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Books > Science & Mathematics > Physics > Thermodynamics & statistical physics > Thermodynamics
The structure of the theory ofthermodynamics has changed enormously since its inception in the middle of the nineteenth century. Shortly after Thomson and Clausius enunciated their versions of the Second Law, Clausius, Maxwell, and Boltzmann began actively pursuing the molecular basis of thermo dynamics, work that culminated in the Boltzmann equation and the theory of transport processes in dilute gases. Much later, Onsager undertook the elucidation of the symmetry oftransport coefficients and, thereby, established himself as the father of the theory of nonequilibrium thermodynamics. Com bining the statistical ideas of Gibbs and Langevin with the phenomenological transport equations, Onsager and others went on to develop a consistent statistical theory of irreversible processes. The power of that theory is in its ability to relate measurable quantities, such as transport coefficients and thermodynamic derivatives, to the results of experimental measurements. As powerful as that theory is, it is linear and limited in validity to a neighborhood of equilibrium. In recent years it has been possible to extend the statistical theory of nonequilibrium processes to include nonlinear effects. The modern theory, as expounded in this book, is applicable to a wide variety of systems both close to and far from equilibrium. The theory is based on the notion of elementary molecular processes, which manifest themselves as random changes in the extensive variables characterizing a system. The theory has a hierarchical character and, thus, can be applied at various levels of molecular detail."
In this unique book, Arieh Ben-Naim invites the reader to experience the joy of appreciating something which has eluded understanding for many years -- entropy and the Second Law of Thermodynamics. The book has a two-pronged message: first, that the Second Law is not "infinitely incomprehensible" as commonly stated in textbooks of thermodynamics but can, in fact, be comprehended through sheer common sense; and second, that entropy is not a mysterious quantity that has "resisted understanding" but a simple, familiar and easily comprehensible concept. Written in an accessible style, the book guides the reader through an abundance of dice games and examples from everyday life. The author paves the way for readers to discover for themselves what entropy is, how it changes, and most importantly, why it always changes in one direction in a spontaneous process.
Thermostable Proteins: Structural Stability and Design provides a comprehensive, updated account of the physical basis of enhanced stability of thermophilic proteins and the design of tailor-made thermostable proteins, paving the way for their possible industrial applications. This book is devoted to understanding the survival mechanisms of "thermophilic life forms" at the molecular level with an emphasis on design strategies. The review chapters presented in Thermostable Proteins span a wide range of protein thermostability research. Basic structural, thermodynamic, and kinetic principles are explained and molecular strategies for the adaptation to high temperatures are delineated. In addition, this book covers:
Understanding the molecular basis of how thermostable and hyperthermostable proteins gain and maintain their stability and biological function at high temperatures remains an important scientific challenge. A more detailed knowledge of protein stability not only deepens our understanding of protein structure but also helps in obtaining insights into processes that drive protein activities folding, unfolding, and misfolding essential to biological function.
* Materials are presented to guide the reader with ease through a difficult subject by providing extra help whenever needed to overcome the more demanding technical and conceptual aspects * Active reading strategies (conceptual problems, discussion questions, worked examples with comments, end of chapter problems, further reading etc.) to stimulate engagement with the text through active, critical thought * Well-balanced textbook design (including introductions, illustrations, keywords defined, highlights, notes in margins, summary of key ideas and concepts, boxes with additional topics that complement the materials presented in the main text)
This second part of Continuum Thermodynamics is designed to match almost one-to-one the chapters of Part I. This is done so that the reader studying thermodynamics will have a deepened understanding of the subjects covered in Part I. The aims of the book are in particular: the illustration of basic features of some simple thermodynamical models such as ideal and viscous fluids, non-Newtonian fluids, nonlinear solids, interactions with electromagnetic fields, and diffusive porous materials. A further aim is the illustration of the above subjects by examples and simple solutions of initial and boundary problems as well as simple exercises to develop skills in the construction of interdisciplinary macroscopic models.
This book explores the challenges our society faces in making the transition to renewable resource use in a way that is truly sustainable - environmentally, economically and socially. After exploring the physical limits the laws of thermodynamics impose on resource exploitation, the book outlines options for managing resources within these limits. It then moves on to look at the resources themselves (from fossil fuels, through minerals to renewable resources such as timber) and the salient question of how the relentless increase in consumption is putting untenable strain on resource use. Case studies investigate what is being done across a range of sectors - and what is and isn't working. The second half of the book turns to solutions, from the promise of industrial ecology to a new economy based on renewable resources such as biobased materials from agricultural crops and forests. Suitable for under- and postgraduate courses on environmental limits and resource use, and continuing professional development - particularly resource management, materials, industrial ecology, energy, resource economics and engineering.
The wide application of technologies in new mechanical, electronic and biomedical systems calls for materials and structures with non-conventional properties (e.g materials with 'memory'). Of equal importance is the understanding of the physical behaviour of these materials and consequently developing mathematical modelling techniques for prediction. This self contained text discusses the mathematical modelling used with these types of electromagnetic materials. It provides a carefully structured, coherent, and comprehensive treatment of electromagnetism of continuous media. The authors provide a systematic review of known subjects along with original results about thermodynamics of electromagnetic materials, well-posedness of initial boundary-value problems, variational settings, and wave propagation. Models of non-linear materials, non-local materials (superconductors), and hysteretic (magnetic) materials are also developed in detail.
This book explores the challenges our society faces in making the transition to renewable resource use in a way that is truly sustainable - environmentally, economically and socially. After exploring the physical limits the laws of thermodynamics impose on resource exploitation, the book outlines options for managing resources within these limits. It then moves on to look at the resources themselves (from fossil fuels, through minerals to renewable resources such as timber) and the salient question of how the relentless increase in consumption is putting untenable strain on resource use. Case studies investigate what is being done across a range of sectors - and what is and isn't working. The second half of the book turns to solutions, from the promise of industrial ecology to a new economy based on renewable resources such as biobased materials from agricultural crops and forests. Suitable for under- and postgraduate courses on environmental limits and resource use, and continuing professional development - particularly resource management, materials, industrial ecology, energy, resource economics and engineering.
This book summarizes the most recent theoretical, computational and experimental results dealing with homogeneous turbulence dynamics. A large class of flows is covered: flows governed by anisotropic production mechanisms (e.g. shear flows) and flows without production but dominated by waves (e.g. homogeneous rotating or stratified turbulence). Compressible turbulent flows are also considered. In each case, main trends are illustrated using computational and experimental results, while both linear and nonlinear theories and closures are discussed. Details about linear theories (e.g. Rapid Distortion Theory and variants) and nonlinear closures (e.g. EDQNM) are provided in dedicated chapters, following a fully unified approach. The emphasis is on homogeneous flows, including several interactions (rotation, stratification, shear, shock waves, acoustic waves, and more) which are pertinent to many applications fields - from aerospace engineering to astrophysics and Earth sciences.
The thermodynamic limit is a mathematical technique for modeling crystals or other macroscopic objects by considering them as infinite periodic arrays of molecules. The technique allows models in solid state physics to be derived directly from models in quantum chemistry. This book presents new results, many previously unpublished, for a large class of models and provides a survey of the mathematics of thermodynamic limit problems. The authors both work closely with Fields Medal-winner Pierre-Louis Lion, and the book will be a valuable tool for applied mathematicians and mathematical physicists studying nonlinear partial differential equations.
This book is an introductory text on fundamental aspects of combustion including thermodynamics, heat and mass transfer and chemical kinetics which are used to systematically derive the basic concepts of combustion. Apart from the fundamental aspects, many of the emerging topics in the field like microscale combustion, combustion dynamics, oxy-fuel combustion and combustion diagnostics are also covered in the book. This would help the beginners in the subject to get initiated to the state of the art topics. Key Features: Coverage of the essential aspects of combustion engineering suitable for both beginners and practicing professionals Topics like entropy generation, microscale combustion, combustion diagnostics, second law-based analysis exclusive to the title Balanced treatment of thermodynamics, transport phenomena and chemical kinetics Discussion on state of the art techniques in combustion diagnostics Illustrates combustion of gaseous, liquid and solid fuels along with emission of pollutants and greenhouse gases
This book provides a solid foundation in the principles of heat and mass transfer and shows how to solve problems by applying modern methods. The basic theory is developed systematically, exploring in detail the solution methods to all important problems. The revised second edition incorporates state-of-the-art findings on heat and mass transfer correlations. The book will be useful not only to upper- and graduate-level students, but also to practicing scientists and engineers. Many worked-out examples and numerous exercises with their solutions will facilitate learning and understanding, and an appendix includes data on key properties of important substances.
This book discusses all three formalisms used in the study of finite temperature field theory, namely the imaginary time formalism, the closed time formalism and thermofield dynamics. Applications of the formalisms are worked out in detail. Gauge field theories and symmetry restoration at finite temperature are among the practical examples discussed in depth. The question of gauge dependence of the effective potential and the Nielsen identities are explained. The nonrestoration of some symmetries at high temperature (such as supersymmetry) and theories on nonsimply connected space-times are also described thoroughly. Other topics include (1+1)- and (2+1)-dimensional field theories at finite temperature and phase transitions, derivative expansion, linear response theory and the question of infrared divergences at finite temperature. In addition, examples of nonequilibrium phenomena are discussed with the disoriented chiral condensates as an illustration.This book is a very useful tool for graduate students, teachers and researchers in theoretical physics.
This volume discusses the advances in numerical heat transfer modeling by applying high-performance computing resources, striking a balance between generic fundamentals, specific fundamentals, generic applications, and specific applications.
The essence of temporal universe creation is that any analytical solution has to comply with the boundary condition of our universe; dimensionality and causality constraints. The essence of this book is to show that everything has a price within our temporal (t > 0) universe; energy and time. In mathematics, every postulation needs proof; there exists a solution before searching for the solution. Yet science does not have seem to have a criterion as mathematics does; to prove first that a postulated science exists within our temporal universe. Without such a criterion, fictitious science emerges, as already have been happening in every day's event. In this book, the author has shown there exists a criterion for a postulated science whether or not it is existed within our universe. The author started this book from Einstein's relativity to the creation of our temporal universe. He has shown that every subspace within our universe is created by energy and time, in which subspace and time are coexisted. The important aspect is that every science has to satisfy the boundary condition of our universe; causality and dimensionality. Following up with temporal universe, the author has shown a profound relationship with the second law of thermodynamics. He examines the relationship between entropy with science as well as communication with quantum limited subspace throughout the book. The author discusses the paradox of Schroedinger's Cat (which has been debated by Einstein, Bohr, Schroedinger and many others since 1935) that triggered his discovering that Schroedinger's quantum mechanics is a timeless machine, in which he has disproved the fundamental principle of superposition within our universe. Since quantum mechanics is a virtual mathematics, he has shown that a temporal quantum machine can, in principle, be built on the top of a temporal platform. This book is intended for cosmologists, particle physicists, astrophysicists, quantum physicists, computer scientists, engineers, professors and students as a reference and research-oriented book.
The concept of traceability has evolved to ensure measurements can be communicated consistently and unambiguously. This new edition of a classic reference offers a systematic treatment of traceable temperature measurement and presents a practical guide to the principles and purpose of measurements. With an emphasis on recognizing sources of uncertainty, Nicholas and White examine the most commonly used thermometers: liquid-in-glass thermometers, platinum resistance thermometers, thermocouples and radiation thermometers. The new edition features:
This graduate-level text gives a self-contained exposition of fundamental topics in modern equilibrium and nonequilibrium statistical thermodynamics. The text follows a balanced approach between the macroscopic (thermodynamic) and microscopic (statistical) points of view. The first half of the book deals with equilibrium thermodynamics and statistical mechanics. In addition to standard subjects, the reader will find a detailed account of broken symmetries, critical phenomena and the renormalization group, as well as an introduction to numerical methods. The second half of the book is devoted to nonequilibrium phenomena, first following a macroscopic approach, with hydrodynamics as an important example. Kinetic theory receives a thorough treatment through analysis of the Boltzmann-Lorentz model and the Boltzmann equation. The book concludes with general nonequilibrium methods such as linear response, projection method and the Langevin and Fokker-Planck equations, including numerical simulations. This advanced textbook will be of interest to graduate students and researchers in physics.
For almost 20 years the author has conducted research on both macroscopic and molecular theories. The results of his investigation, which can be found in this work, are that irreversible thermodynamics and kinetic theory of matter are not separable especially for nonlinear irreversible processes occurring in systems removed far from equilibrium and thus must be examined together in a mutually consistent manner. Includes coverage of such topics as mass and momentum conservation law, bilinear and quadratic forms for entropy production, viscous phenomena, boundary conditions for velocities and much more.
In a universe filled by chaos and disorder, one physicist makes the radical argument that the growth of order drives the passage of time -- and shapes the destiny of the universe. Time is among the universe's greatest mysteries. Why, when most laws of physics allow for it to flow forward and backward, does it only go forward? Physicists have long appealed to the second law of thermodynamics, held to predict the increase of disorder in the universe, to explain this. In The Janus Point, physicist Julian Barbour argues that the second law has been misapplied and that the growth of order determines how we experience time. In his view, the big bang becomes the "Janus point," a moment of minimal order from which time could flow, and order increase, in two directions. The Janus Point has remarkable implications: while most physicists predict that the universe will become mired in disorder, Barbour sees the possibility that order -- the stuff of life -- can grow without bound. A major new work of physics, The Janus Point will transform our understanding of the nature of existence.
The material for these volumes has been selected from the past twenty years' examination questions for graduate students at University of California at Berkeley, Columbia University, the University of Chicago, MIT, State University of New York at Buffalo, Princeton University and University of Wisconsin.
'Hugely readable and entertaining' JIM AL-KHALILI 'An accessible and crystal-clear portrait of this discipline's breadth, largely told through its history' PHIL BALL, PHYSICS WORLD Einstein's Fridge tells the story of how scientists uncovered the least known and yet most consequential of all the sciences, and learned to harness the power of heat and ice. The laws of thermodynamics govern everything from the behaviour of atoms to that of living cells, from the engines that power our world to the black hole at the centre of our galaxy. Not only that, but thermodynamics explains why we must eat and breathe, how the lights come on, and ultimately how the universe will end. The people who decoded its laws came from every branch of the sciences - they were engineers, physicists, chemists, biologists, cosmologists and mathematicians. Their discoveries, set over two hundred years, kick-started the industrial revolution, changed the course of world wars and informed modern understanding of black holes. This book captures the thrill of discovery and the power of revolutionary science to change the world forever.
The material for these volumes has been selected from the past twenty years' examination questions for graduate students at University of California at Berkeley, Columbia University, the University of Chicago, MIT, State University of New York at Buffalo, Princeton University and University of Wisconsin.
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