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Books > Science & Mathematics > Physics > Thermodynamics & statistical physics > Thermodynamics
Preface. From the preface to the Russian edition. Introduction. I: Properties of exact solutions of nondegenerate and degenerate ordinary differential equations. II: Direct methods for constructing exact solutions of semilinear parabolic equations. III: Singularities of nonsmooth solutions to quasilinear parabolic and hyperbolic equations. IV: Wave asymptotic solutions of degenerate semilinear parabolic and hyperbolic equations. V: Finite asymptotic solutions of degenerate equations. VI: Models for mass transfer processes. VII: The flow around a plate. References. Appendix: Justification of asymptotic solutions; S.A. Vakulenko.
The ancient Greeks believed that all matter was composed of four elements: earth, water, air, and fire. By a remarkable coincidence (or perhaps not), today we know that there are four states of matter: solids (e.g. earth), liquids (e.g. water), gasses (e.g. air) and plasma (e.g. ionized gas produced by fire). The plasma state is beyond the scope of this book and we will only look at the first three states. Although on the microscopic level all matter is made from atoms or molecules, everyday experience tells us that the three states have very different properties. The aim of this book is to examine some of these properties and the underlying physics.
This book presents a clear and readable description of one of the most mysterious concepts of physics: Entropy. It contains a self-learning kit that guides the reader in understanding the concepts of entropy. In the first part, the reader is asked to play the familiar twenty-Question game. Once the reader feels comfortable with playing this game and acquires proficiency in playing the game effectively (intelligently), he or she will be able to capture the elusive and used-to-be mysterious concept of entropy.There will be no more speculative or arbitrary interpretations, nor "older" or "modern" views of entropy. This book will guide readers in choosing their own interpretation of entropy.
This book provides state-of-the-art computational approaches for accelerating materials discovery, synthesis, and processing using thermodynamics and kinetics. The authors deliver an overview of current practical computational tools for materials design in the field. They describe ways to integrate thermodynamics and kinetics and how the two can supplement each other.
This work sheds new light on fundamental aspects of phase separation in polymer-blend thin films. A key feature underlying the theoretical models is the unification of one-dimensional thermodynamic phase equilibria with film evolution phenomena in two- and three dimensions. Initially, an established 'phase portrait' method, useful for visualising and calculating phase equilibria of polymer-blend films, is generalised to systems without convenient simplifying symmetries. Thermodynamic equilibria alone are then used to explain a film roughening mechanism in which laterally coexisting phases can have different depths in order to minimise free energy. The phase portraits are then utilised to demonstrate that simulations of lateral phase separation via a transient wetting layer, which conform very well with experiments, can be satisfactorily explained by 1D phase equilibria and a 'surface bifurcation' mechanism. Lastly, a novel 3D model of coupled phase separation and dewetting is developed, which demonstrates that surface roughening shadows phase separation in thin films.
Rational extended thermodynamics (RET) is the theory that is applicable to nonequilibrium phenomena out of local equilibrium. It is expressed by the hyperbolic system of field equations with local constitutive equations and is strictly related to the kinetic theory with the closure method of the hierarchies of moment equations. The book intends to present, in a systematic way, new results obtained by RET of gases in both classical and relativistic cases, and it is a natural continuation of the book "Rational Extended Thermodynamics beyond the Monatomic Gas" by the same authors published in 2015. However, this book addresses much wider topics than those of the previous book. Its contents are as follows: RET of rarefied monatomic gases and of polyatomic gases; a simplified RET theory with 6 fields being valid far from equilibrium; RET where both molecular rotational and vibrational modes exist; mixture of gases with multi-temperature. The theory is applied to several typical topics (sound waves, shock waves, etc.) and is compared with experimental data. From a mathematical point of view, RET can be regarded as a theory of hyperbolic symmetric systems, of which it is possible to conduct a qualitative analysis. The book represents a valuable resource for applied mathematicians, physicists, and engineers, offering powerful models for many potential applications such as reentering satellites into the atmosphere, semiconductors, and nanoscale phenomena.
This pioneering book presents new models for the thermomechanical behavior of composite materials and structures taking into account internal physico-chemical transformations such as thermodecomposition, sublimation and melting at high temperatures (up to 3000 K). It is of great importance for the design of new thermostable materials and for the investigation of reliability and fire safety of composite structures. It also supports the investigation of interaction of composites with laser irradiation and the design of heat-shield systems. Structural methods are presented for calculating the effective mechanical and thermal properties of matrices, fibres and unidirectional, reinforced by dispersed particles and textile composites, in terms of properties of their constituent phases. Useful calculation methods are developed for characteristics such as the rate of thermomechanical erosion of composites under high-speed flow and the heat deformation of composites with account of chemical shrinkage. The author expansively compares modeling results with experimental data, and readers will find unique experimental results on mechanical and thermal properties of composites under temperatures up to 3000 K. Chapters show how the behavior of composite shells under high temperatures is simulated by the finite-element method and so cylindrical and axisymmetric composite shells and composite plates are investigated under local high-temperature heating. < The book will be of interest to researchers and to engineers designing composite structures, and invaluable to materials scientists developing advanced performance thermostable materials.
Capitalism is under attack. Defenders say that capitalism has raised billions of people from poverty. But a central activity of capitalism today, Wall Street style, is speculation (gambling), using other people's money, and privatizing the profits while socializing the debts. Skeptics argue that capitalism has redistributed the wealth of the planet in favor of a very few, meanwhile leaving the planet in bad shape and leaving billions of people out in the cold. Wealth is now extremely mal-distributed, opportunity is far from equal, and upward social mobility has declined significantly in recent decades. This book reviews the evidence and arguments pro and con in considerable detail. The evidence is mixed. The main virtue of capitalism is its emphasis on competition as a driver of innovation and, thus, of economic growth. It is true that economic growth has accelerated in recent centuries, and it is true that billions of people have been lifted from poverty. But it is not necessarily true that intense "winner take all" competition in the marketplace is the explanation for growth. Neoclassical economic theory posits that self-interest is the primary motive for all economic decisions, leaving little room for cooperation and even less for altruism. The theory applies to an unrealistic "model" of human behavior, known as Homo economicus or "economic man", whose characteristic activity is buying or selling. The reason for using the adjective word "social" - as in socialism" or "social service" or "social democracy" -- is, essentially, to deny those postulates of standard economic theory. Real humans are not rational utility maximizers (whatever that is) and very often do things that are not in their own personal best interests. This can happen because other interests, such as family loyalty, professional, religious, or patriotic duty, may take precedence. Real people rarely behave like Homo economicus, who has rivals but no friends. He (or she) does not trust anyone, hence cannot cooperate with others, and can never create, or live in, a viable social system (or marriage). Yet social systems, ranging from families and tribes to firms, cities, and nations do (and must) exist or civilization cannot exist. A viable social system must not allow "winner takes all". It must reallocate some of the societal wealth being created by competitive activities to support the young, the old and the weak, because all of those people have equal rights, if not the same luck or the same skills. Both competition and cooperation have important roles to play. A hybrid capitalism involving both is the only viable solution. The book ends with a specific suggestion, namely Universal Basic Income, or UBI.
This textbook aims to briefly outline the main directions in which the geometrization of thermodynamics has been developed in the last decades. The textbook is accessible to people trained in thermal sciences but not necessarily with solid formation in mathematics. For this, in the first chapters a summary of the main mathematical concepts is made. In some sense, this makes the textbook self-consistent. The rest of the textbook consists of a collection of results previously obtained in this young branch of thermodynamics. The manner of presentation used throughout the textbook is adapted for ease of access of readers with education in natural and technical sciences.
There is a great deal of research into wave propagation in random media, in such fields as applied mathematics, acoustics, optics, materials science, atomic physics and geophysics. This book provides theoretical and practical introductions at research level to topics such as localization of waves, band gap materials, random matrices, dielectric media, laser cooled atoms, wave scattering from rough surfaces, randomly layered media, seismic waves and imaging the earth.
This book is intended to serve as a textbook for advanced undergraduate and graduate students as well as professionals engaged in application of thermo-fluid science to the study of combustion. The relevant thermo-chemistry and thermo-physical data required for this study are provided in the 6 appendices along with appropriate curve-fit coefficients. To facilitate gradual learning, two chapters are devoted to thermodynamics of pure and gaseous mixture substances, followed by one chapter each on chemical equilibrium and chemical kinetics. This material when coupled with a dedicated chapter on understanding of equations governing transport of momentum, heat and mass in the presence of chemical reactions provides adequate grounding to undertake analysis of practical combustion equipment, of premixed and diffusion flames as well as of solid particle and liquid droplet combustion. The learnings from the aforementioned chapters are taken to a uniquely strong chapter on application case studies, some of which have special relevance for developing countries.
In its fifth extended edition the successful monograph package "Multiphase Flow Dynamics" contains theory, methods and practical experience for describing complex transient multi-phase processes in arbitrary geometrical configurations, providing a systematic presentation of the theory and practice of numerical multi-phase fluid dynamics. In the present first volume the local volume and time averaging is used to derive a complete set of conservation equations for three fluids each of them having multi components as constituents. Large parts of the book are devoted on the design of successful numerical methods for solving the obtained system of partial differential equations. Finally the analysis is repeated for boundary fitted curvilinear coordinate systems designing methods applicable for interconnected multi-blocks. This fifth edition includes various updates, extensions, improvements and corrections, as well as a completely new chapter containing the basic physics describing the multi-phase flow in turbines, compressors, pumps and other rotating hydraulic machines.
This book provides a general formalism for the calculation of the spectral correlation function for the fluctuating electromagnetic field. The procedure is applied to the radiative heat transfer and the van der Waals friction using both the semi-classical theory of the fluctuating electromagnetic field and quantum field theory. Applications of the radiative heat transfer and non-contact friction to scanning probe spectroscopy are presented. The theory gives a tentative explanation for the experimental non-contact friction data. The book explains that radiative heat transfer and the van der Waals friction are largely enhanced at short separations between the bodies due to the evanescent electromagnetic waves. Particular strong enhancement occurs if the surfaces of the bodies can support localized surface modes like surface plasmons, surface polaritons or adsorbate vibrational modes. An electromagnetic field outside a moving body can also be created by static charges which are always present on the surface of the body due to inhomogeneities, or due to a bias voltage. This electromagnetic field produces electrostatic friction which can be significantly enhanced if on the surface of the body there is a 2D electron or hole system or an incommensurate adsorbed layer of ions exhibiting acoustic vibrations.
This book explores some of the connections between dissipative and quantum effects from a theoretical point of view. It focuses on three main topics: the relation between synchronization and quantum correlations, the thermodynamical properties of fluctuations, and the performance of quantum thermal machines. Dissipation effects have a profound impact on the behavior and properties of quantum systems, and the unavoidable interaction with the surrounding environment, with which systems continuously exchange information, energy, angular momentum and matter, is ultimately responsible for decoherence phenomena and the emergence of classical behavior. However, there is a wide intermediate regime in which the interplay between dissipative and quantum effects gives rise to a plethora of rich and striking phenomena that has just started to be understood. In addition, the recent breakthrough techniques in controlling and manipulating quantum systems in the laboratory have made this phenomenology accessible in experiments and potentially applicable.
This book discusses the thermal-elastic mechanics problems of concrete rectangular thin plate. Using theoretical derivation combined with numerical examples, it explains in detail the analytical solution of the deflection, bending moment, thermal vibration and thermal buckling of concrete rectangular thin plate. To facilitate application, the book also includes deflection and bending moment calculation tables of concrete rectangular thin plate with four edges supported and with free boundary conditions.
This book serves as a self-contained reference source for engineers, materials scientists, and physicists with an interest in relaxation phenomena. It is made accessible to students and those new to the field by the inclusion of both elementary and advanced math techniques, as well as chapter opening summaries that cover relevant background information and enhance the book's pedagogical value. These summaries cover a wide gamut from elementary to advanced topics. The book is divided into three parts. The opening part, on mathematics, presents the core techniques and approaches. Parts II and III then apply the mathematics to electrical relaxation and structural relaxation, respectively. Part II discusses relaxation of polarization at both constant electric field (dielectric relaxation) and constant displacement (conductivity relaxation), topics that are not often discussed together. Part III primarily discusses enthalpy relaxation of amorphous materials within and below the glass transition temperature range. It takes a practical approach inspired by applied mathematics in which detailed rigorous proofs are eschewed in favor of describing practical tools that are useful to scientists and engineers. Derivations are however given when these provide physical insight and/or connections to other material. A self-contained reference on relaxation phenomena Details both the mathematical basis and applications For engineers, materials scientists, and physicists
Describing non-equilibrium "cold" plasmas through a chemical physics approach, this book uses the state-to-state plasma kinetics, which considers each internal state as a new species with its own cross sections. Extended atomic and molecular master equations are coupled with Boltzmann and Monte Carlo methods to solve the electron energy distribution function. Selected examples in different applied fields, such as microelectronics, fusion, and aerospace, are presented and discussed including the self-consistent kinetics in RF parallel plate reactors, the optimization of negative ion sources and the expansion of high enthalpy flows through nozzles of different geometries. The book will cover the main aspects of the state-to-state kinetic approach for the description of nonequilibrium cold plasmas, illustrating the more recent achievements in the development of kinetic models including the self-consistent coupling of master equations and Boltzmann equation for electron dynamics. To give a complete portrayal, the book will assess fundamental concepts and theoretical formulations, based on a unified methodological approach, and explore the insight in related scientific problems still opened for the research community.
Thermal processes are ubiquitous and an understanding of thermal phenomena is essential for a complete description of the physics of nanoparticles, both for the purpose of modeling the dynamics of the particles and for the correct interpretation of experimental data. The second edition of this book follows the logic of first edition, with an emphasis on presentation of literature results and to guide the reader through derivations. Several topics have been added to the repertoire, notably magnetism, a fuller exposition of aggregation and the related area of nucleation theory. Also a new chapter has been added on the transient hot electron phenomenon. The book remains focused on the fundamental properties of nanosystems in the gas phase. Each chapter is enriched with additional new exercises and three Appendices provide additional useful material.
This monograph addresses the foundations of mechanothermodynamics and analyzes two of its key principles-damage of everything that exists has no conceivable limits, and effective energy (entropy) flows caused by loads of a different nature do not have a cumulative property; they interact dialectically. The authors examine a generalized model of energy and entropy states of a mechanothermodynamical medium, which generally is a continuum (liquid, gaseous) containing distributed solid deformable, and, therefore, damageable bodies, as a problem of information states of movable and damageable systems and express a solution in the first approximation. The book goes on to analyze some directions of further research in its conclusion. It is ideal for scientists, engineers, post graduate and master students of mechanics, mathematics and physics.
In recent years, scientists and researchers have been continually searching for efficient and effective ways to harness solar energy for heat and power production. The development of solar technologies and thermal systems are a prevalent area of study, as they represent a vital step in fully optimizing the potential of solar energy. Unfortunately, research is still lacking on the development and application of these solar thermal systems. Modeling and Optimization of Solar Thermal Systems: Emerging Research and Opportunities provides emerging research exploring the theoretical and practical aspects of optimizing the performance of solar thermal technologies using multicriteria decision-making techniques. Featuring coverage on a broad range of topics such as parabolic trough collectors, hybrid solar energy, and thermal technology, this book is ideally designed for practitioners, engineers, academicians, researchers, students, industry professionals, and educators seeking current research on modern modeling methods of solar thermal systems.
Microcontinuum Field Theories constitutes an extension of classical field theories - of elastic solids, viscous fluids, electromagnetism, and the like - to microscopic length and time scales. Material bodies are viewed as collections of a large number of deformable particles (sub-continua), suitable for modeling blood, porous media, polymers, liquid crystals, slurries, and composite materials. This volume extends and applies the ideas developed in the first volume, Microcontinuum Field Theories: Foundations and Solids, to liquid crystals, biological fluids, and other microstretch and micomorphic fluids. The theory makes it possible to discuss properties of such materials that are beyond the scope of classical field theories and may provide a basis for the resolution of some outstanding problems, such as turbulence.
Various experimental techniques have been advanced in recent years to measure non-equilibrium energy transformations on themicroscopic scale of single molecules. In general, the systems studied inthe correspondingexperiments are exposed to strong thermal fluctuations and thus the relevant energetic variables such as work and heat become stochastic. This thesis addresses challenging theoretical problems in this active field of current research: 1) Exact analytical solutions of work and heat distributions for isothermal non-equilibrium processes in suitable models are obtained; 2) Corresponding solutions for cyclic processes involving two different heat reservoirs are found; 3) Optimization of periodic driving protocols for such cyclic processes with respect to maximal output power, efficiency and minimal power fluctuations is studied. The exact solutions for work and heat distributionsprovide areference for theoretical investigations of more complicated models, giving insight into the structure of the tail of work distributions andserving asvaluable test cases for simulations of the underlying stochastic processes." |
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