grand canonical ensembles of statistical mechanics are derived and used as the starting point for the analysis of fluctuations, blackbody radiation, the Maxwell distribution, Fermi-Dirac statistics, Bose-Einstein condensation, and the statistical basis of computer simulations. Supplementary material including PowerPoint slides and detailed worked solutions can be downloaded online at http://booksupport.wiley.com

Molecular Mixed Crystals (Paperback, 1st ed. 2021): Miquel Angel Cuevas-Diarte, Harry A.J. Oonk Molecular Mixed Crystals (Paperback, 1st ed. 2021)
Miquel Angel Cuevas-Diarte, Harry A.J. Oonk
R4,203 Discovery Miles 42 030 Ships in 10 - 15 working days

This book focuses on mixed crystals formed by molecular substances. The emphasis lies on the elucidation of the structural and thermodynamic properties of two-component systems. Thanks to the fact that the research efforts have been directed to a number of families of chemically coherent substances, rather than to a collection of isolated systems, the knowledge of mixed crystals has substantially increased. This is reflected by the discovery of several empirical relationships between thermodynamic properties, crystallographic properties, and also between thermodynamic mixing properties and exothermodynamic parameters, such as the structural mismatch between the components of the binary systems. This book is a benchmark for material scientists and a unique starting point for anyone interested in mixed crystals.

Thermal Analysis and Thermodynamics - In Materials Science (Paperback): Detlef Klimm Thermal Analysis and Thermodynamics - In Materials Science (Paperback)
Detlef Klimm
R2,199 R1,732 Discovery Miles 17 320 Save R467 (21%) Ships in 10 - 15 working days

This introduction to thermodynamics discusses typical phase diagrams features and presents the wide range of techniques such as Differential Scanning Calorimetry, Thermogravimetry and others. In the last part the author brings many examples for typical practical problems often solved by thermal analysis. As an instructive guideline for practitioners the work reveals the connection between experimental data and theoretical model and vice versa.

Classical and Relativistic Rational Extended Thermodynamics of Gases (Paperback, 1st ed. 2021): Tommaso Ruggeri, Masaru Sugiyama Classical and Relativistic Rational Extended Thermodynamics of Gases (Paperback, 1st ed. 2021)
Tommaso Ruggeri, Masaru Sugiyama
R4,563 Discovery Miles 45 630 Ships in 10 - 15 working days

Rational extended thermodynamics (RET) is the theory that is applicable to nonequilibrium phenomena out of local equilibrium. It is expressed by the hyperbolic system of field equations with local constitutive equations and is strictly related to the kinetic theory with the closure method of the hierarchies of moment equations. The book intends to present, in a systematic way, new results obtained by RET of gases in both classical and relativistic cases, and it is a natural continuation of the book "Rational Extended Thermodynamics beyond the Monatomic Gas" by the same authors published in 2015. However, this book addresses much wider topics than those of the previous book. Its contents are as follows: RET of rarefied monatomic gases and of polyatomic gases; a simplified RET theory with 6 fields being valid far from equilibrium; RET where both molecular rotational and vibrational modes exist; mixture of gases with multi-temperature. The theory is applied to several typical topics (sound waves, shock waves, etc.) and is compared with experimental data. From a mathematical point of view, RET can be regarded as a theory of hyperbolic symmetric systems, of which it is possible to conduct a qualitative analysis. The book represents a valuable resource for applied mathematicians, physicists, and engineers, offering powerful models for many potential applications such as reentering satellites into the atmosphere, semiconductors, and nanoscale phenomena.

Thermodynamics and Chemistry (Paperback): Frank Henry Macdougall Thermodynamics and Chemistry (Paperback)
Frank Henry Macdougall
R925 Discovery Miles 9 250 Ships in 12 - 17 working days
Thermodynamics chemistry (Paperback): P. Duhem Thermodynamics chemistry (Paperback)
P. Duhem
R1,039 Discovery Miles 10 390 Ships in 10 - 15 working days
Entropies of Condensed Phases and Complex Systems - A First Principles Approach (Hardcover, 2011 ed.): Christian Spickermann Entropies of Condensed Phases and Complex Systems - A First Principles Approach (Hardcover, 2011 ed.)
Christian Spickermann
R2,952 Discovery Miles 29 520 Ships in 10 - 15 working days

Predicting thermodynamic quantities for chemically realistic systems on the basis of atomistic calculations is still, even today, a nontrivial task. Nonetheless, accurate treatment of inter-particle interactions, in terms of quantum chemical first principles methods, is a prerequisite for many applications, because of the complexity of both reactants and solvents in modern molecular sciences. Currently, a straightforward calculation of thermodynamic properties from these methods is only possible for high-temperature and low- density systems. Although the enthalpy of a system can often be predicted to a good level of precision with this ideal gas approach, calculating the entropy contribution to the free energy is problematic, especially as the density of the system increases. This thesis contains a compact and coherent introduction of basic theoretical features. The foundations are then laid for the development of approaches suitable for calculation of condensed phase entropies on the basis of well-established quantum chemical methods. The main emphasis of this work is on realistic systems in solution, which is the most important environment for chemical synthesis. The presented results demonstrate how isolated molecular concepts typically employed in modern quantum chemistry can be extended for the accurate determination of thermodynamic properties by means of scale- transferring approaches.

Thermodynamic and Transport Properties of Fluids 5e (Staple bound, 5th Edition): G Rogers Thermodynamic and Transport Properties of Fluids 5e (Staple bound, 5th Edition)
G Rogers
R343 Discovery Miles 3 430 Ships in 9 - 15 working days

The fifth edition of "Thermodynamic and Transport Properties of Fluids" incorporates two new tables: other material is being retained essentially as in the fourth edition, although tables beyond p.11 will be on different pages.

The new tables are as follows: Data of Refrigerant 134a (tetrafluoroethane - CH2F-CF3) are being added because this refrigerant is environmentally more acceptable than Refrigerant 12 which it replaces. The table of R12 is being retained, however, because R12 will survive in much equipment for a long time. At present it is still uncertain whether R134a is a medium-term substitute, or will be used for much longer than a decade.

Figure 15.11 from "Engineering Thermodynamics, Work and Heat Transfer" (Rogers & Mayhew, Longman 1992) is being included. The table contains, for selected substances, molar enthalpies and molar Gibbs functions of formation, and Equilibrium constants of formation, as well as molar heat capacities and absolute entropies.

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