Across the centuries, the development and growth of mathematical concepts have been strongly stimulated by the needs of mechanics. Vector algebra was developed to describe the equilibrium of force systems and originated from Stevin's experiments (1548-1620). Vector analysis was then introduced to study velocity fields and force fields. Classical dynamics required the differential calculus developed by Newton (1687). Nevertheless, the concept of particle acceleration was the starting point for introducing a structured spacetime. Instantaneous velocity involved the set of particle positions in space. Vector algebra theory was not sufficient to compare the different velocities of a particle in the course of time. There was a need to (parallel) transport these velocities at a single point before any vector algebraic operation. The appropriate mathematical structure for this transport was the connection. I The Euclidean connection derived from the metric tensor of the referential body was the only connection used in mechanics for over two centuries. Then, major steps in the evolution of spacetime concepts were made by Einstein in 1905 (special relativity) and 1915 (general relativity) by using Riemannian connection. Slightly later, nonrelativistic spacetime which includes the main features of general relativity I It took about one and a half centuries for connection theory to be accepted as an independent theory in mathematics. Major steps for the connection concept are attributed to a series of findings: Riemann 1854, Christoffel 1869, Ricci 1888, Levi-Civita 1917, WeyJ 1918, Cartan 1923, Eshermann 1950.

Conversion of Coal-Fired Power Plant to Cogeneration and Combined-Cycle presents the methodology, calculation procedures and tools used to support enterprise planning for adapting power stations to cogeneration and combined-cycle forms. The authors analyze the optimum selection of the structure of heat exchangers in a 370 MW power block, the structure of heat recovery steam generators and gas turbines. Conversion of Coal-Fired Power Plant to Cogeneration and Combined-Cycle also addresses the problems of converting existing power plants to dual-fuel gas-steam combined-cycle technologies coupled with parallel systems. Conversion of Coal-Fired Power Plant to Cogeneration and Combined-Cycle is an informative monograph written for researchers, postgraduate students and policy makers in power engineering.

This book is dedicated to the recent developments in RET with the aim to explore polyatomic gas, dense gas and mixture of gases in non-equilibrium. In particular we present the theory of dense gases with 14 fields, which reduces to the Navier-Stokes Fourier classical theory in the parabolic limit. Molecular RET with an arbitrary number of field-variables for polyatomic gases is also discussed and the theory is proved to be perfectly compatible with the kinetic theory in which the distribution function depends on an extra variable that takes into account a molecule's internal degrees of freedom. Recent results on mixtures of gases with multi-temperature are presented together with a natural definition of the average temperature. The qualitative analysis and in particular, the existence of the global smooth solution and the convergence to equilibrium are also studied by taking into account the fact that the differential systems are symmetric hyperbolic. Applications to shock and sound waves are analyzed together with light scattering and heat conduction and the results are compared with experimental data. Rational extended thermodynamics (RET) is a thermodynamic theory that is applicable to non-equilibrium phenomena. It is described by differential hyperbolic systems of balance laws with local constitutive equations. As RET has been strictly related to the kinetic theory through the closure method of moment hierarchy associated to the Boltzmann equation, the applicability range of the theory has been restricted within rarefied monatomic gases. The book represents a valuable resource for applied mathematicians, physicists and engineers, offering powerful models for potential applications like satellites reentering the atmosphere, semiconductors and nano-scale phenomena.

This book presents a solution for direct and inverse heat conduction problems, discussing the theoretical basis for the heat transfer process and presenting selected theoretical and numerical problems in the form of exercises with solutions. The book covers one-, two- and three dimensional problems which are solved by using exact and approximate analytical methods and numerical methods. An accompanying CD-Rom includes computational solutions of the examples and extensive FORTRAN code.

Within the framework of Jaynes' "Predictive Statistical Mechanics," this book presents a detailed derivation of an ensemble formalism for open systems arbitrarily away from equilibrium. This involves a large systematization and extension of the fundamental works and ideas of the outstanding pioneers Gibbs and Boltzmann, and of Bogoliubov, Kirkwood, Green, Mori, Zwanzig, Prigogine and Zubarev, among others.
Chapters 1 to 5 include a description of the philosophy, foundations, and construction (methodology) of the formalism, including the derivation of a nonequilibrium grand-canonical ensemble for far-from-equilibrium systems as well as the derivation of a quantum nonlinear kinetic theory and a response function theory together with a theory of scattering. In chapter 6 applications of the theory are cataloged, making comparisons with experimental data (a basic step for the validation of any theory). Chapter 7 is devoted to the description of irreversible thermodynamics, providing a far-reaching generalization of Informational-Statistical Thermodynamics. The last chapter gives an overall picture of the formalism, and questions and criticisms related to it are discussed.
Audience: This book is directed at an audience of researchers in the field of Statistical Mechanics and Thermodynamics of open nonequilibrium systems. In addition, it is relevant for the study of far-from-equilibrium processes in condensed matter, particularly semiconductor physics, as well as molecular Hydrodynamics, Rheology, many-body systems with complex behavior and areas of engineering, etc. The book can also be used as a complement to advanced graduate courses in Statistical Mechanics.

This book is a modern presentation exploring the equations that govern heat and momentum transfer in laminar and turbulent boundary-layer flows with small temperature differences and buoyant flows. Numerical solutions are used to illustrate physical behavior and to demonstrate calculation methods. A large number of homework problems and several computer programs based on differential and integral methods are included. An accompanying CD-ROM contains computer programs which are of use to engineers and practitioners.

In this book, the authors give an up-to-date account of thermoluminescence (TL) and other thermally stimulated phenomena. Although most recent experimental results of TL in different materials are described in some detail, the main emphasis in the present book is on general processes, and the approach is more theoretical. Thus the details of the possible processes which can take place during the excitation of the sample, and during its heating, are carefully analysed. The methods for analysing TL glow curves are critically discussed, and recommendations as to their application are made. Also discussed is the expected behavior of these phenomena as functions of the experimental parameters, for example, dose of excitation. The consequences of the main applications of TL (for example, radiation dosimetry) are also discussed in detail as are the similarities and dissimilarities of other thermally stimulated phenomena, and the simultaneous measurements of the latter and TL.

The author investigates athermal fluctuation from the viewpoints of statistical mechanics in this thesis. Stochastic methods are theoretically very powerful in describing fluctuation of thermodynamic quantities in small systems on the level of a single trajectory and have been recently developed on the basis of stochastic thermodynamics. This thesis proposes, for the first time, a systematic framework to describe athermal fluctuation, developing stochastic thermodynamics for non-Gaussian processes, while thermal fluctuations are mainly addressed from the viewpoint of Gaussian stochastic processes in most of the conventional studies. First, the book provides an elementary introduction to the stochastic processes and stochastic thermodynamics. The author derives a Langevin-like equation with non-Gaussian noise as a minimal stochastic model for athermal systems, and its analytical solution by developing systematic expansions is shown as the main result. Furthermore, the a uthor shows a thermodynamic framework for such non-Gaussian fluctuations, and studies some thermodynamics phenomena, i.e. heat conduction and energy pumping, which shows distinct characteristics from conventional thermodynamics. The theory introduced in the book would be a systematic foundation to describe dynamics of athermal fluctuation quantitatively and to analyze their thermodynamic properties on the basis of stochastic methods.

This book presents new methods of numerical modelling of tube heat exchangers, which can be used to perform design and operation calculations of exchangers characterized by a complex flow system. It also proposes new heat transfer correlations for laminar, transition and turbulent flows. A large part of the book is devoted to experimental testing of heat exchangers, and methods for assessing the indirect measurement uncertainty are presented. Further, it describes a new method for parallel determination of the Nusselt number correlations on both sides of the tube walls based on the nonlinear least squares method and presents the application of computational fluid dynamic (CFD) modeling to determine the air-side Nusselt number correlations. Lastly, it develops a control system based on the mathematical model of the car radiator and compares this with the digital proportional-integral-derivative (PID) controller. The book is intended for students, academics and researchers, as well as for designers and manufacturers of heat exchangers.

This book is concerned with the prediction of thermodynamic and transport properties of gases and liquids. The prediction of such properties is essential for the solution of many problems encountered in chemical and process engineering as well as in other areas of science and technology. The book aims to present the best of those modern methods which are capable of practical application. It begins with basic scientific principles and formal results which are subsequently developed into practical methods of prediction. Numerous examples, supported by a suite of computer programmes, illustrate applications of the methods. The book is aimed primarily at the student market (for both undergraduate and taught postgraduate courses) but it will also be useful for those engaged in research and for chemical and process engineering professionals.

This book is concerned with the prediction of thermodynamic and transport properties of gases and liquids. The prediction of such properties is essential for the solution of many problems encountered in chemical and process engineering as well as in other areas of science and technology. The book aims to present the best of those modern methods which are capable of practical application. It begins with basic scientific principles and formal results which are subsequently developed into practical methods of prediction. Numerous examples, supported by a suite of computer programmes, illustrate applications of the methods. The book is aimed primarily at the student market (for both undergraduate and taught postgraduate courses) but it will also be useful for those engaged in research and for chemical and process engineering professionals.

This thesis represents the first systematic description of the two-phase flow problem. Two-phase flows of volatile fluids in confined geometries driven by an applied temperature gradient play an important role in a range of applications, including thermal management, such as heat pipes, thermosyphons, capillary pumped loops and other evaporative cooling devices. Previously, this problem has been addressed using a piecemeal approach that relied heavily on correlations and unproven assumptions, and the science and technology behind heat pipes have barely evolved in recent decades. The model introduced in this thesis, however, presents a comprehensive physically based description of both the liquid and the gas phase. The model has been implemented numerically and successfully validated against the available experimental data, and the numerical results are used to determine the key physical processes that control the heat and mass flow and describe the flow stability. One of the key contributions of this thesis work is the description of the role of noncondensables, such as air, on transport. In particular, it is shown that many of the assumptions used by current engineering models of evaporative cooling devices are based on experiments conducted at atmospheric pressures, and these assumptions break down partially or completely when most of the noncondensables are removed, requiring a new modeling approach presented in the thesis. Moreover, Numerical solutions are used to motivate and justify a simplified analytical description of transport in both the liquid and the gas layer, which can be used to describe flow stability and determine the critical Marangoni number and wavelength describing the onset of the convective pattern. As a result, the results presented in the thesis should be of interest both to engineers working in heat transfer and researchers interested in fluid dynamics and pattern formation.

This book deals with models and model-building in classical and quantum physics; it relies on logic and the philosophy of science as well as on modern mathematics. The reader will also find vistas into the history of ideas. The philosophical analysis is based on the separation of syntax and semantics, which is at the root of Kolmogorov's theory of probability; recursive functions and algorithmic complexity are used to discuss entropy and randomness. Basic concepts are discussed, together with concrete physical models for phase transitions, scaling, renormalization semigroups, and the irreversible approach to equilibrium. The book is intended for mathematicians, physicists and philosophers of science, both researchers and graduate students.

The series Advances in Polymer Science presents critical reviews of the present and future trends in polymer and biopolymer science. It covers all areas of research in polymer and biopolymer science including chemistry, physical chemistry, physics, material science.The thematic volumes are addressed to scientists, whether at universities or in industry, who wish to keep abreast of the important advances in the covered topics.Advances in Polymer Science enjoys a longstanding tradition and good reputation in its community. Each volume is dedicated to a current topic, and each review critically surveys one aspect of that topic, to place it within the context of the volume. The volumes typically summarize the significant developments of the last 5 to 10 years and discuss them critically, presenting selected examples, explaining and illustrating the important principles, and bringing together many important references of primary literature. On that basis, future research directions in the area can be discussed. Advances in Polymer Science volumes thus are important references for every polymer scientist, as well as for other scientists interested in polymer science - as an introduction to a neighboring field, or as a compilation of detailed information for the specialist.Review articles for the individual volumes are invited by the volume editors. Single contributions can be specially commissioned.Readership: Polymer scientists, or scientists in related fields interested in polymer and biopolymer science, at universities or in industry, graduate students

This series presents review articles on topics of current interest. Each contribution starts from widely understood principles and brings the reader up to the forefront of the topic being addressed.
The favourable response by the international scientific and engineering community to the 37 volumes published to date is an indication of the success of our authors in fulfilling this purpose. This is recommended reading for all mechanical engineers and researchers.
Provides an overview of review articles on topics of current interest
Bridges the gap between academic researchers and practitioners in industry
A Long running and prestigious series

This book presents the ideas and industrial concepts in compact heat exchanger technology that have been developed in the last 10 years or so. Historically, the development and application of compact heat exchangers and their surfaces has taken place in a piecemeal fashion in a number of rather unrelated areas, principally those of the automotive and prime mover, aerospace, cryogenic and refrigeration sectors. Much detailed technology, familiar in one sector, progressed only slowly over the boundary into another sector. This compartmentalisation was a feature both of the user industries themselves, and also of the supplier, or manufacturing industries. These barriers are now breaking down, with valuable cross-fertilisation taking place.
One of the industrial sectors that is waking up to the challenges of compact heat exchangers is that broadly defined as the process sector. If there is a bias in the book, it is towards this sector. Here, in many cases, the technical challenges are severe, since high pressures and temperatures are often involved, and working fluids can be corrosive, reactive or toxic. The opportunities, however, are correspondingly high, since compacts can offer a combination of lower capital or installed cost, lower temperature differences (and hence running costs), and lower inventory. In some cases they give the opportunity for a radical re-think of the process design, by the introduction of process intensification (PI) concepts such as combining process elements in one unit. An example of this is reaction and heat exchange, which offers, among other advantages, significantly lower by-product production.
To stimulate future research, the author includes coverage of hitherto neglected approaches, such as that of the Second Law (of Thermodynamics), pioneered by Bejan and co- workers. The justification for this is that there is increasing interest in life-cycle and sustainable approaches to industrial activity as a whole, often involving exergy (Second Law) analysis. Heat exchangers, being fundamental components of energy and process systems, are both savers and spenders of exergy, according to interpretation.

This book presents a critical and modern analysis of the conceptual foundations of statistical mechanics as laid down in Boltzmann's works. The author emphasises the relation between microscopic reversibility and macroscopic irreversibility. Students will find a clear and detailed explanation of fundamental concepts such as equipartition, entropy and ergodicity. They will learn about Brownian motion, the modern treatment of the thermodynamic limit phase transitions, the microscopic and macroscopic theory of the coexistence of phases, statistical mechanics of stationary states, and fluctuations and dissipation in chaotic motions.

The Second Volume of Equilibrium between Phases of Matter, when compared with the First Volume, by H.A.J. Oonk and M.T. Calvet, published in 2008, amounts to an extension of subjects, and a deepening of understanding. In the first three sections of the text an extension is given of the theory on isobaric binary systems. The fourth section gives an account of the thermodynamic analyses of four isobaric binary key systems, highlighting the power of empirical, (exo)thermodynamic correlations. The fifth section is devoted to the thermodynamic description of ternary systems. The last three sections concentrate on the properties of materials, and the phase behaviour of systems under the conditions of high temperature and high pressure conditions that prevail in the interior of the Earth. A new equation of state is the subject of the sixth section. In the seventh section a move is made to statistical thermodynamics and vibrational models; the description of the systems has changed from mathematical to physical. The last section is on the system MgO SiO2, looked upon from a geophysical point of view.

Throughout the work high priority is given to the thermodynamic assessment of experimental data; numerous end-of-section exercises and their solutions are included. Along with the First Volume, the work is useful for materials scientists and geophysicists as a reference text.

Audience

Volume II is a lecture book for postgraduate students in chemistry, chemical engineering, geology and metallurgy. It is highly useful as a recommended text for teachers and researchers in all fields of materials science.

"

The book contains, in a concise form, the foundations of both continuum mechanics and modern continuum thermodynamics. It originates from numerous courses delivered by the author during the last 25 years on both subjects at various universities. In contrast to other books on these subjects, it is reasonably self-contained. In addition, examples and remarks scattered throughout the text illustrate the chosen procedures or definitions. Simultaneously, they help to understand the applicability and the limitations of thermodynamical models. The book is an excellent introduction to more advanced monographs on the so-called rational extended thermodynamics.

This book explores water geothermometry, a highly relevant topic in the exploration and exploitation of geothermal energy. Presenting theoretical geothermometers and indicators of CO2 fugacity, it describes a rigorous new approach entirely based on thermodynamics. The book will appeal to geothermal geoscientists, especially those working in research institutions and companies around the globe. It is also of interest to students on advanced courses in applied geochemistry, water-rock interaction and other related areas.

Reinvigorated by advances and insights the quantum theory of irreversible processes has recently attracted growing attention.

This volume introduces the very basic concepts of semigroup dynamics of open quantum systems and reviews a variety of modern applications. Originally published as Volume 286 (1987) in Lecture in Physics, this volume has been newly typeset, revised and corrected and also expanded to include a review on recent developments.

One service mathematics has rendered the Et moi, .... si j'avait su comment en revenir, je human race. It has put common sense back n'y serais point aile.' where it belongs, on the topmost shelf next to Jules Verne the dusty canister labelled 'discarded nonsense'. Eric T. Bell The series is divergent; therefore we may be able to do something with it. O. Heaviside Mathematics is a tool for thought. A highly necessary tool in a world where both feedback and nonlineari ties abound. Similarly, all kinds of parts of mathematics serve as tools for other parts and for other sci ences. Applying a simple rewriting rule to the quote on the right above one finds such statements as: 'One ser vice topology has rendered mathematical physics .. .'; 'One service logic has rendered computer science .. .'; 'One service category theory has rendered mathematics .. .'. All arguably true. And all statements obtainable this way form part of the raison d'etre of this series."

In this monograph, nonequilibrium statistical mechanics is developed by means of ensemble methods on the basis of the Boltzmann equation, the generic Boltzmann equations for classical and quantum dilute gases, and a generalised Boltzmann equation for dense simple fluids. The theories are developed in forms parallel with the equilibrium Gibbs ensemble theory in a way fully consistent with the laws of thermodynamics. The generalised hydrodynamics equations are the integral part of the theory and describe the evolution of macroscopic processes in accordance with the laws of thermodynamics of systems far removed from equilibrium. Audience: This book will be of interest to researchers in the fields of statistical mechanics, condensed matter physics, gas dynamics, fluid dynamics, rheology, irreversible thermodynamics and nonequilibrium phenomena.

Scientists and engineers are nowadays faced with the problem of optimizing complex systems subject to constraints from, ecology, economics, and thermodynamics. It is chiefly to the last of these that this volume is addressed. Intended for physicists, chemists, and engineers, the book uses examples from solar, thermal, mechanical, chemical, and environmental engineering to focus on the use of thermodynamic criteria for optimizing energy conversion and transmission. The early chapters centre on solar energy conversion, the second section discusses the transfer and conversion of chemical energy, while the concluding chapters deal with geometric methods in thermodynamics.