This book looks at new ways of tackling the problem of separating
reaction products from homogeneous catalytic solutions. The new
processes involve low leaching supported catalysts, soluble
supports such as polymers and dendrimers and unusual solvents such
as water, fluorinated organics, ionic liquids and supercritical
fluids. The advantages of the different possibilities are discussed
alongside suggestions for further research that will be required
for commercialisation. Unlike other books, in addition to the
chemistry involved, the book looks at the process design that would
be required to bring the new approaches to fruition. Comparisons
are given with existing processes that have already been
successfully applied and examples are given where these approaches
are not suitable. The book includes:
- New processes for the separation of products from solutions
containing homogeneous catalysts
- Catalysts on insoluble or soluble supports a" fixed bed
catalysts - continuous flow or ultrafiltration
- Biphasic systems: water - organic, fluorous - organic, ionic
liquid a" organic, supercritical fluids (monophasic or biphasic
with water, organic or ionic liquid)
- Comparisons with current processes involving atmospheric or
low temperature distillation
- Consideration of Chemistry and Process Design
- Advantages and disadvantages of each process exposed
- Consideration of what else is need for commercialisation
General
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