This book explains the modelling and simulation of thermal power plants, and introduces readers to the equations needed to model a wide range of industrial energy processes. Also featuring a wealth of illustrative, real-world examples, it covers all types of power plants, including nuclear, fossil-fuel, solar and biomass. The book is based on the authors' expertise and experience in the theory of power plant modelling and simulation, developed over many years of service with EDF. In more than forty examples, they demonstrate the component elements involved in a broad range of energy production systems, with detailed test cases for each chemical, thermodynamic and thermo-hydraulic model. Each of the test cases includes the following information: * component description and parameterization data; * modelling hypotheses and simulation results; * fundamental equations and correlations, with their validity domains; * model validation, and in some cases, experimental validation; and * single-phase flow and two-phase flow modelling equations, which cover all water and steam phases. A practical volume that is intended for a broad readership, from students and researchers, to professional engineers, this book offers the ideal handbook for the modelling and simulation of thermal power plants. It is also a valuable aid in understanding the physical and chemical phenomena that govern the operation of power plants and energy processes.

This unique book is at the nexus of modern software programming practices and electrochemical process engineering. It is the authoritative text on developing open source software for many applications, including: * fuel cells; * electrolyzers; and * batteries. Written by experts in the field in the open source computational fluid dynamics (CFD) code suite OpenFOAM, this book is intended for process engineering professionals developing practical electrochemical designs for industry, as well as researchers focused on finding tomorrow's answers today. The book covers everything from micro-scale to cell-scale to stack-scale models, with numerous illustrations and programming examples. Starting from a clear explanation of electrochemical processes and simple illustrative examples, the book progresses in complexity through a range of diverse applications. After reading this book, the reader is able to take command and control of model development as an expert. The book is aimed at all engineers and scientists with basic knowledge of calculus and programming in C++.

This is a textbook on thermodynamics of materials for junior/senior undergraduate students and first-year graduate students as well as a reference book for researchers who would like to refresh their understanding of thermodynamics. The textbook employs a plain language to explain the thermodynamic concepts and quantities. It embraces the mathematical beauty and rigor of Gibbs thermodynamics through the fundamental equation of thermodynamics from which all thermodynamic properties of a material can be derived. However, a reader with basic first-year undergraduate calculus skills will be able to get through the book without difficulty. One unique feature of this textbook is the descriptions of the step-by-step procedures for computing all the thermodynamic properties from the fundamental equation of thermodynamics and all the thermodynamic energies from a set of common, experimentally measurable thermodynamic properties, supplemented with ample numerical examples. Another unique feature of this textbook is its emphasis on the concept of chemical potential and its applications to phase equilibria in single component systems and binary solutions, chemical reaction equilibria, and lattice and electronic defects in crystals. The concept of chemical potential is introduced at the very beginning of the book together with temperature and pressure. It avoids or minimizes the use of terms such as molar Gibbs free energy, partial molar Gibbs free energy, or Gibbs potential because molar Gibbs free energy or partial molar Gibbs free energy is precisely the chemical potential of a material or a component. It is the chemical potential that determines the stability of chemical species, compounds, and phases and their tendency to chemically react to form new species, transform to new physical state, and migrate from one spatial location to another. Therefore, it is the chemical potential differences or gradients that drive essentially all materials processes of interest. A reader after finishing reading the book is expected to not only achieve a high-level fundamental understanding of thermodynamics but also acquire the analytical skills of applying thermodynamics to determining materials equilibrium and driving forces for materials processes.

The Surface Wettability Effect on Phase Change collects high level contributions from internationally recognised scientists in the field. It thoroughly explores surface wettability, with topics spanning from the physics of phase change, physics of nucleation, mesoscale modeling, analysis of phenomena such drop evaporation, boiling, local heat flux at triple line, Leidenfrost, dropwise condensation, heat transfer enhancement, freezing, icing. All the topics are treated by discussing experimental results, mathematical modeling and numerical simulations. In particular, the numerical methods look at direct numerical simulations in the framework of VOF simulations, phase-field simulations and molecular dynamics. An introduction to equilibrium and non-equilibrium thermodynamics of phase change, wetting phenomena, liquid interfaces, numerical simulation of wetting phenomena and phase change is offered for readers who are less familiar in the field. This book will be of interest to researchers, academics, engineers, and postgraduate students working in the area of thermofluids, thermal management, and surface technology.

Synchronization is a universal phenomenon that is encountered in nature, science and engineering. The book presents a broad view of modern theoretical and experimental approaches to synchronization, especially in complex and chaotic systems, and its applications in life sciences and engineering. Contributors include applied mathematicians, physicists, biologists, and specialists in communications and control theory. The study of synchronization is presented in its many aspects: basic mathematical theory, numerical simulation of complex systems, applications of methods in theoretical physics, experimental implementation, and applications in engineering and life sciences.

This textbook introduces the molecular side of physical chemistry. It offers students and practitioners a new approach to the subject by presenting numerous applications and solved problems that illustrate the concepts introduced for varied and complex technical situations. The book offers a balance between theory, tools, and practical applications. The text aims to be a practical manual for solving engineering problems in industries where processes depend on the chemical composition and physical properties of matter. The book is organized into three main topics: (I) the molecular structure of matter, (II) molecular models in thermodynamics, and (III) transport phenomena and mechanisms. Part I presents methods of analysis of the molecular behavior in a given system, while the following parts use these methods to study the equilibrium states of a material system and to analyze the processes that can take place when the system is in a state of non-equilibrium, in particular the transport phenomena. Molecular Physical Chemistry for Engineering Applications is designed for upper-level undergraduate and graduate courses in physical chemistry for engineers, applied physical chemistry, transport phenomena, colloidal chemistry, and transport/transfer processes. The book will also be a valuable reference guide for engineers, technicians, and scientists working in industry. Offers modeling techniques and tools for solving exercises and practical cases; Provides solutions and conclusions so students can follow results more closely; Step-by-step problem solving enables students to understand how to approach complex issues.

This volume describes the current state of knowledge of random spatial processes, particularly those arising in physics. The emphasis is on survey articles which describe areas of current interest to probabilists and physicists working on the probability theory of phase transition. Special attention is given to topics deserving further research. The principal contributions by leading researchers concern the mathematical theory of random walk, interacting particle systems, percolation, Ising and Potts models, spin glasses, cellular automata, quantum spin systems, and metastability. The level of presentation and review is particularly suitable for postgraduate and postdoctoral workers in mathematics and physics, and for advanced specialists in the probability theory of spatial disorder and phase transition.

This volume presents seven review articles on the recent developments on quantum turbulence. Turbulence has been a great mystery in natural science and technology for more than 500 years since the time of Leonardo da Vinci. Recently turbulence in quantum systems at low temperatures has developed into a new research field. Quantum turbulence is comprised of quantized vortices, realized in superfluid helium and quantum gases of cold atoms. Some of the important topics include energy spectra, vibrating structures, and visualization techniques. The understanding of these remarkable systems can have an impact on the general field of turbulence and will be of broad interest to scientists and students in low temperature physics, hydrodynamics and engineering.
- Key subjects covered: Energy spectra in quantum turbulence, Turbulent dynamics in rotating helium superfluids: a comparison of 3He-B and 4He-II,
Quantum turbulence in superfluid 3He at very low temperatures, The use of vibrating structures in the study of quantum turbulence, Visualization of quantum turbulence, Capillary turbulence on the surface of quantum fluids, Quantized vortices in atomic Bose-Einstein condensates
- Crucial information for all experimenters in low temperature physics

Pierre Duhem (1861 1916) held the chair of theoretical physics at Bordeaux from 1894 to his death. He established a reputation in both the history and philosophy of science as well as in science itself (physics and physical chemistry). Much of his work in the first two areas has been translated into English, but little of his technical scientific work. The present volume contains early work of Duhem s illustrating his interest in the rigorous development of physical theory for which he is famous. It opens with what was the first critical discussion of Gibbs groundbreaking "On the Equilibrium of Heterogeneous Substances" (1876-8), where Duhem addressed the problem that, as he put it, "Mathematicians regret that the principles of Thermodynamics should have been developed in general with so little precision that the same proposition can be regarded by some as a consequence, and by others as a negation, of these principles." The other papers, forming a three-part series, pursue this project of putting the foundations of thermodynamics on a clearer and more secure basis. This book will be of interest to scholars in history and philosophy of science, especially those interested in the development of physical chemistry and the work of Pierre Duhem."

This book includes innovative gas-geothermometers and geobarometers, which are urgently needed to estimate the increasingly higher temperatures and pressures present at depth below the Solfatara volcano, owing to its on-going unrest. Therefore, in this book, new gas geoindicators, applicable up to ca. 1000 DegreesC and 3 kbar, have been implemented and applied to Solfatara fluids. The innovations of this book include: methane, having a sluggish behavior, was treated separately from fast-reacting carbon monoxide; deviations from the ideal gas behavior were considered; the effects of reaction kinetics were taken into account. This was possible because a dataset including many geochemical parameters and extending from 1983 to 2020 with a good sampling frequency is available for Solfatara, making it a case history probably unique worldwide. Nevertheless, the gas geoindicators described in this book can be applied to other similar systems. Thus, this book is of interest to many scientists studying gas geochemistry, geothermometry, and geobarometry for volcanic surveillance and the mitigation of the volcanic risk.

This book covers some fundamental aspects and frontiers in non-equilibrium physics and soft matter research. Apart from the basic knowledge on nonlinear statistic physics, dynamics, computer simulations, and main approaches and emerging systems in soft matter research, particular attention is devoted to new conceptual flexible functional materials and the enriching areas, such as silk meso-molecular materials, molecular gels, liquid crystals, flexible electronics and new types of catalysis, etc. One of the main characteristics of this book is to start with the structure formation dynamics and the correlation between the structures and macroscopic performance. This lays down the foundation for the mesoscopic materials design and functionalization. The book is intended for upper undergraduate students, graduate students, and researchers who are interested in soft matter researches. As one of main references, the basic principles and technologies of computer simulations and experimental methods adopted in soft matter research are also explained. Illustrations and tables are included in this book to improve the readability, and examples and exercises are added to help understanding.

Nucleation is the initial step of every first-order phase transition, and most phase transitions encountered both in everyday life and industrial processes are of the first-order. Using an elegant classical theory based on thermodynamics and kinetics, this book provides a fully detailed picture of multi-component nucleation. As many of the issues concerning multi-component nucleation theory have been solved during the last 10-15 years, it also thoroughly integrates both fundamental theory with recent advances presented in the literature.

Classical Nucleation Theory in Multicomponent Systems serves as a textbook for advanced thermodynamics courses, as well as an important reference for researchers in the field. The main topics covered are: the basic relevant thermodynamics and statistical physics; modelling a molecular cluster as a spherical liquid droplet; predicting the size and composition of the nucleating critical clusters; kinetic models for cluster growth and decay; calculating nucleation rates; and a full derivation and application of nucleation theorems that can be used to extract microscopic cluster properties from nucleation rate measurements.

The assumptions and approximations needed to build the classical theory are described in detail, and the reasons why the theory fails in certain cases are explained. Relevant problems are presented at the end of each chapter.

Properties of systems with long range interactions are still poorly understood despite being of importance in most areas of physics. The present volume introduces and reviews the effort of constructing a coherent thermodynamic treatment of such systems by combining tools from statistical mechanics with concepts and methods from dynamical systems. Analogies and differences between various systems are examined by considering a large range of applications, with emphasis on Bose--Einstein condensates. Written as a set of tutorial reviews, the book will be useful for both the experienced researcher as well as the nonexpert scientist or postgraduate student.

Absolute concepts of time and energy are integral to standard thermal physics, but background independent systems are devoid of them. This thesis explores the foundational question of generalising equilibrium statistical mechanics to background independent systems, and applies the resulting formulation to non-perturbative discrete quantum gravity. It offers a discussion of the rich interface of thermal physics and quantum gravity in this context, providing a broad contextualisation of such topics. This work details how standard tools from many-body physics can be generalised to discrete quantum gravity labelled with graph-based, or dual polyhedral, quanta that are common to various approaches like tensorial group field theory, loop quantum gravity, dynamical triangulations and lattice quantum gravity. It provides a systematic investigation, both conceptual and technical, of quantum gravitational Gibbs states, thermofield double vacuum states, and their application in condensate cosmology to probe questions of Big Bang singularity resolution and geometric inflation.

In this book, an almost new approach to modern thermodynamics has been applied. One or more useful qualitative discussion statements have been extracted from each equation. These and other important statements were numbered and their titles were situated in an index titled "Hilal and Others' statements, definitions and rules." This ensures very quick obtaining of the required statements, rules, definitions, equations, and their theoretical base that will ease readers qualitative discussions and calculations.

This monograph is devoted to an entirely new branch of nonlinear physics - solitary intrinsic states, or autosolitons, which form in a broad class of physical, chemical and biological dissipative systems. Autosolitons are often observed as highly nonequilibrium regions in slightly nonequilibrium systems, in many ways resembling ball lightning which occurs in the atmosphere. We develop a new approach to problems of self-organization and turbulence, treating these phenomena as a result of spontaneous formation and subsequent evolution of autosolitons. Scenarios of self-organization involve sophisticated interactions between autosolitons, whereas turbulence is regarded as a pattern of autosolitons which appear and disappear at random in different parts of the system. This monograph is the first attempt to provide a comprehensive summary of the theory of autosolitons as developed by the authors over the years of research. The monograph is comprised of three more or less autonomous parts. Part I deals with the physical nature and experimental studies of autosolitons and self organization in various physical systems: semiconductor and gas plasma, heated gas mixture, semiconductor structures, composite superconductors, optical and magnetic media, systems with uniformly generated combustion matter, distributed gas-discharge and electronic systems. We discuss feasibility of autosolitons in the form of highly nonequilibrium regions in slightly nonequilibrium gases and semiconductors, "hot" and "cold" regions in semiconductor and gas plasmas, static, pulsating and traveling combustion fronts."

Over the years enormous effort was invested in proving ergodicity, but for a number of reasons, con?dence in the fruitfulness of this approach has waned. - Y. Ben-Menahem and I. Pitowsky [1] Abstract The basic motivation behind the present text is threefold: To give a new explanation for the emergence of thermodynamics, to investigate the interplay between quantum mechanics and thermodynamics, and to explore possible ext- sions of the common validity range of thermodynamics. Originally, thermodynamics has been a purely phenomenological science. Early s- entists (Galileo, Santorio, Celsius, Fahrenheit) tried to give de?nitions for quantities which were intuitively obvious to the observer, like pressure or temperature, and studied their interconnections. The idea that these phenomena might be linked to other ?elds of physics, like classical mechanics, e.g., was not common in those days. Such a connection was basically introduced when Joule calculated the heat equ- alent in 1840 showing that heat was a form of energy, just like kinetic or potential energy in the theory of mechanics. At the end of the 19th century, when the atomic theory became popular, researchers began to think of a gas as a huge amount of bouncing balls inside a box.

The book describes the thermodynamics, fluid dynamics, and working principle of the Ranque Hilsch Vortex Tube. Although vortex tubes have been around for a long time, different explications of their fundamental physics and operation can be found in literature and on the internet. This volume investigates the working principle based on thermodynamics and fluid dynamics. It provides full explication of these parameters in one single work along with results of new investigations not published elsewhere. In addition, the book features a wealth of illustrations on various aspects of the vortex tube that make it easy to read and understand.

The nonequilibrium behavior of nanoscopic and biological systems, which are typically strongly fluctuating, is a major focus of current research. Lately, much progress has been made in understanding such systems from a thermodynamic perspective. However, new theoretical challenges emerge when the fluctuating system is additionally subject to time delay, e.g. due to the presence of feedback loops. This thesis advances this young and vibrant research field in several directions. The first main contribution concerns the probabilistic description of time-delayed systems; e.g. by introducing a versatile approximation scheme for nonlinear delay systems. Second, it reveals that delay can induce intriguing thermodynamic properties such as anomalous (reversed) heat flow. More generally, the thesis shows how to treat the thermodynamics of non-Markovian systems by introducing auxiliary variables. It turns out that delayed feedback is inextricably linked to nonreciprocal coupling, information flow, and to net energy input on the fluctuating level.

This textbook presents the classical treatment of the problems of heat transfer in an exhaustive manner with due emphasis on understanding of the physics of the problems. This emphasis will be especially visible in the chapters on convective heat transfer. Emphasis is also laid on the solution of steady and unsteady two-dimensional heat conduction problems. Another special feature of the book is a chapter on introduction to design of heat exchangers and their illustrative design problems. A simple and understandable treatment of gaseous radiation has been presented. A special chapter on flat plate solar air heater has been incorporated that covers mathematical modeling of the air heater. The chapter on mass transfer has been written looking specifically at the needs of the students of mechanical engineering. The book includes a large number and variety of solved problems with supporting line diagrams. A number of application-based examples have been incorporated where applicable. The end-of-chapter exercise problems are supplemented with stepwise answers. Though the book has been primarily designed to serve as a complete textbook for undergraduate and graduate students of mechanical engineering, it will also be useful for students of chemical, aerospace, automobile, production, and industrial engineering streams. The book fully covers the topics of heat transfer coursework and can also be used as an excellent reference for students preparing for competitive graduate examinations.

This book presents different thermodynamic approaches in the area of constitutive theory: thermodynamics of irreversible processes, rational thermodynamics, and extended thermodynamics. These different approaches are analyzed with respect to their presuppositions, as well as to their results, and each method is applied to several important examples. In many cases these examples are archetypes for numerous technologically important materials; i.e. complex materials having an internal structure. Some of the examples dealt with in this book are liquid crystals, colloid suspensions, ans fiber suspensions. The book well serves students and researchers who have basic knowledge in continuum mechanics and thermodynamics. It provides a systematic overview of the vast field of thermodynamic constitutive theory, beginning from a historical perspective and concluding with outstanding questions in recent research.

This book is based on the analogy between contact mechanics and fracture mechanics as proposed by the author about twenty years ago. It starts with a chapter devoted to the surface energy and tension of solids and surface thermodynamics, which is followed by a chapter on elastic recall. The methods of Muskhelichvili and Hankel transforms for the resolution of plane and axisymmetric problems are studied. Then the essential conepts of fracture mechanics are presented with emphasis on the thermodynamic aspect of the problem. The reader will find complete analytical results and detailed calculations for cracks submitted to pressure distributions and the Dugdale model, as well as a chapter on contact mechanics. The contact and adherence of rough solids is also studied. This book is intended for advanced students and researchers working in the fields of fracture mechanics or adhesion.

This book comprises selected papers from the International Conference on Numerical Heat Transfer and Fluid Flow (NHTFF 2018), and presents the latest developments in computational methods in heat and mass transfer. It also discusses numerical methods such as finite element, finite difference, and finite volume applied to fluid flow problems. Providing a good balance between computational methods and analytical results applied to a wide variety of problems in heat transfer, transport and fluid mechanics, the book is a valuable resource for students and researchers working in the field of heat transfer and fluid dynamics.

Existing texts on the statistical mechanics of liquids treat only spherical molecules. However, nearly all fluids of practical interest are composed of non-spherical molecules that are often dipolar or exhibit other kinds of electrostatic forces. This book describes the statistical mechanical theory of fluids of non-spherical molecules and its application to the calculation of physical properties, and is a sequel to Theory of Molecular Fluids. Volume 1: Fundamentals by C.G. Gray and K.E. Gubbins. The emphasis is on the new phenomena that arise due to the non-spherical nature of the intermolecular forces, such as new phase transitions, structural features and dielectric effects. It contains chapters on the thermodynamic properties of pure and mixed fluids, surface properties, X-ray and neutron diffraction structure factors, dielectric properties and spectroscopic properties. The book is aimed at beginning graduate students and research workers in chemistry, physics, materials science and engineering.