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Books > Science & Mathematics > Physics > Thermodynamics & statistical physics > Thermodynamics
For the thermodynamics course in the Mechanical & Aerospace Engineering department Thermodynamics: An Interactive Approach employs a layered approach that introduces the important concepts of mass, energy, and entropy early, and progressively refines them throughout the text. To create a rich learning experience for today's thermodynamics student, this book melds traditional content with the web-based resources and learning tools of TEST: The Expert System for Thermodynamics.
This textbook covers chemical thermodynamics in materials science from basic to advanced level, especially for iron and steel making processes. To improve a process by applying knowledge of thermodynamics or to assess the calculation results of thermodynamic software, an accurate and systematic understanding of thermodynamics is required. For that purpose, books from which one can learn thermodynamics from the basic to the advanced level are needed, but such books are rarely published. This book bridges the gap between the basics, which are treated in general thermodynamic books, and their application, which are only partially dealt with in most specialized books on a specific field. This textbook can be used to teach the basics of chemical thermodynamics and its applications to beginners. The basic part of the book is written to help learners acquire robust applied skills in an easy-to-understand manner, with in-depth explanations and schematic diagrams included. The same book can be used by advanced learners as well. Those higher-level readers such as post-graduate students and researchers may refer to the basic part of the book to get down to the basic concepts of chemical thermodynamics or to confirm the basic concepts. Abundant pages are also devoted to applications designed to present more advanced applied skills grounded in a deep understanding of the basics. The book contains some 50 examples and their solutions so that readers can learn through self-study.
This book focuses on heat and mass transfer, fluid flow, chemical reaction, and other related processes that occur in engineering equipment, the natural environment, and living organisms. Using simple algebra and elementary calculus, the author develops numerical methods for predicting these processes mainly based on physical considerations. Through this approach, readers will develop a deeper understanding of the underlying physical aspects of heat transfer and fluid flow as well as improve their ability to analyze and interpret computed results.
The point of departure of this book is a triad of themes: information theory, thermodynamics, and quantum mechanics. These are related: thermodynamics and quantum mechanics form the basis of quantum thermodynamics; information and quantum mechanics underly, inter alia, the notorious quantum measurement problem; and information and thermodynamics have much to say about control limits in the tension between micro- and macro-descriptions. Why does the world around us typically look thermal-from cosmology down to individual embedded spins? Do informational measures constitute additional (independent) parameters beyond physical ones? Is the transition between mechanical and thermal systems gradual or discontinuous? Pertinent examples can be found in various processes implemented on small quantum systems. Particularly attractive are model systems that can be treated thermodynamically, but-to some extent-also exactly, that is, based on pure quantum dynamics. This possibility opens the door to nano-thermodynamics. In this sense, the book aims at a modern perspective of nanoscale applications, defined here as a potential realization of various functions as constrained by given resources.
Stochastic Energetics by now commonly designates the emerging field that bridges the gap between stochastic dynamical processes and thermodynamics. Triggered by the vast improvements in spatio-temporal resolution in nanotechnology, stochastic energetics develops a framework for quantifying individual realizations of a stochastic process on the mesoscopic scale of thermal fluctuations. This is needed to answer such novel questions as: Can one cool a drop of water by agitating an immersed nano-particle? How does heat flow if a Brownian particle pulls a polymer chain? Can one measure the free-energy of a system through a single realization of the associated stochastic process? This book will take the reader gradually from the basics to the applications: Part I provides the necessary background from stochastic dynamics (Langevin, master equation), Part II introduces how stochastic energetics describes such basic notions as heat and work on the mesoscopic scale, Part III details several applications, such as control and detection processes, as well as free-energy transducers. It aims in particular at researchers and graduate students working in the fields of nanoscience and technology.
This book is unique in covering phenomena in photon- matter interactions in a unified way over a range of many orders in energy. The quantum field theoretic approach to the fully relativistic theory of quantum electrodynamics (QED) is presented together with the non- relativistic theory in both confined and unconfined geometries. The predictions of QED have been verified to a greater accuracy than any other physical theory. Moreover QED is a paradigm for other gauge theories and is presented in such a way that the generalisation to other gauge theories is natural. Gauge and Poincare symmetry properties and the non-existence of a photon wave function are thoroughly discussed. Starting from the Dirac equation the non-relativistic interaction of the electron with the electromagnetic field is derived as an effective Hamiltonian of multipole expansions. Much of quantum optics is based on the lowest order dipole approximation. From this point on the treatment of fully relativistic QED and quantum optics is done in parallel. Applications of perturbation theory such as Compton and Moller scattering and the theory photdetection are given. After the impressive successes of QED, the limitation of the theory and the necessity of electroweak theory and quantumchromodynamics are discussed. The remaining chapters are devoted to quantum optics inside cavaties. Various approaches to open systems such as master equations are discussed within the context of active systems (e.g. the laser) and passive systems. Semi- classical approximarions are shown to imply a rich non- linear dynamics including chaos for certain parameter regimes. The effect of fluctuations on such non-linear dynamics is also studied. The final chapter is devoted to highly non- classical states of the light field such as photon number, squeezed and two photon entangled states. The latter are studied for the important system of parametric down conversion and the localisation properties of photons are characterised in terms of asympotic tails in photodetection probabilities as a function of time delay. The range of the book has wider benefits. Workers in quantum optics will gain a deeper understanding of the foundations of their subject and field theorists will see concrete examples of open systems, which are beginning to impinge on fundamental theories.
This book, Perturbation Theories for the Thermodynamic Properties of Fluids and Solids, provides a comprehensive review of current perturbation theories-as well as integral equation theories and density functional theories-for the equilibrium thermodynamic and structural properties of classical systems. Emphasizing practical applications, the text avoids complex theoretical derivations as much as possible. It begins with discussions of the nature of intermolecular forces and simple potential models. The book also presents a summary of statistical mechanics concepts and formulae. In addition, it reviews simulation techniques, providing background for the performance analyses of theories executed throughout the text using simulation data. Chapters describe integral equation theories, theoretical approaches for hard-sphere fluid or solid systems, and perturbation theories for simple fluids and solids for monocomponent and multicomponent systems. They also cover density functional theories for inhomogeneous systems and perturbative and nonperturbative approaches to describe the structure and thermodynamics of hard-body molecular fluids. The final chapter examines several more challenging systems, such as fluids near the critical point, liquid metals, molten salts, colloids, and aqueous protein solutions. This book offers a thorough account of the available equilibrium theories for the thermodynamic and structural properties of fluids and solids, with special focus on perturbation theories, emphasizing their applications, strengths, and weaknesses. Appropriate for experienced researchers as well as postgraduate students, the text presents a wide-ranging yet detailed view and provides a useful guide to the application of the theories described.
This book presents a theoretical study of heat transfer due to laminar natural convection of nanofluids, using Al2O3-water nanofluid as an example. An innovative method of similarity transformation of velocity fields on laminar boundary layers is applied for the development of a mathematical governing model of natural convection with actual nanofluids, and a novel model of the nanofluid's variable thermophysical properties is derived by a mathematical analysis based on the developed model of variable physical properties of fluids combined with the model of the nanofluid's thermal conductivity and viscosity. Based on these, the physical property factors of nanofluids are produced, which leads to a simultaneous solution for deep investigations of hydrodynamics and heat transfer of nanofluid's natural convection. The book also proposes novel predictive formulae for the evaluation of heat transfer of Al2O3-water nanofluid's natural convection. The formulae have reliable theoretical and practical value because they are developed by rigorous theoretical analysis of heat transfer combined with full consideration of the effects of the temperature-dependent physical properties of nanofluids and the nanoparticle shape factor and concentration, as well as variations of fluid boundary temperatures. The conversion factors proposed help to turn the heat transfer coefficient and rate of fluid natural convection into those of nanofluid natural convection. Furthermore, several calculation examples are provided to demonstrate the heat transfer application of the proposed predictive formulae.
The field of thermal therapy has been growing tenaciously in the last few decades. The application of heat to living tissues, from mild hyperthermia to high-temperature thermal ablation, has produced a host of well-documented genetic, cellular, and physiological responses that are being researched intensely for medical applications, particularly for treatment of solid cancerous tumors using image guidance. The controlled application of thermal energy to living tissues has proven a great challenge, requiring expertise from multiple disciplines, thereby leading to the development of many sophisticated pre-clinical and clinical devices and treatment techniques. Physics of Thermal Therapy: Fundamentals and Clinical Applications captures the breadth and depth of this highly multidisciplinary field. Focusing on applications in cancer treatment, this book covers basic principles, practical aspects, and clinical applications of thermal therapy. An overview of the fundamentals shows how use of controlled heat in medicine and biology involves electromagnetics, acoustics, thermodynamics, heat transfer, and imaging sciences. The book discusses challenges in the use of thermal energy on living tissues and explores the genetic, cellular, and physiological responses that can be employed in the fight against cancer from the physics and engineering perspectives. It also highlights recent advances, including the treatment of solid tumors using image-guided thermal therapy, microbubbles, nanoparticles, and other cutting-edge techniques.
From the basics of thermodynamics to solutions for modern dynamical problems —the complete beginner's guide to statistical mechanics. Unlike most books on statistical mechanics, this one is written for advanced students in chemistry, chemical engineering, biophysics, and related fields. It targets readers with no prior exposure to statistical mechanics and provides a complete introduction to all the important principles, concepts, and equations, while maintaining a level of mathematical sophistication that most advanced chemistry students will find manageable. The emphasis is on finding solutions to common problems in chemistry. Topics covered include:
Clearly written, and with a minimum of theory, Statistical Mechanics for Chemists takes you step by step through mathematical manipulations and explains the physical and chemical bases for each procedure. It is a valuable resource for advanced students in chemistry, chemical engineering, biophysics, and related fields.
This monograph attempts to provide a systematic and consistent survey of the fundamentals of the theory of free, linear, isentropic oscillations in spherically symmetric, gaseous equilibrium stars, whose structure is affected neither by axial rotation, nor by the tidal action of a companion, nor by a magnetic eld. Three parts can be distinguished. The rst part, consisting of Chaps.1-8, covers the basic concepts and equations, the distinction between spheroidal and toroidal normal modes, the solution of Poisson's differential equation for the perturbation of the gravitational potential, and Hamilton's variational principle. The second part, consisting of Chaps.9-13, is devotedto the possible existenceof waves propagating in the radial direction, the origin and classi cation of normal modes, the comple- ness of the normal modes, and the relation between the local stability with respect to convection and the global stability of a star. In the third part, Chaps.14-18 c- tain asymptoticrepresentationsof normalmodes. Chapter 19 deals with slow period changes in rapidly evolving pulsating stars. The theory is developed within the framework of the Newtonian theory of gr- itation and the hydrodynamics of compressible uids. It is described in its present status, with inclusion of open questions. We give preference to the use of the adjective "isentropic" above that of the adjective "adiabatic," since, from a thermodynamic point of view, these stellar - cillations are described as reversible adiabatic processes and thus as processes that take place at constant entropy.
This book presents a consistent mathematical theory of the non-electronic physical properties of disordered and amorphous solids, starting from the atomic-level dynamics and leading to experimentally verifiable descriptions of macroscopic properties such as elastic and viscoelastic moduli, plasticity, phonons and vibrational spectra, and thermal properties. This theory begins with the assumption of the undeniable existence of an “amorphous latticeâ€, which allows one to relegate the theoretical uncertainties about the ultimate nature of the glass transition to a subsidiary role and thus take a more pragmatic approach towards the modelling of physical properties. The book introduces the reader not only to the subtle physical concepts underlying the dynamics, mechanics, and statistical physics of glasses and amorphous solids, but also to the essential mathematical and numerical methods that cannot be readily gleaned from specialized literature since they are spread out among many often technically demanding papers. These methods are presented in this book in such a way as to be sufficiently general, allowing for the mathematical or numerical description of novel physical phenomena observed in many different types of amorphous solids (including soft and granular systems), regardless of the atomistic details and particular chemistry of the material.  This monograph is aimed at researchers and graduate-level students in physics, materials science, physical chemistry and engineering working in the areas of amorphous materials, soft matter and granular systems, statistical physics, continuum mechanics, plasticity, and solid mechanics. It is also particularly well suited to those working on molecular dynamics simulations, molecular coarse-grained simulations, as well as ab initio atomistic and DFT methods for solid-state and materials science.
The idea of this book is to present the up-to-date research results on Nitrate Esters as explosive materials. It covers many aspects including the material structures, nitrating agent, chemical synthesis devices, preparation technology, and applications etc. In particular, this work sheds light on the comprehensive utilization and thorough destruction of the used Nitrate Easters which is crucial for preventing repeated pollution. This is a highly informative and instructive book providing insight for the researchers working on nitrating theory, energetic materials and chemical equipments.
This book presents the physical science experiments in a space microgravity environment conducted on board the SJ-10 recoverable satellite, which was launched on April 6th, 2016 and recovered on April 18th, 2016. The experiments described were selected from ~100 proposals from various institutions in China and around the world, and have never previously been conducted in the respective fields. They involve fluid physics and materials science, and primarily investigate the kinetic properties of matter in a space microgravity environment. The book provides a comprehensive review of these experiments, as well as the mission's execution, data collection, and scientific outcomes.
This book presents the optimal auxiliary functions method and applies it to various engineering problems and in particular in boundary layer problems. The cornerstone of the presented procedure is the concept of "optimal auxiliary functions" which are needed to obtain accurate results in an efficient way. Unlike other known analytic approaches, this procedure provides us with a simple but rigorous way to control and adjust the convergence of the solutions of nonlinear dynamical systems. The optimal auxiliary functions are depending on some convergence-control parameters whose optimal values are rigorously determined from mathematical point of view. The capital strength of our procedure is its fast convergence, since after only one iteration, we obtain very accurate analytical solutions which are very easy to be verified. Moreover, no simplifying hypothesis or assumptions are made. The book contains a large amount of practical models from various fields of engineering such as classical and fluid mechanics, thermodynamics, nonlinear oscillations, electrical machines, and many more. The book is a continuation of our previous books "Nonlinear Dynamical Systems in Engineering. Some Approximate Approaches", Springer-2011 and "The Optimal Homotopy Asymptotic Method. Engineering Applications", Springer-2015.
This textbook brings together the fundamentals of the macroscopic and microscopic aspects of thermal physics by presenting thermodynamics and statistical mechanics as complementary theories based on small numbers of postulates. The book is designed to give the instructor flexibility in structuring courses for advanced undergraduates and/or beginning graduate students and is written on the principle that a good text should also be a good reference. The presentation of thermodynamics follows the logic of Clausius and Kelvin while relating the concepts involved to familiar phenomena and the modern student's knowledge of the atomic nature of matter. Another unique aspect of the book is the treatment of the mathematics involved. The essential mathematical concepts are briefly reviewed before using them, and the similarity of the mathematics to that employed in other fields of physics is emphasized. The text gives in depth treatments of low density gases, harmonic solids, magnetic and dielectric materials, phase transitions, and the concept of entropy. The microcanonical, canonical, and grand canonical ensembles of statistical mechanics are derived and used as the starting point for the analysis of fluctuations, blackbody radiation, the Maxwell distribution, Fermi-Dirac statistics, Bose-Einstein condensation, and the statistical basis of computer simulations. Supplementary material including PowerPoint slides and detailed worked solutions can be downloaded online at http://booksupport.wiley.com
Rational extended thermodynamics (RET) is the theory that is applicable to nonequilibrium phenomena out of local equilibrium. It is expressed by the hyperbolic system of field equations with local constitutive equations and is strictly related to the kinetic theory with the closure method of the hierarchies of moment equations. The book intends to present, in a systematic way, new results obtained by RET of gases in both classical and relativistic cases, and it is a natural continuation of the book "Rational Extended Thermodynamics beyond the Monatomic Gas" by the same authors published in 2015. However, this book addresses much wider topics than those of the previous book. Its contents are as follows: RET of rarefied monatomic gases and of polyatomic gases; a simplified RET theory with 6 fields being valid far from equilibrium; RET where both molecular rotational and vibrational modes exist; mixture of gases with multi-temperature. The theory is applied to several typical topics (sound waves, shock waves, etc.) and is compared with experimental data. From a mathematical point of view, RET can be regarded as a theory of hyperbolic symmetric systems, of which it is possible to conduct a qualitative analysis. The book represents a valuable resource for applied mathematicians, physicists, and engineers, offering powerful models for many potential applications such as reentering satellites into the atmosphere, semiconductors, and nanoscale phenomena.
Predicting thermodynamic quantities for chemically realistic systems on the basis of atomistic calculations is still, even today, a nontrivial task. Nonetheless, accurate treatment of inter-particle interactions, in terms of quantum chemical first principles methods, is a prerequisite for many applications, because of the complexity of both reactants and solvents in modern molecular sciences. Currently, a straightforward calculation of thermodynamic properties from these methods is only possible for high-temperature and low- density systems. Although the enthalpy of a system can often be predicted to a good level of precision with this ideal gas approach, calculating the entropy contribution to the free energy is problematic, especially as the density of the system increases. This thesis contains a compact and coherent introduction of basic theoretical features. The foundations are then laid for the development of approaches suitable for calculation of condensed phase entropies on the basis of well-established quantum chemical methods. The main emphasis of this work is on realistic systems in solution, which is the most important environment for chemical synthesis. The presented results demonstrate how isolated molecular concepts typically employed in modern quantum chemistry can be extended for the accurate determination of thermodynamic properties by means of scale- transferring approaches.
Fundamentals of the Finite Element Method for Heat and Mass Transfer, Second Edition is a comprehensively updated new edition and is a unique book on the application of the finite element method to heat and mass transfer. Addresses fundamentals, applications and computer implementation Educational computer codes are freely available to download, modify and use Includes a large number of worked examples and exercises Fills the gap between learning and research
This book is based on the premise that the entropy concept, a fundamental element of probability theory as logic, governs all of thermal physics, both equilibrium and nonequilibrium. The variational algorithm of J. Willard Gibbs, dating from the 19th Century and extended considerably over the following 100 years, is shown to be the governing feature over the entire range of thermal phenomena, such that only the nature of the macroscopic constraints changes. Beginning with a short history of the development of the entropy concept by Rudolph Clausius and his predecessors, along with the formalization of classical thermodynamics by Gibbs, the first part of the book describes the quest to uncover the meaning of thermodynamic entropy, which leads to its relationship with probability and information as first envisioned by Ludwig Boltzmann. Recognition of entropy first of all as a fundamental element of probability theory in mid-twentieth Century led to deep insights into both statistical mechanics and thermodynamics, the details of which are presented here in several chapters. The later chapters extend these ideas to nonequilibrium statistical mechanics in an unambiguous manner, thereby exhibiting the overall unifying role of the entropy.
This long-awaited, physics-first and design-oriented text describes and explains the underlying flow and heat transfer theory of secondary air systems. An applications-oriented focus throughout the book provides the reader with robust solution techniques, state-of-the-art three-dimensional computational fluid dynamics (CFD) methodologies, and examples of compressible flow network modeling. It clearly explains elusive concepts of windage, non-isentropic generalized vortex, Ekman boundary layer, rotor disk pumping, and centrifugally-driven buoyant convection associated with gas turbine secondary flow systems featuring rotation. The book employs physics-based, design-oriented methodology to compute windage and swirl distributions in a complex rotor cavity formed by surfaces with arbitrary rotation, counter-rotation, and no rotation. This text will be a valuable tool for aircraft engine and industrial gas turbine design engineers as well as graduate students enrolled in advanced special topics courses.
This book introduces the concepts of physical chemistry of polymers in a format targeted for a blended-learning approach. It provides a basis to bridge polymer chemistry, which targets microscopic chain structures, and polymer engineering, which targets macroscopic material properties and functions. Topics covered are single chain statistics, multi-chain interactions, and chain dynamics, both from a viewpoint of structure, properties (mostly mechanical ones), and their interrelation. In all that, the author encourages the reader to think conceptually. Explains complex facts through simplifying models, diagrams, and illustrations Accessible to chemists, chemical engineers, materials scientists, and physicists Tailored content for an interactive blended-learning format
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