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Books > Science & Mathematics > Chemistry > Organic chemistry > Polymer chemistry
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Polymer Networks - Structure and Mechanical Properties (Paperback, 1971)
Loot Price: R1,465
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Polymer Networks - Structure and Mechanical Properties (Paperback, 1971)
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For several decades, polymer science has sought to rationalize the
mechanical and thermodynamic properties of polymer networks largely
within the framework of statistical thermodynamics. Much of this
effort has been directed toward the rubbery rather than the glassy
state. It is generally assumed that networks possess an av erage
composition to which average properties may be assigned; from such
a continuum view, a powerful analysis of such properties as
modulus, swelling, birefringence and thermoelasticity has emerged.
In the years following the rise of polymer characterization (the
late 40's and early 50's), many scientists began to study ap parent
relations between the properties of linear polymer molecules and
the networks obtainable therefrom. This search was also stimu lated
by the wide range of applications of polymer networks in com
mercial elastomers, thermosets and coatings. Frequently, these data
were confidently matched with curves obtained from statisti cally
describable models of networks of ghost chains, uniformly
distributed in space. More recently, it has become apparent that
polymer chains in networks are not as ideal as assumed in the
formulation of statis tical models, and there has been a shift in
emphasis towards the less than ideal, perturbed and possibly
inhomogeneous networks which are more frequently encountered in
practice. The continuum approach, however, had to be developed
before inhomogeneous systems could be described; the present
volume, therefore, contains both views."
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