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Cellulose Solvents: For Analysis, Shaping and Chemical Modification (Hardcover, New)
Loot Price: R6,853
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Cellulose Solvents: For Analysis, Shaping and Chemical Modification (Hardcover, New)
Series: ACS Symposium Series, 1033
Expected to ship within 12 - 17 working days
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The book gives an overview of the current state-of-the-art
concerning the activation and dissolution of cellulose in a broad
variety of solvents. Research on this topic can lead to new
pathways for the utilization of the most abundant terrestrial
biomolecule and may therefore be the basis for new green strategies
towards advanced materials. Leading scientists in the field show
different conceptions for the solubilization of cellulose. The long
history and groundbreaking developments in the field of polymer
chemistry, which are related to this subject, have lead to timely
alternatives to already established methods. In addition to
discussing attempts for the optimization of known dissolving
procedures, this book also details new solvent systems. New
solvents include inorganic and organic salt melts (ionic liquids),
new aqueous media, multi-component organic solvents and the
dissolution under partial derivatization of the polysaccharide. The
opportunities and the limitations of the solvents are demonstrated,
with a particular emphasis on the stability of the solutions and a
possible recycling of the solvent components.
This book illustrates that the new procedures for cellulose
dissolution can lead to a huge number of unconventional
superstructures of regenerated cellulose material, such as fibers
and polymer layers with a thickness in the nanometer range or
aerogels, i.e. regenerates with a highly porous character and a
large surface. Moreover, cellulose blends can be generated via
solutions. The book also contains chapters that show the amazing
potential of solvents for defined modification reactions on the
cellulose backbone. On one hand, it is possible to synthesize known
cellulose derivatives with new substitution patterns both on the
basis of the repeating unit and along the polymer chain. On the
other hand, completely new derivatives are presented which are
hardly accessible via heterogeneous reactions. Consequently, the
book is intended to give a comprehensive overview of procedures for
dissolution of cellulose. It is of interest for scientists new in
the field but is also a timely summary of trends for experts who
are looking for new approaches for problems related to cellulose
shaping or chemical modification.
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