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Books > Science & Mathematics > Physics > Thermodynamics & statistical physics > Thermodynamics
The contents of this book correspond to Sessions VII and VIII of the International Workshop on Instabilities and Nonequilibrium Structures which took place in Vifia del Mar, Chile, in December 1997 and December 1999, respectively. We were not able to publish this book before and we apologize for this fact to the authors and participants of the meeting. We have made an effort to actualize the courses and articles which have been reviewed by the authors. Both Workshops were organized by Facultad de Ciencias Fisicas y Matematicas, Universidad de Chile, Instituto de Fisica of Universidad Cat61ica de Valparaiso and Centro de Fisica No Lineal y Sistemas Complejos de Santiago. We are glad to acknowledge here the support of the Facultad de Ingenieria of Universidad de los Andes of Santiago which also be from now on one of the organizing Institutions of future Workshops. Enrique Tirapegui PREFACE This book is divided in two parts. In Part I we have collected the courses given in Sessions VII and VIII of the Workshop and in Part II we include a selection of the invited Conferences and Seminars presented at both meetings.
This sixth Volume of the International Workshop on Instabilities and Nonequilibrium Structures is dedicated to the memory of my friend Walter Zeller, Professor of the Universidad C'at6lica df' Valparaiso and Vice-Director of the Workshop. Walter Zeller was much more than an organizer of this meeting: his enthusiasm, dedication and critical views were many times the essential ingredients to continue with a task which in occasions faced difficulties and incomprehensiolls. It is in great part due to him that the workshop has adquired to-day tradition. maturity and international recognition. This Volume should have been coedited by Walter and it is with df'ep emotion that I learned that his disciples Javier Martinez and Rolando Tiemann wanted as a last hommage to their Professor and friend to coedit tfus book. No me seria posible terminal' estas lineas sin pensar en la senora Adriana Gamonal de Zelln. qUf' ella encuentre en este libro la admiraci6n y reconocimiento hacia su marido de quiPIlf's [l\Prall sus discipulos, colegas y amigos.
Contents - 1. ORIGINS OF DTA: AN INTRODUCTION - 2. EQUIPMENT - 3. FACTORS IN QUALITATIVE DTA - 4. SELECTED APPLICATIONS OF QUALITATIVE DATA - 5. THEORETICAL BACKGROUND IN QUANTITATIVE DTA- 6. QUANTITATIVE DTA - 7. USE AND CORRELATION OF DTA RESULTS - 8. COMMERCIAL EQUIPMENT - United States - Germany - Great Britain - Hungary - Japan - APPENDIX - 1. PUBLICATIONS ON DTA - 2. AUTHOR INDEX FOR PUBLICATIONS - 3. ALPHABETICAL LIST OF MATERIALS STUDIED BY DTA - INDEX - Sample view at website
The problem of deriving irreversible thermodynamics from the re versible microscopic dynamics has been on the agenda of theoreti cal physics for a century and has produced more papers than can be digested by any single scientist. Why add to this too long list with yet another work? The goal is definitely not to give a gen eral review of previous work in this field. My ambition is rather to present an approach differing in some key aspects from the stan dard treatments, and to develop it as far as possible using rather simple mathematical tools (mainly inequalities of various kinds). However, in the course of this work I have used a large number of results and ideas from the existing literature, and the reference list contains contributions from many different lines of research. As a consequence the reader may find the arguments a bit difficult to follow without some previous exposure to this set of problems."
In a universe filled by chaos and disorder, one physicist makes the radical argument that the growth of order drives the passage of time -- and shapes the destiny of the universe. Time is among the universe's greatest mysteries. Why, when most laws of physics allow for it to flow forward and backward, does it only go forward? Physicists have long appealed to the second law of thermodynamics, held to predict the increase of disorder in the universe, to explain this. In The Janus Point, physicist Julian Barbour argues that the second law has been misapplied and that the growth of order determines how we experience time. In his view, the big bang becomes the "Janus point," a moment of minimal order from which time could flow, and order increase, in two directions. The Janus Point has remarkable implications: while most physicists predict that the universe will become mired in disorder, Barbour sees the possibility that order -- the stuff of life -- can grow without bound. A major new work of physics, The Janus Point will transform our understanding of the nature of existence.
Offering all aspects of humidity measurement and instrumentation, this work includes rudiments and theory, common applications, advantages and limitations of frequently-used sensors and techniques, and guidelines for installation, maintenance and calibration. The disk is intended for easy conversions of humidity parameters and units.
Material particles, electrons, atoms, molecules, interact with one another by means of electromagnetic forces. That is, these forces are the cause of their being combined into condensed (liquid or solid) states. In these condensed states, the motion of the particles relative to one another proceeds in orderly fashion; their individual properties as well as the electric and magnetic dipole moments and the radiation and absorption spectra, ordinarily vary little by comparison with their properties in the free state. Exceptiotls are the special so-called collective states of condensed media that are formed under phase transitions of the second kind. The collective states of matter are characterized to a high degree by the micro-ordering that arises as a result of the interaction between the particles and which is broken down by chaotic thermal motion under heating. Examples of such pheonomena are the superfluidity of liquid helium, and the superconductivity and ferromagnetism of metals, which exist only at temperatures below the critical temperature. At low temperature states the particles do not exhibit their individual characteristics and conduct themselves as a single whole in many respects. They flow along capillaries in ordered fashion and create an undamped current in a conductor or a macroscopic magnetic moment. In this regard the material acquires special properties that are not usually inherent to it.
This two-volume set presents the proceedings from the 8th International Symposium on Transport Phenomena in Combustion. There are more than 150 chapters that provide an extensive review of topics such as complete numerical simulation of combustion and heat transfer in furnaces and boilers, the interaction of combustion and heat transfer in porous media for low emission, high effieciency applications, industrial combustion technology, experimental and diagnostic methods and active combustion control, and fire research, internal combustion engine, Nox and soot emission.
The book provides an integrated energy/exergy analysis method to identify the energy utilization issues and systematically propose the cost-effective energy-saving and CO2 mitigation/capture solution. There is a strong market needs on energy-saving and greenhouse gas (GHG) reduction. CO2 mitigation/capture will achieve economic benefit of fuel, power, and carbon tax saving as well as environmental GHG reduction. The book is a professional book for energy-saving and GHG gas mitigation technology in oil & gas, oil refining, and chemical industry. It is an integrated technical book that combines energy utilization theory and practical method, including: thermodynamic analysis for unit operation and process units; energy and exergy calculation for various process streams and utilities; three-link energy/exergy analysis model; energy/exergy balance of equipment, process units, and entire plant; approach and technology of energy saving; optimization of pipeline and equipment; pinch energy-saving technology and its application; CO2 capture and utilization with 8 case studies incorporated for all different scenarios; key energy-saving technologies such gas turbine, FCCU regeneration CO combustion and energy recovery, flue gas turbine system optimization, low-grade heat recovery and utilization. The book is intended for engineers and professional personnel who are working in process engineering, EPC companies, chemical and petrochemical plants, refineries, oil & gas production facilities, power generation plant. It can also be a professional reference or textbook for undergraduate or graduate-level university students and teaching personnel of chemical, energy, and process engineering faculties of universities.
Non-Destructive Testing and Condition Monitoring Techniques in Wind Energy looks at the complex and critical components of energy assets and the importance of inspection and maintenance to ensure their high availability and uninterrupted operation. Presenting the main concepts, state-of-the-art advances and case studies, this book approaches the topic by considering it as an integral part of the overall operation of any wind energy project. Linking the essential NDT subject with its sub disciplines, the book uses computational techniques, dynamic analysis, probabilistic methods, and mathematical optimization techniques to support analysis of prognostic problems with defined constraints and requirements. This book is the first of its kind and will provide useful insights to industrial engineers and scientists, academics and students in the possibilities that NDT and condition monitoring technologies can offer.
Thermodynamics is not the oldest of sciences. Mechanics can make that claim. Thermodynamicsisaproductofsomeofthegreatestscienti?cmindsofthe19thand 20th centuries. But it is suf?ciently established that most authors of new textbooks in thermodynamics ?nd it necessary to justify their writing of yet another textbook. I ?nd this an unnecessary exercise because of the centrality of thermodynamics as a science in physics, chemistry, biology, and medicine. I do acknowledge, however, that instruction in thermodynamics often leaves the student in a confused state. My attempt in this book is to present thermodynamics in as simple and as uni?ed a form as possible. As teachers we identify the failures of our own teachers and attempt to correct them. Although I personally acknowledge with a deep gratitude the appreciation for thermodynamics that I found as an undergraduate, I also realize that my teachers did not convey to me the sweeping grandeur of thermodynamics. Speci?cally the s- plicity and the power that James Clerk Maxwell found in the methods of Gibbs were not part of my undergraduate experience. Unfortunately some modern authors also seem to miss this central theme, choosing instead to introduce the thermodynamic potentials as only useful functions at various points in the development.
During the last decade, various powerful experimental tools have been developed, such as small angle X-ray and neutron scattering, X-ray and neutron reflection from interfaces, neutron spin-echo spectroscopy and quasi-elastic multiple light scattering and large scale computer simulations. Due to the rapid progress brought about by these techniques, one witnesses a resurgence of interest in the physicochemical properties of colloids, surfactants and macromolecules in solution. Although these disciplines have a long history, they are at present rapidly transforming into a new, interdisciplinary research area generally known as complex liquids or soft condensed matter physics: names that reflect the considerable involvement of the chemical and condensed matter physicists. This book is based on lectures given at a NATO ASI held in the summer of 1991 and discusses these new developments, both in theory and experiment. It constitutes the most up-to-date and comprehensive summary of the entire field.
This textbook presents the fundamental concepts and theories in thermal physics and elementary statistical mechanics in a very simple, systematic and comprehensive way. This book is written in a way that it presents the topics in a holistic manner with end-of-chapter exercises and examples where concepts are supported by numerous solved examples and multiple-choice questions to aid self-learning. The textbook also contains illustrated diagrams for better understanding of the concepts. The book will benefit students who are taking introductory courses in thermal physics, thermodynamics and statistical mechanics.
This book offers a unique treatment of building insulating products and the integration of these products with building components. This book was written for all those involved in building design, specification, construction, and commissioning, providing them with an understanding of and appreciation for the wide variety of thermal insulation products and technologies available for use in all types of buildings. The book proceeds from basic definitions and discussion of heat-transfer topics and thermal insulation concepts, to the design and use of these products. The impact of thermal insulation on dynamic building performance, including factors other than heating and cooling, is also discussed. The book does not require an advanced mathematical background. The authors provide sufficient information to provide a qualitative understanding, with more mathematical sections included for those interested in modeling and analysis. The basic physics associated with heat transfer in buildings are presented, along with the steady-state and transient analysis techniques needed for the effective implementation of thermal insulation and assemblies. Modern building design involves the integration of comfort, safety, economics, durability and cost considerations, all of which impact the selection and use of thermal insulation materials in buildings. In addition to theoretical explanations of the underlying science, the book details the properties and application of new thermal insulation materials, including vacuum panels, gas-filled panels, aerogels, phase-change materials, and radiation control technologies. Given its scope, the book will be of interest to researchers and building engineers wishing to understand the latest technologies and materials available, so as to achieve reduced energy consumption in commercial and residential buildings.
The thesis presents a systematic study of the Mpemba effect in a colloidal system with a micron-sized particle diffusing in a water bath. While the Mpemba effect, where a system's thermal relaxation time is a non-monotonic function of the initial temperature, has been observed in water since Aristotle's era, the underlying mechanism of the effect is still unknown. Recent studies indicate that the effect is not limited to water and has been studied both experimentally and numerically in a wide variety of systems. By carefully designing a double-well potential using feedback-based optical tweezers, the author demonstrates that an initially hot system can sometimes cool faster than an initially warm system. The author also presents the first observation in any system of another counterintuitive effect-the inverse Mpemba effect-where the colder of the two samples reaches the thermal equilibrium at a hot temperature first. The results for both the observations agree with theoretical predictions based on the Fokker-Planck equation. The experiments reveal that, for carefully chosen conditions, a strong version of both of the effects are observed where a system can relax to the bath temperature exponentially faster than under typical conditions.
This book gives a systematic investigation of convection in systems comprised of liquid layers with deformatable interfaces. This new edition includes completely updated and new material on flows in ultra thin films and brings up to date progress made in the technology on micro and nano scales. Also, this revised edition will reflect progress in thedynamics of complex fluids."
IoT-Enabled Multi-Energy Systems: From Isolated Energy Grids to Modern Interconnected Networks proposes practical solutions for the management and control of energy interactions throughout the interconnected energy infrastructures of the future multi-energy grid. The book discusses a panorama of modeling, planning and optimization considerations for IoT technologies, their applications across grid modernization, and the coordinated operation of multi-vector energy grids. The work is suitable for energy, power, mechanical, chemical, process and environmental engineers, and highly relevant for researchers and postgraduate students who work on energy systems. Sections address core theoretical underpinnings, significant challenges and opportunities, how to support IoT-based developed expert systems, and how AI can empower IoT technologies to sustainably develop fully renewable modern multi-carrier energy networks. Contributors address artificial intelligence technology and its applications in developing IoT-based technologies, cloud-based intelligent energy management schemes, data science and multi-energy big data analysis, machine learning and deep learning techniques in multi-energy systems, and much more.
This textbook on fire dynamics provides a comprehensive description of fuels involved in fires, definitions related to fire, thermodynamics for fire calculations, basics of transport processes and fundamental aspects of combustion related to fire, physical descriptions of premixed and non-premixed flames, detailed analysis of the characteristics of fires from solid and liquid fuels, including ignition, spread and burning rates and physical aspects of fire plumes, compartment fires and dust fires. The contents also highlight fundamental aspects related to the evaporation of liquid fuels and pyrolysis of solid fuels which are explained with simplified mathematical expressions. The book includes pedagogical features such as worked examples to illustrate mathematical calculations involved in fire analysis and end-of-chapter review questions. This book proves useful for students, researchers and industry professionals alike.
The Nature of Biological Systems as Revealed by Thermal Methods is a guide for experiments using thermal methods. The Editor has used his many years of experience to create a unique resource that will enable others with a less mathematical background, to realize the beauty and power of this tool and to gain a better understanding of biological problems. Biological calorimetry (and of course thermal analysis) is of increasing interest and is not covered thoroughly in other resources. The methods presented are macroscopic, for the rather inhomogeneous material (micromethods are often not possible or not pertinent). This book will help beginners in the field of thermal analysis or calorimetry understand the principles of thermodynamics being applied to biological systems. Biological systems are highly organized and very complex. The water and the different types of weak interactions among the macromolecules make the interpretation of thermal events very difficult. This book includes examples how to handle such problems. The Nature of Biological Systems as Revealed by Thermal Methods
is unique in that it: The book is an invaluable resource for anyone interested in thermodynamics, including practising professionals applying thermal methods to biological problems; researchers and graduate students beginning work using thermal methods; and specialists of thermal analysis starting work on biological problems. In addition, this book will be a useful resource for libraries and institutes as the only book covering quantitative thermal analysis of biological systems.
This book presents problems and solutions of the mathematical theories of thermoelasticity and magnetothermoelasticity. The classical, coupled and generalized theories are solved using the eigenvalue methodology. Different methods of numerical inversion of the Laplace transform are presented and their direct applications are illustrated. The book is very useful to those interested in continuum mechanics.
This book presents thermodynamic data on oxides in the system MgO-FeO-Fe2O3-Al2O3-SiO2. These data are produced by a process of assessment that involves the integration of thermochemical (calorimetric) and phase equilibrium data. The latter have been selected from a number of publications in high-pressure research conducted at pressures and temperatures in the range of 1 bar to several Giga Pascals and 300 to 2500 K respectively. A unique feature of the database is that the assessment involves not only the thermodynamic data on pure end member species, but also the data on multicomponent solutions. Since the solution description follows the format used in the popular thermodynamic computational packages such as FACTSAGE, ChemSage and Thermocalc, the database is easy to incorporate in the currently used databases in these packages. The database is highly useful to those working in the field of metallurgy (e.g. slags) and ceramics. It is essential for all those who do thermodynamic modeling of the terrestrial planetary interiors.
This book explains the modelling and simulation of thermal power plants, and introduces readers to the equations needed to model a wide range of industrial energy processes. Also featuring a wealth of illustrative, real-world examples, it covers all types of power plants, including nuclear, fossil-fuel, solar and biomass. The book is based on the authors' expertise and experience in the theory of power plant modelling and simulation, developed over many years of service with EDF. In more than forty examples, they demonstrate the component elements involved in a broad range of energy production systems, with detailed test cases for each chemical, thermodynamic and thermo-hydraulic model. Each of the test cases includes the following information: * component description and parameterization data; * modelling hypotheses and simulation results; * fundamental equations and correlations, with their validity domains; * model validation, and in some cases, experimental validation; and * single-phase flow and two-phase flow modelling equations, which cover all water and steam phases. A practical volume that is intended for a broad readership, from students and researchers, to professional engineers, this book offers the ideal handbook for the modelling and simulation of thermal power plants. It is also a valuable aid in understanding the physical and chemical phenomena that govern the operation of power plants and energy processes. |
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