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Books > Science & Mathematics > Physics > Thermodynamics & statistical physics > Thermodynamics
This book presents thermodynamic data on oxides in the system MgO-FeO-Fe2O3-Al2O3-SiO2. These data are produced by a process of assessment that involves the integration of thermochemical (calorimetric) and phase equilibrium data. The latter have been selected from a number of publications in high-pressure research conducted at pressures and temperatures in the range of 1 bar to several Giga Pascals and 300 to 2500 K respectively. A unique feature of the database is that the assessment involves not only the thermodynamic data on pure end member species, but also the data on multicomponent solutions. Since the solution description follows the format used in the popular thermodynamic computational packages such as FACTSAGE, ChemSage and Thermocalc, the database is easy to incorporate in the currently used databases in these packages. The database is highly useful to those working in the field of metallurgy (e.g. slags) and ceramics. It is essential for all those who do thermodynamic modeling of the terrestrial planetary interiors.
Absolute concepts of time and energy are integral to standard thermal physics, but background independent systems are devoid of them. This thesis explores the foundational question of generalising equilibrium statistical mechanics to background independent systems, and applies the resulting formulation to non-perturbative discrete quantum gravity. It offers a discussion of the rich interface of thermal physics and quantum gravity in this context, providing a broad contextualisation of such topics. This work details how standard tools from many-body physics can be generalised to discrete quantum gravity labelled with graph-based, or dual polyhedral, quanta that are common to various approaches like tensorial group field theory, loop quantum gravity, dynamical triangulations and lattice quantum gravity. It provides a systematic investigation, both conceptual and technical, of quantum gravitational Gibbs states, thermofield double vacuum states, and their application in condensate cosmology to probe questions of Big Bang singularity resolution and geometric inflation.
The book describes the thermodynamics, fluid dynamics, and working principle of the Ranque Hilsch Vortex Tube. Although vortex tubes have been around for a long time, different explications of their fundamental physics and operation can be found in literature and on the internet. This volume investigates the working principle based on thermodynamics and fluid dynamics. It provides full explication of these parameters in one single work along with results of new investigations not published elsewhere. In addition, the book features a wealth of illustrations on various aspects of the vortex tube that make it easy to read and understand.
Thermodynamically constrained averaging theory provides a consistent method for upscaling conservation and thermodynamic equations for application in the study of porous medium systems. The method provides dynamic equations for phases, interfaces, and common curves that are closely based on insights from the entropy inequality. All larger scale variables in the equations are explicitly defined in terms of their microscale precursors, facilitating the determination of important parameters and macroscale state equations based on microscale experimental and computational analysis. The method requires that all assumptions that lead to a particular equation form be explicitly indicated, a restriction which is useful in ascertaining the range of applicability of a model as well as potential sources of error and opportunities to improve the analysis.
Alternative Mathematical Theory of Non-equilibrium Phenomena
presents an entirely new theoretical approach to complex
non-equilibrium phenomena, especially Gibbs/Falk thermodynamics and
fluid mechanics. This innovative new theory allows for inclusion of
all state variables and introduces a new vector-dissipation
velocity-which leads to useful restatements of momentum, the Second
Law, and tensors for the laws of motion, friction, and heat
conduction. This application-oriented text is relatively
self-contained and is an excellent guide-book for engineers with a
strong interest in fundamentals, or for professionals using applied
mathematics and physics in engineering applications.
Synchronization is a universal phenomenon that is encountered in nature, science and engineering. The book presents a broad view of modern theoretical and experimental approaches to synchronization, especially in complex and chaotic systems, and its applications in life sciences and engineering. Contributors include applied mathematicians, physicists, biologists, and specialists in communications and control theory. The study of synchronization is presented in its many aspects: basic mathematical theory, numerical simulation of complex systems, applications of methods in theoretical physics, experimental implementation, and applications in engineering and life sciences.
Pierre Duhem (1861 1916) held the chair of theoretical physics at Bordeaux from 1894 to his death. He established a reputation in both the history and philosophy of science as well as in science itself (physics and physical chemistry). Much of his work in the first two areas has been translated into English, but little of his technical scientific work. The present volume contains early work of Duhem s illustrating his interest in the rigorous development of physical theory for which he is famous. It opens with what was the first critical discussion of Gibbs groundbreaking "On the Equilibrium of Heterogeneous Substances" (1876-8), where Duhem addressed the problem that, as he put it, "Mathematicians regret that the principles of Thermodynamics should have been developed in general with so little precision that the same proposition can be regarded by some as a consequence, and by others as a negation, of these principles." The other papers, forming a three-part series, pursue this project of putting the foundations of thermodynamics on a clearer and more secure basis. This book will be of interest to scholars in history and philosophy of science, especially those interested in the development of physical chemistry and the work of Pierre Duhem."
This volume describes the current state of knowledge of random spatial processes, particularly those arising in physics. The emphasis is on survey articles which describe areas of current interest to probabilists and physicists working on the probability theory of phase transition. Special attention is given to topics deserving further research. The principal contributions by leading researchers concern the mathematical theory of random walk, interacting particle systems, percolation, Ising and Potts models, spin glasses, cellular automata, quantum spin systems, and metastability. The level of presentation and review is particularly suitable for postgraduate and postdoctoral workers in mathematics and physics, and for advanced specialists in the probability theory of spatial disorder and phase transition.
Nucleation is the initial step of every first-order phase transition, and most phase transitions encountered both in everyday life and industrial processes are of the first-order. Using an elegant classical theory based on thermodynamics and kinetics, this book provides a fully detailed picture of multi-component nucleation. As many of the issues concerning multi-component nucleation theory have been solved during the last 10-15 years, it also thoroughly integrates both fundamental theory with recent advances presented in the literature. Classical Nucleation Theory in Multicomponent Systems serves as a textbook for advanced thermodynamics courses, as well as an important reference for researchers in the field. The main topics covered are: the basic relevant thermodynamics and statistical physics; modelling a molecular cluster as a spherical liquid droplet; predicting the size and composition of the nucleating critical clusters; kinetic models for cluster growth and decay; calculating nucleation rates; and a full derivation and application of nucleation theorems that can be used to extract microscopic cluster properties from nucleation rate measurements. The assumptions and approximations needed to build the classical theory are described in detail, and the reasons why the theory fails in certain cases are explained. Relevant problems are presented at the end of each chapter.
This book presents the results of scientific research performed over the past two decades by the authors. The book discusses some issues of separated laminar flows that are of great practical interest for the development of new technologies using microchannel flows, where separation zones can form. Of particular interest is the complex mechanism of flow separation with superimposed high external turbulence. The challenges of finding the optimal location for the cavities and fins on heat exchange surfaces are also considered. This is an important fundamental and practical problem when creating new schemes of efficient heat exchangers in various power plants. A wide class of problems of turbulent flow in tubes with flow separation is considered. These data will be useful in engineering estimates of the thermal-hydraulic efficiency of various heat transfer intensifiers. This book focuses on the analysis of thermal characteristics of separated flows, as well as the possibility of controlling the intensity of heat exchange processes, from the point of view of both their intensification and their suppression.
Properties of systems with long range interactions are still poorly understood despite being of importance in most areas of physics. The present volume introduces and reviews the effort of constructing a coherent thermodynamic treatment of such systems by combining tools from statistical mechanics with concepts and methods from dynamical systems. Analogies and differences between various systems are examined by considering a large range of applications, with emphasis on Bose--Einstein condensates. Written as a set of tutorial reviews, the book will be useful for both the experienced researcher as well as the nonexpert scientist or postgraduate student.
This monograph discusses the essential principles of the evaporationprocess by looking at it at the molecular and atomic level. In the first part methods of statistical physics, physical kinetics andnumerical modeling are outlined including the Maxwell's distributionfunction, the Boltzmann kinetic equation, the Vlasov approach, and theCUDA technique. The distribution functions of evaporating particles are then defined.Experimental results on the evaporation coefficient and the temperaturejump on the evaporation surface are critically reviewed and compared tothe theory and numerical results presented in previous chapters. The book ends with a chapter devoted to evaporation in differentprocesses, such as boiling and cavitation.This monograph addressesgraduate students and researchers working on phase transitions andrelated fields.
The aim of this book is to comment on, and clarify, the mathematical aspects of the theory of thermodynamics. The standard presentations of the subject are often beset by a number of obscurities associated with the words "state," "reversible," "irreversible," and "quasi-static." This book is written in the belief that such obscurities are best removed not by the formal axiomatization of thermodynamics, but by setting the theory in the wider context of a genuine field theory which incorporates the effects of heat conduction and intertia, and proving appropriate results about the governing differential equations of this field theory. Even in the simplest one-dimensional case it is a nontrivial task to carry through the details of this program, and many challenging problems remain open.
Energy is typically regarded as understandable, despite its multiple forms of storage and transfer. Entropy, however, is an enigma, in part because of the common view that it represents disorder. That view is flawed and hides entropy's connection with energy. In fact, macroscopic matter stores internal energy, and that matter's entropy is determined by how the energy is stored. Energy and entropy are intimately linked. Energy and Entropy: A Dynamic Duo illuminates connections between energy and entropy for students, teachers, and researchers. Conceptual understanding is emphasised where possible through examples, analogies, figures, and key points. Features: Qualitative demonstration that entropy is linked to spatial and temporal energy spreading, with equilibrium corresponding to the most equitable distribution of energy, which corresponds to maximum entropy Analysis of energy and entropy of matter and photons, with examples ranging from rubber bands, cryogenic cooling, and incandescent lamps to Hawking radiation of black holes Unique coverage of numerical entropy, the 3rd law of thermodynamics, entropic force, dimensionless entropy, free energy, and fluctuations, from Maxwell's demon to Brownian ratchets, plus attempts to violate the second law of thermodynamics
Over the years enormous effort was invested in proving ergodicity, but for a number of reasons, con?dence in the fruitfulness of this approach has waned. - Y. Ben-Menahem and I. Pitowsky [1] Abstract The basic motivation behind the present text is threefold: To give a new explanation for the emergence of thermodynamics, to investigate the interplay between quantum mechanics and thermodynamics, and to explore possible ext- sions of the common validity range of thermodynamics. Originally, thermodynamics has been a purely phenomenological science. Early s- entists (Galileo, Santorio, Celsius, Fahrenheit) tried to give de?nitions for quantities which were intuitively obvious to the observer, like pressure or temperature, and studied their interconnections. The idea that these phenomena might be linked to other ?elds of physics, like classical mechanics, e.g., was not common in those days. Such a connection was basically introduced when Joule calculated the heat equ- alent in 1840 showing that heat was a form of energy, just like kinetic or potential energy in the theory of mechanics. At the end of the 19th century, when the atomic theory became popular, researchers began to think of a gas as a huge amount of bouncing balls inside a box.
This monograph is devoted to an entirely new branch of nonlinear physics - solitary intrinsic states, or autosolitons, which form in a broad class of physical, chemical and biological dissipative systems. Autosolitons are often observed as highly nonequilibrium regions in slightly nonequilibrium systems, in many ways resembling ball lightning which occurs in the atmosphere. We develop a new approach to problems of self-organization and turbulence, treating these phenomena as a result of spontaneous formation and subsequent evolution of autosolitons. Scenarios of self-organization involve sophisticated interactions between autosolitons, whereas turbulence is regarded as a pattern of autosolitons which appear and disappear at random in different parts of the system. This monograph is the first attempt to provide a comprehensive summary of the theory of autosolitons as developed by the authors over the years of research. The monograph is comprised of three more or less autonomous parts. Part I deals with the physical nature and experimental studies of autosolitons and self organization in various physical systems: semiconductor and gas plasma, heated gas mixture, semiconductor structures, composite superconductors, optical and magnetic media, systems with uniformly generated combustion matter, distributed gas-discharge and electronic systems. We discuss feasibility of autosolitons in the form of highly nonequilibrium regions in slightly nonequilibrium gases and semiconductors, "hot" and "cold" regions in semiconductor and gas plasmas, static, pulsating and traveling combustion fronts."
This book comprises selected papers from the International Conference on Numerical Heat Transfer and Fluid Flow (NHTFF 2018), and presents the latest developments in computational methods in heat and mass transfer. It also discusses numerical methods such as finite element, finite difference, and finite volume applied to fluid flow problems. Providing a good balance between computational methods and analytical results applied to a wide variety of problems in heat transfer, transport and fluid mechanics, the book is a valuable resource for students and researchers working in the field of heat transfer and fluid dynamics.
This book is based on the analogy between contact mechanics and fracture mechanics as proposed by the author about twenty years ago. It starts with a chapter devoted to the surface energy and tension of solids and surface thermodynamics, which is followed by a chapter on elastic recall. The methods of Muskhelichvili and Hankel transforms for the resolution of plane and axisymmetric problems are studied. Then the essential conepts of fracture mechanics are presented with emphasis on the thermodynamic aspect of the problem. The reader will find complete analytical results and detailed calculations for cracks submitted to pressure distributions and the Dugdale model, as well as a chapter on contact mechanics. The contact and adherence of rough solids is also studied. This book is intended for advanced students and researchers working in the fields of fracture mechanics or adhesion.
This thesis presents several related advances in the field of nonequilibrium quantum thermodynamics. The central result is an ingenious proof that the local temperature and voltage measurement in a nonequilibrium system of fermions exists and is unique, placing the concept of local temperature on a rigorous mathematical footing for the first time. As an intermediate step, a proof of the positivity of the Onsager matrix of linear response theory is given -- a statement of the second law of thermodynamics that had lacked an independent proof for 85 years. A new experimental method to measure the local temperature of an electron system using purely electrical techniques is also proposed, which could enable improvements to the spatial resolution of thermometry by several orders of magnitude. Finally, a new mathematically-exact definition for the local entropy of a quantum system in a nonequilibrium steady state is derived. Several different measures of the local entropy are discussed, relating to the thermodynamics of processes that a local observer with varying degrees of information about the microstates of the system could carry out, and it is shown that they satisfy a hierarchy of inequalities. Proofs of the third law of thermodynamics for generic open quantum systems are presented, taking into account the entropic contribution due to localized states. Appropriately normalized (per-state) local entropies are defined and are used to quantify the departure from local equilibrium.
The fifth edition of "Thermodynamic and Transport Properties of Fluids" incorporates two new tables: other material is being retained essentially as in the fourth edition, although tables beyond p.11 will be on different pages. The new tables are as follows: Data of Refrigerant 134a (tetrafluoroethane - CH2F-CF3) are being added because this refrigerant is environmentally more acceptable than Refrigerant 12 which it replaces. The table of R12 is being retained, however, because R12 will survive in much equipment for a long time. At present it is still uncertain whether R134a is a medium-term substitute, or will be used for much longer than a decade. Figure 15.11 from "Engineering Thermodynamics, Work and Heat Transfer" (Rogers & Mayhew, Longman 1992) is being included. The table contains, for selected substances, molar enthalpies and molar Gibbs functions of formation, and Equilibrium constants of formation, as well as molar heat capacities and absolute entropies.
This book contains the courses given at the Fifth School on Complex Systems held at Santiago, Chile, from 9th .to 13th December 1996. At this school met researchers working on areas related with recent trends in Complex Systems, which include dynamical systems, cellular automata, symbolic dynamics, spatial systems, statistical physics and thermodynamics. Scientists working in these subjects come from several areas: pure and applied mathematics, physics, biology, computer science and electrical engineering. Each contribution is devoted to one of the above subjects. In most cases they are structured as surveys, presenting at the same time an original point of view about the topic and showing mostly new results. The paper of Bruno Durand presents the state of the art on the relationships between the notions of surjectivity, injectivity and reversibility in cellular automata when finite, infinite or periodic configurations are considered, also he discusses decidability problems related with the classification of cellular automata as well as global properties mentioned above. The paper of Eric Goles and Martin Matamala gives a uniform presentation of simulations of Turing machines by cellular automata. The main ingredient is the encoding function which must be fixed for all Turing machine. In this context known results are revised and new results are presented.
Features Covers both basic introductory topics, in addition to more advanced content Accompanied by over 200 problems starting from group algebra to the derivation of Migdal-Makeenko equations, Kim - Shifman - Vainshtein - Zakharov axion, and gluon + gluon to Higgs cross section, etc. Solutions are incorporated into the chapters to test understanding
- Focuses on a very physical and specific understanding of how humans measure and interpret the measurements of the quantity of time, unlike existing books which explore qualitative, speculative theories currently entertained in physics and philosophy. |
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