The book drawing on the author's nearly half a century of energetic materials research experience intends to systematically review the global researches on liquid explosives. The book focuses on the study of the conception, explosion mechanism, properties and preparation of liquid explosives. It provides a combination of theoretical knowledge and practical examples in a reader-friendly style. The book is likely to be interest of university researchers and graduate students in the fields of energetic materials, blasting engineering and mining.

The authors are very glad to see the publication ofThermodynamicEquilibriaand Extrema in English and would like to express their gratitude to everybody who contributed to this end. The book is devoted to the analysis of attainability regions and partial equilibria in physicochemical and other systems. This analysis employs the extreme models ofclassicalequilibriumthermodynamics. Considerationisgiventotheproblemof choosing, from the set of equilibrium states belonging to the attainability regions, that equilibrium corresponding to the extreme values of a property of interest to a researcher. For example, one might desire to maximize the concentration of target products of a chemical reaction. The problem of coordinating thermodynamics and kinetics is very important in the analysis presented. Ataglance, itmayseemthattheobjectsofstudyinthermodynamics(thescience ofequilibria)andkinetics(thescienceofmotiontowardequilibrium)coincideonly in the case of complete and ?nal equilibrium. In reality, joint application of th- modynamics and kinetic models gives a clearer understanding of the regularities of the kinetics involved. Relativity of the notions of rest and motion was already ?rmly established in mechanics when the principles of equilibrium were formulated by Galilei, D'Alembert, and Lagrange. Historically, the theories of motion and equilibrium states are related. It is precisely the study of gas kinetics that led Clausius and Boltzmann to the main principles of thermodynamics. The systematic analysis of theseprinciplesintheclassicbookbyGibbs, OntheEquilibriumofHeterogeneous Substances 54], demonstrated the feasibility of substituting the models of rest for themodelsofmotionwhenstudyingvariousphysicochemicalprocesses.

This graduate textbook is concerned with both the formulation and the solution of radiation heat transfer problems in enclosures. The book is essentially self-contained and includes a brief historical survey. The foundations are carefully discussed from the point of view of the exact mathematical basis of boundary value problems and their variational solutions as well as of the physical foundations. The computational methods developed by the authors are used in engineering applications. The combination of exact mathematical modelling with numerical skills makes this a unique textbook.

This book provides an introduction to the most important optical measurement techniques that are applied to engineering problems. It will also serve as a guideline to selecting and applying the appropriate technique to a particular problem. The text of the first edition has been completely revised and new chapters added to describe the latest developments in Phase-Doppler Velocimetry and Particle Image Velocimetry.The editors and authors have made a special effort not only to describe and to explain the fundamentals of measuring techniques, but also to provide guidelines for their application and to demonstrate the capabilities of the various methods.The book comes with a CD-ROM containing high-speed movies visualizing the methods described in the book.

Across the centuries, the development and growth of mathematical concepts have been strongly stimulated by the needs of mechanics. Vector algebra was developed to describe the equilibrium of force systems and originated from Stevin's experiments (1548-1620). Vector analysis was then introduced to study velocity fields and force fields. Classical dynamics required the differential calculus developed by Newton (1687). Nevertheless, the concept of particle acceleration was the starting point for introducing a structured spacetime. Instantaneous velocity involved the set of particle positions in space. Vector algebra theory was not sufficient to compare the different velocities of a particle in the course of time. There was a need to (parallel) transport these velocities at a single point before any vector algebraic operation. The appropriate mathematical structure for this transport was the connection. I The Euclidean connection derived from the metric tensor of the referential body was the only connection used in mechanics for over two centuries. Then, major steps in the evolution of spacetime concepts were made by Einstein in 1905 (special relativity) and 1915 (general relativity) by using Riemannian connection. Slightly later, nonrelativistic spacetime which includes the main features of general relativity I It took about one and a half centuries for connection theory to be accepted as an independent theory in mathematics. Major steps for the connection concept are attributed to a series of findings: Riemann 1854, Christoffel 1869, Ricci 1888, Levi-Civita 1917, WeyJ 1918, Cartan 1923, Eshermann 1950.

Modulation Calorimetry reviews modulation techniques for measuring specific heat, thermal expansivity, temperature derivative of resistance, thermopower, and spectral absorptance. Owing to the periodic nature of the temperature oscillations, high sensitivity and excellent temperature resolution are peculiar to all these methods. The monograph presents the various methods of the modulation and of measuring the temperature oscillations. Important applications of the modulation techniques for studying physical phenomena in solids and liquids are considered in depth (equilibrium point defects, phase transitions, superconductors, liquid crystals, biological materials, relaxation phenomena in specific heat, and more).

This book represents a detailed and systematic account of the basic principles, developments and applications of the theory of nucleation.
The formation of new phases begins with the process of nucleation and is, therefore, a widely spread phenomenon in both nature and technology. Condensation and evaporation, crystal growth, electrodeposition, melt crystallization, growth of thin films for microelectronics, volcano eruption and formation of particulate matter in space are only a few of the processes in which nucleation plays a prominent role.

The book has four parts, which are devoted to the thermodynamics of nucleation, the kinetics of nucleation, the effect of various factors on nucleation and the application of the theory to other processes, which involve nucleation. The first two parts describe in detail the two basic approaches in nucleation theory - the thermodynamic and the kinetic ones. They contain derivations of the basic and most important formulae of the theory and discuss their limitations and possibilities for improvement. The third part deals with some of the factors that can affect nucleation and is a natural continuation of the first two chapters. The last part is devoted to the application of the theory to processes of practical importance such as melt crystallization and polymorphic transformation, crystal growth and growth of thin solid films, size distribution of droplets and crystallites in condensation and crystallization. The book is not just an account of the status quo in nucleation theory - throughout the book there are a number of new results as well as extensions and generalisations of existing ones.

This is a thoroughly revised version of the original book published in 1986. About half of the contents of the previous version remain essentially unchanged, and one quarter has been rewritten and updated. The rest consists of completely new and extended material.

Recent research has focussed on new materials made through "molecular engineering," and computational materials science through ab initio electron structure calculations. Another trend is the ever growing interdisciplinary aspect of both basic and applied materials science. There is an obvious need for reviews that link well established results to the modern approaches. One purpose of this book is to provide such an overview in a specific field of materials science, namely thermophysical phenomena that are intimately connected with the lattice vibrations of solids. This includes, e.g., elastic properties and electrical and thermal transport.

Furthermore, this book attempts to present the results in such a form that the reader can clearly see their domain of applicability, for instance if and how they depend on crystal structure, defects, applied pressure, crystal anisotropy etc. The level and presentation is such that the results can be immediately used in research.

Graduate students in condensed matter physics, metallurgy, inorganic chemistry or geophysical materials will benefit from this book as will theoretical physicists and scientists in industrial research laboratories.

This book presents a solution for direct and inverse heat conduction problems, discussing the theoretical basis for the heat transfer process and presenting selected theoretical and numerical problems in the form of exercises with solutions. The book covers one-, two- and three dimensional problems which are solved by using exact and approximate analytical methods and numerical methods. An accompanying CD-Rom includes computational solutions of the examples and extensive FORTRAN code.

Conversion of Coal-Fired Power Plant to Cogeneration and Combined-Cycle presents the methodology, calculation procedures and tools used to support enterprise planning for adapting power stations to cogeneration and combined-cycle forms. The authors analyze the optimum selection of the structure of heat exchangers in a 370 MW power block, the structure of heat recovery steam generators and gas turbines. Conversion of Coal-Fired Power Plant to Cogeneration and Combined-Cycle also addresses the problems of converting existing power plants to dual-fuel gas-steam combined-cycle technologies coupled with parallel systems. Conversion of Coal-Fired Power Plant to Cogeneration and Combined-Cycle is an informative monograph written for researchers, postgraduate students and policy makers in power engineering.

Atmospheric and climatological studies are becoming more and more important in day-to-day living. Winds and ocean current owe their existence to the thermodynamic imbalances that arise from the differential heating of the Earth and air by the sun. Accounting for heat exchanges with the atmosphere and ocean is essential in any predictive model of the ocean and/or atmosphere. Thermodynamic feedback processes in the atmosphere and ocean are critical to understanding the overall stability of the Earth's climate and climate change. Water and its phase changes make the thermodynamics of the atmosphere and ocean uniquely interesting and challenging.
Written by leading scientists in the field, Thermodynamics of Atmospheres and Oceans incorporates all the relevant information from the varying fields of dynamics meteorology, atmospheric physics and cloud physics, into a comprehensive, self-contained guide ideal for students and researchers of atmospheric thermodynamics. At the moment, courses in atmospheric thermdynamics typically have to use one or two chapters in textbooks on dynamic meteorology, atmospheric physics or cloud physics. This book combines these topics in one text.

This book is dedicated to the recent developments in RET with the aim to explore polyatomic gas, dense gas and mixture of gases in non-equilibrium. In particular we present the theory of dense gases with 14 fields, which reduces to the Navier-Stokes Fourier classical theory in the parabolic limit. Molecular RET with an arbitrary number of field-variables for polyatomic gases is also discussed and the theory is proved to be perfectly compatible with the kinetic theory in which the distribution function depends on an extra variable that takes into account a molecule's internal degrees of freedom. Recent results on mixtures of gases with multi-temperature are presented together with a natural definition of the average temperature. The qualitative analysis and in particular, the existence of the global smooth solution and the convergence to equilibrium are also studied by taking into account the fact that the differential systems are symmetric hyperbolic. Applications to shock and sound waves are analyzed together with light scattering and heat conduction and the results are compared with experimental data. Rational extended thermodynamics (RET) is a thermodynamic theory that is applicable to non-equilibrium phenomena. It is described by differential hyperbolic systems of balance laws with local constitutive equations. As RET has been strictly related to the kinetic theory through the closure method of moment hierarchy associated to the Boltzmann equation, the applicability range of the theory has been restricted within rarefied monatomic gases. The book represents a valuable resource for applied mathematicians, physicists and engineers, offering powerful models for potential applications like satellites reentering the atmosphere, semiconductors and nano-scale phenomena.

Within the framework of Jaynes' "Predictive Statistical Mechanics," this book presents a detailed derivation of an ensemble formalism for open systems arbitrarily away from equilibrium. This involves a large systematization and extension of the fundamental works and ideas of the outstanding pioneers Gibbs and Boltzmann, and of Bogoliubov, Kirkwood, Green, Mori, Zwanzig, Prigogine and Zubarev, among others.
Chapters 1 to 5 include a description of the philosophy, foundations, and construction (methodology) of the formalism, including the derivation of a nonequilibrium grand-canonical ensemble for far-from-equilibrium systems as well as the derivation of a quantum nonlinear kinetic theory and a response function theory together with a theory of scattering. In chapter 6 applications of the theory are cataloged, making comparisons with experimental data (a basic step for the validation of any theory). Chapter 7 is devoted to the description of irreversible thermodynamics, providing a far-reaching generalization of Informational-Statistical Thermodynamics. The last chapter gives an overall picture of the formalism, and questions and criticisms related to it are discussed.
Audience: This book is directed at an audience of researchers in the field of Statistical Mechanics and Thermodynamics of open nonequilibrium systems. In addition, it is relevant for the study of far-from-equilibrium processes in condensed matter, particularly semiconductor physics, as well as molecular Hydrodynamics, Rheology, many-body systems with complex behavior and areas of engineering, etc. The book can also be used as a complement to advanced graduate courses in Statistical Mechanics.

Heat pipes today find many applications, in areas such as electronics cooling, diecasting and injection moulding, heat recovery and energy conservation, de-icing, and manufacturing process temperature control.

"Heat Pipe Technology: Theory, Applications and Prospects" contains the proceedings of an important international gathering of those at the cutting edge of research in the field, with representatives of more than 20 countries. In addition to the finest technical papers, a particularly valuable feature is the inclusion of a series of regional surveys portraying the latest developments worldwide.

The inherent characteristics of heat pipes (passiveness, absence of moving parts, high thermal efficiency) suggest for them an increasingly major role in the evolution of new thermal engineering systems in the years ahead. This volume will undoubtedly be an important resource for researchers worldwide in heat pipe technology.

In this book, the authors give an up-to-date account of thermoluminescence (TL) and other thermally stimulated phenomena. Although most recent experimental results of TL in different materials are described in some detail, the main emphasis in the present book is on general processes, and the approach is more theoretical. Thus the details of the possible processes which can take place during the excitation of the sample, and during its heating, are carefully analysed. The methods for analysing TL glow curves are critically discussed, and recommendations as to their application are made. Also discussed is the expected behavior of these phenomena as functions of the experimental parameters, for example, dose of excitation. The consequences of the main applications of TL (for example, radiation dosimetry) are also discussed in detail as are the similarities and dissimilarities of other thermally stimulated phenomena, and the simultaneous measurements of the latter and TL.

This book is concerned with the prediction of thermodynamic and transport properties of gases and liquids. The prediction of such properties is essential for the solution of many problems encountered in chemical and process engineering as well as in other areas of science and technology. The book aims to present the best of those modern methods which are capable of practical application. It begins with basic scientific principles and formal results which are subsequently developed into practical methods of prediction. Numerous examples, supported by a suite of computer programmes, illustrate applications of the methods. The book is aimed primarily at the student market (for both undergraduate and taught postgraduate courses) but it will also be useful for those engaged in research and for chemical and process engineering professionals.

This book is concerned with the prediction of thermodynamic and transport properties of gases and liquids. The prediction of such properties is essential for the solution of many problems encountered in chemical and process engineering as well as in other areas of science and technology. The book aims to present the best of those modern methods which are capable of practical application. It begins with basic scientific principles and formal results which are subsequently developed into practical methods of prediction. Numerous examples, supported by a suite of computer programmes, illustrate applications of the methods. The book is aimed primarily at the student market (for both undergraduate and taught postgraduate courses) but it will also be useful for those engaged in research and for chemical and process engineering professionals.

This book deals with models and model-building in classical and quantum physics; it relies on logic and the philosophy of science as well as on modern mathematics. The reader will also find vistas into the history of ideas. The philosophical analysis is based on the separation of syntax and semantics, which is at the root of Kolmogorov's theory of probability; recursive functions and algorithmic complexity are used to discuss entropy and randomness. Basic concepts are discussed, together with concrete physical models for phase transitions, scaling, renormalization semigroups, and the irreversible approach to equilibrium. The book is intended for mathematicians, physicists and philosophers of science, both researchers and graduate students.

This thesis represents the first systematic description of the two-phase flow problem. Two-phase flows of volatile fluids in confined geometries driven by an applied temperature gradient play an important role in a range of applications, including thermal management, such as heat pipes, thermosyphons, capillary pumped loops and other evaporative cooling devices. Previously, this problem has been addressed using a piecemeal approach that relied heavily on correlations and unproven assumptions, and the science and technology behind heat pipes have barely evolved in recent decades. The model introduced in this thesis, however, presents a comprehensive physically based description of both the liquid and the gas phase. The model has been implemented numerically and successfully validated against the available experimental data, and the numerical results are used to determine the key physical processes that control the heat and mass flow and describe the flow stability. One of the key contributions of this thesis work is the description of the role of noncondensables, such as air, on transport. In particular, it is shown that many of the assumptions used by current engineering models of evaporative cooling devices are based on experiments conducted at atmospheric pressures, and these assumptions break down partially or completely when most of the noncondensables are removed, requiring a new modeling approach presented in the thesis. Moreover, Numerical solutions are used to motivate and justify a simplified analytical description of transport in both the liquid and the gas layer, which can be used to describe flow stability and determine the critical Marangoni number and wavelength describing the onset of the convective pattern. As a result, the results presented in the thesis should be of interest both to engineers working in heat transfer and researchers interested in fluid dynamics and pattern formation.

This book presents the ideas and industrial concepts in compact heat exchanger technology that have been developed in the last 10 years or so. Historically, the development and application of compact heat exchangers and their surfaces has taken place in a piecemeal fashion in a number of rather unrelated areas, principally those of the automotive and prime mover, aerospace, cryogenic and refrigeration sectors. Much detailed technology, familiar in one sector, progressed only slowly over the boundary into another sector. This compartmentalisation was a feature both of the user industries themselves, and also of the supplier, or manufacturing industries. These barriers are now breaking down, with valuable cross-fertilisation taking place.
One of the industrial sectors that is waking up to the challenges of compact heat exchangers is that broadly defined as the process sector. If there is a bias in the book, it is towards this sector. Here, in many cases, the technical challenges are severe, since high pressures and temperatures are often involved, and working fluids can be corrosive, reactive or toxic. The opportunities, however, are correspondingly high, since compacts can offer a combination of lower capital or installed cost, lower temperature differences (and hence running costs), and lower inventory. In some cases they give the opportunity for a radical re-think of the process design, by the introduction of process intensification (PI) concepts such as combining process elements in one unit. An example of this is reaction and heat exchange, which offers, among other advantages, significantly lower by-product production.
To stimulate future research, the author includes coverage of hitherto neglected approaches, such as that of the Second Law (of Thermodynamics), pioneered by Bejan and co- workers. The justification for this is that there is increasing interest in life-cycle and sustainable approaches to industrial activity as a whole, often involving exergy (Second Law) analysis. Heat exchangers, being fundamental components of energy and process systems, are both savers and spenders of exergy, according to interpretation.

This book presents a critical and modern analysis of the conceptual foundations of statistical mechanics as laid down in Boltzmann's works. The author emphasises the relation between microscopic reversibility and macroscopic irreversibility. Students will find a clear and detailed explanation of fundamental concepts such as equipartition, entropy and ergodicity. They will learn about Brownian motion, the modern treatment of the thermodynamic limit phase transitions, the microscopic and macroscopic theory of the coexistence of phases, statistical mechanics of stationary states, and fluctuations and dissipation in chaotic motions.

The Second Volume of Equilibrium between Phases of Matter, when compared with the First Volume, by H.A.J. Oonk and M.T. Calvet, published in 2008, amounts to an extension of subjects, and a deepening of understanding. In the first three sections of the text an extension is given of the theory on isobaric binary systems. The fourth section gives an account of the thermodynamic analyses of four isobaric binary key systems, highlighting the power of empirical, (exo)thermodynamic correlations. The fifth section is devoted to the thermodynamic description of ternary systems. The last three sections concentrate on the properties of materials, and the phase behaviour of systems under the conditions of high temperature and high pressure conditions that prevail in the interior of the Earth. A new equation of state is the subject of the sixth section. In the seventh section a move is made to statistical thermodynamics and vibrational models; the description of the systems has changed from mathematical to physical. The last section is on the system MgO SiO2, looked upon from a geophysical point of view.

Throughout the work high priority is given to the thermodynamic assessment of experimental data; numerous end-of-section exercises and their solutions are included. Along with the First Volume, the work is useful for materials scientists and geophysicists as a reference text.

Audience

Volume II is a lecture book for postgraduate students in chemistry, chemical engineering, geology and metallurgy. It is highly useful as a recommended text for teachers and researchers in all fields of materials science.

"

The author investigates athermal fluctuation from the viewpoints of statistical mechanics in this thesis. Stochastic methods are theoretically very powerful in describing fluctuation of thermodynamic quantities in small systems on the level of a single trajectory and have been recently developed on the basis of stochastic thermodynamics. This thesis proposes, for the first time, a systematic framework to describe athermal fluctuation, developing stochastic thermodynamics for non-Gaussian processes, while thermal fluctuations are mainly addressed from the viewpoint of Gaussian stochastic processes in most of the conventional studies. First, the book provides an elementary introduction to the stochastic processes and stochastic thermodynamics. The author derives a Langevin-like equation with non-Gaussian noise as a minimal stochastic model for athermal systems, and its analytical solution by developing systematic expansions is shown as the main result. Furthermore, the a uthor shows a thermodynamic framework for such non-Gaussian fluctuations, and studies some thermodynamics phenomena, i.e. heat conduction and energy pumping, which shows distinct characteristics from conventional thermodynamics. The theory introduced in the book would be a systematic foundation to describe dynamics of athermal fluctuation quantitatively and to analyze their thermodynamic properties on the basis of stochastic methods.