This book is a simple and didactic account of the developments and practical applications of predictive, adaptive predictive, and optimized adaptive control from a perspective of stability, including the latest methodology of adaptive predictive expert (ADEX) control. ADEX Optimized Adaptive Control Systems is divided into six parts, with exercises and real-time simulations provided for the reader as appropriate. The text begins with the conceptual and intuitive knowledge of the technology and derives the stability conditions to be verified by the driver block and the adaptive mechanism of the optimized adaptive controller to guaranty the desired control performance. The second and third parts present strategic considerations of predictive control and related adaptive systems necessary for the proper design of driver block and adaptive mechanism and thence their technical realization. The authors then proceed to detail the stability theory that supports predictive, adaptive predictive and optimized adaptive control methodologies. Benchmark applications of these methodologies (distillation column and pulp-factory bleaching plant) are treated next with a focus on practical implementation issues. The final part of the book describes ADEX platforms and illustrates their use in the design and implementation of optimized adaptive control systems to three different challenging-to-control industrial processes: * waste-water treatment;* sulfur recovery; and* temperature control of superheated steam in coal-fired power generation. The presentation is completed by a number of appendices containing technical background associated with the main text including a manual for the ADEX COP platform developed by the first author to exploit the capabilities of adaptive predictive control in real plants. ADEX Optimized Adaptive Control Systems provides practicing process control engineers with a multivariable optimal control solution which is adaptive and resistant to perturbation and the effects of noise. Its pedagogical features also facilitate its use as a teaching tool for formal university and Internet-based open-education-type graduate courses in practical optimal adaptive control and for self-study.

The formation, control, and health effects of DBPs in drinking water are issues of international concern because of the health effects (e.g., bladder cancer and potential adverse reproductive-development impacts) associated with exposure to certain DBPs. As a result, many countries, as well as the World Health Organization, have regulations and/or guidelines on acceptable concentrations of DBPs in water. In recent years, DBP research worldwide has focused on determining the possible adverse health effects of emerging, yet unregulated, DBPs, specifically halogenated (e.g., iodinated) and non-halogenated nitrogenous (e.g., nitrosamines) DBPs. The breadth of DBP research is very broad from source waters (e.g., wastewater, wildfire, seawater intrusion influences) to treatment strategies and technologies, followed by distribution system and point of entry issues (e.g., biofilms, heating, swimming pools), as well as health effects and analytical method developments. Recent research is helping to understand factors controlling formation and to develop a cost-effective control of a wide range of regulated and emerging DBPs. Furthermore, the pace of research on emerging DBP toxicity has increased and generated diverse findings, with comparative toxicity and the molecular mechanisms leading to improved understanding of their toxicity pathways and potential adverse biological effects. This book represents the latest research efforts to understanding these important DBP-related issues. The authors of the chapters in this book are a multidisciplinary group of scientists and engineers, who are conducting studies in many parts of the world. The chapters in this book address both regulated and emerging DBPs and are organized under the sections on DBP toxicology and health effects, modeling of DBP formation, precursors and reactions involving nitrosamines, and formation of halogenated DBPs. This book will be of interest to researchers, drinking water utility scientists and engineers, toxicologists, epidemiologists, and regulators interested in the formation and control of and exposure to DBPs.

This book, based primarily on late breaking work ... provides an interesting snapshot at some of the main lines of current and new research within the field, such as investigation of the novel properties of ionic liquids and their uses in separations (e.g., gases, organics, and metal ions), biochemistry, medicine, and nanochemistry. The chapters also reflect the growing theoretical and computational work within the field leading to new predictive capability.
- From the Preface

New and Future Developments in Catalysis is a package of books that compile the latest ideas concerning alternate and renewable energy sources and the role that catalysis plays in converting new renewable feedstock into biofuels and biochemicals. Both homogeneous and heterogeneous catalysts and catalytic processes will be discussed in a unified and comprehensive approach. There will be extensive cross-referencing within all volumes. This volume presents a complete picture of all carbon dioxide (CO2) sources, outlines the environmental concerns regarding CO2, and critically reviews all current CO2 activation processes. Furthermore, the volume discusses all future developments and gives a critical economic analysis of the various processes.

Offers in-depth coverage of all catalytic topics of current interest and outlines future challenges and research areasA clear and visual description of all parameters and conditions, enabling the reader to draw conclusions for a particular caseOutlines the catalytic processes applicable to energy generation and design of green processes

This book collects papers from meetings of the American Chemical Society held over the past four years, reporting on trends in research for safe, efficient, biologically active agrochemicals. After an overview chapter, a section describes efforts in the discovery of new herbicides. A second section

This book addresses one of the most challenging problems that plagues the environmental field today-subsurface contamination. The past three decades have ushered in various methods for removal of organic and inorganic contaminants from the subsurface to varying degrees of effectiveness. Because of the site-to-site variability in the nature of contamination characteristics, the pattern of waste disposal and accidental releases, the site characteristics and thus contaminant behavior, and hydrologic conditions, predicting the effectiveness of one treatment method over another is a daunting task. Field demonstration of innovative technologies is a key step in their development, however, only after successful scale-up from laboratory testing. This book features chapters written by researchers who have linked laboratory- and field-scales in efforts to find creative, cost-effective methods for prediction of successful remediation of contaminated soil and ground water. State-of-the-art technologies using physicochemical removal methods and biological methods are discussed in the context of not only their effectiveness in remediating organic and inorganic wastes from various subsurface environments but also in terms of useful flask-scale methods for measuring and predicting their field-scale effectiveness. Chapters address sorption and hydrolysis of pesticides by organoclays, use of Fentons agents to destroy chlorinated solvents removed from the subsurface by granulated activated carbon, methanol flushing as a means of removing toxaphene from soils, natural attenuation as a method for effectiveness of remediation metals and biodegrading acid-mine drainage constituents, and biodegradation ofradiologically contaminated soils. Also addressed in this book are current and future methods of assessing microbiological activity potential and diversity and of modeling biodegradation, contaminant flux, and gaseous transport in the subsurface.

The world-wide sales of polysiloxanes or silicones at the beginning of this new millennium is approximately $10 billion per year. Commercial products range from those entirely composed of silicone to products where the silicone is a low level but key component. This symposium covered the recent academic and technological developments behind silicones and silicone-modified materials and the sessions were well attended of wide interest to both the academic and industrial communities. The papers from our two highly successful symposia in this important area were published in the books Silicones and Silicone-Modified Materials, (Eds. S. J. Clarson, J. J. Fitzgerald, M. J. Owen and S. D. Smith), ACS Symposium Series Vol. 729 / Oxford University Press, 2000, ISBN 0-8412-3613-5 and Synthesis and Properties of Silicones and Silicone-Modified Materials, (Eds. S. J. Clarson, J. J. Fitzgerald, M. J. Owen, S. D. Smith and M. E. Van Dyke), ACS Symposium Series Vol 838 / Oxford University Press, 2003, ISBN 0-8412-3804-9

Parameters of fabric texture and their design gives, in a concise and systematic format, a fundamental understanding of fabric structural parameters, their effect on fabric properties and methods of their calculation and design. The book gives an insight into the most popular weaves applied in contemporary weaving practice, the methods of their formation and the kind of fabrics for which they are applied. The book describes conception and methods for fabric design developed by distinguished English, German, Italian, Bulgarian and Russian scientists in accordance with different initial parameters of fabrics. This book has been written for textile designers, technologists, managers, students and researchers.

Polymer Rheology is a fundamental discipline underlying modern polymer processing. The term rheology could be generally defined as the science of deformation and flow for non-traditional materials that display a nonlinear combination of viscous, elastic and plastic effects, such as polymers, food stuffs, lubricating greases etc. The rheology of polymeric liquids is the most complicated part of general rheology. As any scientific discipline it consists of coupled theoretical and experimental parts. The most difficult part for the first studies of polymer rheology is the theory. This textbook attempts to overcome this difficulty and provide the readers with a balanced knowledge of modern types of continuum theories, experiments and some applications.

Corrosion resistance is the property of a material to resist corrosion attack in a particular aggressive environment. Although titanium, tantalum and zirconium are not noble metals, they are the best choice whenever high corrosion resistance is required. The exceptionally good corrosion resistance of these high-performance metals and their alloys results from the formation of a very stable, dense, highly adherent, and self-healing protective oxide film on the metal surface. This naturally occurring oxide layer prevents chemical attack of the underlying metal surface. This behavior also means, however, that high corrosion resistance can be expected only under neutral or oxidizing conditions. Under reducing conditions, a lower resistance must be reckoned with. Only very few inorganic and organic substances are able to attack titanium, tantalum or zirconium at ambient temperature. As the extraordinary corrosion resistance is coupled with an excellent formability and weldability these materials are very valuable for a large number of applications, such as heat exchangers, reaction vessels, funace construction, radiation shielding, implants for medical technology, and capacitor components in electronics.

Derived from the renowned" DECHEMA Corrosion Handbook," this text provides a comprehensive overview of corrosion protection and prevention on the high-performance materials Titanium, Tantalum and Zirconium.

Chemistry is intimately involved in the development of the oldest known civilizations, resulting in a range of chemical technologies that not only continue to be part of modern civilized societies, but are so commonplace that it would be hard to imagine life without them. Such chemical technology has a very long and rich history, in some cases dating back to as early as 20,000 BCE. Chemistry Technology in Antiquity aims to present the discovery, development, and early history of a range of such chemical technologies, with the added goal of including a number of smaller subjects often ignored in the presentation of early chemical technology. While the book does not aim to be a comprehensive coverage of the full range of chemical technologies practiced during antiquity, it provides a feel and appreciation for both the deep history involved with these topics, as well as the complexity of the chemical processes that were being utilized at such a very early time period.

This long-awaited reference source is the first book to focus on this important and hot topic. As such, it provides examples from a wide array of fields where catalyst design has been based on new insights and understanding, presenting such modern and important topics as self-assembly, nature-inspired catalysis, nano-scale architecture of surfaces and theoretical methods. With its inclusion of all the useful and powerful tools for the rational design of catalysts, this is a true "must have" book for every researcher in the field.

A well-rounded and articulate examination of polymer properties at the molecular level, Polymer Chemistry focuses on fundamental principles based on underlying chemical structures, polymer synthesis, characterization, and properties. It emphasizes the logical progression of concepts and provide mathematical tools as needed as well as fully derived problems for advanced calculations. The much-anticipated Third Edition expands and reorganizes material to better develop polymer chemistry concepts and update the remaining chapters. New examples and problems are also featured throughout. This revised edition: Integrates concepts from physics, biology, materials science, chemical engineering, and statistics as needed. Contains mathematical tools and step-by-step derivations for example problems Incorporates new theories and experiments using the latest tools and instrumentation and topics that appear prominently in current polymer science journals. The number of homework problems has been greatly increased, to over 350 in all. The worked examples and figures have been augmented. More examples of relevant synthetic chemistry have been introduced into Chapter 2 ("Step-Growth Polymers"). More details about atom-transfer radical polymerization and reversible addition/fragmentation chain-transfer polymerization have been added to Chapter 4 ("Controlled Polymerization"). Chapter 7 (renamed "Thermodynamics of Polymer Mixtures") now features a separate section on thermodynamics of polymer blends. Chapter 8 (still called "Light Scattering by Polymer Solutions") has been supplemented with an extensive introduction to small-angle neutron scattering. Polymer Chemistry, Third Edition offers a logical presentation of topics that can be scaled to meet the needs of introductory as well as more advanced courses in chemistry, materials science, polymer science, and chemical engineering.

Metal-Catalyzed Asymmetric Hydrogenation, Volume 68 in the Advances in Catalysis series, fills the gap between journal papers and textbooks across diverse areas of catalysis research. For more than 60 years, this series has recorded and presented the latest progress in the field of catalysis, giving the scientific community comprehensive and authoritative reviews. Chapters in this new release include Asymmetric hydrogenation of functionalized olefins, Asymmetric hydrogenation of unfunctionalized olefins or with poorly coordinative groups, Asymmetric hydrogenation of imines, Asymmetric hydrogenation of ketones, Asymmetric hydrogenation in industry, and Computational insights into metal-catalyzed asymmetric hydrogenation. This series is an invaluable and comprehensive resource for chemical engineers and chemists working in the field of catalysis in both academia and industry, with this release focusing on solid acids, surface acidity and heterogeneous acid catalysis.