This is the physical chemistry textbook for students with an affinity for computers! It offers basic and advanced knowledge for students in the second year of chemistry masters studies and beyond. In seven chapters, the book presents thermodynamics, chemical kinetics, quantum mechanics and molecular structure (including an introduction to quantum chemical calculations), molecular symmetry and crystals. The application of physical-chemical knowledge and problem solving is demonstrated in a chapter on water, treating both the water molecule as well as water in condensed phases. Instead of a traditional textbook top-down approach, this book presents the subjects on the basis of examples, exploring and running computer programs (Mathematica (R)), discussing the results of molecular orbital calculations (performed using Gaussian) on small molecules and turning to suitable reference works to obtain thermodynamic data. Selected Mathematica (R) codes are explained at the end of each chapter and cross-referenced with the text, enabling students to plot functions, solve equations, fit data, normalize probability functions, manipulate matrices and test physical models. In addition, the book presents clear and step-by-step explanations and provides detailed and complete answers to all exercises. In this way, it creates an active learning environment that can prepare students for pursuing their own research projects further down the road. Students who are not yet familiar with Mathematica (R) or Gaussian will find a valuable introduction to computer-based problem solving in the molecular sciences. Other computer applications can alternatively be used. For every chapter learning goals are clearly listed in the beginning, so that readers can easily spot the highlights, and a glossary in the end of the chapter offers a quick look-up of important terms.

This textbook is an introduction to the Brownian motion of colloids and nano-particles, and the diffusion of molecules. One very appealing aspect of Brownian motion, as this book illustrates, is that the subject connects a broad variety of topics, including thermal physics, hydrodynamics, reaction kinetics, fluctuation phenomena, statistical thermodynamics, osmosis and colloid science. The book is based on a set of lecture notes that the authors used for an undergraduate course at the University of Utrecht, Netherland. It aims to provide more than a simplified qualitative description of the subject, without getting bogged down in difficult mathematics. Each chapter contains exercises, ranging from straightforward ones to more involved problems, addressing instances from (thermal motion in) chemistry, physics and life sciences. Exercises also deal with derivations or calculations that are skipped in the main text. The book offers a treatment of Brownian motion on a level appropriate for bachelor/undergraduate students of physics, chemistry, soft matter and the life sciences. PhD students attending courses and doing research in colloid science or soft matter will also benefit from this book.

Develop a fundamental understanding of heat transfer analysis techniques as applied to earth based spacecraft with this practical guide. Written in a tutorial style, this essential text provides a how-to manual tailored for those who wish to understand and develop spacecraft thermal analyses. Providing an overview of basic heat transfer analysis fundamentals such as thermal circuits, limiting resistance, MLI, environmental thermal sources and sinks, as well as contemporary space based thermal technologies, and the distinctions between design considerations inherent to room temperature and cryogenic temperature applications, this is the perfect tool for graduate students, professionals and academic researchers.

Small systems are a very active area of research and development due to improved instrumentation that allows for spatial resolution in the range of sizes from one to 100 nm. In this size range, many physical and chemical properties change, which opens up new approaches to the study of substances and their practical application. This affects both traditional fields of knowledge and many other new fields including physics, chemistry, biology, etc. This book highlights new developments in statistical thermodynamics that answer the most important questions about the specifics of small systems - when one cannot apply equations or traditional thermodynamic models.

"Both superb and essential... Succi, with clarity and wit, takes us from quarks and Boltzmann to soft matter - precisely the frontier of physics and life." Stuart Kauffman, MacArthur Fellow, Fellow of the Royal Society of Canada, Gold Medal Accademia Lincea We live in a world of utmost complexity, outside and within us. There are thousand of billions of billions of stars out there in the Universe, a hundred times more molecules in a glass of water, and another hundred times more in our body, all working in sync to keep us alive and well. At face value, such numbers spell certain doom for our ability to make any sense at all of the world around and within us. And yet, they don't. Why, and how - this book endeavours to provide an answer to these questions with specific reference to a selected window of the physics-biology interface. The story unfolds over four main Parts. Part I provides an introduction to the main organizational principles which govern the functioning of complex systems in general, such as nonlinearity, nonlocality and ultra-dimensions. Part II deals with thermodynamics, the science of change, starting with its historical foundations laid down in the 19th century, and then moving on to its modern and still open developments in connection with biology and cosmology. Part III deals with the main character of this book, free energy, and the wondrous scenarios opened up by its merger with the modern tools of statistical physics. It also describes the basic facts about soft matter, the state of matter most relevant to biological organisms. Finally, Part IV discusses the connection between time and complexity, and its profound implications on the human condition, i.e. the one-sided nature of time and the awareness of human mortality. It concludes with a few personal considerations about the special place of emotions and humility in science.

An Introduction to Statistical Mechanics and Thermodynamics returns with a second edition which includes new chapters, further explorations, and updated information into the study of statistical mechanics and thermal dynamics. The first part of the book derives the entropy of the classical ideal gas, using only classical statistical mechanics and an analysis of multiple systems first suggested by Boltzmann. The properties of the entropy are then expressed as "postulates" of thermodynamics in the second part of the book. From these postulates, the formal structure of thermodynamics is developed. The third part of the book introduces the canonical and grand canonical ensembles, which are shown to facilitate calculations for many model systems. An explanation of irreversible phenomena that is consistent with time-reversal invariance in a closed system is presented. The fourth part of the book is devoted to quantum statistical mechanics, including black-body radiation, the harmonic solid, Bose-Einstein and Fermi-Dirac statistics, and an introduction to band theory, including metals, insulators, and semiconductors. The final chapter gives a brief introduction to the theory of phase transitions. Throughout the book, there is a strong emphasis on computational methods to make abstract concepts more concrete.

The role of thermodynamics in modern physics is not just to provide an approximate treatment of large thermal systems, but, more importantly, to provide an organising set of ideas. Thermodynamics: A complete undergraduate course presents thermodynamics as a self-contained and elegant set of ideas and methods. It unfolds thermodynamics for undergraduate students of physics, chemistry or engineering, beginning at first year level. The book introduces the necessary mathematical methods, assuming almost no prior knowledge, and explains concepts such as entropy and free energy at length, with many examples. This book aims to convey the style and power of thermodynamic reasoning, along with applications such as Joule-Kelvin expansion, the gas turbine, magnetic cooling, solids at high pressure, chemical equilibrium, radiative heat exchange and global warming, to name a few. It mentions but does not pursue statistical mechanics, in order to keep the logic clear.

Prof. Newman is considered one of the great chemical engineers of his time. His reputation derives from his mastery of all phases of the subject matter, his clarity of thought, and his ability to reduce complex problems to their essential core elements. He has been teaching undergraduate and graduate core subject courses at the University of California, Berkeley (UC Berkeley), USA, since joining the faculty in 1966. His method is to write out, in long form, everything he expects to convey to his class on a subject on any given day. He has maintained and updated his lecture notes from notepad to computer throughout his career. This book is an exact reproduction of those notes. The book presents concepts needed to define single- and multi-component systems, starting with the Gibbs function. It helps readers derive concepts of entropy and temperature and the development of material properties of pure substances. It acquaints them with applications of thermodynamics, such as cycles, open systems, and phase transitions, and eventually leads them to concepts of multiple-component systems, in particular, chemical and phase equilibria. It clearly presents all concepts that are necessary for engineers.

All technologies depend on the availability of suitable materials. The progress of civilisation is often measured by the materials people have used, from the stone age to the silicon age. Engineers exploit the relationships between the structure, properties and manufacturing methods of a material to optimise their design and production for particular applications. Scientists seek to understand and predict those relationships. This short book sets out fundamental concepts that underpin the science of materials and emphasizes their relevance to mainstream chemistry, physics and biology. These include the thermodynamic stability of materials in various environments, quantum behaviour governing all matter, and active matter. Others include defects as the agents of change in crystalline materials, materials at the nanoscale, the emergence of new science at increasing length scales in materials, and man-made materials with properties determined by their structure rather than their chemistry. The book provides a unique insight into the essence of materials science at a level suitable for pre-university students and undergraduates of materials science. It will also be suitable for graduates in other subjects contemplating postgraduate study in materials science. Professional materials scientists will also find it stimulating and occasionally provocative.

Airbreathing Propulsion covers the physics of combustion, fluid and thermo-dynamics, and structural mechanics of airbreathing engines, including piston, turboprop, turbojet, turbofan, and ramjet engines. End-of-chapter exercises allow the reader to practice the fundamental concepts behind airbreathing propulsion, and the included PAGIC computer code will help the reader to examine the relationships between the performance parameters of different engines. Large amounts of data have on many different piston, turbojet, and turboprop engines have been compiled for this book and are included as an appendix. This textbook is ideal for senior undergraduate and graduate students studying aeronautical engineering, aerospace engineering, and mechanical engineering.

While systems at equilibrium are treated in a unified manner through the partition function formalism, the statistical physics of out-of-equilibrium systems covers a large variety of situations that are often without apparent connection. This book proposes a unified perspective on the whole set of systems near equilibrium: it brings out the profound unity of the laws which govern them and gathers together a large number of results usually fragmented in the literature. The reader will find in this book a pedagogical account of the fundamental results: physical origins of irreversibility, fluctuation-dissipation theorem, Boltzmann equation, linear response, Onsager relations, transport phenomena, Langevin and Fokker-Planck equations. The book's comprehensive organization makes it valuable both as a textbook about irreversible phenomena and as a reference book for researchers.

About 120 years ago, James Clerk Maxwell introduced his now legendary hypothetical "demon" as a challenge to the integrity of the second law of thermodynamics. Fascination with the demon persisted throughout the development of statistical and quantum physics, information theory, and computer science--and linkages have been established between Maxwell's demon and each of these disciplines. The demon's seductive quality makes it appealing to physical scientists, engineers, computer scientists, biologists, psychologists, and historians and philosophers of science. Until now its important source material has been scattered throughout diverse journals.

This book brings under one cover twenty-five reprints, including seminal works by Maxwell and William Thomson; historical reviews by Martin Klein, Edward Daub, and Peter Heimann; information theoretic contributions by Leo Szilard, Leon Brillouin, Dennis Gabor, and Jerome Rothstein; and innovations by Rolf Landauer and Charles Bennett illustrating linkages with the limits of computation. An introductory chapter summarizes the demon's life, from Maxwell's illustration of the second law's statistical nature to the most recent "exorcism" of the demon based on a need periodically to erase its memory. An annotated chronological bibliography is included.

Originally published in 1990.

The Princeton Legacy Library uses the latest print-on-demand technology to again make available previously out-of-print books from the distinguished backlist of Princeton University Press. These paperback editions preserve the original texts of these important books while presenting them in durable paperback editions. The goal of the Princeton Legacy Library is to vastly increase access to the rich scholarly heritage found in the thousands of books published by Princeton University Press since its founding in 1905.

Quantum effects may be modelled by means of stochastic perturbation of non-linear partial differential (field) equations. Contributions to this field of research are collected in this volume. Finite dimensional stochastically perturbed Hamiltonian systems and infinite dimensional white noise analysis are treated. The main part concerns problems encountered in deterministic equations. Papers treat the existence of solutions for given initial data, the existence of non-linear bound states or solitary waves including a thorough discussion of various approaches to stability, and global properties (e.g. time decay properties) for non-linear wave equations. This volume provides a good survey of present-day research in non-linear problems of quantum theory for researchers and graduate students.

This book is based on the premise that the entropy concept, a fundamental element of probability theory as logic, governs all of thermal physics, both equilibrium and nonequilibrium. The variational algorithm of J. Willard Gibbs, dating from the 19th Century and extended considerably over the following 100 years, is shown to be the governing feature over the entire range of thermal phenomena, such that only the nature of the macroscopic constraints changes. Beginning with a short history of the development of the entropy concept by Rudolph Clausius and his predecessors, along with the formalization of classical thermodynamics by Gibbs, the first part of the book describes the quest to uncover the meaning of thermodynamic entropy, which leads to its relationship with probability and information as first envisioned by Ludwig Boltzmann. Recognition of entropy first of all as a fundamental element of probability theory in mid-twentieth Century led to deep insights into both statistical mechanics and thermodynamics, the details of which are presented here in several chapters. The later chapters extend these ideas to nonequilibrium statistical mechanics in an unambiguous manner, thereby exhibiting the overall unifying role of the entropy.

Radiation theory and measurements are at the core of the climate change debate. This new book describes in detail the basic physics used in the radiative transfer codes that are a key part of climate prediction models. The basic principles are extended to the atmospheres of the Earth and the other planets, illustrating the greenhouse effect and other radiation-based phenomena at work. Several chapters deal with the techniques and measurements for monitoring the Earth's radiation budget and thus tracking global change and its effects. Remote sensing instruments on satellites and the theory of remote sensing are also covered. The book is the first comprehensive new publication on atmospheric radiation in more than a decade, and the first to link the theoretical and experimental aspects of the subject to the contemporary climate problem.

This introduction to heat transfer offers advanced undergraduate and graduate engineering students a solid foundation in the subjects of conduction, convection, radiation, and phase-change, in addition to the related topic of mass transfer. A staple of engineering courses around the world for more than three decades, it has been revised and updated regularly by the authors, a pair of recognized experts in the field. The text addresses the implications, limitations, and meanings of many aspects of heat transfer, connecting the subject to its real-world applications and developing students' insight into related phenomena.
Three introductory chapters form a minicourse in heat transfer, covering all of the subjects discussed in detail in subsequent chapters. This unique and effective feature introduces heat exchangers early in the development, rather than at the end. The authors also present a novel and simplified method for dimensional analysis, and they capitalize on the similarity of natural convection and film condensation to develop these two topics in a parallel manner. Worked examples and end-of-chapter exercises appear throughout the book, along with well-drawn, illuminating figures.

This book covers all aspects of supercharging internal combustion engines. It details charging systems and components, the theoretical basic relations between engines and charging systems, as well as layout and evaluation criteria for best interaction. Coverage also describes recent experiences in design and development of supercharging systems, improved graphical presentations, and most advanced calculation and simulation tools.

This book collects together the lecture courses and seminars given at the Les Houches Summer School 2008 on Long-Range Interacting Systems. Leading scientists in different fields of mathematics and physics present their views on this fast growing and interdisciplinary field of research, by venturing upon fundamental problems of probability, transport theory, equilibrium and non-equilibrium statistical mechanics, condensed matter physics, astrophysics and cosmology, physics of plasmas, and hydrodynamics. The thermodynamic and dynamical properties of systems with long-range interactions were poorly understood until a few years ago. Substantial progress has been made only recently by realizing that the lack of additivity induced by long-range interactions does not hinder the development of a consistent thermodynamic formalism. This book reviews the state-of-the-art developments in this field and provides an essential background to future studies. All chapters are written from a pedagogical perspective, making the book accessible to masters and PhD students and all researchers wishing to enter this field.

While systems at equilibrium are treated in a unified manner through the partition function formalism, the statistical physics of out-of-equilibrium systems covers a large variety of situations that are often without apparent connection. This book proposes a unified perspective on the whole set of systems near equilibrium: it brings out the profound unity of the laws which govern them and gathers a large number of results usually fragmented in the literature. The reader will find in this book a pedagogical account of the fundamental results: physical origins of irreversibility, fluctuation-dissipation theorem, Boltzmann equation, linear response, Onsager relations, transport phenomena, Langevin and Fokker-Planck equations. The book's comprehensive organisation makes it valuable both as a textbook about irreversible phenomena and as a reference book for researchers.

Modelling of heterogeneous processes, such as electrochemical reactions, extraction or ion-exchange, usually requires solving the transport problem associated to the process. Since the processes at the phase boundary are described by scalar quantities and transport quantities are vectors or tensors, coupling of them can take place only via conservation of mass, charge or momentum. In this book, transport of ionic species is addressed in a versatile manner, emphasizing the mutual coupling of fluxes in particular. Treatment is based on the formalism of irreversible thermodynamics, i.e. on linear (ionic) phenomenological equations, from which the most frequently used Nernst-Planck equation is derived. Limitations and assumptions made are thoroughly discussed.
The Nernst-Planck equation is applied to selected problems at the electrodes and in membranes. Mathematical derivations are presented in detail so that the reader can learn the methodology of solving transport problems. Each chapter contains a large number of exercises, some of them more demanding than others.

This book offers a comprehensive survey of basic elements of nuclear dynamics at low energies and discusses similarities to mesoscopic systems. It addresses systems with finite excitations of their internal degrees of freedom, so that their collective motion exhibits features typical for transport processes in small and isolated systems. The importance of quantum aspects is examined with respect to both the microscopic damping mechanism and the nature of the transport equations. The latter must account for the fact that the collective motion is self-sustained. This implies highly nonlinear couplings between internal and collective degrees of freedom --- different to assumptions made in treatments known in the literature. A critical discussion of the use of thermal concepts is presented. The book can be considered self-contained. It presents existing models, theories and theoretical tools, both from nuclear physics and other fields, which are relevant to an understanding of the observed physical phenomena.

This classic textbook is the definitive introduction to the thermodynamic behavior of materials systems. Written as a basic text for advanced undergraduates and first year graduate students in metallurgy, metallurgical engineering, ceramics, or materials science, it presents the underlying thermodynamic principles of materials and their plethora of applications. The book is also of proven interest to working professionals in need of a reference or refresher course.

Radiation theory and measurements are at the core of the climate change debate. This new book describes in detail the basic physics used in the radiative transfer codes that are a key part of climate prediction models. The basic principles are extended to the atmospheres of the Earth and the other planets, illustrating the greenhouse effect and other radiation-based phenomena at work. Several chapters deal with the techniques and measurements for monitoring the Earth's radiation budget and thus tracking global change and its effects. Remote sensing instruments on satellites and the theory of remote sensing are also covered. The book is the first comprehensive new publication on atmospheric radiation in more than a decade, and the first to link the theoretical and experimental aspects of the subject to the contemporary climate problem.

Der Autor bietet erstmalig eine entmystifizierende Umdeutung der Quantenphanomene fur eine tiefere statistische Fundierung der Schroedinger-Theorie. Diese Umdeutung wirft ein neues Licht auf die Quantenwelt und bietet innovative Wege zur UEberwindung des Welle-Teilchen-Dualismus'. Der Autor erganzt aktuelle Literatur zur Quantenthermodynamik und Dekoharenz, indem er unter anderem die Dekoharenz quantenmechanischer UEberlagerungszustande thermodynamisch begrundet und die Heisenbergsche Unscharferelation auf den zweiten Hauptsatz zuruckfuhrt.

This textbook on atmospheric thermodynamics is for students of meteorology or atmospheric science. It also serves as a reference text for working professionals in meteorology and weather forecasting. It is unique because it provides complete, calculus-based derivations of basic physics from first principles, and connects mathematical relationships to real-world, practical weather forecasting applications. Worked examples and practice problems are included throughout.