This book is devoted to the problems of oxidation chemical reactions and addresses bimodal reaction sequences. Chemical reactions of oxidation, occurring under certain conditions and in multicomponent systems are complex processes. The process of the oxidation essentially changes in the presence and contact of the solid substances with reactants. The role of solid substances and the appearance of this phenomenon in oxidation reaction are discussed. The reader will understand the "driving forces" of this phenomenon and apply it in practice. Written for chemists, physicists, biologists and engineers working in the domain of oxidation reactions. Key Selling Features: Covers the historical background, modern state of the art, and perspectives in investigations of the coupling between heterogeneous and homogeneous reactions Discusses the feasible pathways of the coupling of heterogeneous and homogeneous reactions in oxidation in man-made and natural chemical systems Addresses the abundance, peculiarities and mechanisms of the bimodal reaction sequences in oxidation with dioxygen in recent decades Discusses the existence of the bimodal reaction sequences in chemical systems investigations in atmospheric chemistry and heterogeneous photocatalysis Presented in a simple concise style, accessible for both specialists and non-specialists

The revised second edition of this practical book reviews the fundamentals of cryogenic liquid behaviour in small and large scale storage systems. The text is based on research findings on the convective and evaporative behaviour of cryogenic fluids, aimed at improving the design, construction and operation of low-loss cryogenic liquid storage systems, with a view to minimising cost and improving operational safety. Since the first edition was published in 2006, the breadth of cryogenic applications and the modelling of cryogenic fluid dynamics (CFD) have expanded in several directions. In this second edition, most chapters have been extended to introduce discussions of these new applications and their safety and energy economy. These include advances in the modelling of CFD required in, for example, the design of miniature cryocoolers and condensers and reboilers, large-scale cryogenic liquid mixture properties and their stability, and the understanding that hazards and safety problems in the public domain increase with the scaling up of cryogenic systems. With helpful summaries at the end of each chapter, the book is an essential reference for anyone working on the design and operation of cryogenic liquid storage and transportation systems.

This textbook introduces thermodynamics with a modern approach, starting from four fundamental physical facts (the atomic nature of matter, the indistinguishability of atoms and molecules of the same species, the uncertainty principle, and the existence of equilibrium states) and analyzing the behavior of complex systems with the tools of information theory, in particular with Shannon's measure of information (or SMI), which can be defined on any probability distribution. SMI is defined and its properties and time evolution are illustrated, and it is shown that the entropy is a particular type of SMI, i.e. the SMI related to the phase-space distribution for a macroscopic system at equilibrium. The connection to SMI allows the reader to understand what entropy is and why isolated systems follow the Second Law of Thermodynamics. The Second Llaw is also formulated for other systems, not thermally isolated and even open with respect to the transfer of particles. All the fundamental aspects of thermodynamics are derived and illustrated with several examples in the first part of the book. The second part addresses important applications of thermodynamics, covering phase transitions, mixtures and solutions (including the Kirkwood-Buff approach and solvation thermodynamics), chemical equilibrium, and the outstanding properties of water.This textbook is unique in two aspects. First, thermodynamics is introduced with a novel approach, based on information theory applied to macroscopic systems at equilibrium. It is shown that entropy is a particular case of Shannon's measure of information (SMI), and the properties and time evolution of the SMI are used to explain the Second Law of Thermodynamics. This represents a real breakthrough, as classical thermodynamics cannot explain entropy, nor clarify why systems should obey the Second Law. Second, this textbook offers the reader the possibility to get in touch with important and advanced applications of thermodynamics, to address the topics discussed in the second part of the book. Although they may go beyond the content of a typical introductory course on thermodynamics, some of them can be important in the curriculum chosen by the student. At the same time, they are of appealing interest to more advanced scholars.

This book focuses on mixed crystals formed by molecular substances. The emphasis lies on the elucidation of the structural and thermodynamic properties of two-component systems. Thanks to the fact that the research efforts have been directed to a number of families of chemically coherent substances, rather than to a collection of isolated systems, the knowledge of mixed crystals has substantially increased. This is reflected by the discovery of several empirical relationships between thermodynamic properties, crystallographic properties, and also between thermodynamic mixing properties and exothermodynamic parameters, such as the structural mismatch between the components of the binary systems. This book is a benchmark for material scientists and a unique starting point for anyone interested in mixed crystals.

The term transport phenomena is used to describe processes in which mass, momentum, energy and entropy move about in matter. Advances in Transport Phenomena provide state-of-the-art expositions of major advances by theoretical, numerical and experimental studies from a molecular, microscopic, mesoscopic, macroscopic or megascopic point of view across the spectrum of transport p- nomena, from scientific enquiries to practical applications. The annual review series intends to fill the information gap between regularly published journals and university-level textbooks by providing in-depth review articles over a broader scope than in journals. The authoritative articles, contributed by international- leading scientists and practitioners, establish the state of the art, disseminate the latest research discoveries, serve as a central source of reference for fundamentals and applications of transport phenomena, and provide potential textbooks to senior undergraduate and graduate students. The series covers mass transfer, fluid mechanics, heat transfer and thermo- namics. The 2009 volume contains the four articles on biomedical, environmental and nanoscale transports. The editorial board expresses its appreciation to the c- tributing authors and reviewers who have maintained the standard associated with Advances in Transport Phenomena. We also would like to acknowledge the efforts of the staff at Springer who have made the professional and attractive pr- entation of the volume. Serial Editorial Board Editor-in-Chief Professor L. Q. Wang The University of Hong Kong, Hong Kong; lqwang@hku. hk Editors Professor A. R. Balakrishnan Indian Institute of Technology Madras, India Professor A.

The simulation of turbulent reacting flows, connected with environmental protection and the design of chemical and mechanical processes, is increasingly important. Statistical Mechanics of Turbulent Flows presents a modern overview of basic ways to calculate such flows. It discusses the fundamental problems related to the use of basic equations and their modifications. Special emphasis is placed on the discussion of very promising statistical methods which provide solutions to these problems by models for the underlying stochastic physics of turbulent reacting flows. Their foundations and important new developments up through current challenges are systematically explained. Students and researchers in atmospheric sciences and oceanography, mechanical and chemical engineering and applied mathematics and physics may use Statistical Mechanics of Turbulent Flows as a guide to solve many problems related, e.g. to the assessment of complex atmospheric chemistry, chemical reactor processes, turbulent combustion, and multi-phase flows.

This book aims to provide a lively working knowledge of the thermodynamic control of microscopic simulations, while summarizing the historical development of the subject, along with some personal reminiscences. Many computational examples are described so that they are well-suited to learning by doing. The contents enhance the current understanding of the reversibility paradox and are accessible to advanced undergraduates and researchers in physics, computation, and irreversible thermodynamics.

The original work by M.D. Sturge has been updated and expanded to include new chapters covering non-equilibrium and biological systems. This second edition re-organizes the material in a more natural manner into four parts that continues to assume no previous knowledge of thermodynamics. The four divisions of the material introduce the subject inductively and rigorously, beginning with key concepts of equilibrium thermodynamics such as heat, temperature and entropy. The second division focuses on the fundamentals of modern thermodynamics: free energy, chemical potential and the partition function. The second half of the book is then designed with the flexibility to meet the needs of both the instructor and the students, with a third section focused on the different types of gases: ideal, Fermi-Dirac, Bose-Einstein, Black Body Radiation and the Photon gases. In the fourth and final division of the book, modern thermostatistical applications are addressed: semiconductors, phase transitions, transport processes, and finally the new chapters on non-equilibrium and biological systems. Key Features: Provides the most readable, thorough introduction to statistical physics and thermodynamics, with magnetic, atomic, and electrical systems addressed alongside development of fundamental topics at a non-rigorous mathematical level. Includes brand-new chapters on biological and chemical systems and non-equilibrium thermodynamics, as well as extensive new examples from soft condensed matter and correction of typos from the prior edition. Incorporates new numerical and simulation exercises throughout the book. Adds more worked examples, problems, and exercises.

This book will help readers understand thermodynamic properties caused by magnetic fields. Providing a concise review of time independent magnetic fields, it goes on to discuss the thermodynamic properties of magnetizing materials of different shapes, and finally, the equilibrium properties of superconductors of different shapes and also of different sizes. Chapters are accompanied by problems illustrating the applications of the principles to optimize and enhance understanding. This book will be of interest to advanced undergraduates, graduate students, and researchers specializing in thermodynamics, solid state physics, magnetism, and superconductivity. Features: The first book to provide comprehensive coverage of thermodynamics in magnetic fields, only previously available, in part, in journal articles Chapters include problems and worked solutions demonstrating real questions in contemporary superconductivity, such as properties of vortex matter

Three-dimensional (3D) integration of microsystems and subsystems has become essential to the future of semiconductor technology development. 3D integration requires a greater understanding of several interconnected systems stacked over each other. While this vertical growth profoundly increases the system functionality, it also exponentially increases the design complexity. Design of 3D Integrated Circuits and Systems tackles all aspects of 3D integration, including 3D circuit and system design, new processes and simulation techniques, alternative communication schemes for 3D circuits and systems, application of novel materials for 3D systems, and the thermal challenges to restrict power dissipation and improve performance of 3D systems. Containing contributions from experts in industry as well as academia, this authoritative text: Illustrates different 3D integration approaches, such as die-to-die, die-to-wafer, and wafer-to-wafer Discusses the use of interposer technology and the role of Through-Silicon Vias (TSVs) Presents the latest improvements in three major fields of thermal management for multiprocessor systems-on-chip (MPSoCs) Explores ThruChip Interface (TCI), NAND flash memory stacking, and emerging applications Describes large-scale integration testing and state-of-the-art low-power testing solutions Complete with experimental results of chip-level 3D integration schemes tested at IBM and case studies on advanced complementary metal-oxide-semiconductor (CMOS) integration for 3D integrated circuits (ICs), Design of 3D Integrated Circuits and Systems is a practical reference that not only covers a wealth of design issues encountered in 3D integration but also demonstrates their impact on the efficiency of 3D systems.

First published in 1922, this book represents the first attempt to popularise the more accessible aspects of Albert Einstein's general theory of relativity. Eschewing the mathematical components that put the theory beyond many people's grasp, the author employs metaphorical examples and thought experiments to convey the fundamental ideas and assertions of one of physics' most famous principles - which remains the accepted description of gravitation more than a century after its first publication. This book will of interest to students of physics as an introductory basis to aid further study.

Multi-phase flows are part of our natural environment such as tornadoes, typhoons, air and water pollution and volcanic activities as well as part of industrial technology such as power plants, combustion engines, propulsion systems, or chemical and biological industry. The industrial use of multi-phase systems requires analytical and numerical strategies for predicting their behavior. .In its fourth extended edition the successful monograph package Multiphase Flow Daynmics contains theory, methods and practical experience for describing complex transient multi-phase processes in arbitrary geometrical configurations, providing a systematic presentation of the theory and practice of numerical multi-phase fluid dynamics.

In the present third volume methods for describing of the thermal interactions in multiphase dynamics are provided. In addition a large number of valuable experiments is collected and predicted using the methods introduced in this monograph. In this way the accuracy of the methods is revealed to the reader.

This fourth edition includes various updates, extensions, improvements and corrections.

"The literature in the field of multiphase flows is numerous. Therefore, it is very important to have a comprehensive and systematic overview including useful numerical methods. The volumes have the character of a handbook and accomplish this function excellently. The models are described in detail and a great number of comprehensive examples and some cases useful for testing numerical solutions are included. These two volumes are very useful for scientists and practicing engineers in the fields of technical thermodynamics, chemical engineering, fluid mechanics, and for mathematicians with interest in technical problems. Besides, they can give a good overview of the dynamically developing, complex field of knowledge to students. This monograph is highly recommended,

BERND PLATZER, ZAAM

In the present third volume methods for describing of the thermal interactions in multiphase dynamics are provided. In addition a large number of valuable experiments is collected and predicted using the methods introduced in this monograph. In this way the accuracy of the methods is revealed to the reader.

This fourth edition includes various updates, extensions, improvements and corrections.

"The literature in the field of multiphase flows is numerous. Therefore, it is very important to have a comprehensive and systematic overview including useful numerical methods. The volumes have the character of a handbook and accomplish this function excellently. The models are described in detail and a great number of comprehensive examples and some cases useful for testing numerical solutions are included. These two volumes are very useful for scientists and practicing engineers in the fields of technical thermodynamics, chemical engineering, fluid mechanics, and for mathematicians with interest in technical problems. Besides, they can give a good overview of the dynamically developing, complex field of knowledge to students. This monograph is highly recommended,

BERND PLATZER, ZAAM

This textbook provides a comprehensive, yet accessible, introduction to statistical mechanics. Crafted and class-tested over many years of teaching, it carefully guides advanced undergraduate and graduate students who are encountering statistical mechanics for the first time through this - sometimes - intimidating subject. The book provides a strong foundation in thermodynamics and the ensemble formalism of statistical mechanics. An introductory chapter on probability theory is included. Applications include degenerate Fermi systems, Bose-Einstein condensation, cavity radiation, phase transitions, and critical phenomena. The book concludes with a treatment of scaling theories and the renormalization group. In addition, it provides clear descriptions of how to understand the foundational mathematics and physics involved and includes exciting case studies of modern applications of the subject in physics and wider interdisciplinary areas. Key Features: Presents the subject in a clear and entertaining style which enables the author to take a sophisticated approach whilst remaining accessible Contains contents that have been carefully reviewed with a substantial panel to ensure that coverage is appropriate for a wide range of courses, worldwide Accompanied by volumes on thermodynamics and non-equilibrium statistical mechanics, which can be used in conjunction with this book, on courses which cover both thermodynamics and statistical mechanics

'Ben-Naim convincingly argues that SMI not only gives a simpler and more broadly applicable definition of entropy, but also clears up much of the historical and modern confusion surrounding the second law. This book will interest any individual who wants to understand how SMI gives a clear definition of entroy.'CHOICE ConnectThis book discusses the proper definitions of entropy, the valid interpretation of entropy and some useful applications of the concept of entropy. Unlike many books which apply the concept of entropy to systems for which it is not even defined (such as living systems, black holes and the entire universe), these applications will help the reader to understand the meaning of entropy. It also emphasizes the limitations of the applicability of the concept of entropy and the Second Law of Thermodynamics. As with the previous books by the author, this book aims at a clear and mystery-free presentation of the central concept in thermodynamics - the entropy.In this book, the concepts of entropy and the Second Law are presented in a friendly, simple language. It is devoid of all kinds of fancy and pompous statements made by authors of popular science books who write on this subject.

Power Plant Synthesis provides an integrated approach to the operation, analysis, simulation, and dimensioning of power plants for electricity and thermal energy production. Fundamental concepts of energy and power, energy conversion, and power plant design are first presented, and integrated approaches for the operation and simulation of conventional electricity production systems are then examined. Hybrid power plants and cogeneration systems are covered, with operating algorithms, optimization, and dimensioning methods explained. The environmental impacts of energy sources are described and compared, with real-life case studies included to show the synthesis of the specific topics covered.

Energy is typically regarded as understandable, despite its multiple forms of storage and transfer. Entropy, however, is an enigma, in part because of the common view that it represents disorder. That view is flawed and hides entropy's connection with energy. In fact, macroscopic matter stores internal energy, and that matter's entropy is determined by how the energy is stored. Energy and entropy are intimately linked. Energy and Entropy: A Dynamic Duo illuminates connections between energy and entropy for students, teachers, and researchers. Conceptual understanding is emphasised where possible through examples, analogies, figures, and key points. Features: Qualitative demonstration that entropy is linked to spatial and temporal energy spreading, with equilibrium corresponding to the most equitable distribution of energy, which corresponds to maximum entropy Analysis of energy and entropy of matter and photons, with examples ranging from rubber bands, cryogenic cooling, and incandescent lamps to Hawking radiation of black holes Unique coverage of numerical entropy, the 3rd law of thermodynamics, entropic force, dimensionless entropy, free energy, and fluctuations, from Maxwell's demon to Brownian ratchets, plus attempts to violate the second law of thermodynamics

This textbook brings together the fundamentals of the macroscopic and microscopic aspects of thermal physics by presenting thermodynamics and statistical mechanics as complementary theories based on small numbers of postulates. The book is designed to give the instructor flexibility in structuring courses for advanced undergraduates and/or beginning graduate students and is written on the principle that a good text should also be a good reference. The presentation of thermodynamics follows the logic of Clausius and Kelvin while relating the concepts involved to familiar phenomena and the modern student's knowledge of the atomic nature of matter. Another unique aspect of the book is the treatment of the mathematics involved. The essential mathematical concepts are briefly reviewed before using them, and the similarity of the mathematics to that employed in other fields of physics is emphasized. The text gives in depth treatments of low density gases, harmonic solids, magnetic and dielectric materials, phase transitions, and the concept of entropy. The microcanonical, canonical, and grand canonical ensembles of statistical mechanics are derived and used as the starting point for the analysis of fluctuations, blackbody radiation, the Maxwell distribution, Fermi-Dirac statistics, Bose-Einstein condensation, and the statistical basis of computer simulations. Supplementary material including PowerPoint slides and detailed worked solutions can be downloaded online at http://booksupport.wiley.com

The book is aimed at undergraduate students in their senior year and first year graduate students. It elucidates the basis of thermodynamics and provides a basis for the understanding of, not only the thermodynamic properties of a microscopic system, but also their fluctuations, correlations and close-to-equilibrium properties.

These lecture notes provide a detailed treatment of the thermal energy storage and transport by conduction in natural and fabricated structures. Thermal energy in two carriers, i.e. phonons and electrons - are explored from first principles. For solid-state transport, a common Landauer framework is used for heat flow. Issues including the quantum of thermal conductance, ballistic interface resistance, and carrier scattering are elucidated. Bulk material properties, such as thermal and electrical conductivity, are derived from particle transport theories, and the effects of spatial confinement on these properties are established.

These lecture notes provide a detailed treatment of the thermal energy storage and transport by conduction in natural and fabricated structures. Thermal energy in two carriers, i.e. phonons and electrons - are explored from first principles. For solid-state transport, a common Landauer framework is used for heat flow. Issues including the quantum of thermal conductance, ballistic interface resistance, and carrier scattering are elucidated. Bulk material properties, such as thermal and electrical conductivity, are derived from particle transport theories, and the effects of spatial confinement on these properties are established.

'Ben-Naim convincingly argues that SMI not only gives a simpler and more broadly applicable definition of entropy, but also clears up much of the historical and modern confusion surrounding the second law. This book will interest any individual who wants to understand how SMI gives a clear definition of entroy.'CHOICE ConnectThis book discusses the proper definitions of entropy, the valid interpretation of entropy and some useful applications of the concept of entropy. Unlike many books which apply the concept of entropy to systems for which it is not even defined (such as living systems, black holes and the entire universe), these applications will help the reader to understand the meaning of entropy. It also emphasizes the limitations of the applicability of the concept of entropy and the Second Law of Thermodynamics. As with the previous books by the author, this book aims at a clear and mystery-free presentation of the central concept in thermodynamics - the entropy.In this book, the concepts of entropy and the Second Law are presented in a friendly, simple language. It is devoid of all kinds of fancy and pompous statements made by authors of popular science books who write on this subject.

Small systems are a very active area of research and development due to improved instrumentation that allows for spatial resolution in the range of sizes from one to 100 nm. In this size range, many physical and chemical properties change, which opens up new approaches to the study of substances and their practical application. This affects both traditional fields of knowledge and many other new fields including physics, chemistry, biology, etc. This book highlights new developments in statistical thermodynamics that answer the most important questions about the specifics of small systems - when one cannot apply equations or traditional thermodynamic models.

Providing a systematic introduction to the techniques which are fundamental to quantum field theory, this book pays special attention to the use of these techniques in a wide variety of areas, including ordinary quantum mechanics, quantum mechanics in the second-quantized formulation, relativistic quantum field theory, Euclidean field theory, quantum statistics at finite temperature, and the classical statistics of nonideal gas and spin systems. The extended chapter on variational methods and functional Legendre transformations contains completely original material.

This book provides an accessible yet thorough introduction to thermodynamics, crafted and class-tested over many years of teaching. Suitable for advanced undergraduate and graduate students, this book delivers clear descriptions of how to think about the mathematics and physics involved. The content has been carefully developed in consultation with a large number of instructors, teaching courses worldwide, to ensure wide applicability to modules on thermodynamics. Modern applications of thermodynamics (in physics and related areas) are included throughout-something not offered to the same degree by existing texts in the field. Features: A sophisticated approach to the subject that is suitable for advanced undergraduate students and above Modern applications of thermodynamics included throughout To be followed by volumes on statistical mechanics, which can be used in conjunction with this book on courses which cover both thermodynamics and statistical mechanics

This book serves as a guide for discovering pathways to more efficient energy use. The first part of the book illustrates basic laws of energy conversion and principles of thermodynamics. Laws of energy conservation and direction of energy conversion are formulated in detail, and the types of thermodynamic processes are explained. Also included is the characterization of various types of real energy conversion. The second part of the book discusses types of energy conversion referred to as thermal-energy technologies. The advantages of the co-generation processes and devices operating within the Brayton direct cycle and their adaptively to household energetics are underlined.