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Books > Science & Mathematics > Physics > Thermodynamics & statistical physics > Thermodynamics
This book contains the expanded lecture notes of the 32nd Saas-Fee Advanced Course. The three contributions present the central themes in modern research on the cold universe, ranging from cold objects at large distances to the physics of dust in cold clouds.
This volume contains the proceedings of a NATO Advanced study Institute held at Geilo, Norway between 2 - 12 april 1991. This institute was the eleventh in a series held biannually at Geilo on the subject of phase transitions. It was intended to capture the latest ideas on selforgan ized patterns and criticality. The Institute brought together many lecturers, students and active re searchers in the field from a wide range of NATO and non-NATO countries. The main financial support came from the NATO scientific Affairs Divi sion, but additional support was obtained from the Norwegian Research Council for Science and the Humanities (NAVF) and Institutt for energi teknikk. The organizers would like to thank all these contributors for their help in promoting an exciting and rewarding meeting, and in doing so are confident that they echo the appreciation of all the parti cipants. In cooperative, equilibrium systems, physical states are described by spatio-temporal correlation functions. The intimate connection between space and time correlations is especially apparent at the critical point, the second order phase transition, where the spatial range and the decay time of the correlation function both become infinite. The salient features of critical phenomena and the history of the devel opment of this field of science are treated in the first chapter of this book."
Despite scientific evidence that business-as-usual is unsustainable, there is a huge and widespread inertia to 'greening' the planet. Warming to Ecocide considers climate change from a thermodynamic perspective and asks whether market-driven organisations have carried us to the point of no return through the flawed economics of endless growth. Warming to Ecocide begins by exploring the thermodynamic origins of climate change. It demonstrates that equilibrium thermodynamics can provide full explanations for the basic processes of life such as photosynthesis and metabolism, and that non-equilibrium thermodynamics is close to providing an explanation for how life started. Armed with a solid appreciation of the power of thermodynamics, the second half of Warming to Ecocide discusses whether multinational corporations have convinced the public that climate change is insignificant and thereby neutered any all attempts by governments to espouse environmentally-friendly policies. It then goes on to offer strategies whereby mankind may avoid propelling the global average temperature above the pre-industrial level by more than 2 DegreesC, which scientists view as a threshold presaging catastrophic run-away processes.
Low-Grade Thermal Energy Harvesting: Advances in Thermoelectrics, Materials, and Emerging Applications provides readers with fundamental and key concepts surrounding low-grade thermal energy conversion while also reviewing the latest research directions. The book covers the most promising and emerging technologies for low-grade heat recovery, harvesting and conversion, including wearable thermoelectrics and organic thermoelectrics. Each chapter includes key materials, principles, design and fabrication strategies for low-grade heat recovery. Special attention on emerging materials such as organic composites, 2D materials and nanomaterials are also included. The book emphasizes materials and device structures that enable the powering of wearable electronics and consumer electronics. The book is suitable for materials scientists and engineers in academia and R&D in manufacturing, industry, energy and electronics.
This monograph provides a comprehensive study about how a dilute gas described by the Boltzmann equation responds under extreme nonequilibrium conditions. This response is basically characterized by nonlinear transport equations relating fluxes and hydrodynamic gradients through generalized transport coefficients that depend on the strength of the gradients. In addition, many interesting phenomena (e.g. chemical reactions or other processes with a high activation energy) are strongly influenced by the population of particles with an energy much larger than the thermal velocity, what motivates the analysis of high-degree velocity moments and the high energy tail of the distribution function. The authors have chosen to focus on shear flows with simple geometries, both for single gases and for gas mixtures. This allows them to cover the subject in great detail. Some of the topics analyzed include: -Non-Newtonian or rheological transport properties, such as the
nonlinear shear viscosity and the viscometric functions. The text can be read as a whole or can be used as a resource for selected topics from specific chapters.
"Temperature and Humidity Independent Control (THIC) of Air-conditioning System" focuses on temperature and humidity independent control (THIC) systems, which represents a new concept and new approach for indoor environmental control. This book presents the main components of the THIC systems, including dehumidification devices, high-temperature cooling devices and indoor terminal devices. Other relevant issues, such as operation and control strategy and case studies, are also included. This book is intended for air-conditioning system designers and engineers as well as researchers working with indoor environments. Xiaohua Liu is an associate professor at the Building Energy Research Center, Tsinghua University, China. Yi Jiang is a member of the Chinese Academy of Engineering, the director of the Building Energy Research Center, Tsinghua University, China and the director of the China-USA Joint Research Center on Clean Energy. Tao Zhang is a Ph.D. candidate at the Building Energy Research Center, Tsinghua University, China.
This textbook explores the working principles of all kinds of turbomachines. The same theoretical framework is used to analyze the different machine types. The order in which the different kinds are treated is chosen by the possibility of gradually building up theoretical concepts. For each of the turbomachine kinds, a balance is sought between fundamental understanding and knowledge of practical aspects. Readers are invited through challenging exercises to consider how the theory applies to particular cases. This textbook appeals to senior undergraduate and graduate students in mechanical engineering and to professional engineers seeking to understand the operation of turbomachines. Readers will gain a fundamental understanding of turbomachines and will be able to make a reasoned choice of a turbomachine for a particular application.
In this volume we continue the logical development of the work begun in Volume I, and the equilibrium theory now becomes a very special case of the exposition presented here. Once a departure is made from equilibrium, however, the problems become deeper and more subtle-and unlike the equilibrium theory, many aspects of nonequilibrium phenomena remain poorly understood. For over a century a great deal of effort has been expended on the attempt to develop a comprehensive and sensible description of nonequilibrium phenomena and irreversible processes. What has emerged is a hodgepodge of ad hoc constructs that do little to provide either a firm foundation, or a systematic means for proceeding to higher levels of understanding with respect to ever more complicated examples of nonequilibria. Although one should rightfully consider this situation shameful, the amount of effort invested testifies to the degree of difficulty of the problems. In Volume I it was emphasized strongly that the traditional exposition of equilibrium theory lacked a certain cogency which tended to impede progress with extending those considerations to more complex nonequilibrium problems. The reasons for this were adduced to be an unfortunate reliance on ergodicity and the notions of kinetic theory, but in the long run little harm was done regarding the treatment of equilibrium problems. On the nonequilibrium level the potential for disaster increases enormously, as becomes evident already in Chapter 1.
This thesis presents pioneering experimental and numerical studies on three aspects of the combustion characteristics of lean premixed syngas/air flames, namely the laminar flame speed, extinction limit and flammability limit. It illustrates a new extinction exponent concept, which enriches the combustion theory. Above all, the book provides the following: a) a series of carefully measured data and theoretical analyses to reveal the intrinsic mechanisms of the fuel composition effect on the propagation and extinction of lean syngas/air flames; b) a mixing model and correlation to predict the laminar flame speed of multi-component syngas fuels, intended for engineering computations; c) a new "extinction exponent" concept to describe the critical effects of chemical kinetics on the extinction of lean premixed syngas/air flames; and d) the effects and mechanism of the dilution of incombustible components on lean premixed syngas/air flames and the preferential importance among the thermal, chemical and diffusion effects.
In the present volume numerous descriptions of Ram accelerators are presented. These descriptions provide good overview on the progress made and the present state of the Ram accelerator technology worldwide. In addition, articles describing light gas gun, ballistic range including a chapter dealing with shock waves in solids are given. Along with the technical description of considered facilities, samples of obtained results are also included. Each chapter is written by an expert in the described topic providing a comprehensive description of the discussed phenomena.
This volume provides a compact presentation of modern statistical physics at an advanced level, from the foundations of statistical mechanics to the main modern applications of statistical physics. Special attention is given to new approaches, such as quantum field theory methods and non-equilibrium problems. This second, revised edition is expanded with biographical notes contextualizing the main results in statistical physics.
This book studies the collision, coalescence and deposition of nanoparticles in stagnation flames. With the help of synthesis experiments, in-situ laser diagnostics and molecular dynamics simulations, it investigates the growth of nanoparticles in flames and their deposition in boundary layers at a macroscopic flow field scale, as well as particle and molecular scale issues such as the interaction force between particles, how the collision rate is enhanced by attractive forces, and how the nano-scale coalescence process is influenced by the high surface curvature - all of which are crucial to understanding nanoparticle transport phenomena at high temperatures. The book also reports on a novel in-situ laser diagnostics phenomenon called phase-selective laser-induced breakdown spectroscopy and related applications for tracing gas-to-particle transitions and measuring local particle volume fractions in nano-aerosols.
Observation, Prediction and Simulation of Phase Transitions in Complex Fluids presents an overview of the phase transitions that occur in a variety of soft-matter systems: colloidal suspensions of spherical or rod-like particles and their mixtures, directed polymers and polymer blends, colloid--polymer mixtures, and liquid-forming mesogens. This modern and fascinating branch of condensed matter physics is presented from three complementary viewpoints. The first section, written by experimentalists, emphasises the observation of basic phenomena (by light scattering, for example). The second section, written by theoreticians, focuses on the necessary theoretical tools (density functional theory, path integrals, free energy expansions). The third section is devoted to the results of modern simulation techniques (Gibbs ensemble, free energy calculations, configurational bias Monte Carlo). The interplay between the disciplines is clearly illustrated. For all those interested in modern research in equilibrium statistical mechanics.
This book is based on the premise that the entropy concept, a fundamental element of probability theory as logic, governs all of thermal physics, both equilibrium and nonequilibrium. The variational algorithm of J. Willard Gibbs, dating from the 19th Century and extended considerably over the following 100 years, is shown to be the governing feature over the entire range of thermal phenomena, such that only the nature of the macroscopic constraints changes. Beginning with a short history of the development of the entropy concept by Rudolph Clausius and his predecessors, along with the formalization of classical thermodynamics by Gibbs, the first part of the book describes the quest to uncover the meaning of thermodynamic entropy, which leads to its relationship with probability and information as first envisioned by Ludwig Boltzmann. Recognition of entropy first of all as a fundamental element of probability theory in mid-twentieth Century led to deep insights into both statistical mechanics and thermodynamics, the details of which are presented here in several chapters. The later chapters extend these ideas to nonequilibrium statistical mechanics in an unambiguous manner, thereby exhibiting the overall unifying role of the entropy.
This book presents the theory of periodic conjugate heat transfer in a detailed way. The effects of thermophysical properties and geometry of a solid body on the commonly used and experimentally determined heat transfer coefficient are analytically presented from a general point of view. The main objective of the book is a simplified description of the interaction between a solid body and a fluid as a boundary value problem of the heat conduction equation for the solid body. At the body surface, the true heat transfer coefficient is composed of two parts: the true mean value resulting from the solution of the steady state heat transfer problem and a periodically variable part, the periodic time and length to describe the oscillatory hydrodynamic effects. The second edition is extended by (i) the analysis of stability boundaries in helium flow at supercritical conditions in a heated channel with respect to the interaction between a solid body and a fluid; (ii) a periodic model and a method of heat transfer simulation in a fluid at supercritical pressure and (iii) a periodic quantum-mechanical model for homogeneous vapor nucleation in a fluid with respect to nanoscale effects.
This book consists of peer-reviewed articles and reviews presented as lectures at the Sixth International Symposium on Thermal Engineering and Sciences for Cold Regions in Darmstadt, Germany. It addresses all relevant aspects of thermal physics and engineering in cold regions, such as the Arctic regions. These environments present many unique freezing and melting phenomena and the relevant heat and mass transfer processes are of basic importance with respect to both the technological applications and the natural context in which they occur. Intended for physicists, engineers, geoscientists, climatologists and cryologists alike, these proceedings cover topics such as: ice formation and decay, heat conduction with phase change, convection with freezing and melting, thermal properties at low temperature, frost heave and permafrost, climate impact in cold regions, thermal design of structures, bio-engineering in cold regions, and many more.
Thermodiffusion describes the coupling between a temperature gradient and a resulting mass flux. Traditionally, the focus has been on simple fluids, and it is now extending to more complex systems such as electrolytes, polymers, colloidal dispersions and magnetic fluids. This book widens the scope even further by including applications in ionic solids. Written as a set of tutorial reviews, it will be useful to experts, nonspecialist researchers and postgraduate students alike.
Materials sciences relate the macroscopic properties of materials to their microscopic structure and postulate the need for holistic multiscale research. The investigation of shape memory alloys is a prime example in this regard. This particular class of materials exhibits strong coupling of temperature, strain and stress, determined by solid state phase transformations of their metallic lattices. The present book presents a collection of simulation studies of this behaviour. Employing conceptually simple but comprehensive models, the fundamental material properties of shape memory alloys are qualitatively explained from first principles. Using contemporary methods of molecular dynamics simulation experiments, it is shown how microscale dynamics may produce characteristic macroscopic material properties. The work is rooted in the materials sciences of shape memory alloys and covers thermodynamical, micro-mechanical and crystallographical aspects. It addresses scientists in these research fields and their students.
This superb text describes a novel and powerful method for allowing
design engineers to firstly model a linear problem in heat
conduction, then build a solution in an explicit form and finally
obtain a numerical solution. It constitutes a modelling and
calculation tool based on a very efficient and systemic
methodological approach.
"Great progress has been made in electrical science, chiefly in Germany, by cultivators of the theory of action at a distance. The valuable electrical measurements of W. Weber are interpreted by him according to this theory, and the electromagnetic speculation which was originated by Gauss, and carried on by Weber, Riemann, F. and C. Neumann, Lorenz, etc. , is founded on the theory of action at a distance, but depending either directly on the relative velocity of the particles, or on the gradual propagation of something, whether potential or force, from the one particle to the other. The great success which these eminent men have attained in the application of mathematics to electrical phenomena, gives, as is natural, additional weight to their theoretical speculations, so that those who, as students of electricity, turn to them as the greatest authorities in mathematical electricity, would probably imbibe, along with their mathematical methods, their physical hypothesis. These physical hypotheses, however, are entirely alien from the way of looking at things which I adopt, and one object which I have in view is that some of those who wish to study electricity may, by reading this treatise, come to see that there is another way of treating the subject, which is no less fitted to explain the phenomena, and which, though in some parts it may appear less definite, corresponds, as I think, more faithfuHy with our actual knowledge, both in what it affirms and in what it leaves undecided.
This book presents recent findings on the global existence, the uniqueness and the large-time behavior of global solutions of thermo(vis)coelastic systems and related models arising in physics, mechanics and materials science such as thermoviscoelastic systems, thermoelastic systems of types II and III, as well as Timoshenko-type systems with past history. Part of the book is based on the research conducted by the authors and their collaborators in recent years. The book will benefit interested beginners in the field and experts alike.
Models for the mechanical behavior of porous media introduced more than 50 years ago are still relied upon today, but more recent work shows that, in some cases, they may violate the laws of thermodynamics. In The Thermophysics of Porous Media, the author shows that physical consistency requires a unique description of dynamic processes that involve porous media, and that new dynamic variables-porosity, saturation, and megascale concentration-naturally enter into the large-scale description of porous media. The new degrees of freedom revealed in this study predict new dynamic processes that are not associated with compressional motions.
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