This volume is a compilation of carefully selected questions at the PhD qualifying exam level, including many actual questions from Columbia University, University of Chicago, MIT, State University of New York at Buffalo, Princeton University, University of Wisconsin and the University of California at Berkeley over a twenty-year period. Topics covered in this book include the laws of thermodynamics, phase changes, Maxwell-Boltzmann statistics and kinetic theory of gases.This latest edition has been updated with more problems and solutions and the original problems have also been modernized, excluding outdated questions and emphasizing those that rely on calculations. The problems range from fundamental to advanced in a wide range of topics on thermodynamics and statistical physics, easily enhancing the student's knowledge through workable exercises. Simple-to-solve problems play a useful role as a first check of the student's level of knowledge whereas difficult problems will challenge the student's capacity on finding the solutions.

This book gives the definitive mathematical answer to what thermodynamics really is: a variational calculus applied to probability distributions. Extending Gibbs's notion of ensemble, the Author imagines the ensemble of all possible probability distributions and assigns probabilities to them by selection rules that are fairly general. The calculus of the most probable distribution in the ensemble produces the entire network of mathematical relationships we recognize as thermodynamics. The first part of the book develops the theory for discrete and continuous distributions while the second part applies this thermodynamic calculus to problems in population balance theory and shows how the emergence of a giant component in aggregation, and the shattering transition in fragmentation may be treated as formal phase transitions. While the book is intended as a research monograph, the material is self-contained and the style sufficiently tutorial to be accessible for self-paced study by an advanced graduate student in such fields as physics, chemistry, and engineering.

This textbook provides an accessible introduction to various energy transformation technologies and their influences on the environment. Here the energy transformation is understood as any physical process induced by humans, in which energy is intentionally transformed from one form to another. This book provides an accessible introduction to the subject: covering the theory, principles of design, operation, and efficiency of the systems in addition to discerning concepts such as energy, entropy, exergy, efficiency, and sustainability. It is not assumed that readers have any previous exposure to such concepts as laws of thermodynamics, entropy, exergy, fluid mechanics or heat transfer, and is therefore an ideal textbook for advanced undergraduate students. Key features: Represents a complete source of information on sustainable energy transformation systems and their externalities. Includes all existing and major emerging technologies in the field. Chapters include numerous examples and problems for further learning opportunities.

This textbook provides an accessible introduction to various energy transformation technologies and their influences on the environment. Here the energy transformation is understood as any physical process induced by humans, in which energy is intentionally transformed from one form to another. This book provides an accessible introduction to the subject: covering the theory, principles of design, operation, and efficiency of the systems in addition to discerning concepts such as energy, entropy, exergy, efficiency, and sustainability. It is not assumed that readers have any previous exposure to such concepts as laws of thermodynamics, entropy, exergy, fluid mechanics or heat transfer, and is therefore an ideal textbook for advanced undergraduate students. Key features: Represents a complete source of information on sustainable energy transformation systems and their externalities. Includes all existing and major emerging technologies in the field. Chapters include numerous examples and problems for further learning opportunities.

Discusses advances in the computation of phase diagrams Offers expanded treatment of eutectic solidification with practical examples and new coverage of ternary phase diagrams, covering the concepts of orthoequilibrium and paraequilibrium Updates discussion of bainite transformation to reflect current opinions Includes new case studies covering grain refiners in aluminium alloys, additive manufacturing, thin film growth, important aerospace Al-Li alloys, and quenched and partitioned steels, and metastable austenitic stainless steels. Each chapter now begins with a list of key concepts, includes simpler illustrative exercises with relevance to real practical applications, and references to scientific publications updated to reflect experimental and computational advances in metallurgy

Presents a clear path to developing quantitative multi-phase and multi-component phase field models for solidification and other phase transformation kinetics based on practical grand potential functional Derives explicitly and discusses the quantitative nature of the model formulations through matched interface asymptotic analysis Explores a framework for quantitative treatment of rapid solidification to control solute trapping and solute drag dynamics

This undergraduate textbook provides a statistical mechanical foundation to the classical laws of thermodynamics via a comprehensive treatment of the basics of classical thermodynamics, equilibrium statistical mechanics, irreversible thermodynamics, and the statistical mechanics of non-equilibrium phenomena.This timely book has a unique focus on the concept of entropy, which is studied starting from the well-known ideal gas law, employing various thermodynamic processes, example systems and interpretations to expose its role in the second law of thermodynamics. This modern treatment of statistical physics includes studies of neutron stars, superconductivity and the recently developed fluctuation theorems. It also presents figures and problems in a clear and concise way, aiding the student's understanding.

The revised second edition of this practical book reviews the fundamentals of cryogenic liquid behaviour in small and large scale storage systems. The text is based on research findings on the convective and evaporative behaviour of cryogenic fluids, aimed at improving the design, construction and operation of low-loss cryogenic liquid storage systems, with a view to minimising cost and improving operational safety. Since the first edition was published in 2006, the breadth of cryogenic applications and the modelling of cryogenic fluid dynamics (CFD) have expanded in several directions. In this second edition, most chapters have been extended to introduce discussions of these new applications and their safety and energy economy. These include advances in the modelling of CFD required in, for example, the design of miniature cryocoolers and condensers and reboilers, large-scale cryogenic liquid mixture properties and their stability, and the understanding that hazards and safety problems in the public domain increase with the scaling up of cryogenic systems. With helpful summaries at the end of each chapter, the book is an essential reference for anyone working on the design and operation of cryogenic liquid storage and transportation systems.

This book focuses on mixed crystals formed by molecular substances. The emphasis lies on the elucidation of the structural and thermodynamic properties of two-component systems. Thanks to the fact that the research efforts have been directed to a number of families of chemically coherent substances, rather than to a collection of isolated systems, the knowledge of mixed crystals has substantially increased. This is reflected by the discovery of several empirical relationships between thermodynamic properties, crystallographic properties, and also between thermodynamic mixing properties and exothermodynamic parameters, such as the structural mismatch between the components of the binary systems. This book is a benchmark for material scientists and a unique starting point for anyone interested in mixed crystals.

First published in 1922, this book represents the first attempt to popularise the more accessible aspects of Albert Einstein's general theory of relativity. Eschewing the mathematical components that put the theory beyond many people's grasp, the author employs metaphorical examples and thought experiments to convey the fundamental ideas and assertions of one of physics' most famous principles - which remains the accepted description of gravitation more than a century after its first publication. This book will of interest to students of physics as an introductory basis to aid further study.

This book will help readers understand thermodynamic properties caused by magnetic fields. Providing a concise review of time independent magnetic fields, it goes on to discuss the thermodynamic properties of magnetizing materials of different shapes, and finally, the equilibrium properties of superconductors of different shapes and also of different sizes. Chapters are accompanied by problems illustrating the applications of the principles to optimize and enhance understanding. This book will be of interest to advanced undergraduates, graduate students, and researchers specializing in thermodynamics, solid state physics, magnetism, and superconductivity. Features: The first book to provide comprehensive coverage of thermodynamics in magnetic fields, only previously available, in part, in journal articles Chapters include problems and worked solutions demonstrating real questions in contemporary superconductivity, such as properties of vortex matter

The term transport phenomena is used to describe processes in which mass, momentum, energy and entropy move about in matter. Advances in Transport Phenomena provide state-of-the-art expositions of major advances by theoretical, numerical and experimental studies from a molecular, microscopic, mesoscopic, macroscopic or megascopic point of view across the spectrum of transport p- nomena, from scientific enquiries to practical applications. The annual review series intends to fill the information gap between regularly published journals and university-level textbooks by providing in-depth review articles over a broader scope than in journals. The authoritative articles, contributed by international- leading scientists and practitioners, establish the state of the art, disseminate the latest research discoveries, serve as a central source of reference for fundamentals and applications of transport phenomena, and provide potential textbooks to senior undergraduate and graduate students. The series covers mass transfer, fluid mechanics, heat transfer and thermo- namics. The 2009 volume contains the four articles on biomedical, environmental and nanoscale transports. The editorial board expresses its appreciation to the c- tributing authors and reviewers who have maintained the standard associated with Advances in Transport Phenomena. We also would like to acknowledge the efforts of the staff at Springer who have made the professional and attractive pr- entation of the volume. Serial Editorial Board Editor-in-Chief Professor L. Q. Wang The University of Hong Kong, Hong Kong; lqwang@hku. hk Editors Professor A. R. Balakrishnan Indian Institute of Technology Madras, India Professor A.

This textbook provides a comprehensive, yet accessible, introduction to statistical mechanics. Crafted and class-tested over many years of teaching, it carefully guides advanced undergraduate and graduate students who are encountering statistical mechanics for the first time through this - sometimes - intimidating subject. The book provides a strong foundation in thermodynamics and the ensemble formalism of statistical mechanics. An introductory chapter on probability theory is included. Applications include degenerate Fermi systems, Bose-Einstein condensation, cavity radiation, phase transitions, and critical phenomena. The book concludes with a treatment of scaling theories and the renormalization group. In addition, it provides clear descriptions of how to understand the foundational mathematics and physics involved and includes exciting case studies of modern applications of the subject in physics and wider interdisciplinary areas. Key Features: Presents the subject in a clear and entertaining style which enables the author to take a sophisticated approach whilst remaining accessible Contains contents that have been carefully reviewed with a substantial panel to ensure that coverage is appropriate for a wide range of courses, worldwide Accompanied by volumes on thermodynamics and non-equilibrium statistical mechanics, which can be used in conjunction with this book, on courses which cover both thermodynamics and statistical mechanics

The simulation of turbulent reacting flows, connected with environmental protection and the design of chemical and mechanical processes, is increasingly important. Statistical Mechanics of Turbulent Flows presents a modern overview of basic ways to calculate such flows. It discusses the fundamental problems related to the use of basic equations and their modifications. Special emphasis is placed on the discussion of very promising statistical methods which provide solutions to these problems by models for the underlying stochastic physics of turbulent reacting flows. Their foundations and important new developments up through current challenges are systematically explained. Students and researchers in atmospheric sciences and oceanography, mechanical and chemical engineering and applied mathematics and physics may use Statistical Mechanics of Turbulent Flows as a guide to solve many problems related, e.g. to the assessment of complex atmospheric chemistry, chemical reactor processes, turbulent combustion, and multi-phase flows.

The book is aimed at undergraduate students in their senior year and first year graduate students. It elucidates the basis of thermodynamics and provides a basis for the understanding of, not only the thermodynamic properties of a microscopic system, but also their fluctuations, correlations and close-to-equilibrium properties.

We know very little about the time-evolution of many-particle dynamical systems, the subject of our book. Even the 3-body problem has no explicit solution (we cannot solve the corresponding system of differential equations, and computer simulation indicates hopelessly chaotic behaviour). For example, what can we say about the typical time evolution of a large system starting from a stage far from equilibrium? What happens in a realistic time scale? The reader's first reaction is probably: What about the famous Second Law (of thermodynamics)?Unfortunately, there are plenty of notorious mathematical problems surrounding the Second Law. (1) How to rigorously define entropy? How to convert the well known intuitions (like 'disorder' and 'energy spreading') into precise mathematical definitions? (2) How to express the Second Law in forms of a rigorous mathematical theorem? (3) The Second Law is a 'soft' qualitative statement about entropy increase, but does not say anything about the necessary time to reach equilibrium.The object of this book is to answer questions (1)-(2)-(3). We rigorously prove a Time-Quantitative Second Law that works on a realistic time scale. As a by product, we clarify the Loschmidt-paradox and the related reversibility/irreversibility paradox.

This book provides the foundations of analytical thermodynamics for graduate level. The content is based on the author's lecture notes developed over 30 years of academic teaching. It aims to present thermodynamics to the readers as easy to understand as possible, being suitable for professors teaching advanced thermodynamics or graduate students learning thermodynamics. The chapters include the basics of analytical thermodynamics, modelling of homogeneous and heterogeneous systems, thermodynamics of interfaces and three-phase contact lines and the Second Law in engineering thermodynamics.

Three-dimensional (3D) integration of microsystems and subsystems has become essential to the future of semiconductor technology development. 3D integration requires a greater understanding of several interconnected systems stacked over each other. While this vertical growth profoundly increases the system functionality, it also exponentially increases the design complexity. Design of 3D Integrated Circuits and Systems tackles all aspects of 3D integration, including 3D circuit and system design, new processes and simulation techniques, alternative communication schemes for 3D circuits and systems, application of novel materials for 3D systems, and the thermal challenges to restrict power dissipation and improve performance of 3D systems. Containing contributions from experts in industry as well as academia, this authoritative text: Illustrates different 3D integration approaches, such as die-to-die, die-to-wafer, and wafer-to-wafer Discusses the use of interposer technology and the role of Through-Silicon Vias (TSVs) Presents the latest improvements in three major fields of thermal management for multiprocessor systems-on-chip (MPSoCs) Explores ThruChip Interface (TCI), NAND flash memory stacking, and emerging applications Describes large-scale integration testing and state-of-the-art low-power testing solutions Complete with experimental results of chip-level 3D integration schemes tested at IBM and case studies on advanced complementary metal-oxide-semiconductor (CMOS) integration for 3D integrated circuits (ICs), Design of 3D Integrated Circuits and Systems is a practical reference that not only covers a wealth of design issues encountered in 3D integration but also demonstrates their impact on the efficiency of 3D systems.

Energy is typically regarded as understandable, despite its multiple forms of storage and transfer. Entropy, however, is an enigma, in part because of the common view that it represents disorder. That view is flawed and hides entropy's connection with energy. In fact, macroscopic matter stores internal energy, and that matter's entropy is determined by how the energy is stored. Energy and entropy are intimately linked. Energy and Entropy: A Dynamic Duo illuminates connections between energy and entropy for students, teachers, and researchers. Conceptual understanding is emphasised where possible through examples, analogies, figures, and key points. Features: Qualitative demonstration that entropy is linked to spatial and temporal energy spreading, with equilibrium corresponding to the most equitable distribution of energy, which corresponds to maximum entropy Analysis of energy and entropy of matter and photons, with examples ranging from rubber bands, cryogenic cooling, and incandescent lamps to Hawking radiation of black holes Unique coverage of numerical entropy, the 3rd law of thermodynamics, entropic force, dimensionless entropy, free energy, and fluctuations, from Maxwell's demon to Brownian ratchets, plus attempts to violate the second law of thermodynamics

Multi-phase flows are part of our natural environment such as tornadoes, typhoons, air and water pollution and volcanic activities as well as part of industrial technology such as power plants, combustion engines, propulsion systems, or chemical and biological industry. The industrial use of multi-phase systems requires analytical and numerical strategies for predicting their behavior. .In its fourth extended edition the successful monograph package Multiphase Flow Daynmics contains theory, methods and practical experience for describing complex transient multi-phase processes in arbitrary geometrical configurations, providing a systematic presentation of the theory and practice of numerical multi-phase fluid dynamics.

In the present third volume methods for describing of the thermal interactions in multiphase dynamics are provided. In addition a large number of valuable experiments is collected and predicted using the methods introduced in this monograph. In this way the accuracy of the methods is revealed to the reader.

This fourth edition includes various updates, extensions, improvements and corrections.

"The literature in the field of multiphase flows is numerous. Therefore, it is very important to have a comprehensive and systematic overview including useful numerical methods. The volumes have the character of a handbook and accomplish this function excellently. The models are described in detail and a great number of comprehensive examples and some cases useful for testing numerical solutions are included. These two volumes are very useful for scientists and practicing engineers in the fields of technical thermodynamics, chemical engineering, fluid mechanics, and for mathematicians with interest in technical problems. Besides, they can give a good overview of the dynamically developing, complex field of knowledge to students. This monograph is highly recommended,

BERND PLATZER, ZAAM

In the present third volume methods for describing of the thermal interactions in multiphase dynamics are provided. In addition a large number of valuable experiments is collected and predicted using the methods introduced in this monograph. In this way the accuracy of the methods is revealed to the reader.

This fourth edition includes various updates, extensions, improvements and corrections.

"The literature in the field of multiphase flows is numerous. Therefore, it is very important to have a comprehensive and systematic overview including useful numerical methods. The volumes have the character of a handbook and accomplish this function excellently. The models are described in detail and a great number of comprehensive examples and some cases useful for testing numerical solutions are included. These two volumes are very useful for scientists and practicing engineers in the fields of technical thermodynamics, chemical engineering, fluid mechanics, and for mathematicians with interest in technical problems. Besides, they can give a good overview of the dynamically developing, complex field of knowledge to students. This monograph is highly recommended,

BERND PLATZER, ZAAM

This book provides a comprehensive exposition of the theory of equilibrium thermodynamics and statistical mechanics at a level suitable for well-prepared undergraduate students. The fundamental message of the book is that all results in equilibrium thermodynamics and statistical mechanics follow from a single unprovable axiom - namely, the principle of equal a priori probabilities - combined with elementary probability theory, elementary classical mechanics, and elementary quantum mechanics.

This book provides a comprehensive exposition of the theory of equilibrium thermodynamics and statistical mechanics at a level suitable for well-prepared undergraduate students. The fundamental message of the book is that all results in equilibrium thermodynamics and statistical mechanics follow from a single unprovable axiom - namely, the principle of equal a priori probabilities - combined with elementary probability theory, elementary classical mechanics, and elementary quantum mechanics.

Small systems are a very active area of research and development due to improved instrumentation that allows for spatial resolution in the range of sizes from one to 100 nm. In this size range, many physical and chemical properties change, which opens up new approaches to the study of substances and their practical application. This affects both traditional fields of knowledge and many other new fields including physics, chemistry, biology, etc. This book highlights new developments in statistical thermodynamics that answer the most important questions about the specifics of small systems - when one cannot apply equations or traditional thermodynamic models.

This book provides an accessible yet thorough introduction to thermodynamics, crafted and class-tested over many years of teaching. Suitable for advanced undergraduate and graduate students, this book delivers clear descriptions of how to think about the mathematics and physics involved. The content has been carefully developed in consultation with a large number of instructors, teaching courses worldwide, to ensure wide applicability to modules on thermodynamics. Modern applications of thermodynamics (in physics and related areas) are included throughout-something not offered to the same degree by existing texts in the field. Features: A sophisticated approach to the subject that is suitable for advanced undergraduate students and above Modern applications of thermodynamics included throughout To be followed by volumes on statistical mechanics, which can be used in conjunction with this book on courses which cover both thermodynamics and statistical mechanics